FR2384036A1 - Supported cathode esp. for sodium chloride electrolysis - having iron or nickel (alloy) support plated with iron, cobalt or nickel - Google Patents

Supported cathode esp. for sodium chloride electrolysis - having iron or nickel (alloy) support plated with iron, cobalt or nickel

Info

Publication number
FR2384036A1
FR2384036A1 FR7807957A FR7807957A FR2384036A1 FR 2384036 A1 FR2384036 A1 FR 2384036A1 FR 7807957 A FR7807957 A FR 7807957A FR 7807957 A FR7807957 A FR 7807957A FR 2384036 A1 FR2384036 A1 FR 2384036A1
Authority
FR
France
Prior art keywords
nickel
iron
pref
alloy
ion exchange
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7807957A
Other languages
French (fr)
Other versions
FR2384036B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tokuyama Corp
Original Assignee
Tokuyama Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2980577A external-priority patent/JPS53115674A/en
Priority claimed from JP6585477A external-priority patent/JPS541282A/en
Priority claimed from JP52075610A external-priority patent/JPS6047352B2/en
Priority claimed from JP12575377A external-priority patent/JPS5460293A/en
Priority claimed from JP12879477A external-priority patent/JPS5462933A/en
Application filed by Tokuyama Corp filed Critical Tokuyama Corp
Publication of FR2384036A1 publication Critical patent/FR2384036A1/en
Application granted granted Critical
Publication of FR2384036B1 publication Critical patent/FR2384036B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00—Electroplating: Baths therefor
    • C25D3/02—Electroplating: Baths therefor from solutions
    • C25D3/12—Electroplating: Baths therefor from solutions of nickel or cobalt
    • C25D3/14—Electroplating: Baths therefor from solutions of nickel or cobalt from baths containing acetylenic or heterocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/34—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis
    • C25B1/46—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis in diaphragm cells
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Electroplating And Plating Baths Therefor (AREA)

Abstract

Electrolytic cell cathode consists of a Fe or Ni (alloy) support with a surface coating of Gp. VIII metal(s), pref. Fe, Co or Ni, produced by electroplating or thermal deposition. This coating pref. is 5-100 mu m. thick. Cathode is used specifically for the electrolysis of NaCl (to NaOH) in a cell with an ion exchange membrane as diaphragm, pref. with a perfluorocarbon main chain and ion exchange gps. in the side chains. It meets the requirements for a low H2 over-voltage, hence low power consumption and durability. In an example, expanded steel was electroplated with Cu from an alkaline cyanide bath and then with Ni from a thiocyanate bath. When used in conjunction with a sulphonated fluorocarbon polymer ion exchange membrane for the electrolysis of aq. 5 N NaCl soln. to aq. 6 N NaOH soln., the concn. of hypochlorite formed remained low (1 ppm.) and the electrode potential constant.
FR7807957A 1977-03-19 1978-03-20 Supported cathode esp. for sodium chloride electrolysis - having iron or nickel (alloy) support plated with iron, cobalt or nickel Granted FR2384036A1 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
JP2980577A JPS53115674A (en) 1977-03-19 1977-03-19 Cathod for use in electrolysis
JP6585477A JPS541282A (en) 1977-06-06 1977-06-06 Cathode
JP52075610A JPS6047352B2 (en) 1977-06-27 1977-06-27 Cathode manufacturing method
JP12575377A JPS5460293A (en) 1977-10-21 1977-10-21 Electrolysis of alkale metal salts
JP12879477A JPS5462933A (en) 1977-10-28 1977-10-28 Nickel electroplating method

Publications (2)

Publication Number Publication Date
FR2384036A1 true FR2384036A1 (en) 1978-10-13
FR2384036B1 FR2384036B1 (en) 1980-04-04

Family

ID=27521176

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7807957A Granted FR2384036A1 (en) 1977-03-19 1978-03-20 Supported cathode esp. for sodium chloride electrolysis - having iron or nickel (alloy) support plated with iron, cobalt or nickel

Country Status (2)

Country Link
DE (1) DE2811472A1 (en)
FR (1) FR2384036A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0085431A1 (en) * 1982-02-04 1983-08-10 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha A corrosion-resisting electrolytic cell
EP0849378A1 (en) * 1996-12-17 1998-06-24 Tosoh Corporation Low hydrogen overvoltage cathode and process for production thereof

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4298447A (en) * 1980-03-07 1981-11-03 E. I. Du Pont De Nemours And Company Cathode and cell for lowering hydrogen overvoltage in a chlor-akali cell
DE3322169A1 (en) * 1983-06-21 1985-01-10 Sigri Elektrographit Gmbh, 8901 Meitingen CATHODE FOR AQUEOUS ELECTROLYSIS
DE3344416A1 (en) * 1983-12-08 1985-12-05 Sigri GmbH, 8901 Meitingen Method of producing a cathode for aqueous electrolysis
DE102006017356B4 (en) * 2006-04-11 2015-12-17 Flabeg Deutschland Gmbh Process for producing a multilayer system on a support, in particular in an electrochromic element
JP4857255B2 (en) * 2007-12-17 2012-01-18 株式会社日立製作所 Electrolysis electrode, method for producing the same, and hydrogen production apparatus
DE102010023418A1 (en) 2010-06-11 2011-12-15 Uhde Gmbh Single or multi-sided substrate coating

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE411528C (en) * 1923-11-02 1925-03-30 Basf Ag Cathode for electrolytic cells, especially for water decomposition
US3282808A (en) * 1961-06-14 1966-11-01 Kandler Ludwig Nickel impregnated porous cathode and method of making same
FR2259919A1 (en) * 1974-02-04 1975-08-29 Diamond Shamrock Corp

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1818579A (en) * 1923-11-01 1931-08-11 Ig Farbenindustrie Ag Electrode

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE411528C (en) * 1923-11-02 1925-03-30 Basf Ag Cathode for electrolytic cells, especially for water decomposition
US3282808A (en) * 1961-06-14 1966-11-01 Kandler Ludwig Nickel impregnated porous cathode and method of making same
FR2259919A1 (en) * 1974-02-04 1975-08-29 Diamond Shamrock Corp

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0085431A1 (en) * 1982-02-04 1983-08-10 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha A corrosion-resisting electrolytic cell
EP0849378A1 (en) * 1996-12-17 1998-06-24 Tosoh Corporation Low hydrogen overvoltage cathode and process for production thereof
US5944966A (en) * 1996-12-17 1999-08-31 Tosoh Corporation Low hydrogen overvoltage cathode and process for production thereof
EP1626108A1 (en) * 1996-12-17 2006-02-15 Tosoh Corporation Low hydrogen overvoltage cathode and process for production thereof

Also Published As

Publication number Publication date
DE2811472A1 (en) 1978-09-21
DE2811472C2 (en) 1989-11-02
FR2384036B1 (en) 1980-04-04

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