DE69414907D1 - Katalysator für die Alkylierung von Paraffinen - Google Patents

Katalysator für die Alkylierung von Paraffinen

Info

Publication number
DE69414907D1
DE69414907D1 DE69414907T DE69414907T DE69414907D1 DE 69414907 D1 DE69414907 D1 DE 69414907D1 DE 69414907 T DE69414907 T DE 69414907T DE 69414907 T DE69414907 T DE 69414907T DE 69414907 D1 DE69414907 D1 DE 69414907D1
Authority
DE
Germany
Prior art keywords
catalyst
paraffin alkylation
alkylation
paraffin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69414907T
Other languages
English (en)
Other versions
DE69414907T2 (de
Inventor
Jean-Francois Joly
Nathalie Ferrer
Jean-Yves Bernhard
Eric Benazzi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Application granted granted Critical
Publication of DE69414907D1 publication Critical patent/DE69414907D1/de
Publication of DE69414907T2 publication Critical patent/DE69414907T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B01J31/0225—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts
    • B01J31/0227—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts being perfluorinated, i.e. comprising at least one perfluorinated moiety as substructure in case of polyfunctional compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/053—Sulfates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/51—Spheres
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C07C2/58—Catalytic processes
    • C07C2/62—Catalytic processes with acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/638—Pore volume more than 1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/053—Sulfates or other compounds comprising the anion (SnO3n+1)2-
    • C07C2527/054—Sulfuric acid or other acids with the formula H2Sn03n+1
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/025—Sulfonic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
DE69414907T 1993-04-20 1994-04-11 Katalysator für die Alkylierung von Paraffinen Expired - Fee Related DE69414907T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9304735A FR2704161B1 (fr) 1993-04-20 1993-04-20 Catalyseur d'alkylation de paraffines.

Publications (2)

Publication Number Publication Date
DE69414907D1 true DE69414907D1 (de) 1999-01-14
DE69414907T2 DE69414907T2 (de) 1999-04-22

Family

ID=9446312

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69414907T Expired - Fee Related DE69414907T2 (de) 1993-04-20 1994-04-11 Katalysator für die Alkylierung von Paraffinen

Country Status (9)

Country Link
US (1) US5475184A (de)
EP (1) EP0623388B1 (de)
JP (1) JPH06320005A (de)
CN (1) CN1098963A (de)
AU (1) AU6055194A (de)
CA (1) CA2121733A1 (de)
DE (1) DE69414907T2 (de)
FR (1) FR2704161B1 (de)
TW (1) TW267108B (de)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2719504B1 (fr) * 1994-05-04 1996-06-21 Inst Francais Du Petrole Catalyseur d'alkylation d'isoparaffine C4-C5 par au moins une oléfine C2-C6.
US5731256A (en) * 1994-05-04 1998-03-24 Institut Francais Du Petrole Alkylation catalyst for C4 -C5 isoparaffins using at least one C2 -C6 olefin
DK171932B1 (da) * 1994-12-02 1997-08-18 Topsoe Haldor As Fremgangsmåde til alkylering af alifatiske carbonhydrider
FR2738503B1 (fr) * 1995-09-11 1997-10-03 Inst Francais Du Petrole Catalyseur solides d'alkylation aliphatique
US6395673B1 (en) 2000-06-29 2002-05-28 E. I. Du Pont De Nemours And Company Catalyst of mixed fluorosulfonic acids

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA711745A (en) * 1965-06-15 Shell Oil Company Alkylation process
US2434833A (en) * 1942-07-09 1948-01-20 Atlantic Refining Co Process for condensation of hydrocarbons by contact with concentrated sulfuric acid in silica gel
US4038212A (en) * 1975-03-24 1977-07-26 Texaco Inc. Alkylation process for production of motor fuels
US3970721A (en) * 1975-03-24 1976-07-20 Texaco Inc. Alkylation process for production of motor fuels utilizing sulfuric acid catalyst with trifluoromethane sulfonic acid
DK168520B1 (da) * 1989-12-18 1994-04-11 Topsoe Haldor As Fremgangsmåde til væskefase-alkylering af et carbonhydrid med et olefinalkyleringsmiddel
DE69207548T2 (de) * 1991-10-25 1996-05-15 Inst Francais Du Petrole Verwendung von einem Katalysator zur Alkylierung von Paraffinen
FR2682891A1 (fr) * 1991-10-25 1993-04-30 Inst Francais Du Petrole Catalyseur d'alkylation de paraffines.
FR2683739A1 (fr) * 1991-11-14 1993-05-21 Inst Francais Du Petrole Catalyseur d'alkylation de paraffines.
US5292986A (en) * 1992-04-20 1994-03-08 Phillips Petroleum Company Isoparaffin-olefin alkylation catalyst composition and process
US5233119A (en) * 1992-11-09 1993-08-03 Phillips Petroleum Company Alkylation process and catalyst therefor

Also Published As

Publication number Publication date
DE69414907T2 (de) 1999-04-22
US5475184A (en) 1995-12-12
EP0623388B1 (de) 1998-12-02
FR2704161B1 (fr) 1995-06-02
CN1098963A (zh) 1995-02-22
TW267108B (de) 1996-01-01
JPH06320005A (ja) 1994-11-22
AU6055194A (en) 1994-10-27
CA2121733A1 (fr) 1994-10-21
EP0623388A1 (de) 1994-11-09
FR2704161A1 (fr) 1994-10-28

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Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee