FR2452319B1 - Catalyseurs superacides supportes pour la conversion des hydrocarbures - Google Patents
Catalyseurs superacides supportes pour la conversion des hydrocarburesInfo
- Publication number
- FR2452319B1 FR2452319B1 FR8006320A FR8006320A FR2452319B1 FR 2452319 B1 FR2452319 B1 FR 2452319B1 FR 8006320 A FR8006320 A FR 8006320A FR 8006320 A FR8006320 A FR 8006320A FR 2452319 B1 FR2452319 B1 FR 2452319B1
- Authority
- FR
- France
- Prior art keywords
- hydrocarbon conversion
- superacid catalysts
- supported
- supported superacid
- catalysts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0215—Sulfur-containing compounds
- B01J31/0225—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts
- B01J31/0227—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts being perfluorinated, i.e. comprising at least one perfluorinated moiety as substructure in case of polyfunctional compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/36—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of vanadium, niobium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/56—Addition to acyclic hydrocarbons
- C07C2/58—Catalytic processes
- C07C2/62—Catalytic processes with acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
- C07C2/66—Catalytic processes
- C07C2/70—Catalytic processes with acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
- C07C5/2767—Changing the number of side-chains
- C07C5/277—Catalytic processes
- C07C5/2794—Catalytic processes with hydrides or organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
- C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
- C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
- C07C6/126—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of more than one hydrocarbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
- B01J2231/42—Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
- B01J2231/4205—C-C cross-coupling, e.g. metal catalyzed or Friedel-Crafts type
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
- B01J2231/52—Isomerisation reactions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- C07C2521/08—Silica
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/06—Halogens; Compounds thereof
- C07C2527/08—Halides
- C07C2527/12—Fluorides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/06—Halogens; Compounds thereof
- C07C2527/133—Compounds comprising a halogen and vanadium, niobium, tantalium, antimonium or bismuth
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- C07C2531/025—Sulfonic acids
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US2367679A | 1979-03-26 | 1979-03-26 |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2452319A1 FR2452319A1 (fr) | 1980-10-24 |
FR2452319B1 true FR2452319B1 (fr) | 1987-08-14 |
Family
ID=21816558
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR8006320A Expired FR2452319B1 (fr) | 1979-03-26 | 1980-03-21 | Catalyseurs superacides supportes pour la conversion des hydrocarbures |
Country Status (10)
Country | Link |
---|---|
US (2) | US4547474A (fr) |
JP (1) | JPS55129154A (fr) |
BE (1) | BE882427A (fr) |
CA (1) | CA1146926A (fr) |
DE (1) | DE3011128C2 (fr) |
FR (1) | FR2452319B1 (fr) |
GB (1) | GB2044628B (fr) |
IT (1) | IT1129809B (fr) |
LU (1) | LU82289A1 (fr) |
NL (1) | NL8001749A (fr) |
Families Citing this family (39)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1129809B (it) * | 1979-03-26 | 1986-06-11 | Ugine Kuhlmann | Composizione catalitica per la conversione di idrocarburi e procedimento per la disidratazione di acidi perfluoroalcansolfonici destinati a fare parte bella composizione |
DE3407596A1 (de) * | 1984-03-01 | 1985-09-05 | Merck Patent Gmbh, 6100 Darmstadt | Verfahren zur herstellung von mikrokristalliner triacetylcellulose |
US4721559A (en) * | 1986-10-17 | 1988-01-26 | Olah George A | Boron, aluminum and gallium perfluoro alkanesulfonate and resinsulfonate catalysts |
US5110778A (en) * | 1986-10-17 | 1992-05-05 | Olah George A | Boron aluminum and gallium perfluoro alkanesulfonate and resinsulfonate catalysts |
US4943553A (en) * | 1986-12-25 | 1990-07-24 | Nippon Steel Chemical Co., Ltd. | Method of making ethylbiphenyls |
US4983566A (en) * | 1987-03-09 | 1991-01-08 | Aluminum Company Of America | Surface-modified adsorbent comprising metal oxide/hydroxide particles reacted with one or more perfluorinated organic acids |
EP0371034A4 (en) * | 1987-07-02 | 1993-02-24 | Exabyte Corporation | Method and apparatus for data buffer management |
DK168520B1 (da) * | 1989-12-18 | 1994-04-11 | Topsoe Haldor As | Fremgangsmåde til væskefase-alkylering af et carbonhydrid med et olefinalkyleringsmiddel |
US5084586A (en) * | 1990-02-12 | 1992-01-28 | Minnesota Mining And Manufacturing Company | Novel initiators for cationic polymerization |
US5124417A (en) * | 1990-02-12 | 1992-06-23 | Minnesota Mining And Manufacturing Company | Initiators for cationic polymerization |
US5073674A (en) * | 1990-04-20 | 1991-12-17 | Olah George A | Environmentally safe catalytic alkyation using liquid onium poly (hydrogen fluorides) |
US5097087A (en) * | 1990-10-15 | 1992-03-17 | Texaco Chemical Company | Dimerization of long-chain olefins using a fluorocarbonsulfonic acid polymer on an inert support |
US5157196A (en) * | 1990-12-24 | 1992-10-20 | Chemical Research & Licensing Company | Paraffin alkylation process |
US5190904A (en) * | 1990-12-24 | 1993-03-02 | Chemical Research & Licensing Company | Paraffin alkylation catalyst |
US5157199A (en) * | 1991-04-01 | 1992-10-20 | Exxon Research And Engineering Co. | Isomerization of paraffins with strong solid acid catalyst and adamantane |
US5276239A (en) * | 1992-07-27 | 1994-01-04 | Texaco Chemical Company | Dimerization of long-chain olefins using a silica gel alkylsulfonic acid |
US5233119A (en) * | 1992-11-09 | 1993-08-03 | Phillips Petroleum Company | Alkylation process and catalyst therefor |
IT1265051B1 (it) * | 1993-08-06 | 1996-10-28 | Eniricerche Spa | Processo per l'alchilazione di idrocarburi alifatici con olefine |
US5364976A (en) * | 1993-10-29 | 1994-11-15 | Phillips Petroleum Company | Alkylation/etherification process |
US5824622A (en) * | 1994-01-12 | 1998-10-20 | E. I. Du Pont De Nemours And Company | Porous microcomposite of perfluorinated ion-exchange polymer and metal oxide, a network of silica, or a network of metal oxide and silica derived via a sol-gel process |
EP0663377A1 (fr) * | 1994-01-13 | 1995-07-19 | Haldor Topsoe A/S | Procédé d'alkylation |
US5489564A (en) * | 1994-09-07 | 1996-02-06 | Phillips Petroleum Company | Alkane disproportionation |
DK172069B1 (da) * | 1994-12-21 | 1997-10-13 | Topsoe Haldor As | Fremgangsmåde til fremstilling af et isobutan/isohexanholdigt produkt |
EP0787706B1 (fr) * | 1996-01-30 | 2000-11-22 | BP Amoco Corporation | Procédé pour l'isomérisation des oléfines |
FR2744720B1 (fr) * | 1996-02-09 | 1998-04-10 | Rhone Poulenc Chimie | Procede d'hydroxylation de composes phenoliques |
US5798417A (en) * | 1996-10-15 | 1998-08-25 | E. I. Du Pont De Nemours And Company | (Fluorovinyl ether)-grafted high-surface-area polyolefins and preparation thereof |
US6281309B1 (en) | 1997-01-08 | 2001-08-28 | Eastman Chemical Company | Flourinated solid acids as catalysts for the preparation of hydrocarbon resins |
DK39897A (da) * | 1997-04-09 | 1998-10-10 | Haldor Topsoe As | Fremgangsmåde til fjernelse af aromatiske forbindelser fra en carbonhydridblanding |
US5922635A (en) * | 1997-05-07 | 1999-07-13 | Olah; George A. | Nanoscale solid superacid catalysts with pendant fluoroalkylsulfonic acid or fluoro, perfluoroalkylsulfonic acid groups |
US6018088A (en) * | 1997-05-07 | 2000-01-25 | Olah; George A. | Superacid catalyzed formylation-rearrangement of saturated hydrocarbons |
FR2771419B1 (fr) * | 1997-11-25 | 1999-12-31 | Inst Francais Du Petrole | Essences a haut indice d'octane et leur production par un procede associant hydro-isomerisation et separation |
US6228797B1 (en) | 1998-12-11 | 2001-05-08 | Phillips Petroleum Company | Oligomerization catalyst system and method of making and method of using such catalyst system in the oligomerization of olefins |
US6479598B1 (en) | 1999-07-20 | 2002-11-12 | Exxonmobil Chemical Patents Inc. | Petroleum resins and their production with BF3 catalyst |
US6281401B1 (en) * | 1999-09-16 | 2001-08-28 | Phillips Petroleum Company | Oligomerization of olefins |
US6395673B1 (en) | 2000-06-29 | 2002-05-28 | E. I. Du Pont De Nemours And Company | Catalyst of mixed fluorosulfonic acids |
DE60112196T2 (de) | 2000-08-28 | 2005-12-29 | Haldor Topsoe A/S | Verfahren zur Herstellung von monoalkylierten aromatischen Verbindungen |
US6855857B2 (en) * | 2000-10-11 | 2005-02-15 | Bp Oil International Limited | Isomerisation process |
EP1357167A1 (fr) * | 2002-04-18 | 2003-10-29 | Haldor Topsoe A/S | Procédé pour la production d'essence de haute qualité à faible teneur en aromatiques |
US20080116053A1 (en) * | 2006-11-20 | 2008-05-22 | Abb Lummus Global Inc. | Non-refluxing reactor stripper |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3766286A (en) * | 1971-06-25 | 1973-10-16 | Exxon Research Engineering Co | Process for the isomerization of hydrocarbons |
US3708553A (en) * | 1971-06-25 | 1973-01-02 | Exxon Research Engineering Co | Alkylation process utilizing a lewis acid halide with fluorosulfuric or trifluoromethanesulfonic acid |
US3878261A (en) * | 1973-08-24 | 1975-04-15 | Phillips Petroleum Co | Hydroisomerization of paraffin hydrocarbon with a supported catalyst of SbF{HD 5 {B and CF{HD 3{B SO{HD 3{B H |
US4044069A (en) * | 1973-09-26 | 1977-08-23 | Societe Nationale Elf Aquitaine | Catalytic composition for the isomerization and alkylation of hydrocarbons |
FR2244563B1 (fr) * | 1973-09-26 | 1976-06-18 | Erap | |
US4116880A (en) * | 1977-06-16 | 1978-09-26 | Produits Chimiques Ugine Kuhlmann | Solid catalysts based on fluorinated graphite |
IT1129809B (it) * | 1979-03-26 | 1986-06-11 | Ugine Kuhlmann | Composizione catalitica per la conversione di idrocarburi e procedimento per la disidratazione di acidi perfluoroalcansolfonici destinati a fare parte bella composizione |
US4288646A (en) * | 1979-10-05 | 1981-09-08 | Pcuk Produits Chimiques Ugine Kuhlmann | Regioselective preparation of β-isopropylnaphthalene over superacidic solid or supported perfluorinated sulfonic acid catalysts |
US4547606A (en) * | 1980-03-14 | 1985-10-15 | Pcuk Produits Chimiques Ugine Kuhlmann | Selective isomerization of di-isopropyl benzene to meta-di-isopropyl benzene |
US4339614A (en) * | 1980-03-14 | 1982-07-13 | Pcuk Produits Chimiques Ugine Kuhlmann | Superacid catalyzed preparation of resorcinol from meta-isopropylphenol |
US4423254A (en) * | 1980-03-14 | 1983-12-27 | Pcuk Produits Chimiques Ugine Kuhlmann | Superacid catalyzed preparation of resorcinol from meta-isopropylphenol |
US4424382A (en) * | 1980-03-14 | 1984-01-03 | Pcuk Produits Chimiques Ugine Kuhlmann | Superacid catalyzed preparation of resorcinol from meta-isopropylepheol |
US4339613A (en) * | 1980-03-14 | 1982-07-13 | Pcuk Produits Chimiques Ugine Kuhlmann | Superacid catalyzed preparation of resorcinol from meta-diisopropylbenzene |
US4547604A (en) * | 1980-03-14 | 1985-10-15 | Pcuk Produits Chimiques Ugine Kuhlmann | Selective isopropylation of cumene to meta-diisopropylbenzene |
US4503263A (en) * | 1980-08-18 | 1985-03-05 | Atochem | Process for the preparation of octane boosting branched aliphatic ethers using solid superacid catalysts |
-
1980
- 1980-03-13 IT IT67393/80A patent/IT1129809B/it active
- 1980-03-17 GB GB8008997A patent/GB2044628B/en not_active Expired
- 1980-03-21 FR FR8006320A patent/FR2452319B1/fr not_active Expired
- 1980-03-22 DE DE3011128A patent/DE3011128C2/de not_active Expired
- 1980-03-24 LU LU82289A patent/LU82289A1/fr unknown
- 1980-03-25 NL NL8001749A patent/NL8001749A/nl not_active Application Discontinuation
- 1980-03-25 BE BE0/199947A patent/BE882427A/fr not_active IP Right Cessation
- 1980-03-25 CA CA000348397A patent/CA1146926A/fr not_active Expired
- 1980-03-26 JP JP3767780A patent/JPS55129154A/ja active Granted
-
1984
- 1984-01-03 US US06/568,272 patent/US4547474A/en not_active Expired - Fee Related
- 1984-01-03 US US06/568,273 patent/US4613723A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
JPS55129154A (en) | 1980-10-06 |
DE3011128A1 (de) | 1980-10-23 |
FR2452319A1 (fr) | 1980-10-24 |
JPH0312938B2 (fr) | 1991-02-21 |
CA1146926A (fr) | 1983-05-24 |
DE3011128C2 (de) | 1986-01-30 |
GB2044628A (en) | 1980-10-22 |
IT1129809B (it) | 1986-06-11 |
NL8001749A (nl) | 1980-09-30 |
US4547474A (en) | 1985-10-15 |
IT8067393A0 (it) | 1980-03-13 |
GB2044628B (en) | 1983-08-17 |
US4613723A (en) | 1986-09-23 |
BE882427A (fr) | 1980-09-25 |
LU82289A1 (fr) | 1981-10-30 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |