FR2545841A1 - Electrolyte pour le depot de chrome trivalent et son procede d'utilisation - Google Patents
Electrolyte pour le depot de chrome trivalent et son procede d'utilisation Download PDFInfo
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- FR2545841A1 FR2545841A1 FR8407436A FR8407436A FR2545841A1 FR 2545841 A1 FR2545841 A1 FR 2545841A1 FR 8407436 A FR8407436 A FR 8407436A FR 8407436 A FR8407436 A FR 8407436A FR 2545841 A1 FR2545841 A1 FR 2545841A1
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- chromium
- electrolyte
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- 239000003792 electrolyte Substances 0.000 title claims abstract description 149
- 238000000034 method Methods 0.000 title claims abstract description 14
- 230000008021 deposition Effects 0.000 title claims description 11
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 147
- -1 EUROPE Chemical compound 0.000 claims abstract description 116
- 239000000203 mixture Substances 0.000 claims abstract description 64
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 36
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 23
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims abstract description 21
- 150000002500 ions Chemical class 0.000 claims abstract description 16
- 229910052684 Cerium Inorganic materials 0.000 claims abstract description 13
- 229910052727 yttrium Inorganic materials 0.000 claims abstract description 13
- 229910052709 silver Inorganic materials 0.000 claims abstract description 12
- 239000004332 silver Substances 0.000 claims abstract description 12
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052733 gallium Inorganic materials 0.000 claims abstract description 11
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims abstract description 11
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052741 iridium Inorganic materials 0.000 claims abstract description 10
- 229910052762 osmium Inorganic materials 0.000 claims abstract description 10
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 10
- 230000008569 process Effects 0.000 claims abstract description 10
- 239000011669 selenium Substances 0.000 claims abstract description 10
- 229910052692 Dysprosium Inorganic materials 0.000 claims abstract description 9
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052775 Thulium Inorganic materials 0.000 claims abstract description 9
- 229910052770 Uranium Inorganic materials 0.000 claims abstract description 9
- 229910052769 Ytterbium Inorganic materials 0.000 claims abstract description 9
- 229910052785 arsenic Inorganic materials 0.000 claims abstract description 9
- 229910052738 indium Inorganic materials 0.000 claims abstract description 9
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims abstract description 9
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- 229910052763 palladium Inorganic materials 0.000 claims abstract description 9
- 229910052702 rhenium Inorganic materials 0.000 claims abstract description 9
- 239000010948 rhodium Substances 0.000 claims abstract description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims abstract description 8
- 229910052688 Gadolinium Inorganic materials 0.000 claims abstract description 8
- 229910052689 Holmium Inorganic materials 0.000 claims abstract description 8
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- 229910052772 Samarium Inorganic materials 0.000 claims abstract description 8
- 229910052771 Terbium Inorganic materials 0.000 claims abstract description 8
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- 239000010931 gold Substances 0.000 claims abstract description 8
- 229910052737 gold Inorganic materials 0.000 claims abstract description 8
- 229910052735 hafnium Inorganic materials 0.000 claims abstract description 8
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims abstract description 8
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052703 rhodium Inorganic materials 0.000 claims abstract description 8
- 229910052707 ruthenium Inorganic materials 0.000 claims abstract description 8
- 229910052706 scandium Inorganic materials 0.000 claims abstract description 8
- 229910052711 selenium Inorganic materials 0.000 claims abstract description 8
- 239000010936 titanium Substances 0.000 claims abstract description 8
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 8
- 229910052691 Erbium Inorganic materials 0.000 claims abstract description 7
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 claims abstract description 7
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims abstract description 7
- KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 claims abstract description 7
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims abstract description 7
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims abstract description 7
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 claims abstract description 7
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 claims abstract description 7
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims abstract description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 6
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 claims abstract description 6
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 claims abstract description 6
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims abstract description 6
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims abstract description 6
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims abstract description 6
- KJZYNXUDTRRSPN-UHFFFAOYSA-N holmium atom Chemical compound [Ho] KJZYNXUDTRRSPN-UHFFFAOYSA-N 0.000 claims abstract description 6
- OHSVLFRHMCKCQY-UHFFFAOYSA-N lutetium atom Chemical compound [Lu] OHSVLFRHMCKCQY-UHFFFAOYSA-N 0.000 claims abstract description 6
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 claims abstract description 6
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 claims abstract description 6
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 claims abstract description 6
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 claims abstract description 6
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000011260 aqueous acid Substances 0.000 claims abstract description 4
- 239000011651 chromium Substances 0.000 claims description 125
- 229910052804 chromium Inorganic materials 0.000 claims description 123
- 238000000576 coating method Methods 0.000 claims description 56
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 claims description 54
- 239000011248 coating agent Substances 0.000 claims description 51
- 229910001430 chromium ion Inorganic materials 0.000 claims description 45
- 229910021645 metal ion Inorganic materials 0.000 claims description 34
