FR2487379A1 - Procede pour la separation d'ions plutonium a partir de solutions aqueuses d'acide sulfurique - Google Patents

Procede pour la separation d'ions plutonium a partir de solutions aqueuses d'acide sulfurique Download PDF

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Publication number
FR2487379A1
FR2487379A1 FR8110653A FR8110653A FR2487379A1 FR 2487379 A1 FR2487379 A1 FR 2487379A1 FR 8110653 A FR8110653 A FR 8110653A FR 8110653 A FR8110653 A FR 8110653A FR 2487379 A1 FR2487379 A1 FR 2487379A1
Authority
FR
France
Prior art keywords
extraction
aqueous
plutonium
organic phase
solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR8110653A
Other languages
English (en)
French (fr)
Other versions
FR2487379B1 (OSRAM
Inventor
Karl Heinrich Lieser
Bernd Stojanik
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Karlsruher Institut fuer Technologie KIT
Original Assignee
Kernforschungszentrum Karlsruhe GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kernforschungszentrum Karlsruhe GmbH filed Critical Kernforschungszentrum Karlsruhe GmbH
Publication of FR2487379A1 publication Critical patent/FR2487379A1/fr
Application granted granted Critical
Publication of FR2487379B1 publication Critical patent/FR2487379B1/fr
Granted legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C22B3/40—Mixtures
    • C22B3/409—Mixtures at least one compound being an organo-metallic compound
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G56/00—Compounds of transuranic elements
    • C01G56/001—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G56/00—Compounds of transuranic elements
    • C01G56/003—Compounds containing transuranic elements, with or without oxygen or hydrogen, and containing two or more other elements
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C22B3/32—Carboxylic acids
    • C22B3/322—Oxalic acids
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C22B3/38—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
    • C22B3/384—Pentavalent phosphorus oxyacids, esters thereof
    • C22B3/3846—Phosphoric acid, e.g. (O)P(OH)3
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C22B3/40—Mixtures
    • C22B3/408—Mixtures using a mixture of phosphorus-based acid derivatives of different types
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B60/00—Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
    • C22B60/02—Obtaining thorium, uranium, or other actinides
    • C22B60/04—Obtaining plutonium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Geology (AREA)
  • Manufacturing & Machinery (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Metallurgy (AREA)
  • Environmental & Geological Engineering (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Inorganic Chemistry (AREA)
  • Extraction Or Liquid Replacement (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
FR8110653A 1980-07-24 1981-05-27 Procede pour la separation d'ions plutonium a partir de solutions aqueuses d'acide sulfurique Granted FR2487379A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE3028024A DE3028024C2 (de) 1980-07-24 1980-07-24 Verfahren zum Abtrennen von Plutoniumionen aus wäßrigen, schwefelsauren Lösungen

Publications (2)

Publication Number Publication Date
FR2487379A1 true FR2487379A1 (fr) 1982-01-29
FR2487379B1 FR2487379B1 (OSRAM) 1983-07-29

Family

ID=6107985

Family Applications (1)

Application Number Title Priority Date Filing Date
FR8110653A Granted FR2487379A1 (fr) 1980-07-24 1981-05-27 Procede pour la separation d'ions plutonium a partir de solutions aqueuses d'acide sulfurique

Country Status (5)

Country Link
US (1) US4442071A (OSRAM)
JP (1) JPS6035291B2 (OSRAM)
DE (1) DE3028024C2 (OSRAM)
FR (1) FR2487379A1 (OSRAM)
GB (1) GB2084123B (OSRAM)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0251399A1 (fr) * 1986-06-23 1988-01-07 "Centre d'Etude de l'Energie Nucléaire", "C.E.N." Procédé de séparation ou de récupération de plutonium et plutonium ainsi obtenu

