FR2520155A1 - Condensateur a electrolyte solide - Google Patents
Condensateur a electrolyte solide Download PDFInfo
- Publication number
- FR2520155A1 FR2520155A1 FR8215722A FR8215722A FR2520155A1 FR 2520155 A1 FR2520155 A1 FR 2520155A1 FR 8215722 A FR8215722 A FR 8215722A FR 8215722 A FR8215722 A FR 8215722A FR 2520155 A1 FR2520155 A1 FR 2520155A1
- Authority
- FR
- France
- Prior art keywords
- salt
- tcnq
- solid electrolyte
- capacitor
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007784 solid electrolyte Substances 0.000 title abstract description 33
- 239000003990 capacitor Substances 0.000 title description 39
- PCCVSPMFGIFTHU-UHFFFAOYSA-N tetracyanoquinodimethane Chemical class N#CC(C#N)=C1C=CC(=C(C#N)C#N)C=C1 PCCVSPMFGIFTHU-UHFFFAOYSA-N 0.000 abstract description 16
- 238000000354 decomposition reaction Methods 0.000 abstract description 7
- 230000008018 melting Effects 0.000 abstract description 7
- 238000002844 melting Methods 0.000 abstract description 7
- 238000010438 heat treatment Methods 0.000 abstract description 6
- 150000003839 salts Chemical class 0.000 description 113
- 229910052751 metal Inorganic materials 0.000 description 36
- 239000002184 metal Substances 0.000 description 36
- AWJUIBRHMBBTKR-UHFFFAOYSA-N isoquinoline Chemical compound C1=NC=CC2=CC=CC=C21 AWJUIBRHMBBTKR-UHFFFAOYSA-N 0.000 description 14
- 238000000034 method Methods 0.000 description 13
- 238000005470 impregnation Methods 0.000 description 12
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 10
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 10
- 229910052782 aluminium Inorganic materials 0.000 description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 9
- 239000007788 liquid Substances 0.000 description 8
- 239000013078 crystal Substances 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- 238000001816 cooling Methods 0.000 description 6
- 239000010410 layer Substances 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 238000007711 solidification Methods 0.000 description 6
- 230000008023 solidification Effects 0.000 description 6
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 5
- 150000002739 metals Chemical class 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 230000004927 fusion Effects 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 3
- 238000006731 degradation reaction Methods 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical compound C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- 239000004332 silver Substances 0.000 description 3
- HSNJJEPLDNIQTM-UHFFFAOYSA-N 1-propan-2-yl-2h-quinoline Chemical compound C1=CC=C2N(C(C)C)CC=CC2=C1 HSNJJEPLDNIQTM-UHFFFAOYSA-N 0.000 description 2
- WGBFAILGFRYCLA-UHFFFAOYSA-N 1-propylisoquinoline Chemical compound C1=CC=C2C(CCC)=NC=CC2=C1 WGBFAILGFRYCLA-UHFFFAOYSA-N 0.000 description 2
- LDKOKMMYTFCGMT-UHFFFAOYSA-N 2-ethyl-1h-isoquinoline Chemical class C1=CC=C2C=CN(CC)CC2=C1 LDKOKMMYTFCGMT-UHFFFAOYSA-N 0.000 description 2
- ACYHWHAJAANUCX-UHFFFAOYSA-N 2-propan-2-yl-1h-isoquinoline Chemical class C1=CC=C2C=CN(C(C)C)CC2=C1 ACYHWHAJAANUCX-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- XWSORTDXXONREX-UHFFFAOYSA-N 1-propyl-2h-quinoline Chemical compound C1=CC=C2N(CCC)CC=CC2=C1 XWSORTDXXONREX-UHFFFAOYSA-N 0.000 description 1
- XNMYNYSCEJBRPZ-UHFFFAOYSA-N 2-[(3-butyl-1-isoquinolinyl)oxy]-N,N-dimethylethanamine Chemical group C1=CC=C2C(OCCN(C)C)=NC(CCCC)=CC2=C1 XNMYNYSCEJBRPZ-UHFFFAOYSA-N 0.000 description 1
- ZOVSKNKQFDVLMJ-UHFFFAOYSA-N 2-butyl-1h-isoquinoline Chemical class C1=CC=C2C=CN(CCCC)CC2=C1 ZOVSKNKQFDVLMJ-UHFFFAOYSA-N 0.000 description 1
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- IHZJPHSLRAKNDC-UHFFFAOYSA-N 2-propyl-1h-isoquinoline Chemical compound C1=CC=C2C=CN(CCC)CC2=C1 IHZJPHSLRAKNDC-UHFFFAOYSA-N 0.000 description 1
- RQMWVVBHJMUJNZ-UHFFFAOYSA-N 4-chloropyridin-2-amine Chemical group NC1=CC(Cl)=CC=N1 RQMWVVBHJMUJNZ-UHFFFAOYSA-N 0.000 description 1
- 241000238876 Acari Species 0.000 description 1
- -1 P-1 salt Chemical class 0.000 description 1
- 241000158147 Sator Species 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229940111121 antirheumatic drug quinolines Drugs 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000010981 drying operation Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- SMWDFEZZVXVKRB-UHFFFAOYSA-O hydron;quinoline Chemical compound [NH+]1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-O 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 150000002537 isoquinolines Chemical group 0.000 description 1
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000002892 organic cations Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229960005038 quinisocaine Drugs 0.000 description 1
- UCFSULAKAYDAAE-UHFFFAOYSA-N quinolin-1-ium;iodide Chemical compound I.N1=CC=CC2=CC=CC=C21 UCFSULAKAYDAAE-UHFFFAOYSA-N 0.000 description 1
