FR2443452A1 - Nouveau procede de dedoublement de l'acide dl cis et dl trans chrysanthemique - Google Patents

Nouveau procede de dedoublement de l'acide dl cis et dl trans chrysanthemique

Info

Publication number
FR2443452A1
FR2443452A1 FR7834591A FR7834591A FR2443452A1 FR 2443452 A1 FR2443452 A1 FR 2443452A1 FR 7834591 A FR7834591 A FR 7834591A FR 7834591 A FR7834591 A FR 7834591A FR 2443452 A1 FR2443452 A1 FR 2443452A1
Authority
FR
France
Prior art keywords
splitting
trans
chrysanthemic
new process
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7834591A
Other languages
English (en)
Other versions
FR2443452B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sanofi Aventis France
Original Assignee
Roussel Uclaf SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Roussel Uclaf SA filed Critical Roussel Uclaf SA
Priority to FR7834591A priority Critical patent/FR2443452A1/fr
Priority to SE7908765A priority patent/SE430984B/sv
Priority to US06/096,028 priority patent/US4257976A/en
Priority to HU79RO1050A priority patent/HU181948B/hu
Priority to CA341,406A priority patent/CA1127180A/fr
Priority to CH1087779A priority patent/CH641751A5/fr
Priority to DE19792949384 priority patent/DE2949384A1/de
Priority to BE0/198472A priority patent/BE880490A/fr
Priority to ES486670A priority patent/ES486670A1/es
Priority to IT51027/79A priority patent/IT1164774B/it
Priority to GB7942289A priority patent/GB2039895B/en
Priority to JP15822679A priority patent/JPS56108736A/ja
Priority to NL7908881A priority patent/NL7908881A/nl
Publication of FR2443452A1 publication Critical patent/FR2443452A1/fr
Application granted granted Critical
Publication of FR2443452B1 publication Critical patent/FR2443452B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/487—Separation; Purification; Stabilisation; Use of additives by treatment giving rise to chemical modification

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

L'invention concerne un procédé de dédoublement de l'acide DL cis et DL trans chrysanthémique, caractérisé en ce que l'on fait réagir ledit acide avec la L ou la D N-méthyl éphédrine dans un solvant organique puis isole et décompose par hydrolyse acide le sel formé cristallisé et obtient l'acide correspondant.
FR7834591A 1978-12-07 1978-12-08 Nouveau procede de dedoublement de l'acide dl cis et dl trans chrysanthemique Granted FR2443452A1 (fr)

Priority Applications (13)

Application Number Priority Date Filing Date Title
FR7834591A FR2443452A1 (fr) 1978-12-08 1978-12-08 Nouveau procede de dedoublement de l'acide dl cis et dl trans chrysanthemique
SE7908765A SE430984B (sv) 1978-12-08 1979-10-23 Sett att spalta dl-cis och dl-trans krysantemsyra
US06/096,028 US4257976A (en) 1978-12-08 1979-11-20 Resolution process using L or D N-methyl-ephedrine
CA341,406A CA1127180A (fr) 1978-12-08 1979-12-06 Procede de dedoublement de l'acide dl cis et dl trans chrysanthemique
HU79RO1050A HU181948B (en) 1978-12-08 1979-12-06 Process for the resolution of dl-cys- and dl-trans-2,2-dimethyl-3-/2'-methyl-1'-propylene/-cyclopropane-1-carboxylic acid /chrysanthemic acid/
DE19792949384 DE2949384A1 (de) 1978-12-08 1979-12-07 Neues verfahren zur spaltung der dl-cis- und dl-trans-chrysanthemumsaeure
CH1087779A CH641751A5 (fr) 1978-12-08 1979-12-07 Nouveau procede de dedoublement de l'acide dl-cis et dl-trans chrysanthemique.
BE0/198472A BE880490A (fr) 1978-12-08 1979-12-07 Nouveau procede de dedoublement de l'acide dl-cis et dl-trans chrysanthemique
ES486670A ES486670A1 (es) 1978-12-08 1979-12-07 Un procedimiento de desdoblamiento del acido dl-cis y dl- trans crisantemico
IT51027/79A IT1164774B (it) 1978-12-08 1979-12-07 Procedimento di separazione dell'acido dl-cis crisantemico e dell'acido dl-trans crisantemico
GB7942289A GB2039895B (en) 1978-12-07 1979-12-07 4-substituted-2(1h)quinazolinones
JP15822679A JPS56108736A (en) 1978-12-08 1979-12-07 Novel resolution of dllciss and dlltransschrysanthemic acid
NL7908881A NL7908881A (nl) 1978-12-08 1979-12-10 Nieuwe werkwijze voor de splitsing van dl-cis en dl-trans chrysanthemumzuur.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7834591A FR2443452A1 (fr) 1978-12-08 1978-12-08 Nouveau procede de dedoublement de l'acide dl cis et dl trans chrysanthemique

