FR2499146A1 - Recuperation assistee du petrole mettant en oeuvre un petrole brut modifie par oxydation - Google Patents
Recuperation assistee du petrole mettant en oeuvre un petrole brut modifie par oxydation Download PDFInfo
- Publication number
- FR2499146A1 FR2499146A1 FR8102084A FR8102084A FR2499146A1 FR 2499146 A1 FR2499146 A1 FR 2499146A1 FR 8102084 A FR8102084 A FR 8102084A FR 8102084 A FR8102084 A FR 8102084A FR 2499146 A1 FR2499146 A1 FR 2499146A1
- Authority
- FR
- France
- Prior art keywords
- crude
- oxidized
- oil
- crude oil
- phase
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000011084 recovery Methods 0.000 title abstract description 21
- 239000003208 petroleum Substances 0.000 title description 3
- 239000010779 crude oil Substances 0.000 abstract description 37
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 abstract description 34
- 238000000034 method Methods 0.000 abstract description 22
- 238000007254 oxidation reaction Methods 0.000 abstract description 22
- 230000003647 oxidation Effects 0.000 abstract description 21
- 239000012071 phase Substances 0.000 description 37
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 30
- 239000002253 acid Substances 0.000 description 28
- 239000003921 oil Substances 0.000 description 23
- 239000004094 surface-active agent Substances 0.000 description 22
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 21
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 19
- 239000004530 micro-emulsion Substances 0.000 description 18
- 239000000203 mixture Substances 0.000 description 15
- 239000000243 solution Substances 0.000 description 15
- 239000003795 chemical substances by application Substances 0.000 description 14
- 238000012360 testing method Methods 0.000 description 14
- 239000007864 aqueous solution Substances 0.000 description 13
- 238000012546 transfer Methods 0.000 description 12
- 239000011780 sodium chloride Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 239000002736 nonionic surfactant Substances 0.000 description 7
- 229910001925 ruthenium oxide Inorganic materials 0.000 description 7
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 description 7
- -1 fatty acid salts Chemical class 0.000 description 6
- 229930195733 hydrocarbon Natural products 0.000 description 6
- 150000002430 hydrocarbons Chemical class 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 6
- 239000003085 diluting agent Substances 0.000 description 5
- 239000007800 oxidant agent Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 239000005708 Sodium hypochlorite Substances 0.000 description 4
- 239000008346 aqueous phase Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000010908 decantation Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 3
- 238000010992 reflux Methods 0.000 description 3
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical class C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229910019093 NaOCl Inorganic materials 0.000 description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 239000012670 alkaline solution Substances 0.000 description 2
- 229910001424 calcium ion Inorganic materials 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 150000004676 glycans Chemical class 0.000 description 2
- 230000009931 harmful effect Effects 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000012074 organic phase Substances 0.000 description 2
- 229920001282 polysaccharide Polymers 0.000 description 2
- 239000005017 polysaccharide Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 230000000284 resting effect Effects 0.000 description 2
- 229910052707 ruthenium Inorganic materials 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 241000894007 species Species 0.000 description 2
- IGFHQQFPSIBGKE-UHFFFAOYSA-N 4-nonylphenol Polymers CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 241000579895 Chlorostilbon Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 238000010793 Steam injection (oil industry) Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 125000000217 alkyl group Polymers 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000012455 biphasic mixture Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000012043 crude product Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 229910052876 emerald Inorganic materials 0.000 description 1
- 239000010976 emerald Substances 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 229960000789 guanidine hydrochloride Drugs 0.000 description 1
- PJJJBBJSCAKJQF-UHFFFAOYSA-N guanidinium chloride Chemical compound [Cl-].NC(N)=[NH2+] PJJJBBJSCAKJQF-UHFFFAOYSA-N 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Polymers CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000010587 phase diagram Methods 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 238000010408 sweeping Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/58—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids
- C09K8/584—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids characterised by the use of specific surfactants
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S507/00—Earth boring, well treating, and oil field chemistry
- Y10S507/935—Enhanced oil recovery
- Y10S507/936—Flooding the formation
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8102084A FR2499146A1 (fr) | 1981-02-02 | 1981-02-02 | Recuperation assistee du petrole mettant en oeuvre un petrole brut modifie par oxydation |
| US06/345,104 US4473118A (en) | 1981-02-02 | 1982-02-02 | Enhanced oil recovery using oxidized crude oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8102084A FR2499146A1 (fr) | 1981-02-02 | 1981-02-02 | Recuperation assistee du petrole mettant en oeuvre un petrole brut modifie par oxydation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2499146A1 true FR2499146A1 (fr) | 1982-08-06 |
| FR2499146B1 FR2499146B1 (enExample) | 1984-05-04 |
Family
ID=9254802
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR8102084A Granted FR2499146A1 (fr) | 1981-02-02 | 1981-02-02 | Recuperation assistee du petrole mettant en oeuvre un petrole brut modifie par oxydation |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US4473118A (enExample) |
| FR (1) | FR2499146A1 (enExample) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4508171A (en) * | 1984-04-13 | 1985-04-02 | Shaw James E | Oil recovery method |
| US4553593A (en) * | 1984-06-07 | 1985-11-19 | Phillips Petroleum Company | Oil recovery method |
| US20090078414A1 (en) * | 2007-09-25 | 2009-03-26 | Schlumberger Technology Corp. | Chemically enhanced thermal recovery of heavy oil |
| US20140174737A1 (en) * | 2012-12-21 | 2014-06-26 | Halliburton Energy Services, Inc. | Wellbore Servicing Materials and Methods of Making and Using Same |
| WO2020184040A1 (ja) * | 2019-03-12 | 2020-09-17 | 国立大学法人東京農工大学 | 石油の生産方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3817329A (en) * | 1972-07-27 | 1974-06-18 | Witco Chemical Corp | Process for petroleum recovery utilizing miscible fluids |
| US3833061A (en) * | 1972-12-27 | 1974-09-03 | Phillips Petroleum Co | Method for selectively reducing brine permeability in a subterranean oil-wet formation |
| US3929190A (en) * | 1974-11-05 | 1975-12-30 | Mobil Oil Corp | Secondary oil recovery by waterflooding with extracted petroleum acids |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3195629A (en) * | 1962-12-31 | 1965-07-20 | Pan American Petroleum Corp | Use of partially oxidized oil in a waterflooding process |
| US3482636A (en) * | 1967-04-06 | 1969-12-09 | Dow Chemical Co | Method of lessening the inhibitory effects to fluid flow due to the presence of solid organic substances in a subterranean formation |
| US3556221A (en) * | 1969-01-06 | 1971-01-19 | Marathon Oil Co | Well stimulation process |
| US3709297A (en) * | 1970-12-28 | 1973-01-09 | Texaco Inc | Petroleum recovery process |
| US3757861A (en) * | 1971-04-01 | 1973-09-11 | Dow Chemical Co | Oil recovery employing peroxides and alkalis |
| US3710861A (en) * | 1971-05-26 | 1973-01-16 | Marathon Oil Co | Miscible-type flooding of oil reservoirs having water saturated bottom zones |
| US3731741A (en) * | 1971-07-06 | 1973-05-08 | Texaco Inc | Secondary oil recovery process using oxyalkylated additives |
| US4059154A (en) * | 1973-12-03 | 1977-11-22 | Texaco Inc. | Micellar dispersions with tolerance for extreme water hardness for use in petroleum recovery |
| US3927716A (en) * | 1974-09-25 | 1975-12-23 | Mobil Oil Corp | Alkaline waterflooding process |
| US3994344A (en) * | 1974-12-26 | 1976-11-30 | Getty Oil Company | Method for recovery of acidic crude oils |
| US4008769A (en) * | 1975-04-30 | 1977-02-22 | Mobil Oil Corporation | Oil recovery by microemulsion injection |
-
1981
- 1981-02-02 FR FR8102084A patent/FR2499146A1/fr active Granted
-
1982
- 1982-02-02 US US06/345,104 patent/US4473118A/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3817329A (en) * | 1972-07-27 | 1974-06-18 | Witco Chemical Corp | Process for petroleum recovery utilizing miscible fluids |
| US3833061A (en) * | 1972-12-27 | 1974-09-03 | Phillips Petroleum Co | Method for selectively reducing brine permeability in a subterranean oil-wet formation |
| US3929190A (en) * | 1974-11-05 | 1975-12-30 | Mobil Oil Corp | Secondary oil recovery by waterflooding with extracted petroleum acids |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2499146B1 (enExample) | 1984-05-04 |
| US4473118A (en) | 1984-09-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |