FR2405911A1 - Hydrogenation asymetrique des olefines possedant le pouvoir rotatoire par des complexes de metaux de transitions fixes dans des mineraux argileux - Google Patents

Hydrogenation asymetrique des olefines possedant le pouvoir rotatoire par des complexes de metaux de transitions fixes dans des mineraux argileux

Info

Publication number
FR2405911A1
FR2405911A1 FR7829446A FR7829446A FR2405911A1 FR 2405911 A1 FR2405911 A1 FR 2405911A1 FR 7829446 A FR7829446 A FR 7829446A FR 7829446 A FR7829446 A FR 7829446A FR 2405911 A1 FR2405911 A1 FR 2405911A1
Authority
FR
France
Prior art keywords
olefins
clay minerals
rotatory power
metal complexes
fixed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7829446A
Other languages
English (en)
Other versions
FR2405911B1 (fr
Inventor
Marcello Mazzei
Mario Riocci
Walter Marconi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SnamProgetti SpA
Original Assignee
SnamProgetti SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SnamProgetti SpA filed Critical SnamProgetti SpA
Publication of FR2405911A1 publication Critical patent/FR2405911A1/fr
Application granted granted Critical
Publication of FR2405911B1 publication Critical patent/FR2405911B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/36—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by hydrogenation of carbon-to-carbon unsaturated bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B01J31/1855—Triamide derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1865—Phosphonites (RP(OR)2), their isomeric phosphinates (R2(RO)P=O) and RO-substitution derivatives thereof
    • B01J31/187—Amide derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
    • B01J31/188—Amide derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Hydrogénation asymétrique des oléfines possédant le pouvoir rotatoire par des complexes de métaux de transitions fixés dans des minéraux argileux. La présente invention concerne un système catalytique qui est constitué par un complexe cationique du rhodium fixé sur un minéral argileux, tel que hectorite, bentonite et halloysite. Utilisation de ce catalyseur pour l'hydrogénation asymétrique d'oléfines possédant le pouvoir rotatoire.
FR7829446A 1977-10-17 1978-10-16 Hydrogenation asymetrique des olefines possedant le pouvoir rotatoire par des complexes de metaux de transitions fixes dans des mineraux argileux Granted FR2405911A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT28666/77A IT1087963B (it) 1977-10-17 1977-10-17 Idrogenazione asimmetrica di olefine prochirali mediante complessi di metalli di transazione immobilizzati in minerali argillosi.

Publications (2)

Publication Number Publication Date
FR2405911A1 true FR2405911A1 (fr) 1979-05-11
FR2405911B1 FR2405911B1 (fr) 1981-03-20

Family

ID=11223981

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7829446A Granted FR2405911A1 (fr) 1977-10-17 1978-10-16 Hydrogenation asymetrique des olefines possedant le pouvoir rotatoire par des complexes de metaux de transitions fixes dans des mineraux argileux

Country Status (20)

Country Link
JP (1) JPS5466615A (fr)
AU (1) AU520574B2 (fr)
BE (1) BE871320A (fr)
CA (1) CA1148564A (fr)
CH (1) CH636589A5 (fr)
CS (1) CS208483B2 (fr)
DD (1) DD139251A5 (fr)
DE (1) DE2845216C2 (fr)
DK (1) DK461478A (fr)
FR (1) FR2405911A1 (fr)
GB (1) GB2006770B (fr)
HU (1) HU181953B (fr)
IL (1) IL55733A (fr)
IT (1) IT1087963B (fr)
LU (1) LU80370A1 (fr)
NL (1) NL7810236A (fr)
NO (1) NO148778C (fr)
SE (1) SE435923B (fr)
YU (1) YU237578A (fr)
ZA (1) ZA785486B (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
HU190864B (en) * 1983-12-08 1986-11-28 Alkaloida Vegyeszeti Gyar Process for production of phenil-alanin derivatives
GB8519008D0 (en) * 1985-07-27 1985-09-04 British Petroleum Co Plc Chemical process

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2349555A1 (fr) * 1976-04-26 1977-11-25 Snam Progetti Hydrogenation asymetrique et moyens pour la realiser

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4008281A (en) * 1973-12-03 1977-02-15 Monsanto Company Asymmetric catalysis

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2349555A1 (fr) * 1976-04-26 1977-11-25 Snam Progetti Hydrogenation asymetrique et moyens pour la realiser

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
EXBK/75 *

Also Published As

Publication number Publication date
AU520574B2 (en) 1982-02-11
BE871320A (fr) 1979-04-17
GB2006770A (en) 1979-05-10
NO783492L (no) 1979-04-18
ZA785486B (en) 1979-09-26
NO148778B (no) 1983-09-05
YU237578A (en) 1983-01-21
CH636589A5 (it) 1983-06-15
AU4025178A (en) 1980-04-03
NO148778C (no) 1983-12-14
DD139251A5 (de) 1979-12-19
LU80370A1 (fr) 1979-03-19
DE2845216A1 (de) 1979-04-19
CS208483B2 (en) 1981-09-15
IT1087963B (it) 1985-06-04
JPS5466615A (en) 1979-05-29
DK461478A (da) 1979-04-18
IL55733A (en) 1981-11-30
FR2405911B1 (fr) 1981-03-20
IL55733A0 (en) 1978-12-17
NL7810236A (nl) 1979-04-19
CA1148564A (fr) 1983-06-21
DE2845216C2 (de) 1984-05-10
HU181953B (en) 1983-11-28
SE435923B (sv) 1984-10-29
SE7810776L (sv) 1979-04-18
GB2006770B (en) 1982-03-17

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