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3243841C2 (de) * 1982-11-26 1986-02-06 Kernforschungszentrum Karlsruhe Gmbh, 7500 Karlsruhe Verfahren zur Denitrierung von salpetersauren, Aktiniden enthaltenden Abfall-Lösungen unter gleichzeitiger Abtrennung der Aktiniden
DE3418986A1 (de) * 1984-05-22 1985-11-28 Kernforschungszentrum Karlsruhe Gmbh, 7500 Karlsruhe Verfahren zur ueberfuehrung von im festen rueckstand eines sulfataufarbeitungsverfahrens fuer organische, aktinidenhaltige, radioaktive festabfaelle befindliche aktinidenionen in einen verwertbaren zustand
JPS61170528A (ja) * 1985-01-22 1986-08-01 Sutaaroi Sangyo Kk コバルトの剥離回収方法
DE3843887C1 (OSRAM) * 1988-12-24 1990-06-21 Kernforschungszentrum Karlsruhe Gmbh, 7500 Karlsruhe, De
GB8904433D0 (en) * 1989-02-27 1989-04-12 British Nuclear Fuels Plc Removal of thorium from raffinate
US5183541A (en) * 1990-04-09 1993-02-02 Westinghouse Electric Corp. Decontamination of radioactive metals
DE4110128A1 (de) * 1990-04-09 1991-11-07 Westinghouse Electric Corp Dekontamination von radioaktiv verseuchten metallen
US5188736A (en) * 1991-08-27 1993-02-23 Institute Of Nuclear Energy Research Process for the separation and recovery of extractant from spent solvent
US5217585A (en) * 1991-12-20 1993-06-08 Westinghouse Electric Corp. Transition metal decontamination process
CN1116005A (zh) * 1993-10-28 1996-01-31 摩托罗拉公司 被改造为特定设备外部控制的装置以及所用到的方法
CN112680609B (zh) * 2020-12-14 2022-06-03 中国人民解放军63653部队 一种钚回收离子液体萃取剂及其从含钚废液中萃取分离钚的方法
CN114478851B (zh) * 2022-01-26 2022-09-09 核工业北京化工冶金研究院 交联聚苯乙烯树脂及其制备方法和用途

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1237082B (de) * 1961-10-11 1967-03-23 Europ Pour Le Traitement Chimi Verfahren zur Abtrennung, Reinigung und Dekontaminierung von Verbindungen der Metalle Plutonium, Uran und Thorium
DE1583881B1 (de) * 1967-12-29 1970-08-27 Kernforschung Gmbh Ges Fuer Verfahren zur Gewinnung von Neptunium und gegebenenfalls Plutonium neben Uran aus waessrigen Loesungen
BE768709A (fr) * 1970-06-23 1971-11-03 Commissariat Energie Atomique Procede de separation du plutonium a partir d'une phase organique

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2924506A (en) * 1947-05-08 1960-02-09 Herbert H Anderson Solvent extraction process for plutonium
US2859094A (en) * 1957-02-07 1958-11-04 John M Schmitt Uranium extraction process using synergistic reagents
FR1387127A (fr) * 1963-11-26 1965-01-29 Commissariat Energie Atomique Procédé de séparation de l'uranium et du plutonium
US3288568A (en) * 1960-11-18 1966-11-29 Tokyo Shibaura Electric Co Direct dissolution of water-insoluble uranium compounds by contact with neutral organic solvents pretreated with nitric acid
FR90703E (fr) * 1964-06-19 1968-02-02 Commissariat Energie Atomique Procédé de purification et de concentration simultanées du plutonium et plutonium obtenu selon ce procédé
CA1139956A (en) * 1978-10-10 1983-01-25 Mark A. Rose Process for extracting uranium from crude phosphoric acids

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1237082B (de) * 1961-10-11 1967-03-23 Europ Pour Le Traitement Chimi Verfahren zur Abtrennung, Reinigung und Dekontaminierung von Verbindungen der Metalle Plutonium, Uran und Thorium
DE1583881B1 (de) * 1967-12-29 1970-08-27 Kernforschung Gmbh Ges Fuer Verfahren zur Gewinnung von Neptunium und gegebenenfalls Plutonium neben Uran aus waessrigen Loesungen
BE768709A (fr) * 1970-06-23 1971-11-03 Commissariat Energie Atomique Procede de separation du plutonium a partir d'une phase organique
FR2092832A1 (en) * 1970-06-23 1972-01-28 Commissariat Energie Atomique Plutonium recovery - from organic phase by pptn using a soluble - pptg agent

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
EXBK/79 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0251399A1 (fr) * 1986-06-23 1988-01-07 "Centre d'Etude de l'Energie Nucléaire", "C.E.N." Procédé de séparation ou de récupération de plutonium et plutonium ainsi obtenu

Also Published As

Publication number Publication date
FR2487379B1 (OSRAM) 1983-07-29
DE3028024A1 (de) 1982-05-27
JPS5751132A (en) 1982-03-25
GB2084123A (en) 1982-04-07
US4442071A (en) 1984-04-10
DE3028024C2 (de) 1985-07-04
JPS6035291B2 (ja) 1985-08-14
GB2084123B (en) 1984-06-20

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