FR2445837A1 - Composes organometalliques d'insertion - Google Patents
Composes organometalliques d'insertionInfo
- Publication number
- FR2445837A1 FR2445837A1 FR8000041A FR8000041A FR2445837A1 FR 2445837 A1 FR2445837 A1 FR 2445837A1 FR 8000041 A FR8000041 A FR 8000041A FR 8000041 A FR8000041 A FR 8000041A FR 2445837 A1 FR2445837 A1 FR 2445837A1
- Authority
- FR
- France
- Prior art keywords
- compounds
- cation
- organometallic
- arsenate
- uranium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000001875 compounds Chemical class 0.000 title abstract 5
- 230000037431 insertion Effects 0.000 title abstract 3
- 238000003780 insertion Methods 0.000 title abstract 3
- 150000001768 cations Chemical class 0.000 abstract 3
- DJHGAFSJWGLOIV-UHFFFAOYSA-K Arsenate3- Chemical compound [O-][As]([O-])([O-])=O DJHGAFSJWGLOIV-UHFFFAOYSA-K 0.000 abstract 2
- 229910019142 PO4 Inorganic materials 0.000 abstract 2
- 229910052770 Uranium Inorganic materials 0.000 abstract 2
- 229940000489 arsenate Drugs 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000010452 phosphate Substances 0.000 abstract 2
- -1 vanadate anion Chemical class 0.000 abstract 2
- 230000002378 acidificating effect Effects 0.000 abstract 1
- 229910052785 arsenic Inorganic materials 0.000 abstract 1
- 238000005341 cation exchange Methods 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 125000002524 organometallic group Chemical group 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000002243 precursor Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
- DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 abstract 1
- 125000005289 uranyl group Chemical group 0.000 abstract 1
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical compound [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F11/00—Compounds containing elements of Groups 6 or 16 of the Periodic Table
- C07F11/005—Compounds containing elements of Groups 6 or 16 of the Periodic Table compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/06—Cobalt compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Supercharger (AREA)
- Catalysts (AREA)
Abstract
L'invention concerne des composés organométalliques d'insertion. Les composés de l'invention ont des structures stratifiées de sels insolubles dans l'eau comprenant un cation de métal tétravalent et un anion phosphate, arséniate ou vanadate acide. Il s'agit, par exemple, de composés d'insertion dans des structures stratifiées de phosphate, arséniate et vanadate d'uranyle et de trans-uranyl. Les hôtes incluants sont représentés par l'une des formules M(H1-y Ay XO4 )2.n H2 O et H1-y Ay TO2 XO4.n H2 O où M est au moins un cation tétravalent, A est au moins un cation monovalent, X est au moins un élément tel que P, As et V, T est au moins l'uranium ou un trans-uranien, y a une valeur de 0 à 1, n a une valeur de 0 à 6, et les hôtes inclus comprennent un cation organométallique formé d'un métal de transition auquel sont attachés 2 à 6 ligands. Les composés de l'invention sont utiles comme catalyseurs ou précurseurs de catalyseurs, réseaux de diffraction et substances d'échange cationique.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/000,191 US4237061A (en) | 1979-01-02 | 1979-01-02 | Organometallic intercalates |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2445837A1 true FR2445837A1 (fr) | 1980-08-01 |
FR2445837B1 FR2445837B1 (fr) | 1985-06-28 |
Family
ID=21690326
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR8000041A Expired FR2445837B1 (fr) | 1979-01-02 | 1980-01-02 | Composes organometalliques d'insertion |
Country Status (7)
Country | Link |
---|---|
US (1) | US4237061A (fr) |
JP (2) | JPS5592394A (fr) |
CA (1) | CA1116624A (fr) |
DE (1) | DE2951613A1 (fr) |
FR (1) | FR2445837B1 (fr) |
GB (1) | GB2039910B (fr) |
IT (1) | IT1209173B (fr) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4454061A (en) * | 1979-01-02 | 1984-06-12 | Exxon Research And Engineering Co. | Organometallic intercalates |
US4414142A (en) * | 1980-04-18 | 1983-11-08 | Vogel F Lincoln | Organic matrix composites reinforced with intercalated graphite |
US4374760A (en) * | 1980-09-12 | 1983-02-22 | Harold Charles | Electro conductive polymer compositions and new materials found useful in their preparation |
US4376709A (en) * | 1980-11-10 | 1983-03-15 | Exxon Research And Engineering Co. | Intercalated layered mixed oxides |
US4606915A (en) * | 1981-04-23 | 1986-08-19 | Bristol-Myers Company | Antiperspirant combination containing an aluminum halohydrate and a stannic halide |
US4424145A (en) | 1981-06-22 | 1984-01-03 | Union Carbide Corporation | Calcium intercalated boronated carbon fiber |
JPS5950011A (ja) * | 1982-09-10 | 1984-03-22 | Central Glass Co Ltd | 黒鉛とフッ化アルカリ金属及びフッ素との3成分系黒鉛層間化合物、及びその製造方法ならびにそれから成る電導材料 |
US4518534A (en) * | 1983-08-22 | 1985-05-21 | Exxon Research & Engineering Co. | Layered vanadium compounds containing phosphorus or arsenic and pendant organic groups |
US4532074A (en) * | 1983-11-07 | 1985-07-30 | Rca Corporation | Capacitance electronic disc molding composition |
US5273778A (en) * | 1985-03-20 | 1993-12-28 | Sharp Kabushiki Kaisha | Method for producing graphite intercalation compound |
US4900853A (en) * | 1987-08-05 | 1990-02-13 | The Standard Oil Company | Salts and resinoids of 1:4 organoarsonate molybdenum polyoxoanions and process of making |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3980684A (en) * | 1974-11-26 | 1976-09-14 | Exxon Research And Engineering Company | Metallocene intercalates |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE551488A (fr) * | 1955-10-05 | |||
US3673015A (en) * | 1969-05-23 | 1972-06-27 | Us Army | Explosive pyrotechnic complexes of ferrocene and inorganic nitrates |
US3688109A (en) * | 1970-07-14 | 1972-08-29 | Synvar Ass | X-ray diffraction grating crystals |
US4024170A (en) * | 1975-11-11 | 1977-05-17 | The University Of Alabama | Liquid clathrates |
US4094893A (en) * | 1976-11-24 | 1978-06-13 | Exxon Research & Engineering Co. | Isonitrile intercalation complexes |
US4119655A (en) * | 1977-01-17 | 1978-10-10 | Exxon Research & Engineering Co. | Novel graphite intercalation compounds and method of making same |
-
1979
- 1979-01-02 US US06/000,191 patent/US4237061A/en not_active Expired - Lifetime
- 1979-11-27 CA CA000340720A patent/CA1116624A/fr not_active Expired
- 1979-12-21 DE DE19792951613 patent/DE2951613A1/de not_active Withdrawn
- 1979-12-28 JP JP17400379A patent/JPS5592394A/ja active Pending
- 1979-12-28 GB GB7944446A patent/GB2039910B/en not_active Expired
- 1979-12-28 JP JP17387279A patent/JPS5598616A/ja active Pending
- 1979-12-31 IT IT7928478A patent/IT1209173B/it active
-
1980
- 1980-01-02 FR FR8000041A patent/FR2445837B1/fr not_active Expired
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3980684A (en) * | 1974-11-26 | 1976-09-14 | Exxon Research And Engineering Company | Metallocene intercalates |
Non-Patent Citations (1)
Title |
---|
EXBK/78 * |
Also Published As
Publication number | Publication date |
---|---|
JPS5598616A (en) | 1980-07-26 |
IT7928478A0 (it) | 1979-12-31 |
DE2951613A1 (de) | 1980-07-10 |
FR2445837B1 (fr) | 1985-06-28 |
IT1209173B (it) | 1989-07-10 |
CA1116624A (fr) | 1982-01-19 |
GB2039910A (en) | 1980-08-20 |
JPS5592394A (en) | 1980-07-12 |
GB2039910B (en) | 1983-03-02 |
US4237061A (en) | 1980-12-02 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |