FR2523770A1 - Nouveaux electrolytes solides polymeres - Google Patents
Nouveaux electrolytes solides polymeres Download PDFInfo
- Publication number
- FR2523770A1 FR2523770A1 FR8204623A FR8204623A FR2523770A1 FR 2523770 A1 FR2523770 A1 FR 2523770A1 FR 8204623 A FR8204623 A FR 8204623A FR 8204623 A FR8204623 A FR 8204623A FR 2523770 A1 FR2523770 A1 FR 2523770A1
- Authority
- FR
- France
- Prior art keywords
- cation
- solid
- sep
- ionic
- alkali metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003792 electrolyte Substances 0.000 title claims abstract description 18
- 229910052783 alkali metal Inorganic materials 0.000 title claims abstract description 11
- 150000001340 alkali metals Chemical class 0.000 title claims abstract description 11
- 239000007787 solid Substances 0.000 title claims abstract description 10
- 229920001577 copolymer Polymers 0.000 title claims abstract description 9
- 229910000085 borane Inorganic materials 0.000 title 1
- UORVGPXVDQYIDP-UHFFFAOYSA-N trihydridoboron Substances B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 title 1
- 239000000463 material Substances 0.000 claims abstract description 16
- 150000001768 cations Chemical class 0.000 claims abstract description 10
- 239000000178 monomer Substances 0.000 claims abstract description 8
- 125000005842 heteroatom Chemical group 0.000 claims abstract description 7
- 239000004033 plastic Substances 0.000 claims abstract description 6
- 229920003023 plastic Polymers 0.000 claims abstract description 6
- 150000001450 anions Chemical class 0.000 claims abstract description 5
- 229910052751 metal Inorganic materials 0.000 claims abstract description 5
- 239000002184 metal Substances 0.000 claims abstract description 5
- 150000008040 ionic compounds Chemical class 0.000 claims description 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- 239000007784 solid electrolyte Substances 0.000 claims description 7
- 239000006104 solid solution Substances 0.000 claims description 7
- 229910052736 halogen Inorganic materials 0.000 claims description 6
- 150000002367 halogens Chemical class 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims description 5
- 125000004429 atom Chemical group 0.000 claims description 5
- 229930195733 hydrocarbon Natural products 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 239000000460 chlorine Substances 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 239000005518 polymer electrolyte Substances 0.000 claims description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 229910052801 chlorine Inorganic materials 0.000 claims description 3
- 150000002500 ions Chemical class 0.000 claims description 3
- LKMJVFRMDSNFRT-UHFFFAOYSA-N 2-(methoxymethyl)oxirane Chemical compound COCC1CO1 LKMJVFRMDSNFRT-UHFFFAOYSA-N 0.000 claims description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 2
- NFMAZVUSKIJEIH-UHFFFAOYSA-N bis(sulfanylidene)iron Chemical compound S=[Fe]=S NFMAZVUSKIJEIH-UHFFFAOYSA-N 0.000 claims description 2
- 239000000470 constituent Substances 0.000 claims 2
- 229910001413 alkali metal ion Inorganic materials 0.000 claims 1
- 150000002431 hydrogen Chemical class 0.000 claims 1
- 229910000339 iron disulfide Inorganic materials 0.000 claims 1
- CFJRPNFOLVDFMJ-UHFFFAOYSA-N titanium disulfide Chemical compound S=[Ti]=S CFJRPNFOLVDFMJ-UHFFFAOYSA-N 0.000 claims 1
- 239000007772 electrode material Substances 0.000 abstract description 5
- 239000002131 composite material Substances 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract description 2
- 230000035939 shock Effects 0.000 abstract description 2
- 238000005054 agglomeration Methods 0.000 abstract 1
- 230000002776 aggregation Effects 0.000 abstract 1
- 125000000129 anionic group Chemical group 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 1
- 239000011734 sodium Substances 0.000 description 7
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 3
- 229910052744 lithium Inorganic materials 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229910052702 rhenium Inorganic materials 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 229910010903 Li2B12Cl12 Inorganic materials 0.000 description 1
- 229910003092 TiS2 Inorganic materials 0.000 description 1
- JFBZPFYRPYOZCQ-UHFFFAOYSA-N [Li].[Al] Chemical compound [Li].[Al] JFBZPFYRPYOZCQ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 239000000010 aprotic solvent Substances 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 150000004770 chalcogenides Chemical class 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 159000000011 group IA salts Chemical class 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- 239000011244 liquid electrolyte Substances 0.000 description 1
