FR2556738A1 - Agglomerated material with a high degree of nonflammability - Google Patents

Agglomerated material with a high degree of nonflammability Download PDF

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Publication number
FR2556738A1
FR2556738A1 FR8320190A FR8320190A FR2556738A1 FR 2556738 A1 FR2556738 A1 FR 2556738A1 FR 8320190 A FR8320190 A FR 8320190A FR 8320190 A FR8320190 A FR 8320190A FR 2556738 A1 FR2556738 A1 FR 2556738A1
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FR
France
Prior art keywords
drying
layer
binder
sheets
posidonia
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
FR8320190A
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French (fr)
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Individual
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Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
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Priority to FR8320190A priority Critical patent/FR2556738A1/en
Publication of FR2556738A1 publication Critical patent/FR2556738A1/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/02Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising animal or vegetable substances, e.g. cork, bamboo, starch
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27NMANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N3/00Manufacture of substantially flat articles, e.g. boards, from particles or fibres
    • B27N3/02Manufacture of substantially flat articles, e.g. boards, from particles or fibres from particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27NMANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N9/00Arrangements for fireproofing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2607/00Walls, panels

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Wood Science & Technology (AREA)
  • Forests & Forestry (AREA)
  • Ceramic Engineering (AREA)
  • Dry Formation Of Fiberboard And The Like (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)
  • Veneer Processing And Manufacture Of Plywood (AREA)

Abstract

This material consists of fibrous residues of the leaves of posidonia which are agglomerated under pressure with a compatible binder. This material is usable especially for the production of antifire walls.

Description

Matériau aggloméré à haut degré d'ininflammabilité.  Agglomerated material with a high degree of flammability.

La présente invention a pour but de créer un matériau aggloméré à base d'une substance fibreuse d'origine végétale présentant un haut degré d'ininflammabilité, c'est-à-dire résistant notam- ment à la flamme du chalumeau et plus généralement à des tempé- ratures atteignant 1000 degrés centigrades. Ce but paraissait pratiquement impossible à atteindre avec des substances fibreuses d'origine végétale dont une caractéristique est la combustibilité- sans incorporation de quantité économiquement prohibitive de substances ignifuges.The object of the present invention is to create an agglomerated material based on a fibrous substance of vegetable origin having a high degree of non-flammability, that is to say resistant in particular to the flame of the torch and more generally to temperatures reaching 1000 degrees centigrade. This goal seemed practically impossible to achieve with fibrous substances of vegetable origin, one characteristic of which is combustibility - without the incorporation of an economically prohibitive quantity of flame retardants.

Le matériau aggloméré à haut degré d'ininflammabilité conforme à l'invention est caractérisé en ce qu'il est constitué par des restes fibreux des feuilles de posidonies agglomérés sous pression avec un liant compatible.The agglomerated material with a high degree of flammability in accordance with the invention is characterized in that it consists of fibrous remains of the sheets of posidonia agglomerated under pressure with a compatible binder.

Les posidonies sont des herbes marines submergées à feuilles rubanées, fréquentes sous forme d'herbiers importants sur les côtes méditerranéennes. Les feuilles des posidonies constituent la majeure partie du goémon épave méditerranéen et elles peuvent s'accumuler après les tempêtes en quantité considérable sur les plages. L'utilisation de ces amas de feuilles desséchées de posidonies s'est surtout limitée jusqu'ici à l'emploi comme litière ou comme matériau d'emballage.Posidonia are submerged sea grasses with banded leaves, frequent in the form of important herbaria on the Mediterranean coasts. Posidonia leaves make up most of the Mediterranean wrecked seaweed and can accumulate after storms in considerable quantities on beaches. The use of these heaps of dried leaves of Posidonia has so far been mainly limited to use as litter or as packaging material.

A la suite d'observations sur la modification de la salinité de l'eau de mer dans les champs de posidonies, l'inventeur a émis l'hypothèse d'une fixation importante de minéraux en solution par les posidonies et notamment par les feuilles.Following observations on the modification of the salinity of sea water in the fields of Posidonia, the inventor put forward the hypothesis of a significant fixation of minerals in solution by the Posidonia and in particular by the leaves.

Les études effectuées sur les restes fibreux des feuilles constituant les amas de goémon épave ont confirmé cette minéralisation importante qui se traduit par une stabilisation physique de la fibre et l'extinction rapide de toute amorce de combustion, les résidus minéraux de la combustion formant en outre, sous une très faible épaisseur, une carapace incombustible.The studies carried out on the fibrous remains of the leaves constituting the clumps of wrecked seaweed have confirmed this significant mineralization which results in a physical stabilization of the fiber and the rapid extinction of any initiation of combustion, the mineral residues of combustion also forming , under a very small thickness, an incombustible shell.

Lorsque ce matériau est mis sous forme de plaques agglomérées, sous des pressions de l'ordre de 6 à 10kg/cm2, les feuilles lamellaires de posidonies se superposent à plat et sont stabilisées dans cette position par le liant, sans canaux internes notables entre feuilles, lesdits canaux ou interstices étant de préférence remplis par le liant. Une attaque d'une flamme incinère les feuilles formant la couche superficielle avec un reste de cendres salines qui forme une croûte auto-extinctrice.When this material is put in the form of agglomerated plates, under pressures of the order of 6 to 10 kg / cm2, the lamellar sheets of posidonia overlap flat and are stabilized in this position by the binder, without notable internal channels between sheets. , said channels or interstices being preferably filled with the binder. A flame attack incinerates the leaves forming the surface layer with a residue of salt ash which forms a self-extinguishing crust.

La nature du liant ne joue pas un rôle essentiel sur le degré d'ininflammabilité du matériau qui semble résulter de la forte minéralisation des feuilles. Il est donc possible d'utiliser d'une manière générale toutes les colles pour substances végétales compatibles avec une forte teneur en chlorure de sodium.The nature of the binder does not play an essential role on the degree of flammability of the material which seems to result from the strong mineralization of the leaves. It is therefore possible to use in general all the adhesives for vegetable substances compatible with a high content of sodium chloride.

On peut donc utiliser une colle blanche à bois ou des liants phénoliques. Selon un mode de réalisation préférentiel, on utilise une colle vinylique à raison de 0,5kg par décimètre cube d'aggloméré. Le volume du liant doit être de préférence tel qu'il assure un remplissage des interstices subsistant entre les feuilles après pressage. We can therefore use a white wood glue or phenolic binders. According to a preferred embodiment, a vinyl adhesive is used at a rate of 0.5 kg per cubic decimeter of agglomerate. The volume of the binder should preferably be such that it fills the gaps remaining between the sheets after pressing.

Claims (8)

