FR2404311A1 - Batteries reversibles a cathode en chalcogenure metallique, a anode en metal alcalin et a electrolyte non aqueux - Google Patents

Batteries reversibles a cathode en chalcogenure metallique, a anode en metal alcalin et a electrolyte non aqueux

Info

Publication number
FR2404311A1
FR2404311A1 FR7816724A FR7816724A FR2404311A1 FR 2404311 A1 FR2404311 A1 FR 2404311A1 FR 7816724 A FR7816724 A FR 7816724A FR 7816724 A FR7816724 A FR 7816724A FR 2404311 A1 FR2404311 A1 FR 2404311A1
Authority
FR
France
Prior art keywords
organic
alkali metal
aqueous electrolyte
cells
chalcogenide cathode
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7816724A
Other languages
English (en)
Other versions
FR2404311B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of FR2404311A1 publication Critical patent/FR2404311A1/fr
Application granted granted Critical
Publication of FR2404311B1 publication Critical patent/FR2404311B1/fr
Granted legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0568—Liquid materials characterised by the solutes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • General Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Secondary Cells (AREA)
  • Primary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

La présente invention concerne des cellules électrochimiques à anode en métal alcalin et à cathode en chalcogénure métallique, par exemple des batteries au lithium. Les compositions électrolytiques de ces cellules comprennent un solvant organique choisi parmi les éthers, les sulfones, les sulfates organiques, les sulfites organiques, les composés nitrés organiques et les nitrites organiques; et au moins une quantité électrolytiquement active d'un sel polyarylique d'un métal alcalin, de formule ZMRn où Z est un métal alcalin et M est Zn, Cd, B, Al, Ga, Sn (stanneaux) In, TI, P ou As, et Rn représente n radicaux aryle, identiques ou différents, ayant chacun 6 à 50 atomes de carbone, n étant égal à 1 augmenté de la valence de M. Ces cellules peuvent être rechargées de nombreuses fois et présentent une densité d'énergie élevée.
FR7816724A 1977-09-26 1978-06-05 Batteries reversibles a cathode en chalcogenure metallique, a anode en metal alcalin et a electrolyte non aqueux Granted FR2404311A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/836,314 US4104451A (en) 1977-09-26 1977-09-26 Alkali metal anode/chalcogenide cathode reversible batteries having alkali metal polyaryl metallic compound electrolytes

Publications (2)

Publication Number Publication Date
FR2404311A1 true FR2404311A1 (fr) 1979-04-20
FR2404311B1 FR2404311B1 (fr) 1982-08-20

Family

ID=25271700

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7816724A Granted FR2404311A1 (fr) 1977-09-26 1978-06-05 Batteries reversibles a cathode en chalcogenure metallique, a anode en metal alcalin et a electrolyte non aqueux

Country Status (10)

Country Link
US (1) US4104451A (fr)
JP (1) JPS5450927A (fr)
BE (1) BE870730A (fr)
CA (1) CA1089928A (fr)
CH (1) CH643689A5 (fr)
DE (1) DE2840795A1 (fr)
FR (1) FR2404311A1 (fr)
GB (1) GB1559767A (fr)
IT (1) IT1096587B (fr)
NL (1) NL188822C (fr)

Families Citing this family (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4248946A (en) * 1978-10-30 1981-02-03 Exxon Research & Engineering Co. Cell having an alkali metal anode, a fluorinated carbon cathode and an electrolyte which includes an alkali metal halide salt and a solvent system consisting of an ether solvent and a cyclic carbonate cosolvent
US4201839A (en) * 1978-11-01 1980-05-06 Exxon Research And Engineering Co. Cell containing an alkali metal anode, a solid cathode, and a closoborane and/or closocarborane electrolyte
US4215188A (en) * 1979-08-13 1980-07-29 Honeywell Inc. Rechargeable electrochemical cell
US4416960A (en) * 1980-01-28 1983-11-22 Exxon Research And Engineering Co. Li/TiS2 Current producing system
US4284692A (en) * 1980-04-28 1981-08-18 Exxon Research & Engineering Co. Compositions for stabilizing electrolytes in Li/TiS2 systems
US4293623A (en) * 1980-07-03 1981-10-06 Exxon Research & Engineering Co. Electrolytes for alkali-metal electrochemical devices
US4279976A (en) * 1980-07-07 1981-07-21 Exxon Research & Engineering Co. Pseudohalide-containing salts for electrolytes of alkali-metal electrochemical devices
US4456520A (en) * 1982-03-01 1984-06-26 Medtronic, Inc. Porous rigid titanium disulfide electrodes for electrochemical cells and method for preparing same
US4522901A (en) * 1983-03-16 1985-06-11 Allied Corporation Secondary battery containing organoborate electrolyte
US4894302A (en) * 1985-06-14 1990-01-16 The Dow Chemical Company Alkaline earth metal anode-containing cell having electrolyte of organometallic alkaline earth metal salt and organic solvent
US5021368A (en) * 1988-09-29 1991-06-04 The Dow Chemical Company Novel ceramic-metal compounds
US5462821A (en) * 1993-11-19 1995-10-31 Dowa Mining Co., Ltd. Gallium based active material for the negative electrode, a negative electrode using the same, and batteries using said negative electrode
FR2715508B1 (fr) * 1994-01-21 1996-03-29 Renata Ag Générateur électrochimique primaire ou secondaire à électrode nanoparticulaire.
CA2216898C (fr) * 1997-09-26 2005-03-22 Moli Energy (1990) Limited Additifs ameliores pour la protection contre la surcharge des piles rechargeables au lithium, non aqueuses
US6316141B1 (en) * 1999-10-18 2001-11-13 Bar Ilan University High-energy, rechargeable, electrochemical cells with non-aqueous electrolytes
US6436583B1 (en) * 2000-08-04 2002-08-20 Moltech Corporation Storage life enhancement in lithium-sulfur batteries
US8828610B2 (en) * 2004-01-06 2014-09-09 Sion Power Corporation Electrolytes for lithium sulfur cells
US7358012B2 (en) 2004-01-06 2008-04-15 Sion Power Corporation Electrolytes for lithium sulfur cells
US7019494B2 (en) * 2004-01-06 2006-03-28 Moltech Corporation Methods of charging lithium sulfur cells
US10297827B2 (en) 2004-01-06 2019-05-21 Sion Power Corporation Electrochemical cell, components thereof, and methods of making and using same
US20060024579A1 (en) 2004-07-27 2006-02-02 Vladimir Kolosnitsyn Battery electrode structure and method for manufacture thereof
WO2006077380A2 (fr) * 2005-01-18 2006-07-27 Oxis Energy Limited Ameliorations apportees a des compositions d'electrolyte destinees a des batteries mettant en oeuvre du soufre ou des composes de soufre
WO2006100464A2 (fr) 2005-03-22 2006-09-28 Oxis Energy Limited Batterie au sulfure de lithium et son procede de production
WO2007021151A1 (fr) * 2005-08-19 2007-02-22 Lg Chem, Ltd. Electrolyte contenant un melange eutectique et dispositif electrochimique utilisant ledit electrolyte
US9012072B2 (en) * 2007-01-25 2015-04-21 Bar-Ilan University Rechargeable magnesium battery
CN103283064B (zh) 2010-08-24 2017-07-11 锡安能量公司 用于在电化学电池中使用的电解质材料
US8951680B2 (en) 2011-03-08 2015-02-10 Pellion Technologies, Inc. Rechargeable magnesium ion cell components and assembly
US8361661B2 (en) * 2011-03-08 2013-01-29 Pellion Technologies Inc. Rechargeable magnesium ion cell components and assembly
US8735002B2 (en) 2011-09-07 2014-05-27 Sion Power Corporation Lithium sulfur electrochemical cell including insoluble nitrogen-containing compound
EP2629352A1 (fr) 2012-02-17 2013-08-21 Oxis Energy Limited Électrode de feuille métallique renforcée
US9577289B2 (en) 2012-12-17 2017-02-21 Sion Power Corporation Lithium-ion electrochemical cell, components thereof, and methods of making and using same
ES2671399T3 (es) 2013-03-25 2018-06-06 Oxis Energy Limited Un método para cargar una celda de litio-azufre
EP2784850A1 (fr) 2013-03-25 2014-10-01 Oxis Energy Limited Procédé de cycle d'une cellule au lithium-soufre
EP2784851B1 (fr) 2013-03-25 2015-08-19 Oxis Energy Limited Procédé de charge d'une cellule au lithium-soufre
GB2517228B (en) 2013-08-15 2016-03-02 Oxis Energy Ltd Laminate cell
US9899705B2 (en) 2013-12-17 2018-02-20 Oxis Energy Limited Electrolyte for a lithium-sulphur cell
KR102445459B1 (ko) 2014-05-30 2022-09-20 옥시스 에너지 리미티드 리튬-황 셀

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3935025A (en) * 1972-07-06 1976-01-27 Etat Francais Electric storage battery providing high energy density

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3764385A (en) * 1970-12-22 1973-10-09 Exxon Research Engineering Co Electric battery using complexed inorganic lithium salts as charge transfer agent
US4009052A (en) * 1975-02-24 1977-02-22 Exxon Research And Engineering Company Chalcogenide battery
US4002492A (en) * 1975-07-01 1977-01-11 Exxon Research And Engineering Company Rechargeable lithium-aluminum anode
US4060674A (en) * 1976-12-14 1977-11-29 Exxon Research And Engineering Company Alkali metal anode-containing cells having electrolytes of organometallic-alkali metal salts and organic solvents
JPS5856232A (ja) * 1981-09-30 1983-04-02 Toshiba Corp 磁気記録媒体

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3935025A (en) * 1972-07-06 1976-01-27 Etat Francais Electric storage battery providing high energy density

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
EXBK/65 *

Also Published As

Publication number Publication date
NL188822B (nl) 1992-05-06
FR2404311B1 (fr) 1982-08-20
DE2840795A1 (de) 1979-04-05
US4104451A (en) 1978-08-01
IT1096587B (it) 1985-08-26
JPS5450927A (en) 1979-04-21
BE870730A (fr) 1979-03-26
JPS6238830B2 (fr) 1987-08-19
NL7805714A (nl) 1979-03-28
DE2840795C2 (fr) 1988-02-25
CA1089928A (fr) 1980-11-18
NL188822C (nl) 1992-10-01
CH643689A5 (de) 1984-06-15
IT7824761A0 (it) 1978-06-20
GB1559767A (en) 1980-01-23

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