Publications (2)

Publication Number Publication Date
FR2443452A1 true FR2443452A1 (fr) 1980-07-04
FR2443452B1 FR2443452B1 (fr) 1981-08-14

Family

ID=9215840

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7834591A Granted FR2443452A1 (fr) 1978-12-07 1978-12-08 Nouveau procede de dedoublement de l'acide dl cis et dl trans chrysanthemique

Country Status (12)

Country Link
US (1) US4257976A (fr)
JP (1) JPS56108736A (fr)
BE (1) BE880490A (fr)
CA (1) CA1127180A (fr)
CH (1) CH641751A5 (fr)
DE (1) DE2949384A1 (fr)
ES (1) ES486670A1 (fr)
FR (1) FR2443452A1 (fr)
HU (1) HU181948B (fr)
IT (1) IT1164774B (fr)
NL (1) NL7908881A (fr)
SE (1) SE430984B (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU543276B2 (en) * 1981-06-18 1985-04-18 Stauffer Chemical Company Resolution of dl-trans-chrysanthemic acid
US4542235A (en) * 1982-04-12 1985-09-17 Sumitomo Chemical Company, Limited Method for producing an optically active 2,2-dimethylcyclopropanecarboxylic acid
US4663474A (en) * 1983-02-22 1987-05-05 Pfizer Inc. Synthetic intermediates for a chiral 3-(substituted-phenyl)-4-(3-hydroxypropyl) cyclohexanol
CA2137378C (fr) 1992-06-05 2008-08-05 Stephen Brian Henry Kent Compositions de d-enzyme et methodes d'utilisation
US5447897A (en) * 1993-05-17 1995-09-05 Shell Oil Company Ethylene oxide catalyst and process
ITMI20050231A1 (it) * 2005-02-17 2006-08-18 Endura Spa Processo per l'ottenimento di enantiomeri dell'acido crisantemico

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1394170A (en) * 1971-08-12 1975-05-14 Richter Gedeon Vegyeszet Process for the preparation of alpha-aminoxy-carboxylic acids

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR92748E (fr) * 1966-01-26 1968-12-20 Roussel Uclaf Nouveaux composés optiquement actifs et procédé pour leur utilisation au dédoublement de produits racémiques.
FR1536458A (fr) * 1967-07-07 1968-08-16 Roussel Uclaf Procédé d'obtention de l'acide d-trans chrysanthémique
NL6705942A (fr) * 1966-04-27 1967-10-30
FR1507192A (fr) * 1966-08-26 1967-12-29 Roussel Uclaf Nouvelles aryl allylsulfones et procédé de préparation
US3739019A (en) * 1969-07-02 1973-06-12 Sumitomo Chemical Co Preparation of optically active trans chrysanthemic acid
BE755498A (fr) * 1969-09-12 1971-02-01 Sumitomo Chemical Co Preparation d'acide chrysanthemique optiquement
BE790240A (fr) * 1971-10-19 1973-02-15 Sumitomo Chemical Co Procede de preparation de l'acide mixte (+)-cis, (+)-trans- chrysanthemique
JPS5123497B2 (fr) * 1972-01-07 1976-07-17
JPS4992049A (fr) * 1973-01-09 1974-09-03
JPS51143647A (en) * 1975-06-06 1976-12-10 Sumitomo Chem Co Ltd Process for obtaining optically active trans-2,2-dimethyl-3-(2,2-dichl orovinyl) cyclopropanecarboxylic acid

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1394170A (en) * 1971-08-12 1975-05-14 Richter Gedeon Vegyeszet Process for the preparation of alpha-aminoxy-carboxylic acids

Also Published As

Publication number Publication date
US4257976A (en) 1981-03-24
ES486670A1 (es) 1980-05-16
NL7908881A (nl) 1980-06-10
BE880490A (fr) 1980-06-09
CH641751A5 (fr) 1984-03-15
DE2949384A1 (de) 1980-06-26
JPS6410508B2 (fr) 1989-02-22
FR2443452B1 (fr) 1981-08-14
HU181948B (en) 1983-11-28
IT7951027A0 (it) 1979-12-07
JPS56108736A (en) 1981-08-28
SE7908765L (sv) 1980-06-09
IT1164774B (it) 1987-04-15
SE430984B (sv) 1983-12-27
DE2949384C2 (fr) 1990-09-13
CA1127180A (fr) 1982-07-06

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