- 239000000654 additive Substances 0.000 claims description 28
- 150000003839 salts Chemical class 0.000 claims description 26
- 230000000996 additive effect Effects 0.000 claims description 23
- 230000003716 rejuvenation Effects 0.000 claims description 14
- 239000000758 substrate Substances 0.000 claims description 13
- 230000009466 transformation Effects 0.000 claims description 11
- 229910052779 Neodymium Inorganic materials 0.000 claims description 10
- 229910052746 lanthanum Inorganic materials 0.000 claims description 9
- 229910052714 tellurium Inorganic materials 0.000 claims description 9
- 239000008139 complexing agent Substances 0.000 claims description 8
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 claims description 7
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 6
- 229910052693 Europium Inorganic materials 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 229910052777 Praseodymium Inorganic materials 0.000 claims description 5
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 claims description 4
- 230000036541 health Effects 0.000 claims description 4
- 230000000750 progressive effect Effects 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 3
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- FRNOGLGSGLTDKL-UHFFFAOYSA-N thulium atom Chemical compound [Tm] FRNOGLGSGLTDKL-UHFFFAOYSA-N 0.000 claims description 3
- 230000002378 acidificating effect Effects 0.000 claims description 2
- 238000009713 electroplating Methods 0.000 claims description 2
- 150000001455 metallic ions Chemical class 0.000 claims description 2
- 238000012545 processing Methods 0.000 claims description 2
- 230000035943 smell Effects 0.000 claims 7
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- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
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- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 4
- GRWVQDDAKZFPFI-UHFFFAOYSA-H chromium(III) sulfate Chemical compound [Cr+3].[Cr+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRWVQDDAKZFPFI-UHFFFAOYSA-H 0.000 description 4
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- 230000001681 protective effect Effects 0.000 description 1
- 231100000916 relative toxicity Toxicity 0.000 description 1
- 150000003282 rhenium compounds Chemical class 0.000 description 1
- YUCDNKHFHNORTO-UHFFFAOYSA-H rhenium hexafluoride Chemical compound F[Re](F)(F)(F)(F)F YUCDNKHFHNORTO-UHFFFAOYSA-H 0.000 description 1
- 150000003284 rhodium compounds Chemical class 0.000 description 1
- MPJHDLITZOASKY-UHFFFAOYSA-H rhodium(3+) trisulfate hydrate Chemical compound O.S(=O)(=O)([O-])[O-].[Rh+3].S(=O)(=O)([O-])[O-].S(=O)(=O)([O-])[O-].[Rh+3] MPJHDLITZOASKY-UHFFFAOYSA-H 0.000 description 1
- PJRGNVSDUQPLCM-UHFFFAOYSA-H rhodium(3+);trisulfite Chemical compound [Rh+3].[Rh+3].[O-]S([O-])=O.[O-]S([O-])=O.[O-]S([O-])=O PJRGNVSDUQPLCM-UHFFFAOYSA-H 0.000 description 1
- 150000003304 ruthenium compounds Chemical class 0.000 description 1
- 229910001927 ruthenium tetroxide Inorganic materials 0.000 description 1
- VDRDGQXTSLSKKY-UHFFFAOYSA-K ruthenium(3+);trihydroxide Chemical compound [OH-].[OH-].[OH-].[Ru+3] VDRDGQXTSLSKKY-UHFFFAOYSA-K 0.000 description 1
- IREVRWRNACELSM-UHFFFAOYSA-J ruthenium(4+);tetrachloride Chemical compound Cl[Ru](Cl)(Cl)Cl IREVRWRNACELSM-UHFFFAOYSA-J 0.000 description 1
- 150000003317 samarium compounds Chemical class 0.000 description 1
- JNFXLBYFDYRNBF-UHFFFAOYSA-K samarium(3+);tribromate Chemical compound [Sm+3].[O-]Br(=O)=O.[O-]Br(=O)=O.[O-]Br(=O)=O JNFXLBYFDYRNBF-UHFFFAOYSA-K 0.000 description 1
- LVSITDBROURTQX-UHFFFAOYSA-H samarium(3+);trisulfate Chemical compound [Sm+3].[Sm+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O LVSITDBROURTQX-UHFFFAOYSA-H 0.000 description 1
- DVMZCYSFPFUKKE-UHFFFAOYSA-K scandium chloride Chemical compound Cl[Sc](Cl)Cl DVMZCYSFPFUKKE-UHFFFAOYSA-K 0.000 description 1
- 150000003326 scandium compounds Chemical class 0.000 description 1
- LUTIEZWAESMFSV-UHFFFAOYSA-H scandium(3+);trisulfate;hexahydrate Chemical compound O.O.O.O.O.O.[Sc+3].[Sc+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O LUTIEZWAESMFSV-UHFFFAOYSA-H 0.000 description 1
- CQLFBEKRDQMJLZ-UHFFFAOYSA-M silver acetate Chemical compound [Ag+].CC([O-])=O CQLFBEKRDQMJLZ-UHFFFAOYSA-M 0.000 description 1
- 229940071536 silver acetate Drugs 0.000 description 1
- SDLBJIZEEMKQKY-UHFFFAOYSA-M silver chlorate Chemical compound [Ag+].[O-]Cl(=O)=O SDLBJIZEEMKQKY-UHFFFAOYSA-M 0.000 description 1
- 229940096017 silver fluoride Drugs 0.000 description 1
- REYHXKZHIMGNSE-UHFFFAOYSA-M silver monofluoride Chemical compound [F-].[Ag+] REYHXKZHIMGNSE-UHFFFAOYSA-M 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 229960001471 sodium selenite Drugs 0.000 description 1
- 239000011781 sodium selenite Substances 0.000 description 1
- 235000015921 sodium selenite Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- VOADVZVYWFSHSM-UHFFFAOYSA-L sodium tellurite Chemical compound [Na+].[Na+].[O-][Te]([O-])=O VOADVZVYWFSHSM-UHFFFAOYSA-L 0.000 description 1
- WZWGGYFEOBVNLA-UHFFFAOYSA-N sodium;dihydrate Chemical compound O.O.[Na] WZWGGYFEOBVNLA-UHFFFAOYSA-N 0.000 description 1
- 210000000952 spleen Anatomy 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- RVUXIPACAZKWHU-UHFFFAOYSA-N sulfuric acid;heptahydrate Chemical compound O.O.O.O.O.O.O.OS(O)(=O)=O RVUXIPACAZKWHU-UHFFFAOYSA-N 0.000 description 1
- YROXCPPXYHBXKS-UHFFFAOYSA-N sulfuric acid;nonahydrate Chemical compound O.O.O.O.O.O.O.O.O.OS(O)(=O)=O YROXCPPXYHBXKS-UHFFFAOYSA-N 0.000 description 1
- RBXMKXVXLWDKDD-UHFFFAOYSA-N sulfuric acid;octahydrate Chemical compound O.O.O.O.O.O.O.O.OS(O)(=O)=O RBXMKXVXLWDKDD-UHFFFAOYSA-N 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 230000002889 sympathetic effect Effects 0.000 description 1
- 235000013616 tea Nutrition 0.000 description 1
- 150000003498 tellurium compounds Chemical class 0.000 description 1
- 150000003502 terbium compounds Chemical class 0.000 description 1
- UFPWIQQSPQSOKM-UHFFFAOYSA-H terbium(3+);trisulfate Chemical compound [Tb+3].[Tb+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O UFPWIQQSPQSOKM-UHFFFAOYSA-H 0.000 description 1
- GFISHBQNVWAVFU-UHFFFAOYSA-K terbium(iii) chloride Chemical compound Cl[Tb](Cl)Cl GFISHBQNVWAVFU-UHFFFAOYSA-K 0.000 description 1
- IYWTUWKWQJIZPO-UHFFFAOYSA-J tetrabromoiridium Chemical compound Br[Ir](Br)(Br)Br IYWTUWKWQJIZPO-UHFFFAOYSA-J 0.000 description 1
- IEXRMSFAVATTJX-UHFFFAOYSA-N tetrachlorogermane Chemical compound Cl[Ge](Cl)(Cl)Cl IEXRMSFAVATTJX-UHFFFAOYSA-N 0.000 description 1
- CALMYRPSSNRCFD-UHFFFAOYSA-J tetrachloroiridium Chemical compound Cl[Ir](Cl)(Cl)Cl CALMYRPSSNRCFD-UHFFFAOYSA-J 0.000 description 1
- UXMRNSHDSCDMLG-UHFFFAOYSA-J tetrachlororhenium Chemical compound Cl[Re](Cl)(Cl)Cl UXMRNSHDSCDMLG-UHFFFAOYSA-J 0.000 description 1
- PPMWWXLUCOODDK-UHFFFAOYSA-N tetrafluorogermane Chemical compound F[Ge](F)(F)F PPMWWXLUCOODDK-UHFFFAOYSA-N 0.000 description 1
- CUDGTZJYMWAJFV-UHFFFAOYSA-N tetraiodogermane Chemical compound I[Ge](I)(I)I CUDGTZJYMWAJFV-UHFFFAOYSA-N 0.000 description 1
- ILOTUXNTERMOJL-UHFFFAOYSA-K thulium(iii) chloride Chemical compound Cl[Tm](Cl)Cl ILOTUXNTERMOJL-UHFFFAOYSA-K 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- UBZYKBZMAMTNKW-UHFFFAOYSA-J titanium tetrabromide Chemical compound Br[Ti](Br)(Br)Br UBZYKBZMAMTNKW-UHFFFAOYSA-J 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- XROWMBWRMNHXMF-UHFFFAOYSA-J titanium tetrafluoride Chemical compound [F-].[F-].[F-].[F-].[Ti+4] XROWMBWRMNHXMF-UHFFFAOYSA-J 0.000 description 1
- NLLZTRMHNHVXJJ-UHFFFAOYSA-J titanium tetraiodide Chemical compound I[Ti](I)(I)I NLLZTRMHNHVXJJ-UHFFFAOYSA-J 0.000 description 1
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 1
- NLPMQGKZYAYAFE-UHFFFAOYSA-K titanium(iii) fluoride Chemical compound F[Ti](F)F NLPMQGKZYAYAFE-UHFFFAOYSA-K 0.000 description 1
- JKNHZOAONLKYQL-UHFFFAOYSA-K tribromoindigane Chemical compound Br[In](Br)Br JKNHZOAONLKYQL-UHFFFAOYSA-K 0.000 description 1
- TYEZTGPOVBHTQW-UHFFFAOYSA-K tribromouranium Chemical compound Br[U](Br)Br TYEZTGPOVBHTQW-UHFFFAOYSA-K 0.000 description 1
- UJBPGOAZQSYXNT-UHFFFAOYSA-K trichloroerbium;hexahydrate Chemical compound O.O.O.O.O.O.[Cl-].[Cl-].[Cl-].[Er+3] UJBPGOAZQSYXNT-UHFFFAOYSA-K 0.000 description 1
- PNYPSKHTTCTAMD-UHFFFAOYSA-K trichlorogadolinium;hexahydrate Chemical compound O.O.O.O.O.O.[Cl-].[Cl-].[Cl-].[Gd+3] PNYPSKHTTCTAMD-UHFFFAOYSA-K 0.000 description 1
- BUQFCXABQYNXLP-UHFFFAOYSA-K trichloroholmium;hexahydrate Chemical compound O.O.O.O.O.O.Cl[Ho](Cl)Cl BUQFCXABQYNXLP-UHFFFAOYSA-K 0.000 description 1
- UAIHPMFLFVHDIN-UHFFFAOYSA-K trichloroosmium Chemical compound Cl[Os](Cl)Cl UAIHPMFLFVHDIN-UHFFFAOYSA-K 0.000 description 1
- UACQLNPCDXDCID-UHFFFAOYSA-K trichloroosmium;trihydrate Chemical compound O.O.O.Cl[Os](Cl)Cl UACQLNPCDXDCID-UHFFFAOYSA-K 0.000 description 1
- CTDPVEAZJVZJKG-UHFFFAOYSA-K trichloroplatinum Chemical compound Cl[Pt](Cl)Cl CTDPVEAZJVZJKG-UHFFFAOYSA-K 0.000 description 1
- TYLYVJBCMQFRCB-UHFFFAOYSA-K trichlororhodium;trihydrate Chemical compound O.O.O.[Cl-].[Cl-].[Cl-].[Rh+3] TYLYVJBCMQFRCB-UHFFFAOYSA-K 0.000 description 1
- ZTWIEIFKPFJRLV-UHFFFAOYSA-K trichlororuthenium;trihydrate Chemical compound O.O.O.Cl[Ru](Cl)Cl ZTWIEIFKPFJRLV-UHFFFAOYSA-K 0.000 description 1
- FKZFOHABAHJDIK-UHFFFAOYSA-K trichloroscandium;hexahydrate Chemical compound O.O.O.O.O.O.[Cl-].[Cl-].[Cl-].[Sc+3] FKZFOHABAHJDIK-UHFFFAOYSA-K 0.000 description 1
- ULJUVCOAZNLCJZ-UHFFFAOYSA-K trichloroterbium;hexahydrate Chemical compound O.O.O.O.O.O.[Cl-].[Cl-].[Cl-].[Tb+3] ULJUVCOAZNLCJZ-UHFFFAOYSA-K 0.000 description 1
- LEYFXTUKPKKWMP-UHFFFAOYSA-K trichloroytterbium;hexahydrate Chemical compound O.O.O.O.O.O.Cl[Yb](Cl)Cl LEYFXTUKPKKWMP-UHFFFAOYSA-K 0.000 description 1
- IINACGXCEZNYTF-UHFFFAOYSA-K trichloroyttrium;hexahydrate Chemical compound O.O.O.O.O.O.[Cl-].[Cl-].[Cl-].[Y+3] IINACGXCEZNYTF-UHFFFAOYSA-K 0.000 description 1
- GCZKMPJFYKFENV-UHFFFAOYSA-K triiodogold Chemical compound I[Au](I)I GCZKMPJFYKFENV-UHFFFAOYSA-K 0.000 description 1
- LOIHSHVELSAXQN-UHFFFAOYSA-K trirhenium nonachloride Chemical compound Cl[Re](Cl)Cl LOIHSHVELSAXQN-UHFFFAOYSA-K 0.000 description 1
- ZXGOACRTCPRVON-UHFFFAOYSA-K trisodium;2-sulfonatobutanedioate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(C([O-])=O)S([O-])(=O)=O ZXGOACRTCPRVON-UHFFFAOYSA-K 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 150000003671 uranium compounds Chemical class 0.000 description 1
- IMNIORQANNGBDO-UHFFFAOYSA-J uranium(4+);tetrabromide Chemical compound Br[U](Br)(Br)Br IMNIORQANNGBDO-UHFFFAOYSA-J 0.000 description 1
- HPICRATUQFHULE-UHFFFAOYSA-J uranium(4+);tetrachloride Chemical compound Cl[U](Cl)(Cl)Cl HPICRATUQFHULE-UHFFFAOYSA-J 0.000 description 1
- PUBUIOWBJCONDZ-UHFFFAOYSA-J uranium(4+);tetraiodide Chemical compound I[U](I)(I)I PUBUIOWBJCONDZ-UHFFFAOYSA-J 0.000 description 1
- SFIHWLKHBCDNCE-UHFFFAOYSA-N uranyl formate Chemical compound OC=O.OC=O.O=[U]=O SFIHWLKHBCDNCE-UHFFFAOYSA-N 0.000 description 1
- 229910000384 uranyl sulfate Inorganic materials 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 150000003747 ytterbium compounds Chemical class 0.000 description 1
- OSCVBYCJUSOYPN-UHFFFAOYSA-K ytterbium(3+);triacetate Chemical compound [Yb+3].CC([O-])=O.CC([O-])=O.CC([O-])=O OSCVBYCJUSOYPN-UHFFFAOYSA-K 0.000 description 1
- KVCOOBXEBNBTGL-UHFFFAOYSA-H ytterbium(3+);trisulfate Chemical compound [Yb+3].[Yb+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O KVCOOBXEBNBTGL-UHFFFAOYSA-H 0.000 description 1
- 229940105965 yttrium bromide Drugs 0.000 description 1
- BUGCDNRPNRJANA-UHFFFAOYSA-K yttrium(3+);tribromate Chemical compound [Y+3].[O-]Br(=O)=O.[O-]Br(=O)=O.[O-]Br(=O)=O BUGCDNRPNRJANA-UHFFFAOYSA-K 0.000 description 1
- LFWQXIMAKJCMJL-UHFFFAOYSA-K yttrium(3+);triiodide Chemical compound I[Y](I)I LFWQXIMAKJCMJL-UHFFFAOYSA-K 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/04—Electroplating: Baths therefor from solutions of chromium
- C25D3/06—Electroplating: Baths therefor from solutions of chromium from solutions of trivalent chromium
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D21/00—Processes for servicing or operating cells for electrolytic coating
- C25D21/16—Regeneration of process solutions
- C25D21/18—Regeneration of process solutions of electrolytes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating And Plating Baths Therefor (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/492,304 US4439285A (en) | 1980-11-10 | 1983-05-12 | Trivalent chromium electrolyte and process employing neodymium reducing agent |
| US06/492,302 US4477315A (en) | 1980-11-10 | 1983-05-12 | Trivalent chromium electrolyte and process employing reducing agents |
| US06/492,303 US4477318A (en) | 1980-11-10 | 1983-05-12 | Trivalent chromium electrolyte and process employing metal ion reducing agents |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| FR2545841A1 true FR2545841A1 (fr) | 1984-11-16 |
Family
ID=27413928
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR8407436A Pending FR2545841A1 (fr) | 1983-05-12 | 1984-05-14 | Electrolyte pour le depot de chrome trivalent et son procede d'utilisation |
Country Status (7)
| Country | Link |
|---|---|
| AU (1) | AU2796484A (enrdf_load_stackoverflow) |
| BR (1) | BR8402245A (enrdf_load_stackoverflow) |
| CA (1) | CA1244376A (enrdf_load_stackoverflow) |
| DE (1) | DE3417416A1 (enrdf_load_stackoverflow) |
| ES (1) | ES532467A0 (enrdf_load_stackoverflow) |
| FR (1) | FR2545841A1 (enrdf_load_stackoverflow) |
| GB (1) | GB2141138B (enrdf_load_stackoverflow) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2669050T3 (es) * | 2006-03-31 | 2018-05-23 | Atotech Deutschland Gmbh | Depósito de cromo cristalino |
| MX2010003543A (es) * | 2007-10-02 | 2010-05-17 | Atotech Deutschland Gmbh | Deposito de aleacion de cromo cristalino. |
| AT510422B1 (de) * | 2010-11-04 | 2012-04-15 | Univ Wien Tech | Verfahren zur abscheidung von hartchrom aus cr(vi)- freien elektrolyten |
| CO7190036A1 (es) * | 2014-02-11 | 2015-02-19 | Garcia Carlos Enrique Muñoz | Proceso de cromado trivalente continuo |
| CN108808030B (zh) * | 2018-07-03 | 2023-08-08 | 重庆大学 | 基于b-z振荡反应的脉冲电池设计 |
| EP4151779A1 (de) * | 2021-09-15 | 2023-03-22 | Trivalent Oberflächentechnik GmbH | Chrom-indium-, chrom-bismut- und chrom-antimon-beschichtung, verfahren zur herstellung und verwendung |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3303114A (en) * | 1964-01-10 | 1967-02-07 | Udylite Corp | Chromium plating |
| DE1496983A1 (de) * | 1965-01-20 | 1969-04-17 | Wilhelm Roggendorf | Selen,Titan- und Zirkonverbindungen enthaltendes Tetrachromatbad |
| DE2049038A1 (de) * | 1969-10-06 | 1971-04-29 | M & T Chemicals Inc | Verfahren zur elektrolytischen Abscheidung eines Chrombelags |
| US3694328A (en) * | 1970-08-24 | 1972-09-26 | Udylite Corp | Composition and process for chromium plating |
| US4054494A (en) * | 1973-12-13 | 1977-10-18 | Albright & Wilson Ltd. | Compositions for use in chromium plating |
| GB2086939A (en) * | 1980-11-10 | 1982-05-19 | Hooker Chemicals Plastics Corp | Trivalent chromium electrolyte and process employing vanadium reducing agent |
-
1984
- 1984-05-09 CA CA000453954A patent/CA1244376A/en not_active Expired
- 1984-05-11 ES ES532467A patent/ES532467A0/es active Granted
- 1984-05-11 DE DE19843417416 patent/DE3417416A1/de active Granted
- 1984-05-11 GB GB08412122A patent/GB2141138B/en not_active Expired
- 1984-05-11 AU AU27964/84A patent/AU2796484A/en not_active Abandoned
- 1984-05-14 FR FR8407436A patent/FR2545841A1/fr active Pending
- 1984-11-12 BR BR8402245A patent/BR8402245A/pt not_active IP Right Cessation
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3303114A (en) * | 1964-01-10 | 1967-02-07 | Udylite Corp | Chromium plating |
| DE1496983A1 (de) * | 1965-01-20 | 1969-04-17 | Wilhelm Roggendorf | Selen,Titan- und Zirkonverbindungen enthaltendes Tetrachromatbad |
| DE2049038A1 (de) * | 1969-10-06 | 1971-04-29 | M & T Chemicals Inc | Verfahren zur elektrolytischen Abscheidung eines Chrombelags |
| US3694328A (en) * | 1970-08-24 | 1972-09-26 | Udylite Corp | Composition and process for chromium plating |
| US4054494A (en) * | 1973-12-13 | 1977-10-18 | Albright & Wilson Ltd. | Compositions for use in chromium plating |
| GB2086939A (en) * | 1980-11-10 | 1982-05-19 | Hooker Chemicals Plastics Corp | Trivalent chromium electrolyte and process employing vanadium reducing agent |
Non-Patent Citations (1)
| Title |
|---|
| GALVANOTECHNIK, vol. 72, no. 11, novembre 1981, page 1237, Saulgau, DE; & SU-A-836 231 * |
Also Published As
| Publication number | Publication date |
|---|---|
| BR8402245A (pt) | 1984-12-18 |
| DE3417416C2 (enrdf_load_stackoverflow) | 1988-07-07 |
| AU2796484A (en) | 1984-11-15 |
| CA1244376A (en) | 1988-11-08 |
| ES8603592A1 (es) | 1985-12-16 |
| GB2141138B (en) | 1986-07-09 |
| GB8412122D0 (en) | 1984-06-20 |
| DE3417416A1 (de) | 1984-11-22 |
| ES532467A0 (es) | 1985-12-16 |
| GB2141138A (en) | 1984-12-12 |
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