FR2370062A1 - Procede de preparation d'un copolymere fluore portant des groupements echangeurs d'ions - Google Patents

Procede de preparation d'un copolymere fluore portant des groupements echangeurs d'ions

Info

Publication number
FR2370062A1
FR2370062A1 FR7633623A FR7633623A FR2370062A1 FR 2370062 A1 FR2370062 A1 FR 2370062A1 FR 7633623 A FR7633623 A FR 7633623A FR 7633623 A FR7633623 A FR 7633623A FR 2370062 A1 FR2370062 A1 FR 2370062A1
Authority
FR
France
Prior art keywords
ion exchange
preparation
exchange groups
copolymer
fluorinated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7633623A
Other languages
English (en)
Other versions
FR2370062B1 (fr
Inventor
Hiroshi Ukihashi
Tatsuro Asawa
Masaaki Yamabe
Haruhisa Miyake
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
AGC Inc
Original Assignee
Asahi Glass Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to GB44891/76A priority Critical patent/GB1550874A/en
Application filed by Asahi Glass Co Ltd filed Critical Asahi Glass Co Ltd
Priority to US05/739,728 priority patent/US4116888A/en
Priority to DE2650979A priority patent/DE2650979C2/de
Priority to FR7633623A priority patent/FR2370062A1/fr
Publication of FR2370062A1 publication Critical patent/FR2370062A1/fr
Application granted granted Critical
Publication of FR2370062B1 publication Critical patent/FR2370062B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/34—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis
    • C25B1/46—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis in diaphragm cells
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C08F214/184—Monomers containing fluorine with fluorinated vinyl ethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F216/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F216/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
    • C08F216/14—Monomers containing only one unsaturated aliphatic radical
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F216/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F216/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
    • C08F216/14—Monomers containing only one unsaturated aliphatic radical
    • C08F216/1408—Monomers containing halogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • C08J5/2237—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Electrochemistry (AREA)
  • Metallurgy (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

a. Procédé de préparation d'un copolymère fluoré présentant des groupements échangeurs d'ions. b. Ce copolymère fluoré contenant de 1 à 50 moles % d'un composé présentant un acide carboxylique ou un groupement qui peut etre transformé en acide carboxylique, est obtenu en copolymérisant un monomère éthylénique insaturé fluoré et un monomère fonctionnel présentant le groupement fonctionnel, en présence d'un initiateur de polymérisation dans 0 à 10 moles d'un solvant organique inerte vis-à-vis de la réaction par mole de monomère fonctionnel et sous une pression supérieure à 6kg/cm**2. Le copolymère obtenu présente une valeur TQ supérieure à 150 degrés C et une capacité d'échange d'ions comprise entre 0,5 et 4 meq/g de polymère sec. c. Applications du copolymère de l'invention comme diaphragme dans l'électrolyse du chlorure de sodium.
FR7633623A 1976-10-28 1976-11-08 Procede de preparation d'un copolymere fluore portant des groupements echangeurs d'ions Granted FR2370062A1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
GB44891/76A GB1550874A (en) 1976-10-28 1976-10-28 Process for producing fluorinated copolymer having ion-exchange groups
US05/739,728 US4116888A (en) 1976-10-28 1976-11-08 Process for producing fluorinated copolymer having ion-exchange groups
DE2650979A DE2650979C2 (de) 1976-10-28 1976-11-08 Verfahren zur Herstellung eines fluorierten Copolymeren mit Ionenaustauschgruppen
FR7633623A FR2370062A1 (fr) 1976-10-28 1976-11-08 Procede de preparation d'un copolymere fluore portant des groupements echangeurs d'ions

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GB44891/76A GB1550874A (en) 1976-10-28 1976-10-28 Process for producing fluorinated copolymer having ion-exchange groups
US05/739,728 US4116888A (en) 1976-10-28 1976-11-08 Process for producing fluorinated copolymer having ion-exchange groups
DE2650979A DE2650979C2 (de) 1976-10-28 1976-11-08 Verfahren zur Herstellung eines fluorierten Copolymeren mit Ionenaustauschgruppen
FR7633623A FR2370062A1 (fr) 1976-10-28 1976-11-08 Procede de preparation d'un copolymere fluore portant des groupements echangeurs d'ions

Publications (2)

Publication Number Publication Date
FR2370062A1 true FR2370062A1 (fr) 1978-06-02
FR2370062B1 FR2370062B1 (fr) 1980-04-11

Family

ID=27432156

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7633623A Granted FR2370062A1 (fr) 1976-10-28 1976-11-08 Procede de preparation d'un copolymere fluore portant des groupements echangeurs d'ions

Country Status (4)

Country Link
US (1) US4116888A (fr)
DE (1) DE2650979C2 (fr)
FR (1) FR2370062A1 (fr)
GB (1) GB1550874A (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0011853A2 (fr) * 1978-11-30 1980-06-11 E.I. Du Pont De Nemours And Company Copolymères fluorés vulcanisables
EP0050447A1 (fr) * 1980-10-17 1982-04-28 Asahi Glass Company Ltd. Solution organique de copolymère fluoré ayant des groupes acide carboxylique

Families Citing this family (60)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4267364A (en) * 1977-04-20 1981-05-12 E. I. Dupont De Nemours And Company Fluorinated ion exchange polymer containing carboxylic groups, process for making same, and film and membrane thereof
US4487668A (en) * 1977-04-20 1984-12-11 E. I. Du Pont De Nemours And Company Fluorinated ion exchange polymer containing carboxylic groups, and film and membrane thereof
JPS53144481A (en) * 1977-05-24 1978-12-15 Asahi Glass Co Ltd Method of joining fluorine contained cation exchange resin membrane
JPS54107949A (en) * 1978-02-14 1979-08-24 Asahi Glass Co Ltd Solution of fluorine-containing polymer bearing carboxyl group as side chain
US4544458A (en) * 1978-11-13 1985-10-01 E. I. Du Pont De Nemours And Company Fluorinated ion exchange polymer containing carboxylic groups, process for making same, and film and membrane thereof
US4329435A (en) 1979-05-31 1982-05-11 Asahi Kasei Kogyo Kabushiki Kaisha Novel fluorinated copolymer with tridihydro fluorosulfonyl fluoride pendant groups and preparation thereof
JPS5645911A (en) * 1979-09-25 1981-04-25 Asahi Glass Co Ltd Production of ion-exchangeable fluorinated polymer
US4348310A (en) * 1979-09-26 1982-09-07 E. I. Du Pont De Nemours And Company Solutions of sulfonyl fluoride compounds and fluoropolymers
US4341685A (en) * 1979-11-20 1982-07-27 Asahi Glass Company, Ltd. Process for preparing organic dispersion of acid type fluorinated polymer
US4335255A (en) * 1980-04-03 1982-06-15 E. I. Du Pont De Nemours And Company Alkyl perfluoro (2-methyl-5-oxo-3-oxahexanoate)
US5023362A (en) * 1980-04-03 1991-06-11 E. I. Du Pont De Nemours And Company Alkyl perfluoro(2-methyl-5-oxo-3-oxahexanoate)
AU541096B2 (en) * 1980-06-11 1984-12-13 Dow Chemical Company, The Fluorocarbon vinyl ethers and their polymers
US4330654A (en) * 1980-06-11 1982-05-18 The Dow Chemical Company Novel polymers having acid functionality
US4804727A (en) * 1980-06-11 1989-02-14 The Dow Chemical Company Process to produce novel fluorocarbon vinyl ethers and resulting polymers
US4401711A (en) * 1981-01-16 1983-08-30 E. I. Du Pont De Nemours And Company Cation exchange membrane with high equivalent weight component
US4434116A (en) 1981-06-26 1984-02-28 Diamond Shamrock Corporation Method for making a porous fluorinated polymer structure
US4390720A (en) * 1981-10-14 1983-06-28 E. I. Du Pont De Nemours And Company Alkyl-ω-fluoroformyl ester and process
US4454247A (en) * 1981-12-14 1984-06-12 E. I. Du Pont De Nemours & Company Ion exchange membranes
US4834922A (en) * 1982-02-04 1989-05-30 The Dow Chemical Company Process to produce novel fluorocarbon vinyl ethers and resulting polymers
DE3348412C2 (de) * 1982-02-05 1995-05-24 Asahi Glass Co Ltd Fluorhaltiges Polymeres für Beschichtungszwecke
JPS58136605A (ja) * 1982-02-05 1983-08-13 Asahi Glass Co Ltd カルボキシル基含有含フツ素重合体の製造方法
JPS59197411A (ja) * 1983-04-25 1984-11-09 Daikin Ind Ltd エチレン−テトラフルオロエチレンまたはクロロトリフルオロエチレン系共重合体
US4871703A (en) * 1983-05-31 1989-10-03 The Dow Chemical Company Process for preparation of an electrocatalyst
US4513128A (en) * 1983-06-23 1985-04-23 E. I. Du Pont De Nemours And Company Fluorinated vinyl ether copolymers having low glass transition temperatures
US4591439A (en) * 1984-05-08 1986-05-27 E. I. Du Pont De Nemours And Company Ion exchange process and apparatus
US4784882A (en) * 1985-05-31 1988-11-15 The Dow Chemical Company Method for forming composite polymer films
US4784900A (en) * 1985-05-31 1988-11-15 University Of Bath Method for sizing polytretrafluoroethylene fabrics
US4610762A (en) * 1985-05-31 1986-09-09 The Dow Chemical Company Method for forming polymer films having bubble release surfaces
US4650551A (en) * 1985-05-31 1987-03-17 The Dow Chemical Company Supported ion exchange membrane films
US5110385A (en) * 1985-05-31 1992-05-05 The Dow Chemical Company Method for forming polymer composite films using a removable substrate
US5114515A (en) * 1985-05-31 1992-05-19 The Dow Chemical Company Method for forming polymer composite films using removable substrates
US4650711A (en) * 1985-05-31 1987-03-17 The Dow Chemical Company Method for sizing polytetrafluoroethylene fabrics
US4668372A (en) * 1985-12-16 1987-05-26 The Dow Chemical Company Method for making an electrolytic unit from a plastic material
US4666579A (en) * 1985-12-16 1987-05-19 The Dow Chemical Company Structural frame for a solid polymer electrolyte electrochemical cell
US4670123A (en) * 1985-12-16 1987-06-02 The Dow Chemical Company Structural frame for an electrochemical cell
US4668371A (en) * 1985-12-16 1987-05-26 The Dow Chemical Company Structural frame for an electrochemical cell
US4666580A (en) * 1985-12-16 1987-05-19 The Dow Chemical Company Structural frame for an electrochemical cell
US4778723A (en) * 1986-06-20 1988-10-18 The Dow Chemical Company Method for sizing polytetrafluoroethylene fibers, yarn, or threads
US4698243A (en) * 1986-06-20 1987-10-06 The Dow Chemical Company Method for sizing and hydrolyzing polytetrafluoroethylene fabrics, fibers, yarns, or threads
US4731263A (en) * 1986-09-26 1988-03-15 The Dow Chemical Company Method for the preparation of ionomer films
US4752370A (en) * 1986-12-19 1988-06-21 The Dow Chemical Company Supported membrane/electrode structure combination wherein catalytically active particles are coated onto the membrane
US5039389A (en) * 1986-12-19 1991-08-13 The Dow Chemical Company Membrane/electrode combination having interconnected roadways of catalytically active particles
US4738741A (en) * 1986-12-19 1988-04-19 The Dow Chemical Company Method for forming an improved membrane/electrode combination having interconnected roadways of catalytically active particles
US4889577A (en) * 1986-12-19 1989-12-26 The Dow Chemical Company Method for making an improved supported membrane/electrode structure combination wherein catalytically active particles are coated onto the membrane
US4940525A (en) * 1987-05-08 1990-07-10 The Dow Chemical Company Low equivalent weight sulfonic fluoropolymers
US4859745A (en) * 1987-12-22 1989-08-22 The Dow Chemical Company Stratified fibrous fluoropolymer compositions and process for forming such fluoropolymers
DE3912148A1 (de) * 1989-04-13 1990-10-18 Hoechst Ag Transparente thermoplastische formmasse und ihre verwendung
US5013414A (en) * 1989-04-19 1991-05-07 The Dow Chemical Company Electrode structure for an electrolytic cell and electrolytic process used therein
US5252193A (en) * 1991-11-04 1993-10-12 E. I. Du Pont De Nemours And Company Controlled roughening of reinforced cation exchange membrane
EP0545068A3 (en) * 1991-11-08 1993-12-22 Du Pont Wetting of diaphragms
US5281680A (en) * 1993-01-14 1994-01-25 E. I. Du Pont De Nemours And Company Polymerization of fluorinated copolymers
US5433861A (en) * 1993-09-17 1995-07-18 The Dow Chemical Company Permanent deformation and use of sulfonated halopolymer articles
RU2074199C1 (ru) * 1994-04-18 1997-02-27 Государственное предприятие "Научно-исследовательский институт синтетического каучука им.акад.С.В.Лебедева" Низкомолекулярные тройные сополимеры винилиденфторида, отверждаемые при низкой температуре, в качестве основы термоагрессивостойких герметиков и защитных покрытий и способ их получения
US5739233A (en) * 1995-08-14 1998-04-14 E. I. Du Pont De Nemours And Company Low molecular weight vinylidene fluoride copolymers curable at room temperature
US6248469B1 (en) 1997-08-29 2001-06-19 Foster-Miller, Inc. Composite solid polymer electrolyte membranes
US7550216B2 (en) * 1999-03-03 2009-06-23 Foster-Miller, Inc. Composite solid polymer electrolyte membranes
US6861489B2 (en) 2001-12-06 2005-03-01 Gore Enterprise Holdings, Inc. Low equivalent weight ionomer
WO2012173153A1 (fr) * 2011-06-15 2012-12-20 旭硝子株式会社 Procédé de production d'un copolymère contenant du fluor
JP5799926B2 (ja) * 2012-09-27 2015-10-28 旭硝子株式会社 含フッ素共重合体の製造方法
FR3079834B1 (fr) * 2018-04-10 2021-09-10 Arkema Inc Fluoropolymeres fonctionnels

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3041317A (en) * 1960-05-02 1962-06-26 Du Pont Fluorocarbon sulfonyl fluorides
US3503945A (en) * 1966-08-10 1970-03-31 Dow Corning Fluoroethylene compounds
US3624250A (en) * 1970-01-20 1971-11-30 Du Pont Copolymers of ethylene/tetrafluoroethylene and of ethylene/chlorotrifluoroethylene
BE788557A (fr) * 1971-09-09 1973-03-08 Ppg Industries Inc Diaphragmes pour cellules electrolytiques
US3853720A (en) * 1972-10-24 1974-12-10 Ppg Industries Inc Electrolysis of brine using permeable membranes comprising fluorocarbon copolymers
US3985501A (en) * 1974-01-04 1976-10-12 E. I. Du Pont De Nemours And Company Ion-exchange fabric of fluorinated polymer containing pendant side chains with sulfonyl groups
JPS551351B2 (fr) * 1974-03-07 1980-01-12

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0011853A2 (fr) * 1978-11-30 1980-06-11 E.I. Du Pont De Nemours And Company Copolymères fluorés vulcanisables
EP0011853A3 (en) * 1978-11-30 1980-07-23 E.I. Du Pont De Nemours And Company Vulcanizable fluorinated copolymers
EP0050447A1 (fr) * 1980-10-17 1982-04-28 Asahi Glass Company Ltd. Solution organique de copolymère fluoré ayant des groupes acide carboxylique

Also Published As

Publication number Publication date
DE2650979C2 (de) 1983-09-22
US4116888A (en) 1978-09-26
DE2650979A1 (de) 1978-05-11
FR2370062B1 (fr) 1980-04-11
GB1550874A (en) 1979-08-22

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