RevendicationsClaims 1. Un matériau aggloméré à haut degré d'ininflammabilité, caractérisé en ce qu'il est constitué par des restes fibreux des feuilles de posidonies agglomérés sous pression avec un liant compatible.1. An agglomerated material with a high degree of non-flammability, characterized in that it consists of fibrous remains of the sheets of posidonia agglomerated under pressure with a compatible binder. 2. Un procédé de fabrication d'unSmatériau aggloméré selon la revendication 1, caractérisé en ce qu'il comporte :2. A process for manufacturing an agglomerated material according to claim 1, characterized in that it comprises: un préséchage du goémon épave sélectionné pour sa haute teneur en feuilles de posidonies; a pre-drying of the wrecked seaweed selected for its high content of Posidonia leaves; un triage pour séparer les minéraux et rhizomes des feuilles; sorting to separate minerals and rhizomes from the leaves; un malaxage des feuilles avec un liant; mixing the sheets with a binder; un pressage du mélange, et pressing the mixture, and un séchage pour assurer la prise et le séchage définitif du panneau. drying to ensure the setting and final drying of the panel. 3. Un procédé selon la revendication 2, caractérisé en ce que le liant est choisi parmi la colle blanche à bois, les liants phénoliques et les colles vinyliques.3. A method according to claim 2, characterized in that the binder is chosen from white wood glue, phenolic binders and vinyl adhesives. 4. Un procédé selon l'une quelconque des revendications 2 et 3, caractérisé en ce que le volume du liant est déterminé pour remplir les interstices subsistant entre les feuilles après pressage.4. A method according to any one of claims 2 and 3, characterized in that the volume of the binder is determined to fill the gaps remaining between the sheets after pressing. 5. Un procédé selon l'une quelconque des revendications 2 à 4, caractérisé en ce que la pression de pressage est comprise environ entre 6 et l0kg/cm2. 5. A method according to any one of claims 2 to 4, characterized in that the pressing pressure is between approximately 6 and 10 kg / cm2. 6. Un procédé selon 11 une quelconque des revendications 2 à 5, caractérisé en ce que le séchage s'effectue en deux stades, un premier stade assurant la prise du panneau, par exemple à 900C pendant six heures, et un second stade de séchage défi nitif, par exemple à 300C pendant douze heures6. A method according to any one of claims 2 to 5, characterized in that the drying is carried out in two stages, a first stage ensuring the setting of the panel, for example at 900C for six hours, and a second drying stage final challenge, for example at 300C for twelve hours 7. Un procédé selon l'une quelconque des-revendications 2 à 6, caractérisé en ce que le mélange de feuilles de posidonies et de liant est aggloméré sous pression sur au moins une face d'un panneau de particules ou d'un panneau en bois ou contreplaqué ou autre plaque support combustible.7. A method according to any one of claims 2 to 6, characterized in that the mixture of posidonia sheets and binder is agglomerated under pressure on at least one face of a particle board or a panel in wood or plywood or other combustible backing plate. 8. Un matériau selon la revendication l, caractérisé en ce qu'une feuille du matériau est incorporée comme couche intermédiaire entre une couche de revêtement décorative et une couche support mécaniquement résistante. 8. A material according to claim 1, characterized in that a sheet of the material is incorporated as an intermediate layer between a decorative coating layer and a mechanically resistant support layer. 50/ un séchage en deux stades, un premier stade assurant la prise du panneau, par exemple à 900C pendant six heures, et un second stade de séchage définitif, par exemple à 309C pendant douze heures. 50 / drying in two stages, a first stage ensuring the setting of the panel, for example at 900C for six hours, and a second final drying stage, for example at 309C for twelve hours. 40/ un pressage du mélange sous une pression d'environ 6 à l0kg/cm; et 40 / pressing the mixture under a pressure of approximately 6 to 10 kg / cm; and 30/ un malaxage des feuilles avec un liant; 30 / mixing the sheets with a binder; 20/ un triage par un procédé quelconque connu par exemple un triage densimétrique dans un courant d'air pour séparer les minéraux, les rhizomes et autres des feuilles; 20 / sorting by any known method, for example densimetric sorting in an air stream to separate the minerals, rhizomes and others from the leaves; 1 / un préséchage du goémon épave sélectionné pour sa haute teneur en feuilles de posidonies; 1 / a pre-drying of the wrecked seaweed selected for its high content of Posidonia leaves; Le procédé de fabrication du matériau conforme à l'invention comporte:The process for manufacturing the material according to the invention comprises: Le produit peut être en plaque agglomérée homogène ayant une épaisseur d'au moins six millimètres pour présenter une résls- tance mécanique suffisante.The product can be in a homogeneous agglomerated plate having a thickness of at least six millimeters to have sufficient mechanical strength. On peut toute foi utiliser également le matériau comme couche ignifuge de protection d'un matériau combustible et, par exemple, agglomérer le produit sous pression sur au moins une face d'un panneau de particules ou d'un panneau en bois ou contreplaqué ou autre plaque support combustible. La couche de feuilles de posidonies agglomérées sous pression peut galbent être incorporée comme couche intermédiaire entre une couche de reve teent décorative et une couche support mécaniguement résistante et rentrer dans la constitution des panneaux en contreplaqué, la combustion de la couche superficielle ne prouvant etre transmise au-dela de la couche conforme à l'invention. It is also possible to use the material as a fire-retardant protective layer for a combustible material and, for example, to agglomerate the product under pressure on at least one face of a particle board or of a wooden or plywood or other panel. combustible support plate. The layer of sheets of posidonia agglomerated under pressure can be incorporated as an intermediate layer between a layer of decorative coating and a mechanically resistant support layer and enter into the constitution of the plywood panels, the combustion of the surface layer not proving to be transmitted to the of the layer according to the invention.
FR8320190A 1983-12-16 1983-12-16 Agglomerated material with a high degree of nonflammability Pending FR2556738A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR8320190A FR2556738A1 (en) 1983-12-16 1983-12-16 Agglomerated material with a high degree of nonflammability

