FR2461947A1 - Element de detection de la concentration en oxygene et son procede de fabrication - Google Patents
Element de detection de la concentration en oxygene et son procede de fabrication Download PDFInfo
- Publication number
- FR2461947A1 FR2461947A1 FR8015650A FR8015650A FR2461947A1 FR 2461947 A1 FR2461947 A1 FR 2461947A1 FR 8015650 A FR8015650 A FR 8015650A FR 8015650 A FR8015650 A FR 8015650A FR 2461947 A1 FR2461947 A1 FR 2461947A1
- Authority
- FR
- France
- Prior art keywords
- solid electrolyte
- oxide
- substrate
- zirconium oxide
- oxygen concentration
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000001301 oxygen Substances 0.000 title claims abstract description 33
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 33
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 29
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 8
- 238000000034 method Methods 0.000 title claims description 7
- 238000001514 detection method Methods 0.000 title abstract description 10
- 239000007784 solid electrolyte Substances 0.000 claims abstract description 78
- 239000000758 substrate Substances 0.000 claims abstract description 50
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims abstract description 30
- 229910001928 zirconium oxide Inorganic materials 0.000 claims abstract description 30
- VQCBHWLJZDBHOS-UHFFFAOYSA-N erbium(iii) oxide Chemical compound O=[Er]O[Er]=O VQCBHWLJZDBHOS-UHFFFAOYSA-N 0.000 claims abstract description 22
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 claims abstract description 16
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000000843 powder Substances 0.000 claims description 10
- 238000010411 cooking Methods 0.000 claims description 8
- 239000003792 electrolyte Substances 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 5
- -1 oxygen ions Chemical class 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- 239000001856 Ethyl cellulose Substances 0.000 claims description 2
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 claims description 2
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 claims description 2
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 claims description 2
- 229920001249 ethyl cellulose Polymers 0.000 claims description 2
- 235000019325 ethyl cellulose Nutrition 0.000 claims description 2
- 229940116411 terpineol Drugs 0.000 claims description 2
- 229960004667 ethyl cellulose Drugs 0.000 claims 1
- 238000002485 combustion reaction Methods 0.000 abstract description 4
- 239000007789 gas Substances 0.000 abstract description 4
- 230000027734 detection of oxygen Effects 0.000 abstract 1
- 150000002500 ions Chemical class 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 description 15
- 230000035939 shock Effects 0.000 description 10
- 238000002474 experimental method Methods 0.000 description 9
- 238000012360 testing method Methods 0.000 description 9
- 239000000654 additive Substances 0.000 description 7
- 230000000996 additive effect Effects 0.000 description 6
- 238000005336 cracking Methods 0.000 description 5
- 239000000292 calcium oxide Substances 0.000 description 4
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 4
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 238000010304 firing Methods 0.000 description 3
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 230000002159 abnormal effect Effects 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000010416 ion conductor Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/406—Cells and probes with solid electrolytes
- G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
- G01N27/4073—Composition or fabrication of the solid electrolyte
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/406—Cells and probes with solid electrolytes
- G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
- G01N27/4071—Cells and probes with solid electrolytes for investigating or analysing gases using sensor elements of laminated structure
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M8/124—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte
- H01M8/1246—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte the electrolyte consisting of oxides
- H01M8/1253—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte the electrolyte consisting of oxides the electrolyte containing zirconium oxide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Electrochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Physics & Mathematics (AREA)
- Pathology (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Immunology (AREA)
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- General Chemical & Material Sciences (AREA)
- Measuring Oxygen Concentration In Cells (AREA)
- Compositions Of Oxide Ceramics (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8924479A JPS5614150A (en) | 1979-07-16 | 1979-07-16 | Manufacture of oxygen-concentration detecting element |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2461947A1 true FR2461947A1 (fr) | 1981-02-06 |
| FR2461947B1 FR2461947B1 (enExample) | 1984-06-15 |
Family
ID=13965330
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR8015650A Granted FR2461947A1 (fr) | 1979-07-16 | 1980-07-15 | Element de detection de la concentration en oxygene et son procede de fabrication |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JPS5614150A (enExample) |
| DE (1) | DE3026801A1 (enExample) |
| FR (1) | FR2461947A1 (enExample) |
| GB (1) | GB2054167B (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2998584A1 (fr) * | 2012-11-28 | 2014-05-30 | Areva | Electrolyseur comportant une membrane electrolytique a conduction anionique et procede d'electrolyse de vapeur d'eau |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6036948A (ja) * | 1983-08-09 | 1985-02-26 | Ngk Insulators Ltd | 電気化学的装置 |
| DE3543818A1 (de) * | 1985-12-12 | 1987-06-25 | Draegerwerk Ag | Gassensor mit einem festelektrolyten aus tetragonalem zirkondioxid |
| GB8707091D0 (en) * | 1987-03-25 | 1988-02-10 | Emi Plc Thorn | Ionic conductivity accelerometer |
| EP1026502B1 (en) | 1999-02-03 | 2007-12-19 | NGK Spark Plug Company Limited | Solid electrolyte containing insulating ceramic grains for gas sensor, and method for fabricating same |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3843400A (en) * | 1972-09-18 | 1974-10-22 | Westinghouse Electric Corp | Solid electrolyte cell |
| DE2742279A1 (de) * | 1976-09-22 | 1978-03-23 | Nissan Motor | Sauerstoff-sensor |
| DE2742278A1 (de) * | 1976-09-22 | 1978-03-23 | Nissan Motor | Sauerstoff-sensor |
| FR2426339A1 (fr) * | 1978-05-18 | 1979-12-14 | Nissan Motor | Pate d'electrolyte solide conductrice de l'ion oxygene |
| EP0008175A1 (en) * | 1978-07-24 | 1980-02-20 | Nissan Motor Co., Ltd. | Process for forming a dense thin sintered layer |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5348594A (en) * | 1976-10-14 | 1978-05-02 | Nissan Motor | Oxygen sensor |
| JPS5947258A (ja) * | 1982-09-10 | 1984-03-16 | Mitsui Petrochem Ind Ltd | 芳香族系重合体組成物 |
-
1979
- 1979-07-16 JP JP8924479A patent/JPS5614150A/ja active Pending
-
1980
- 1980-07-15 FR FR8015650A patent/FR2461947A1/fr active Granted
- 1980-07-15 DE DE19803026801 patent/DE3026801A1/de not_active Ceased
- 1980-07-16 GB GB8023164A patent/GB2054167B/en not_active Expired
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3843400A (en) * | 1972-09-18 | 1974-10-22 | Westinghouse Electric Corp | Solid electrolyte cell |
| DE2742279A1 (de) * | 1976-09-22 | 1978-03-23 | Nissan Motor | Sauerstoff-sensor |
| DE2742278A1 (de) * | 1976-09-22 | 1978-03-23 | Nissan Motor | Sauerstoff-sensor |
| FR2426339A1 (fr) * | 1978-05-18 | 1979-12-14 | Nissan Motor | Pate d'electrolyte solide conductrice de l'ion oxygene |
| EP0008175A1 (en) * | 1978-07-24 | 1980-02-20 | Nissan Motor Co., Ltd. | Process for forming a dense thin sintered layer |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2998584A1 (fr) * | 2012-11-28 | 2014-05-30 | Areva | Electrolyseur comportant une membrane electrolytique a conduction anionique et procede d'electrolyse de vapeur d'eau |
| WO2014083134A1 (fr) * | 2012-11-28 | 2014-06-05 | Areva | Electrolyseur comportant une membrane electrolytique a conduction anionique et procede d'electrolyse de vapeur d'eau |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2054167A (en) | 1981-02-11 |
| GB2054167B (en) | 1984-03-14 |
| JPS5614150A (en) | 1981-02-10 |
| FR2461947B1 (enExample) | 1984-06-15 |
| DE3026801A1 (de) | 1981-01-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |