FR2380310A1 - Polyepoxyester diluable a l'eau renfermant un acide monocarboxylique comme agent de reglage du poids moleculaire - Google Patents

Polyepoxyester diluable a l'eau renfermant un acide monocarboxylique comme agent de reglage du poids moleculaire

Info

Publication number
FR2380310A1
FR2380310A1 FR7804149A FR7804149A FR2380310A1 FR 2380310 A1 FR2380310 A1 FR 2380310A1 FR 7804149 A FR7804149 A FR 7804149A FR 7804149 A FR7804149 A FR 7804149A FR 2380310 A1 FR2380310 A1 FR 2380310A1
Authority
FR
France
Prior art keywords
acid
monocarboxylic acid
equivalents
ester
epoxy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
FR7804149A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Publication of FR2380310A1 publication Critical patent/FR2380310A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/42—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/42—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof
    • C08G59/4292—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof together with monocarboxylic acids
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31511—Of epoxy ether
    • Y10T428/31529—Next to metal

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Epoxy Resins (AREA)
  • Epoxy Compounds (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

L'invention concerne un polyépoxyester, caractérisé en ce qu'il comprend un adduct d'ester d'une résine 1,2-époxy polyfonctionnelle et d'un acide monocarboxylique aliphatique en C8 -C18 environ, ou leurs mélanges, et d'un acide dicarboxylique aliphatique en environ C6 -C10 , le rapport de l'acide dicarboxylique à l'acide monocarboxylique étant d'environ 2 à 5, rapporté au poids équivalent de chaque acide, le rapport des equivalents d'acide carboxylique aliphatique total (acide monocarboxylique plus acide dicarboxylique) aux équivalents d'époxyde étant de 1,0 à 1,2 et de l'anhydride trimellitique, le rapport des équivalents d'anhydride dans ledit anhydride trimellitique aux équivalents d'epoxy étant de 0,15 à 0,35, la réaction entre ladite résine époxy, ledit acide monocarboxylique et ledit acide dicarboxylique étant effectuée dans un solvant au reflux, à température élevée, jusqu'à ce que l'indice d'acide soit de 3-22 et la teneur en époxy de 0,025 à 0,035 milliéquivalent par gramme, pour obtenir un ester initial et réaction dudit ester initial avec l'anhydride trimellitique à une température moins élevée, jusqu'à ce que l'indice d'acide alcoolique et l'indice d'acide aqueux soient sensiblement égaux.
FR7804149A 1977-02-14 1978-02-14 Polyepoxyester diluable a l'eau renfermant un acide monocarboxylique comme agent de reglage du poids moleculaire Withdrawn FR2380310A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/768,312 US4098735A (en) 1977-02-14 1977-02-14 Water reducible epoxy ester using monocarboxylic acid to control molecular weight

Publications (1)

Publication Number Publication Date
FR2380310A1 true FR2380310A1 (fr) 1978-09-08

Family

ID=25082142

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7804149A Withdrawn FR2380310A1 (fr) 1977-02-14 1978-02-14 Polyepoxyester diluable a l'eau renfermant un acide monocarboxylique comme agent de reglage du poids moleculaire

Country Status (14)

Country Link
US (1) US4098735A (fr)
JP (1) JPS53102995A (fr)
AU (1) AU519841B2 (fr)
BE (1) BE863915A (fr)
BR (1) BR7800881A (fr)
CA (1) CA1124443A (fr)
DE (1) DE2805902A1 (fr)
DK (1) DK64178A (fr)
FR (1) FR2380310A1 (fr)
GB (1) GB1580772A (fr)
IT (1) IT1095408B (fr)
NL (1) NL7801657A (fr)
NO (1) NO780493L (fr)
ZA (1) ZA78871B (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0015917A4 (fr) * 1978-03-09 1980-07-17 Kazys Sekmakas Copolymeres esters epoxydes solubles dans l'eau utilises pour les seaux hygieniques.

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2851962A1 (de) * 1978-03-18 1980-06-19 Hoechst Ag Verwendung eines wasserloeslichen reaktiven bindemittels fuer klebstoffe
US4304804A (en) * 1978-09-18 1981-12-08 The Continental Group, Inc. Metal container coatings having a reduced tendency to absorb odors
US4212776A (en) * 1978-10-16 1980-07-15 Mobil Oil Corporation Self crosslinking water dispersible epoxy ester-acrylate polymers
US4222919A (en) * 1978-12-20 1980-09-16 Inmont Corporation Aqueous organic coatings for metal surfaces
US4413015A (en) * 1979-06-21 1983-11-01 Mobil Oil Corporation Storage stable water-dilutable acid adducted epoxy based coating for metal food contact surfaces
US4267300A (en) * 1979-10-01 1981-05-12 Minnesota Mining And Manufacturing Company Epoxy resin powder for applying electrical-insulating coating to wire
US4331574A (en) * 1980-04-25 1982-05-25 Shell Oil Company Process for preparation of water-thinnable epoxy resins
DE3109900A1 (de) * 1981-03-14 1982-09-23 Hoechst Ag, 6000 Frankfurt Mit wasser verduennbares epoxyd, verfahren zu seiner herstellung und dessen verwendung
CA1221193A (fr) * 1982-06-14 1987-04-28 Panagiotis I. Kordomenos Resine epoxyde-ester et nouvelle composition de revetement thermodurcissable qui en renferme
JPS62500178A (ja) * 1984-12-04 1987-01-22 ザ　ダウ　ケミカル　カンパニ− 熱安定性熱可塑性樹脂の製造方法
US4855366A (en) * 1988-06-22 1989-08-08 The Dow Chemical Company Monocarboxylic acid derivatives of aromatic based epoxy resins
US4855385A (en) * 1988-06-22 1989-08-08 The Dow Chemical Company Monocarboxylic acid derivatives of aliphatic based epoxy resins
US20050043490A1 (en) * 1993-05-26 2005-02-24 Klee Joachim E. Polymerizable compounds and compositions
US6369164B1 (en) 1993-05-26 2002-04-09 Dentsply G.M.B.H. Polymerizable compounds and compositions
US6353061B1 (en) * 1993-05-26 2002-03-05 Dentsply Gmbh α, ω-methacrylate terminated macromonomer compounds
US5998499A (en) 1994-03-25 1999-12-07 Dentsply G.M.B.H. Liquid crystalline (meth)acrylate compounds, composition and method
CA2146816A1 (fr) * 1994-04-22 1995-10-23 Joachim E. Klee Methode et composition pour la preparation d'un produit polymerique dentaire
EP1584638A1 (fr) * 2004-03-29 2005-10-12 Imperial Chemical Industries Plc. Composition de revêtement à base de résines epoxy modifiées
JP5632603B2 (ja) * 2009-09-30 2014-11-26 互応化学工業株式会社 カルボキシル基含有樹脂、それを含有する組成物及び硬化物、並びにカルボキシル基含有樹脂の製造方法
US11673995B2 (en) 2019-08-08 2023-06-13 Ppg Industries Ohio, Inc. Polyol polymers, methods of preparing such polymers, and coating compositions containing the same

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3985695A (en) * 1974-11-25 1976-10-12 Mobil Oil Corporation Water reducible epoxy ester coating composition

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3280056A (en) * 1953-07-30 1966-10-18 Devoe & Raynolds Co Epoxide compositions prepared from dimeric unsaturated higher fatty acids
US3878145A (en) * 1965-03-13 1975-04-15 Reichhold Albert Chemie Ag Process for producing water-dilutable coating compositions suitable for electrocoating
US3374193A (en) * 1965-07-19 1968-03-19 Shell Oil Co Polyepoxide fluidized bed coating compositions
US3709846A (en) * 1970-09-25 1973-01-09 Ford Motor Co Trimellitic anhydride modified polycarboxylic acid electrocoating resins
US3707516A (en) * 1971-04-28 1972-12-26 Du Pont Coating composition of an acrylic-epoxy graft copolymer
US3706684A (en) * 1971-06-11 1972-12-19 Shell Oil Co Traffic paint compositions

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3985695A (en) * 1974-11-25 1976-10-12 Mobil Oil Corporation Water reducible epoxy ester coating composition

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0015917A4 (fr) * 1978-03-09 1980-07-17 Kazys Sekmakas Copolymeres esters epoxydes solubles dans l'eau utilises pour les seaux hygieniques.
EP0015917A1 (fr) * 1978-03-09 1980-10-01 SEKMAKAS, Kazys Copolymeres esters epoxydes solubles dans l'eau utilises pour les seaux hygieniques

Also Published As

Publication number Publication date
JPS53102995A (en) 1978-09-07
IT7820237A0 (it) 1978-02-13
AU3323978A (en) 1979-08-23
ZA78871B (en) 1979-09-26
GB1580772A (en) 1980-12-03
NL7801657A (nl) 1978-08-16
US4098735A (en) 1978-07-04
IT1095408B (it) 1985-08-10
AU519841B2 (en) 1981-12-24
DK64178A (da) 1978-08-15
NO780493L (no) 1978-08-15
BE863915A (fr) 1978-08-14
CA1124443A (fr) 1982-05-25
DE2805902A1 (de) 1978-08-17
BR7800881A (pt) 1978-10-24

Similar Documents

Publication Publication Date Title
FR2380310A1 (fr) Polyepoxyester diluable a l'eau renfermant un acide monocarboxylique comme agent de reglage du poids moleculaire
FR2413409A1 (fr) Procede pour preparer des polystyrenes resistant a la chaleur, bromes sur le noyau
NO870243D0 (no) Brusende blandinger.
MC2212A1 (fr) Procede de fabrication d'une construction artificielle de grande-dimension au fond d'une piece d'eau,comme par exemple une ile artificielle,appareil pour executer le procede selon l'invention et forme de realisation preferee de sa construction
FR2506715A2 (fr) Dispositif de securite pour plate-forme marine
NO874081L (no) Fremgangsmaate for fremstilling av oksy-ftalsyreanhydrider.
MA19287A1 (fr) Procede pour entrainer l'uranium d'un acide alcoypyrophosphorique .
DE69107002D1 (de) Mischvorrichtung.
DE3163579D1 (en) Brackets for use during the erection of walls
GB1533165A (en) Scaffold for performing operations in enclosed spaces
FR2386652A1 (fr) Procede pour fabriquer et eriger des elements unitaires de construction
GB2020545A (en) Collapsible support stand
FR2438188A1 (fr) Organe de liaison avec un element allonge tel qu'un etai
SU1070055A1 (ru) Судова заваливающа с мачта
BE831331A (fr) Dispositif pour refroidir de l'eau de refroidissement par tirage naturel ou force, d'air
GB594387A (en) Improvements in or relating to adjustable supports for moulds used in the casting ofconcrete roofs, ceilings or the like
NO853888L (no) Koplingssystem for l¯sbar kopling av en i det vesentlige r ektangul|r konstruksjonsdel til og mellom to stendere, s|r lig et rekkverk til et stillas.
SU1138287A1 (ru) Устройство дл демонтажа прессовых соединений деталей типа вал-втулка
SU389233A1 (fr)
FR2385753A1 (fr) Polyamides reticulables
JPS5247243A (en) Temporary elevator
IMAI et al. Determination of Alkyl Ketene Dimers with Monomethyl Amine
FR2424901A1 (fr) Diesters de l'ethyleneglycol et procede pour leur preparation
WO1992009575A3 (fr) Esters d'acide 2-aminocinnamique
NAKABAYASHI Application of the Photo-Titration Apparatus for the Determination of Tannin by Löwenthal's Method

Legal Events

Date Code Title Description
RE Withdrawal of published application