- 229910052960 marcasite Inorganic materials 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- -1 polytetrafluoroethylene Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 1
- 229910052683 pyrite Inorganic materials 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 150000003623 transition metal compounds Chemical class 0.000 description 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
- H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
- H01B1/122—Ionic conductors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
- H01M6/181—Cells with non-aqueous electrolyte with solid electrolyte with polymeric electrolytes
Landscapes
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Primary Cells (AREA)
- Secondary Cells (AREA)
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8204623A FR2523770A1 (fr) | 1982-03-18 | 1982-03-18 | Nouveaux electrolytes solides polymeres |
| PCT/EP1983/000076 WO1983003322A1 (en) | 1982-03-18 | 1983-03-16 | Electrolytes formed of solid solutions of closoboranes in a plastic macromolecular material and electrochemical generators containing such electrolytes |
| JP58501133A JPS59500493A (ja) | 1982-03-18 | 1983-03-16 | 可塑性の巨大分子材料中のクロソボラン（篭型ボラン）の固溶体から構成された電解質及びそのような電解質を含有する電気化学的発電機 |
| AU13772/83A AU1377283A (en) | 1982-03-18 | 1983-03-16 | Electrolytes formed of solid solutions of closoboranes in a02plastic macromolecular material and electrochemical generators containing such electrolytes |
| CA000423808A CA1197085A (fr) | 1982-03-18 | 1983-03-17 | Electrolytes formes de solutions solides de closoboranes dans un materiau macromoleculaire plastique et generateur electrochimique contenant de tels electrolytes |
| MA19962A MA19744A1 (fr) | 1982-03-18 | 1983-03-17 | Electrolytes formes de solutions solides de closoboranes dans un materiau macromoleculaire palstique et generateur electrochimiques contenant de tels electrolytes . |
| OA57940A OA07343A (fr) | 1982-03-18 | 1983-03-18 | Electrolytes formés de solutions solides de closobranes dans un matériau macromoléculaire plastique et générateur électrochimique contenant de tels électrolytes. |
| ZA831892A ZA831892B (en) | 1982-03-18 | 1983-03-18 | Electrolytes formed of solid solutions of closoboranes in a plastic macromolecular material and electrochemical generators containing such electrolytes |
| EP83400564A EP0090710A1 (fr) | 1982-03-18 | 1983-03-18 | Electrolytes formés de solutions solides de closoboranes dans un matériau macromoléculaire plastique et générateur électrochimique contenant de tels électrolytes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8204623A FR2523770A1 (fr) | 1982-03-18 | 1982-03-18 | Nouveaux electrolytes solides polymeres |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2523770A1 true FR2523770A1 (fr) | 1983-09-23 |
| FR2523770B1 FR2523770B1 (en)) | 1984-06-29 |
Family
ID=9272141
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR8204623A Granted FR2523770A1 (fr) | 1982-03-18 | 1982-03-18 | Nouveaux electrolytes solides polymeres |
Country Status (4)
| Country | Link |
|---|---|
| FR (1) | FR2523770A1 (en)) |
| MA (1) | MA19744A1 (en)) |
| OA (1) | OA07343A (en)) |
| ZA (1) | ZA831892B (en)) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1630895A3 (en) * | 2004-08-23 | 2008-02-13 | Air Products And Chemicals, Inc. | High purity lithium polyhalogenated boron cluster salts useful in lithium batteries |
| EP1763099A3 (en) * | 2005-08-23 | 2008-08-27 | Air Products And Chemicals, Inc. | Stable electrolyte counteranions for electrochemical devices |
| US7981388B2 (en) | 2004-08-23 | 2011-07-19 | Air Products And Chemicals, Inc. | Process for the purification of lithium salts |
-
1982
- 1982-03-18 FR FR8204623A patent/FR2523770A1/fr active Granted
-
1983
- 1983-03-17 MA MA19962A patent/MA19744A1/fr unknown
- 1983-03-18 ZA ZA831892A patent/ZA831892B/xx unknown
- 1983-03-18 OA OA57940A patent/OA07343A/xx unknown
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1630895A3 (en) * | 2004-08-23 | 2008-02-13 | Air Products And Chemicals, Inc. | High purity lithium polyhalogenated boron cluster salts useful in lithium batteries |
| US7465517B2 (en) | 2004-08-23 | 2008-12-16 | Air Products And Chemicals, Inc. | High purity lithium polyhalogenated boron cluster salts useful in lithium batteries |
| US7981388B2 (en) | 2004-08-23 | 2011-07-19 | Air Products And Chemicals, Inc. | Process for the purification of lithium salts |
| EP1763099A3 (en) * | 2005-08-23 | 2008-08-27 | Air Products And Chemicals, Inc. | Stable electrolyte counteranions for electrochemical devices |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2523770B1 (en)) | 1984-06-29 |
| MA19744A1 (fr) | 1983-10-01 |
| OA07343A (fr) | 1984-08-31 |
| ZA831892B (en) | 1983-11-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |