FR2395274A1 - Procede de preparation de complexes organo-magnesiens - Google Patents
Procede de preparation de complexes organo-magnesiensInfo
- Publication number
- FR2395274A1 FR2395274A1 FR7818209A FR7818209A FR2395274A1 FR 2395274 A1 FR2395274 A1 FR 2395274A1 FR 7818209 A FR7818209 A FR 7818209A FR 7818209 A FR7818209 A FR 7818209A FR 2395274 A1 FR2395274 A1 FR 2395274A1
- Authority
- FR
- France
- Prior art keywords
- formula
- complexes
- magnesian
- carbon atoms
- defined above
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title abstract 3
- 239000011777 magnesium Substances 0.000 abstract 4
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 125000002734 organomagnesium group Chemical group 0.000 abstract 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical group [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical compound [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 125000001309 chloro group Chemical group Cl* 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 229910052740 iodine Chemical group 0.000 abstract 1
- 229910052744 lithium Chemical group 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- -1 phenyl halide Chemical class 0.000 abstract 1
- 239000011591 potassium Chemical group 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/02—Magnesium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/061—Aluminium compounds with C-aluminium linkage
- C07F5/062—Al linked exclusively to C
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
La présente invention a pour objet un procédé de préparation de complexes organo-magnésiens d'hydrocarbures solubles de formule : (RR'Mg)m , (R3 AL)n dans laquelle : R est un radical alkyle primaire, secondaire ou tertiaire comportant 1 à 25 atomes de carbone; R' est un radical alkyle primaire comportant 1 à 25 atomes de carbone, et/ou un radical phényle; m et n sont des nombres tels que le rapport m/n soit de l'ordre de 1 ou supérieur; ce procédé comprenant les deux étapes suivantes : a. à faire réagir du magnésium métallique avec un halogénure d'alkyle ou de phényle de formule R'X où R' est tel que défini ci-dessus et X est un atome de chlore, brome ou iode à une température comprise entre 20 et 200 degrés C, le rapport molaire Mg/X étant compris entre 1 et 2; b. à ajouter au mélange réactionnel résultant un organo-aluminate métallique de formule R4 AlM dans laquelle R est tel que défini ci-dessus et M est du sodium, du potassium ou du lithium, le rapport molaire M/Mg employé dans l'étape a. étant inférieur à 1/1. Elle se rapporte à un procédé de préparation de complexes organo-magnésiens.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/809,750 US4128501A (en) | 1977-06-24 | 1977-06-24 | Process for the preparation of organo-magnesium complexes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2395274A1 true FR2395274A1 (fr) | 1979-01-19 |
| FR2395274B1 FR2395274B1 (fr) | 1984-08-17 |
Family
ID=25202137
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR7818209A Granted FR2395274A1 (fr) | 1977-06-24 | 1978-06-19 | Procede de preparation de complexes organo-magnesiens |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US4128501A (fr) |
| JP (1) | JPS5412328A (fr) |
| AU (1) | AU518020B2 (fr) |
| BE (1) | BE868388A (fr) |
| BR (1) | BR7803893A (fr) |
| CA (1) | CA1103691A (fr) |
| DD (1) | DD137232A5 (fr) |
| DE (1) | DE2826498C2 (fr) |
| ES (1) | ES471082A1 (fr) |
| FR (1) | FR2395274A1 (fr) |
| GB (1) | GB2000142B (fr) |
| IT (1) | IT1193745B (fr) |
| NL (1) | NL7806819A (fr) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4276191A (en) * | 1979-06-04 | 1981-06-30 | Standard Oil Company (Indiana) | Catalyst and process for polymerization of alpha-olefins |
| US4263217A (en) * | 1979-09-24 | 1981-04-21 | Texas Alkyls, Inc. | Hydrocarbon-soluble magnesium-aluminum compositions |
| US4297240A (en) * | 1980-02-25 | 1981-10-27 | The General Tire & Rubber Company | Solution polymerization |
| US4615843A (en) * | 1984-09-05 | 1986-10-07 | Texas Alkyls, Inc. | Treatment of hydrocarbon solutions of dialkylmagnesium compounds to reduce the content of soluble chloride-containing complexes |
| US5141667A (en) * | 1987-03-30 | 1992-08-25 | Fmc Corporation | Preparation of organometallic and organobimetallic compounds |
| US4976886A (en) * | 1987-03-30 | 1990-12-11 | Lithium Corporation Of America | Preparation of organometallic and organobimetallic compounds |
| DE3943841C2 (de) * | 1988-02-25 | 2000-07-13 | Lithium Corp Of America Gaston | Bimetallische Organoamid-Zusammensetzungen und Verfahren zu ihrer Herstellung |
| US5002689A (en) * | 1988-02-25 | 1991-03-26 | Lithium Corporation Of America | Preparation of organometallic amide compositions |
| US5171467A (en) * | 1990-03-06 | 1992-12-15 | Fmc Corporation | Synthesis of organometallic/organobimetallic compositions |
| WO2021233930A1 (fr) | 2020-05-20 | 2021-11-25 | Lanxess Organometallics Gmbh | Nouveaux composés d'organo-magnésium et leur utilisation |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2232685A1 (de) * | 1971-07-13 | 1973-01-18 | Texas Alkyls Inc | Organische aluminium-magnesium komplexverbindungen, verfahren zu ihrer herstellung und ihre verwendung als polymerisationskatalysatoren |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL139981B (nl) * | 1969-06-04 | 1973-10-15 | Stamicarbon | Werkwijze voor de bereiding van oplosbare complexen van magnesiumdialkylen en organo-aluminiumverbindingen. |
-
1977
- 1977-06-24 US US05/809,750 patent/US4128501A/en not_active Expired - Lifetime
-
1978
- 1978-06-14 CA CA305,405A patent/CA1103691A/fr not_active Expired
- 1978-06-16 JP JP7228978A patent/JPS5412328A/ja active Granted
- 1978-06-16 DE DE2826498A patent/DE2826498C2/de not_active Expired
- 1978-06-19 BR BR787803893A patent/BR7803893A/pt unknown
- 1978-06-19 FR FR7818209A patent/FR2395274A1/fr active Granted
- 1978-06-22 IT IT49972/78A patent/IT1193745B/it active
- 1978-06-23 DD DD78206244A patent/DD137232A5/xx unknown
- 1978-06-23 NL NL7806819A patent/NL7806819A/xx not_active Application Discontinuation
- 1978-06-23 BE BE2057087A patent/BE868388A/xx not_active IP Right Cessation
- 1978-06-23 AU AU37427/78A patent/AU518020B2/en not_active Expired
- 1978-06-23 ES ES471082A patent/ES471082A1/es not_active Expired
- 1978-06-23 GB GB7827705A patent/GB2000142B/en not_active Expired
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2232685A1 (de) * | 1971-07-13 | 1973-01-18 | Texas Alkyls Inc | Organische aluminium-magnesium komplexverbindungen, verfahren zu ihrer herstellung und ihre verwendung als polymerisationskatalysatoren |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6123798B2 (fr) | 1986-06-07 |
| BE868388A (nl) | 1978-12-27 |
| AU518020B2 (en) | 1981-09-10 |
| BR7803893A (pt) | 1979-02-20 |
| DD137232A5 (de) | 1979-08-22 |
| IT1193745B (it) | 1988-08-24 |
| DE2826498A1 (de) | 1979-01-11 |
| NL7806819A (nl) | 1978-12-28 |
| GB2000142A (en) | 1979-01-04 |
| DE2826498C2 (de) | 1986-04-30 |
| IT7849972A0 (it) | 1978-06-22 |
| GB2000142B (en) | 1982-02-24 |
| FR2395274B1 (fr) | 1984-08-17 |
| AU3742778A (en) | 1980-01-03 |
| CA1103691A (fr) | 1981-06-23 |
| JPS5412328A (en) | 1979-01-30 |
| US4128501A (en) | 1978-12-05 |
| ES471082A1 (es) | 1979-01-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |