FR2369871A1 - Matiere siliceuse et production catalytique d'hydrocarbures au moyen de cette matiere - Google Patents

Matiere siliceuse et production catalytique d'hydrocarbures au moyen de cette matiere

Info

Publication number
FR2369871A1
FR2369871A1 FR7732876A FR7732876A FR2369871A1 FR 2369871 A1 FR2369871 A1 FR 2369871A1 FR 7732876 A FR7732876 A FR 7732876A FR 7732876 A FR7732876 A FR 7732876A FR 2369871 A1 FR2369871 A1 FR 2369871A1
Authority
FR
France
Prior art keywords
hydrocarbons
catalytic production
siliceous
relates
zeolite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7732876A
Other languages
English (en)
Other versions
FR2369871B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB46130/76A external-priority patent/GB1563346A/en
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Publication of FR2369871A1 publication Critical patent/FR2369871A1/fr
Application granted granted Critical
Publication of FR2369871B1 publication Critical patent/FR2369871B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80—Mixtures of different zeolites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
    • C07C4/06—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2702—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
    • C07C5/2708—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2729—Changing the branching point of an open chain or the point of substitution on a ring
    • C07C5/2732—Catalytic processes
    • C07C5/2737—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/36—Steaming
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/37—Acid treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S208/00—Mineral oils: processes and products
    • Y10S208/02—Molecular sieve
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S585/00—Chemistry of hydrocarbon compounds
    • Y10S585/929—Special chemical considerations
    • Y10S585/94—Opening of hydrocarbon ring

Abstract

L'invention concerne l'industrie chimique. Elle a pour objet une matière siliceuse apparentée aux zéolites et dite zeolite FU-1 de la composition 0,6 à 1,4 R2 O.Al2 O 3 , plus de 5 SiO2 .O à 40 H2 O, où R représente un cation monovalent ou 1/n d'un cation de valence n, qui peut s'obtenir par synthèse hydrothermale en présence de composés d'ammonium ou de phosphonium quaternaires méthylés. Cette zéolite est préférée comme catalyseur pour des conversions d'hydrocarbures comme l'isomérisation des xylènes, et le craquage d'hydrocarbures en C10 en un produit à haute teneur en hydrocarbures en C6 -.
FR7732876A 1976-11-05 1977-11-02 Matiere siliceuse et production catalytique d'hydrocarbures au moyen de cette matiere Granted FR2369871A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB46130/76A GB1563346A (en) 1976-11-05 1976-11-05 Silica-containing material and manufacture of hydrocarbons catalysed thereby
GB2826777 1977-07-06

Publications (2)

Publication Number Publication Date
FR2369871A1 true FR2369871A1 (fr) 1978-06-02
FR2369871B1 FR2369871B1 (fr) 1982-09-17

Family

ID=26259293

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7732876A Granted FR2369871A1 (fr) 1976-11-05 1977-11-02 Matiere siliceuse et production catalytique d'hydrocarbures au moyen de cette matiere

Country Status (9)

Country Link
US (2) US4209498A (fr)
JP (1) JPS5358500A (fr)
CA (1) CA1098104A (fr)
DD (1) DD134242A5 (fr)
DE (1) DE2748278A1 (fr)
DK (1) DK152574C (fr)
ES (2) ES463862A1 (fr)
FR (1) FR2369871A1 (fr)
NL (1) NL7712173A (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2416215A1 (fr) * 1978-02-06 1979-08-31 Ici Ltd Procede de preparation d'amines a l'aide de zeolite
FR2423474A1 (fr) * 1978-04-21 1979-11-16 Ici Ltd Production d'amines
FR2429041A1 (fr) * 1978-06-22 1980-01-18 Snam Progetti Silice modifiee par de l'aluminium et son utilisation comme catalyseur
EP0055529A1 (fr) * 1980-12-19 1982-07-07 Imperial Chemical Industries Plc Zéolites
FR2937632A1 (fr) * 2008-10-29 2010-04-30 Inst Francais Du Petrole PROCEDE DE PREPARATION D'UN SOLIDE CRISTALLISE FU-1 UTILISANT UN CATION DE TYPE POLYMETHYLENE a-w DIAMMONIUM COMME STRUCTURANT ORGANIQUE

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4247416A (en) * 1979-02-28 1981-01-27 Mobil Oil Corporation Crystalline zeolite ZSM-25
EP0040016B1 (fr) * 1980-05-13 1984-09-12 Imperial Chemical Industries Plc Zéolithe nu-3
DE3165380D1 (en) * 1980-06-12 1984-09-13 Ici Plc Zeolite eu-1
JPS57169445A (en) * 1981-04-10 1982-10-19 Nitto Chem Ind Co Ltd Preparation of methylamine
JPS57191222A (en) * 1981-05-13 1982-11-25 Mobil Oil Corp Crystalline zeolite substance, manufacture and conversion of organic raw material using same
DE3372088D1 (en) * 1982-10-04 1987-07-23 Ici Plc Zeolites
US4554146A (en) * 1983-11-10 1985-11-19 Exxon Research And Engineering Co. Process for preparing a zeolite of the L type using organic templates
US4952744A (en) * 1986-01-29 1990-08-28 Chevron Research Company New zeolite SSZ-23 and its use in conversion of lower alkanols into hydrocarbons
US4902844A (en) * 1989-04-05 1990-02-20 Chevron Research Company New zeolite SSZ-23 and xylene isomerization therewith
GB8712880D0 (en) * 1987-06-02 1987-07-08 Shell Int Research Crystalline silicates
US4873387A (en) * 1987-10-13 1989-10-10 Uop Process for the isomerization of aromatics
US5110478A (en) * 1990-06-05 1992-05-05 Mobil Oil Corp. Catalytic conversion over membrane composed of a pure molecular sieve
DE69332602T2 (de) * 1992-10-14 2003-11-13 Sagem Modem enthaltender Fernsprecher
US6512155B1 (en) 2000-04-25 2003-01-28 Uop Llc Process for the activation of an alkylaromatic isomerization catalyst by water
US6890511B2 (en) 2003-03-21 2005-05-10 Uop Llc Crystalline aluminosilicate zeolitic composition: UZM-15
JP5027655B2 (ja) * 2004-04-20 2012-09-19 ユーオーピー エルエルシー 結晶性アルミノシリケートゼオライト質組成物：ｕｚｍ−１５
JP5613694B2 (ja) * 2012-01-19 2014-10-29 ユーオーピー エルエルシー 結晶性アルミノシリケートゼオライト質組成物：ｕｚｍ−１５

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2090674A5 (fr) * 1970-04-23 1972-01-14 Mobil Oil Corp

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL150082B (nl) * 1965-11-24 1976-07-15 Mobil Oil Corp Werkwijze ter bereiding van een kristallijn aluminosilicaat-zeoliet, alsmede voorwerpen, geheel of grotendeels bestaande uit kristallijne aluminosilicaten verkregen onder toepassing van deze werkwijze.
US3849463A (en) * 1969-12-18 1974-11-19 Mobil Oil Corp Prevention of silica pore obstruction in crystalline aluminosilicates
US4052479A (en) * 1973-08-09 1977-10-04 Mobil Oil Corporation Conversion of methanol to olefinic components
US4021502A (en) * 1975-02-24 1977-05-03 Mobil Oil Corporation Converting low molecular weight olefins over zeolites
US4021447A (en) * 1975-04-30 1977-05-03 Mobil Oil Corporation Synthesis of zeolite ZSM-4
DE2643928A1 (de) * 1975-10-03 1977-04-21 Ici Ltd Zeolithartiges material und verfahren zur herstellung desselben und dessen verwendung
US4066714A (en) * 1975-12-08 1978-01-03 Mobil Oil Corporation Manufacture of light olefins
US4162214A (en) * 1977-10-04 1979-07-24 Gokhman Boris K Method of preparing benzene and xylenes

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2090674A5 (fr) * 1970-04-23 1972-01-14 Mobil Oil Corp

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2416215A1 (fr) * 1978-02-06 1979-08-31 Ici Ltd Procede de preparation d'amines a l'aide de zeolite
FR2423474A1 (fr) * 1978-04-21 1979-11-16 Ici Ltd Production d'amines
FR2429041A1 (fr) * 1978-06-22 1980-01-18 Snam Progetti Silice modifiee par de l'aluminium et son utilisation comme catalyseur
EP0055529A1 (fr) * 1980-12-19 1982-07-07 Imperial Chemical Industries Plc Zéolites
FR2937632A1 (fr) * 2008-10-29 2010-04-30 Inst Francais Du Petrole PROCEDE DE PREPARATION D'UN SOLIDE CRISTALLISE FU-1 UTILISANT UN CATION DE TYPE POLYMETHYLENE a-w DIAMMONIUM COMME STRUCTURANT ORGANIQUE
EP2196437A1 (fr) * 2008-10-29 2010-06-16 Ifp Procédé de préparation d'un solide cristallisé FU-1 utilisant un cation de type polyméthylène alpha-psi diammonium comme structurant organique

Also Published As

Publication number Publication date
DK491977A (da) 1978-05-06
DK152574C (da) 1988-09-05
JPS5358500A (en) 1978-05-26
DD134242A5 (de) 1979-02-14
DE2748278A1 (de) 1978-05-11
US4209498A (en) 1980-06-24
ES463862A1 (es) 1978-12-16
DK152574B (da) 1988-03-21
JPS618009B2 (fr) 1986-03-11
US4300013A (en) 1981-11-10
ES467610A1 (es) 1979-09-01
CA1098104A (fr) 1981-03-24
NL7712173A (nl) 1978-05-09
FR2369871B1 (fr) 1982-09-17

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