FR2390493A1 - Procede de preparation d'olefines - Google Patents
Procede de preparation d'olefinesInfo
- Publication number
- FR2390493A1 FR2390493A1 FR7813505A FR7813505A FR2390493A1 FR 2390493 A1 FR2390493 A1 FR 2390493A1 FR 7813505 A FR7813505 A FR 7813505A FR 7813505 A FR7813505 A FR 7813505A FR 2390493 A1 FR2390493 A1 FR 2390493A1
- Authority
- FR
- France
- Prior art keywords
- zeolite
- olefins
- relates
- preparation process
- stage
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- 238000002360 preparation method Methods 0.000 title abstract 2
- 229910021536 Zeolite Inorganic materials 0.000 abstract 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 2
- 238000005984 hydrogenation reaction Methods 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 239000010457 zeolite Substances 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000000470 constituent Substances 0.000 abstract 1
- 238000005336 cracking Methods 0.000 abstract 1
- 239000012013 faujasite Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-O oxonium Chemical compound [OH3+] XLYOFNOQVPJJNP-UHFFFAOYSA-O 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- 239000003208 petroleum Substances 0.000 abstract 1
- -1 rare earth ion Chemical class 0.000 abstract 1
- 229910052761 rare earth metal Inorganic materials 0.000 abstract 1
- 150000003568 thioethers Chemical group 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
- C10G47/12—Inorganic carriers
- C10G47/16—Crystalline alumino-silicate carriers
- C10G47/20—Crystalline alumino-silicate carriers the catalyst containing other metals or compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/16—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/44—Hydrogenation of the aromatic hydrocarbons
- C10G45/46—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used
- C10G45/54—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/20—C2-C4 olefins
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Steroid Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
La présente invention a pour objet un procédé de préparation d'oléfines comprenant deux étapes, à savoir, une première étape d'hydrogénation par l'hydrogene de fractions pétrolières lourdes en présence d'un catalyseur d'hydrogénation, et une deuxième étape de craquage thermique de la fraction hydrogénée résultante en présence de vapeur d'eau. Elle est caractérisée en ce qu'on utilise en tant que catalyseur d'hydrogénation une zéolite ayant la structure de la faujasite et contenant des éléments des Sous-Groupes VI à VII de la Classification Périodique, les constituants alcalins de la zéolite ayant au moins partiellement été échangés avec un ion ammonium, hydronium, alcalino-terreux et/ou de terres rares et en ce que lesdits éléments sont sous forme métallique, ionique, oxydée et/ou sulfurée. Elle se rapporte à de tels procédés.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2721503 | 1977-05-12 | ||
DE19782815859 DE2815859C2 (de) | 1978-04-12 | 1978-04-12 | Verfahren zur Herstellung von Olefinen |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2390493A1 true FR2390493A1 (fr) | 1978-12-08 |
FR2390493B1 FR2390493B1 (fr) | 1985-04-26 |
Family
ID=25772016
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7813505A Expired FR2390493B1 (fr) | 1977-05-12 | 1978-05-08 | Procede de preparation d'olefines |
Country Status (9)
Country | Link |
---|---|
US (1) | US4188281A (fr) |
JP (1) | JPS5416407A (fr) |
BR (1) | BR7802986A (fr) |
ES (1) | ES469731A1 (fr) |
FR (1) | FR2390493B1 (fr) |
GB (1) | GB1566677A (fr) |
IT (1) | IT1094821B (fr) |
NL (1) | NL7805119A (fr) |
NO (1) | NO152758C (fr) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2806854C2 (de) * | 1978-02-17 | 1986-01-02 | Linde Ag, 6200 Wiesbaden | Verfahren zum thermischen Spalten von Kohlenwasserstoffen zu Olefinen |
DE2840986C2 (de) * | 1978-09-21 | 1987-03-26 | Linde Ag, 6200 Wiesbaden | Verfahren zur Aufarbeitung der bei der Spaltung von Kohlenwasserstoffen entstehenden über 200 °C siedenden Kohlenwasserstoff-Fraktionen |
DE2840987A1 (de) * | 1978-09-21 | 1980-04-03 | Linde Ag | Verfahren zum spalten von kohlenwasserstoffen |
DE2941851A1 (de) * | 1979-10-16 | 1981-05-14 | Linde Ag, 6200 Wiesbaden | Verfahren zur hydrierung schwerer kohlenwasserstoffe |
US4305808A (en) * | 1980-04-14 | 1981-12-15 | Mobil Oil Corporation | Catalytic hydrocracking |
JPS585393A (ja) * | 1981-07-01 | 1983-01-12 | Asahi Chem Ind Co Ltd | 重質油の熱分解方法 |
DE3232395A1 (de) * | 1982-08-31 | 1984-03-01 | Linde Ag, 6200 Wiesbaden | Verfahren zur herstellung von olefinen |
JPS60219295A (ja) * | 1984-04-16 | 1985-11-01 | Res Assoc Residual Oil Process<Rarop> | 重質炭化水素油の水素化処理方法 |
JPS61289049A (ja) * | 1985-05-27 | 1986-12-19 | Agency Of Ind Science & Technol | プロピレンの製造方法 |
JPH0157882U (fr) * | 1987-10-07 | 1989-04-11 | ||
US4962264A (en) * | 1989-10-23 | 1990-10-09 | Betz Laboratories, Inc. | Methods for retarding coke formation during pyrolytic hydrocarbon processing |
US5045174A (en) * | 1990-03-21 | 1991-09-03 | Exxon Chemical Patents Inc. | Process for the production of heartcut distillate resin precursors |
US6190533B1 (en) * | 1996-08-15 | 2001-02-20 | Exxon Chemical Patents Inc. | Integrated hydrotreating steam cracking process for the production of olefins |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1503063A (fr) * | 1965-11-30 | 1967-11-24 | Standard Oil Co | Catalyseur pour l'hydrogénation d'hydrocarbures et procédé utilisant ce catalyseur |
DE2164951A1 (de) * | 1971-01-06 | 1972-07-20 | Bp Chemicals International Ltd., London | Verfahren zur Herstellung gasförmiger Olefine |
FR2221510A1 (fr) * | 1973-03-15 | 1974-10-11 | Mitsubishi Petrochemical Co | |
US3875081A (en) * | 1969-10-24 | 1975-04-01 | Union Oil Co | Hydrocarbon conversion catalyst |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3510258A (en) * | 1966-07-19 | 1970-05-05 | Engelhard Ind Inc | Process for the manufacture of faujasite-type crystalline aluminosilicates |
US3472909A (en) * | 1967-02-27 | 1969-10-14 | Universal Oil Prod Co | Process for producing olefinic hydrocarbons |
GB1173469A (en) * | 1967-03-23 | 1969-12-10 | British Petroleum Co | Improvements relating to the Hydrogenation of Aromatics |
US3598721A (en) * | 1969-06-02 | 1971-08-10 | Universal Oil Prod Co | Gasoline producing process |
US3720729A (en) * | 1970-11-02 | 1973-03-13 | Lummus Co | Pyrolysis of hydrotreated feedstocks |
US3779899A (en) * | 1971-05-03 | 1973-12-18 | D Mears | Hydrogenation of aromatic hydrocarbons |
US3723299A (en) * | 1971-11-23 | 1973-03-27 | Sun Research Development | Hydrogenation process |
GB1383229A (en) * | 1972-11-08 | 1975-02-05 | Bp Chem Int Ltd | Production of gaseous olefins from petroleum residue feedstocks |
GB1537822A (en) * | 1975-01-22 | 1979-01-04 | Shell Int Research | Process for the production of normally gaseous olefins |
US4017380A (en) * | 1975-07-18 | 1977-04-12 | Gulf Research & Development Company | Sequential residue hydrodesulfurization and thermal cracking operations in a common reactor |
US4061562A (en) * | 1976-07-12 | 1977-12-06 | Gulf Research & Development Company | Thermal cracking of hydrodesulfurized residual petroleum oils |
US4097363A (en) * | 1976-07-12 | 1978-06-27 | Gulf Research & Development Company | Thermal cracking of light gas oil at high severity to ethylene |
-
1978
- 1978-05-08 FR FR7813505A patent/FR2390493B1/fr not_active Expired
- 1978-05-11 JP JP5503878A patent/JPS5416407A/ja active Pending
- 1978-05-11 BR BR7802986A patent/BR7802986A/pt unknown
- 1978-05-11 ES ES469731A patent/ES469731A1/es not_active Expired
- 1978-05-11 IT IT23268/78A patent/IT1094821B/it active
- 1978-05-11 NO NO781678A patent/NO152758C/no unknown
- 1978-05-11 GB GB18869/78A patent/GB1566677A/en not_active Expired
- 1978-05-11 NL NL7805119A patent/NL7805119A/xx not_active Application Discontinuation
- 1978-05-12 US US05/905,486 patent/US4188281A/en not_active Expired - Lifetime
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1503063A (fr) * | 1965-11-30 | 1967-11-24 | Standard Oil Co | Catalyseur pour l'hydrogénation d'hydrocarbures et procédé utilisant ce catalyseur |
US3875081A (en) * | 1969-10-24 | 1975-04-01 | Union Oil Co | Hydrocarbon conversion catalyst |
DE2164951A1 (de) * | 1971-01-06 | 1972-07-20 | Bp Chemicals International Ltd., London | Verfahren zur Herstellung gasförmiger Olefine |
FR2121579A1 (fr) * | 1971-01-06 | 1972-08-25 | Bp Chem Int Ltd | |
FR2221510A1 (fr) * | 1973-03-15 | 1974-10-11 | Mitsubishi Petrochemical Co |
Also Published As
Publication number | Publication date |
---|---|
ES469731A1 (es) | 1978-12-16 |
IT7823268A0 (it) | 1978-05-11 |
IT1094821B (it) | 1985-08-10 |
NO152758B (no) | 1985-08-05 |
BR7802986A (pt) | 1979-01-23 |
NL7805119A (nl) | 1978-11-14 |
US4188281A (en) | 1980-02-12 |
JPS5416407A (en) | 1979-02-07 |
GB1566677A (en) | 1980-05-08 |
NO781678L (no) | 1978-11-14 |
NO152758C (no) | 1985-11-13 |
FR2390493B1 (fr) | 1985-04-26 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |