FR2378808A1 - Nouveaux copolymeres hydrophiles a base de n-(tris(hydroxy-methyl)methyl)acrylamide ou de n-(tris (hydroxymethyl)methyl)methacrylamide, leur preparation et leur emploi dans les techniques de separation - Google Patents

Nouveaux copolymeres hydrophiles a base de n-(tris(hydroxy-methyl)methyl)acrylamide ou de n-(tris (hydroxymethyl)methyl)methacrylamide, leur preparation et leur emploi dans les techniques de separation

Info

Publication number
FR2378808A1
FR2378808A1 FR7702391A FR7702391A FR2378808A1 FR 2378808 A1 FR2378808 A1 FR 2378808A1 FR 7702391 A FR7702391 A FR 7702391A FR 7702391 A FR7702391 A FR 7702391A FR 2378808 A1 FR2378808 A1 FR 2378808A1
Authority
FR
France
Prior art keywords
methyl
tris
hydroxymethyl
methacrylamide
acrylamide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7702391A
Other languages
English (en)
Other versions
FR2378808B1 (fr
Inventor
Eric Brown
Egisto Boschetti
Monique Corgier
Joel Touet
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MAR PHA ETU EXPL MARQUES
Original Assignee
MAR PHA ETU EXPL MARQUES
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by MAR PHA ETU EXPL MARQUES filed Critical MAR PHA ETU EXPL MARQUES
Priority to FR7702391A priority Critical patent/FR2378808A1/fr
Priority to BE184258A priority patent/BE862843A/fr
Priority to CH54378A priority patent/CH631467A5/fr
Priority to DK034578A priority patent/DK151038C/da
Priority to DE2803421A priority patent/DE2803421C3/de
Priority to NLAANVRAGE7800931,A priority patent/NL183766C/xx
Priority to GB3311/78A priority patent/GB1594374A/en
Priority to IT67156/78A priority patent/IT1111602B/it
Priority to US05/873,026 priority patent/US4192784A/en
Priority to ES466434A priority patent/ES466434A1/es
Priority to SE7801052A priority patent/SE438863B/sv
Priority to NO780312A priority patent/NO148072C/no
Priority to JP820078A priority patent/JPS5396090A/ja
Priority to NO782694A priority patent/NO148674C/no
Publication of FR2378808A1 publication Critical patent/FR2378808A1/fr
Application granted granted Critical
Publication of FR2378808B1 publication Critical patent/FR2378808B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/52—Amides or imides
    • C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F220/58—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing oxygen in addition to the carbonamido oxygen, e.g. N-methylolacrylamide, N-(meth)acryloylmorpholine
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
    • C12N11/00—Carrier-bound or immobilised enzymes; Carrier-bound or immobilised microbial cells; Preparation thereof
    • C12N11/02—Enzymes or microbial cells immobilised on or in an organic carrier
    • C12N11/08—Enzymes or microbial cells immobilised on or in an organic carrier the carrier being a synthetic polymer
    • C12N11/082—Enzymes or microbial cells immobilised on or in an organic carrier the carrier being a synthetic polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
    • C12N11/00—Carrier-bound or immobilised enzymes; Carrier-bound or immobilised microbial cells; Preparation thereof
    • C12N11/02—Enzymes or microbial cells immobilised on or in an organic carrier
    • C12N11/08—Enzymes or microbial cells immobilised on or in an organic carrier the carrier being a synthetic polymer
    • C12N11/082—Enzymes or microbial cells immobilised on or in an organic carrier the carrier being a synthetic polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C12N11/087—Acrylic polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S524/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S524/916—Hydrogel compositions
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/909—Polymerization characterized by particle size of product
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991—Coated
    • Y10T428/2998—Coated including synthetic resin or polymer

Abstract

Copolymères statistiques réticulés tridimensionnels, insolubles dans l'eau, caractérisés en ce qu'ils contiennent, sous forme copolymérisée : a. 25 % à 98 % en poids de N-Øtris(hydroxyméthyl)méthylõ acrylamide ou de N-Øtris(hydroxyméthyl)méthylõ méthacrylamide, ou d'un mélange de ces deux composés; b. 2 % à 50 % en poids d'un ou plusieurs monomères possédant plusieurs doubles liaisons éthyléniques polymérisables et un ou plusieurs groupes hydroxy, et exempts de groupe NH2 ou COOH; c. 0 % à 50 % en poids d'un ou plusieurs monomères possédant une double liaison éthylénique polymérisable et un ou plusieurs groupes amino ou carboxylique. Ces copolymères sont utilisables, sous forme de gels aqueux, comme supports dans les techniques de séparation telles que la chromatographie de perméation.
FR7702391A 1977-01-28 1977-01-28 Nouveaux copolymeres hydrophiles a base de n-(tris(hydroxy-methyl)methyl)acrylamide ou de n-(tris (hydroxymethyl)methyl)methacrylamide, leur preparation et leur emploi dans les techniques de separation Granted FR2378808A1 (fr)

Priority Applications (14)

Application Number Priority Date Filing Date Title
FR7702391A FR2378808A1 (fr) 1977-01-28 1977-01-28 Nouveaux copolymeres hydrophiles a base de n-(tris(hydroxy-methyl)methyl)acrylamide ou de n-(tris (hydroxymethyl)methyl)methacrylamide, leur preparation et leur emploi dans les techniques de separation
BE184258A BE862843A (fr) 1977-01-28 1978-01-12 Nouveaux copolymers hydrophiles, leur preparation et leur emploi dans les techniques de separation
CH54378A CH631467A5 (fr) 1977-01-28 1978-01-18 Copolymeres statistiques reticules.
DK034578A DK151038C (da) 1977-01-28 1978-01-24 Statistisk opbyggede, tredimensional tvaerbundne copolymere samt deres anvendelse
NLAANVRAGE7800931,A NL183766C (nl) 1977-01-28 1978-01-26 Werkwijze voor het bereiden van verknoopte, in water onoplosbare copolymeren, werkwijze voor het bereiden van een waterig gel en werkwijze voor het uitvoeren van een chromatografische bepaling of het immobiliseren van een biologisch macromolecuul.
DE2803421A DE2803421C3 (de) 1977-01-28 1978-01-26 Statistisch aufgebaute, dreidimensional nernetzte, wasserunlösliche Copolymere und deren Verwendung
GB3311/78A GB1594374A (en) 1977-01-28 1978-01-27 Hydrophilic copolymers
IT67156/78A IT1111602B (it) 1977-01-28 1978-01-27 Copolimeri idrofili loro preparazione e loro impiego nelle tecniche di separazione
US05/873,026 US4192784A (en) 1977-01-28 1978-01-27 Hydrophilic copolymers, their preparation and their use in separation techniques
ES466434A ES466434A1 (es) 1977-01-28 1978-01-27 Un procedimiento para la preparacion de copolimeros estati- cos reticulados tridimensionales.
SE7801052A SE438863B (sv) 1977-01-28 1978-01-27 Hydrofila sampolymerer och anvendning derav i vattenhaltiga geler
NO780312A NO148072C (no) 1977-01-28 1978-01-27 Hydrofile kopolymerer.
JP820078A JPS5396090A (en) 1977-01-28 1978-01-27 Novel hydrophilic copolymer
NO782694A NO148674C (no) 1977-01-28 1978-08-07 Vandige geler.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7702391A FR2378808A1 (fr) 1977-01-28 1977-01-28 Nouveaux copolymeres hydrophiles a base de n-(tris(hydroxy-methyl)methyl)acrylamide ou de n-(tris (hydroxymethyl)methyl)methacrylamide, leur preparation et leur emploi dans les techniques de separation

Publications (2)

Publication Number Publication Date
FR2378808A1 true FR2378808A1 (fr) 1978-08-25
FR2378808B1 FR2378808B1 (fr) 1980-03-21

Family

ID=9186013

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7702391A Granted FR2378808A1 (fr) 1977-01-28 1977-01-28 Nouveaux copolymeres hydrophiles a base de n-(tris(hydroxy-methyl)methyl)acrylamide ou de n-(tris (hydroxymethyl)methyl)methacrylamide, leur preparation et leur emploi dans les techniques de separation

Country Status (13)

Country Link
US (1) US4192784A (fr)
JP (1) JPS5396090A (fr)
BE (1) BE862843A (fr)
CH (1) CH631467A5 (fr)
DE (1) DE2803421C3 (fr)
DK (1) DK151038C (fr)
ES (1) ES466434A1 (fr)
FR (1) FR2378808A1 (fr)
GB (1) GB1594374A (fr)
IT (1) IT1111602B (fr)
NL (1) NL183766C (fr)
NO (2) NO148072C (fr)
SE (1) SE438863B (fr)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2482112A1 (fr) * 1980-05-09 1981-11-13 Pharmindustrie Nouveaux copolymeres hydrophiles a base de n-(tris (hydroxymethyl) methyl) acrylamide, procedes pour leur preparation, gels aqueux desdits copolymeres et leur utilisation comme echangeurs d'ions
WO2001070132A2 (fr) 2000-03-20 2001-09-27 Biosphere Medical, Inc. Microspheres injectables et gonflables conçues pour une augmentation dermique
US6335028B1 (en) 1998-03-06 2002-01-01 Biosphere Medical, Inc. Implantable particles for urinary incontinence
US6660301B1 (en) 1998-03-06 2003-12-09 Biosphere Medical, Inc. Injectable microspheres for dermal augmentation and tissue bulking
EP2283880A2 (fr) 2000-03-20 2011-02-16 Biosphere Medical, Inc. Microspheres injectables pour la regeneration tissulaire
EP2286799A2 (fr) 2000-03-24 2011-02-23 Biosphere Medical, Inc. Microsphères pour embolisation active
EP2484344A2 (fr) 2005-05-09 2012-08-08 Biosphere Medical, S.A. Compositions et procédés pour utiliser des microsphères et des agents de contraste non ioniques
US8647639B2 (en) 2004-10-01 2014-02-11 Allergan, Inc. Cosmetic neurotoxin compositions and methods
US8778333B2 (en) 2000-03-20 2014-07-15 Biosphere Medical, Inc. Injectable microspheres for tissue construction
US9017710B2 (en) 2000-03-20 2015-04-28 Biosphere Medical, Inc. Injectable and swellable microspheres for tissue bulking

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4649183A (en) 1985-06-12 1987-03-10 University Of Southern Mississippi Calcium-tolerant N-substituted acrylamides as thickeners for aqueous systems
US4970290A (en) * 1986-02-24 1990-11-13 Nalco Chemical Company Alkoxylated/cationically modified amide-containing polymers
US4731419A (en) * 1986-02-24 1988-03-15 Nalco Chemical Company Alkoxylated/cationically modified amide-containing polymers
GB8713854D0 (en) * 1987-06-13 1987-07-15 Kozulic B Poly-n-acryloyl-tris(hydroxymethyl)aminomethane gels
IL89371A (en) * 1988-02-24 1993-07-08 Us Commerce Polyacrylamide gels, their preparation and their use for detection and separation of proteins
US4999340A (en) * 1988-08-04 1991-03-12 Board Of Regents, The University Of Texas System Rehydratable agarose gels
US4950708A (en) * 1988-08-29 1990-08-21 Bio-Rad Laboratories, Inc. Stable polyacrylamide gels containing chaotropic agents
CA2017570C (fr) * 1989-05-31 2000-12-19 James R. Gross Structure poreuse d'un polymere absorbant
US5354290A (en) * 1989-05-31 1994-10-11 Kimberly-Clark Corporation Porous structure of an absorbent polymer
DE3931418A1 (de) * 1989-09-21 1991-04-04 Bayer Ag Alkandiyl-bis-carbonamide, adhaesivkomponenten zur behandlung kollagenhaltiger materialien, enthaltend diese verbindungen, sowie herstellung und anwendung dieser adhaesivkomponenten
US5084520A (en) * 1990-07-06 1992-01-28 Nalco Chemical Company Synthesis of hydrophobic/alkoxylated polymers
US5075390A (en) * 1990-07-06 1991-12-24 Nalco Chemical Company Synthesis of hydrophobic/alkoxylated polymers
US6046246A (en) * 1998-06-11 2000-04-04 Prometic Biosciences, Inc. Process for making fluorinated polymer adsorbent particles
US6464850B1 (en) * 1998-07-31 2002-10-15 Biowhittaker Molecular Applications, Inc. Method for producing hydrophilic monomers and uses thereof
US20030212022A1 (en) * 2001-03-23 2003-11-13 Jean-Marie Vogel Compositions and methods for gene therapy
EP2646146A1 (fr) * 2010-11-30 2013-10-09 GE Healthcare Bio-Sciences AB Compositions de tampon enfermées dans une matrice d'exclusion de tailles

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2260597A1 (fr) * 1974-02-08 1975-09-05 Ceskoslovenska Akademie Ved

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US3591387A (en) * 1969-04-02 1971-07-06 Eastman Kodak Co Silver halide emulsions comprising polymeric acrylamides as sensitizing additives
US3658734A (en) * 1970-10-20 1972-04-25 Kelco Co Guar gum-polyacrylamide compositions
US3733196A (en) * 1971-02-04 1973-05-15 Eastman Kodak Co Chemically hardened silver halide emulsions containing tempering concentrations of simple organic polyols
US3785855A (en) * 1972-01-14 1974-01-15 D Sausaman Method for coating steel
DE2357079C2 (de) * 1973-11-15 1982-07-29 Hoechst Ag, 6000 Frankfurt Verfahren zum Herstellen von Wasser aufnehmenden, aber darin zu mehr als 50% unlöslichen Celluloseethern
FR2279770A1 (fr) * 1974-07-26 1976-02-20 Aquitaine Petrole Polymeres acryliques modifies hydrophiles, notamment hydrodispersibles ou hydrosolubles et procede pour leur preparation
FR2279769A1 (fr) * 1974-07-26 1976-02-20 Aquitaine Petrole Polymeres acryliques modifies hydrophiles, notamment hydrodispersibles ou hydrosolubles, et procede pour leur preparation
DE2447690C2 (de) * 1974-10-07 1982-02-25 Hoechst Ag, 6000 Frankfurt Verfahren zur Herstellung eines Kunststoffs auf Basis von chemisch modifiziertem Casein und seine Verwendung
FR2297879A1 (fr) * 1975-01-14 1976-08-13 Sogeras Procede de preparation de plaques sechees rehydratables contenant de l'agarose ou de la gelose

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FR2260597A1 (fr) * 1974-02-08 1975-09-05 Ceskoslovenska Akademie Ved

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0040124A1 (fr) * 1980-05-09 1981-11-18 Pharmuka Laboratoires Nouveaux copolymères hydrophiles à base de N- tris (hydroxyméthyl) méthyl acrylamide, procédés pour leur préparation, gels aqueux desdits copolymères et leur utilisation comme échangeurs d'ions
US4452916A (en) * 1980-05-09 1984-06-05 Pharmindustrie Hydrophilic copolymers based on N-[tris(hydroxymethyl)methyl]-acrylamide, processes for their preparation, aqueous gels of said copolymers and their use as ion exchangers
FR2482112A1 (fr) * 1980-05-09 1981-11-13 Pharmindustrie Nouveaux copolymeres hydrophiles a base de n-(tris (hydroxymethyl) methyl) acrylamide, procedes pour leur preparation, gels aqueux desdits copolymeres et leur utilisation comme echangeurs d'ions
US7060298B2 (en) 1998-03-06 2006-06-13 Biosphere Medical, Inc. Implantable particles for the treatment of gastroesophageal reflux disease
US9205053B2 (en) 1998-03-06 2015-12-08 Biosphere Medical, Inc. Injectable microspheres for dermal augmentation and tissue bulking
US6335028B1 (en) 1998-03-06 2002-01-01 Biosphere Medical, Inc. Implantable particles for urinary incontinence
US6660301B1 (en) 1998-03-06 2003-12-09 Biosphere Medical, Inc. Injectable microspheres for dermal augmentation and tissue bulking
US8778333B2 (en) 2000-03-20 2014-07-15 Biosphere Medical, Inc. Injectable microspheres for tissue construction
WO2001070132A2 (fr) 2000-03-20 2001-09-27 Biosphere Medical, Inc. Microspheres injectables et gonflables conçues pour une augmentation dermique
EP2283880A2 (fr) 2000-03-20 2011-02-16 Biosphere Medical, Inc. Microspheres injectables pour la regeneration tissulaire
EP2311404A1 (fr) 2000-03-20 2011-04-20 Biosphere Medical, Inc. Microspheres injectables, susceptibles de foisonnement, destinees a l'augmentation dermique
US8142815B2 (en) 2000-03-20 2012-03-27 Biosphere Medical, Inc. Injectable and swellable microspheres for dermal augmentation
US6790456B2 (en) 2000-03-20 2004-09-14 Biosphere Medical, Inc. Injectable and swellable microspheres for dermal augmentation
US6436424B1 (en) 2000-03-20 2002-08-20 Biosphere Medical, Inc. Injectable and swellable microspheres for dermal augmentation
US9017710B2 (en) 2000-03-20 2015-04-28 Biosphere Medical, Inc. Injectable and swellable microspheres for tissue bulking
EP2286799A2 (fr) 2000-03-24 2011-02-23 Biosphere Medical, Inc. Microsphères pour embolisation active
US10265271B2 (en) 2000-03-24 2019-04-23 Biosphere Medical, Inc. Microspheres for the treatment of a prostate hyperplasia by active embolization
US8647639B2 (en) 2004-10-01 2014-02-11 Allergan, Inc. Cosmetic neurotoxin compositions and methods
US9056059B2 (en) 2004-10-01 2015-06-16 Allergan, Inc. Cosmetic neurotoxin compositions and methods
EP3085362A1 (fr) 2005-05-09 2016-10-26 Biosphere Medical, S.A. Compositions et procédés utilisant des microsphères et des agents de contraste non ioniques
EP2484344A2 (fr) 2005-05-09 2012-08-08 Biosphere Medical, S.A. Compositions et procédés pour utiliser des microsphères et des agents de contraste non ioniques

Also Published As

Publication number Publication date
NO780312L (no) 1978-07-31
NL7800931A (nl) 1978-08-01
BE862843A (fr) 1978-07-12
NO148674C (no) 1983-11-23
JPS5396090A (en) 1978-08-22
NO782694L (no) 1978-07-31
DK151038B (da) 1987-10-12
DE2803421B2 (de) 1981-07-09
JPS6352053B2 (fr) 1988-10-17
IT7867156A0 (it) 1978-01-27
NO148072C (no) 1983-08-03
US4192784A (en) 1980-03-11
NO148072B (no) 1983-04-25
ES466434A1 (es) 1979-05-16
DE2803421A1 (de) 1978-08-03
DK151038C (da) 1988-05-02
GB1594374A (en) 1981-07-30
FR2378808B1 (fr) 1980-03-21
NL183766C (nl) 1989-01-16
CH631467A5 (fr) 1982-08-13
SE7801052L (sv) 1978-07-29
DK34578A (da) 1978-07-29
SE438863B (sv) 1985-05-13
IT1111602B (it) 1986-01-13
NO148674B (no) 1983-08-15
DE2803421C3 (de) 1982-04-29

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