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Application Number Priority Date Filing Date Title
FR8320190A FR2556738A1 (en) 1983-12-16 1983-12-16 Agglomerated material with a high degree of nonflammability

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FR2556738A1 true FR2556738A1 (en) 1985-06-21

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010000983A1 (en) * 2008-07-03 2010-01-07 Energia Sarl Novel plant-based material
WO2018029496A1 (en) * 2016-08-09 2018-02-15 Pavlakis Loannis Environmentally friendly panel from the dead seagrass leaves of posidonia oceanica
GR1009444B (en) * 2017-10-09 2019-01-28 Νικολαος Γεωργιου Αθανασοπουλος Dead posidonia oceanica biomass treatment method - production of composite material the reinforcing means and matrix of which is composed of said dead biomass and thermally-hardened plastics
IT201800011152A1 (en) * 2018-12-17 2020-06-17 Starcell S P A Plant-based composite panel
ES2935306A1 (en) * 2022-03-23 2023-03-03 Lambda Al Cuadrado Sl INSULATING PANEL (Machine-translation by Google Translate, not legally binding)
WO2023180116A1 (en) * 2022-03-23 2023-09-28 Poplac Development S.L. Building material

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2490142A1 (en) * 1980-09-15 1982-03-19 23 Szamu Allami Epitoipari Val PROCESS FOR THE PRODUCTION OF INSULATION BOARDS FROM FIBROUS AGRICULTURAL WASTE AND A BINDER
FR2503026A1 (en) * 1981-04-02 1982-10-08 Chevalier Pierre Moulding material of foamed chopped vegetable fibres - plus polymeric fillers and binders, made from recycled paper or other wastes and shaped using pressure and heat

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2490142A1 (en) * 1980-09-15 1982-03-19 23 Szamu Allami Epitoipari Val PROCESS FOR THE PRODUCTION OF INSULATION BOARDS FROM FIBROUS AGRICULTURAL WASTE AND A BINDER
FR2503026A1 (en) * 1981-04-02 1982-10-08 Chevalier Pierre Moulding material of foamed chopped vegetable fibres - plus polymeric fillers and binders, made from recycled paper or other wastes and shaped using pressure and heat

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
CHEMICAL ABSTRACTS, vol. 86, 1977, page 278, résumé 136386p, COLUMBUS, OHIO (US), W.R. BIRCH: "Some chemical and calorific properties of tropical marine angiosperms compared with those of other plants", & J. Appl. Ecol. 1975, 12(1), 201-12. *

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010000983A1 (en) * 2008-07-03 2010-01-07 Energia Sarl Novel plant-based material
FR2933473A1 (en) * 2008-07-03 2010-01-08 En Sarl NEW VEGETABLE MATERIAL
WO2018029496A1 (en) * 2016-08-09 2018-02-15 Pavlakis Loannis Environmentally friendly panel from the dead seagrass leaves of posidonia oceanica
GR1009444B (en) * 2017-10-09 2019-01-28 Νικολαος Γεωργιου Αθανασοπουλος Dead posidonia oceanica biomass treatment method - production of composite material the reinforcing means and matrix of which is composed of said dead biomass and thermally-hardened plastics
IT201800011152A1 (en) * 2018-12-17 2020-06-17 Starcell S P A Plant-based composite panel
WO2020127048A1 (en) * 2018-12-17 2020-06-25 Starcell S.P.A. Plant-based composite panel
ES2935306A1 (en) * 2022-03-23 2023-03-03 Lambda Al Cuadrado Sl INSULATING PANEL (Machine-translation by Google Translate, not legally binding)
EP4223719A1 (en) * 2022-03-23 2023-08-09 Lambda al Cuadrado S.L. Building material
WO2023180116A1 (en) * 2022-03-23 2023-09-28 Poplac Development S.L. Building material

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