- 150000003248 quinolines Chemical group 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 238000007738 vacuum evaporation Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/022—Electrolytes; Absorbents
- H01G9/025—Solid electrolytes
- H01G9/028—Organic semiconducting electrolytes, e.g. TCNQ
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/48—Conductive polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/54—Electrolytes
- H01G11/56—Solid electrolytes, e.g. gels; Additives therein
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Power Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Materials Engineering (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
- Conductive Materials (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP634482A JPS58123715A (ja) | 1982-01-18 | 1982-01-18 | 固体電解コンデンサの製造方法 |
| US06/368,001 US4580855A (en) | 1981-04-17 | 1982-04-13 | Solid electrolyte capacitor |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2520155A1 true FR2520155A1 (fr) | 1983-07-22 |
| FR2520155B1 FR2520155B1 (enrdf_load_stackoverflow) | 1985-03-15 |
Family
ID=26340460
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR8215722A Granted FR2520155A1 (fr) | 1982-01-18 | 1982-09-17 | Condensateur a electrolyte solide |
Country Status (3)
| Country | Link |
|---|---|
| FR (1) | FR2520155A1 (enrdf_load_stackoverflow) |
| GB (2) | GB2113916B (enrdf_load_stackoverflow) |
| NL (1) | NL189936C (enrdf_load_stackoverflow) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3570007D1 (en) * | 1984-02-10 | 1989-06-08 | Nippon Chemicon | An organic semiconductor electrolyte capacitor and process for producing the same |
| US4679124A (en) * | 1985-01-14 | 1987-07-07 | Matsushita Electric Industrial Co., Ltd. | Solid electrolytic capacitors |
| JPH0610199B2 (ja) * | 1985-11-18 | 1994-02-09 | 日本カ−リツト株式会社 | 電荷移動錯体 |
| FR2625602B1 (fr) * | 1987-12-30 | 1994-07-01 | Europ Composants Electron | Procede de fabrication de condensateurs electrolytiques a l'aluminium et condensateur a anode integree obtenu par ce procede |
| FR2625601A1 (fr) * | 1987-12-30 | 1989-07-07 | Europ Composants Electron | Procede de fabrication de condensateurs electrolytiques a l'aluminium a electrolyte solide et condensateur a anode monobloc obtenu par ce procede |
| FR2625832A1 (fr) * | 1988-01-08 | 1989-07-13 | Europ Composants Electron | Procede de fabrication de condensateurs electrolytiques a l'aluminium et condensateur a anode fil obtenu par ce procede |
| FR2627008B1 (fr) * | 1988-02-05 | 1990-06-08 | Europ Composants Electron | Procede d'impregnation de condensateurs electrolytiques par des sels de tetracyanoquinodimethane |
| FR2628257A1 (fr) * | 1988-03-01 | 1989-09-08 | Europ Composants Electron | Ruban metallique destine a la fabrication de condensateurs electrolytiques a electrolyte solide, procede de fabrication et condensateurs obtenus |
| US5031077A (en) * | 1989-01-20 | 1991-07-09 | Sanyo Electric Co., Ltd. | Solid electrolyte capacitor and manufacturing method therefor |
| JPH0750663B2 (ja) * | 1990-06-29 | 1995-05-31 | 三洋電機株式会社 | 有機半導体固体電解コンデンサの製造方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2176820A1 (enrdf_load_stackoverflow) * | 1972-03-17 | 1973-11-02 | Matsushita Electric Ind Co Ltd | |
| DE2513420A1 (de) * | 1974-03-26 | 1975-10-09 | Matsushita Electric Ind Co Ltd | Verfahren zur herstellung von elektrolytkondensatoren mit feststoffelektrolyten |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5610777B2 (enrdf_load_stackoverflow) * | 1972-06-13 | 1981-03-10 | ||
| JPS5042368A (enrdf_load_stackoverflow) * | 1973-08-16 | 1975-04-17 | ||
| JPS5065859A (enrdf_load_stackoverflow) * | 1973-10-12 | 1975-06-03 | ||
| JPS5745050B2 (enrdf_load_stackoverflow) * | 1973-11-07 | 1982-09-25 |
-
1982
- 1982-09-15 GB GB08226300A patent/GB2113916B/en not_active Expired
- 1982-09-17 FR FR8215722A patent/FR2520155A1/fr active Granted
- 1982-09-17 NL NLAANVRAGE8203608,A patent/NL189936C/xx not_active IP Right Cessation
-
1985
- 1985-02-26 GB GB08504864A patent/GB2153148B/en not_active Expired
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2176820A1 (enrdf_load_stackoverflow) * | 1972-03-17 | 1973-11-02 | Matsushita Electric Ind Co Ltd | |
| DE2513420A1 (de) * | 1974-03-26 | 1975-10-09 | Matsushita Electric Ind Co Ltd | Verfahren zur herstellung von elektrolytkondensatoren mit feststoffelektrolyten |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2113916B (en) | 1986-07-09 |
| GB2113916A (en) | 1983-08-10 |
| GB2153148B (en) | 1986-07-09 |
| GB8504864D0 (en) | 1985-03-27 |
| GB2153148A (en) | 1985-08-14 |
| NL189936B (nl) | 1993-04-01 |
| FR2520155B1 (enrdf_load_stackoverflow) | 1985-03-15 |
| NL189936C (nl) | 1993-09-01 |
| NL8203608A (nl) | 1983-08-16 |
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