ES463862A1 - Procedimiento de obtencion de un material conteniendo silicedel tipo de las zeolitas. - Google Patents

Procedimiento de obtencion de un material conteniendo silicedel tipo de las zeolitas.

Info

Publication number
ES463862A1
ES463862A1 ES463862A ES463862A ES463862A1 ES 463862 A1 ES463862 A1 ES 463862A1 ES 463862 A ES463862 A ES 463862A ES 463862 A ES463862 A ES 463862A ES 463862 A1 ES463862 A1 ES 463862A1
Authority
ES
Spain
Prior art keywords
silica
containing material
cation
xylenes
al2o3
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES463862A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB46130/76A external-priority patent/GB1563346A/en
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Publication of ES463862A1 publication Critical patent/ES463862A1/es
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80—Mixtures of different zeolites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
    • C07C4/06—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2702—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
    • C07C5/2708—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2729—Changing the branching point of an open chain or the point of substitution on a ring
    • C07C5/2732—Catalytic processes
    • C07C5/2737—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/36—Steaming
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/37—Acid treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S208/00—Mineral oils: processes and products
    • Y10S208/02—Molecular sieve
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S585/00—Chemistry of hydrocarbon compounds
    • Y10S585/929—Special chemical considerations
    • Y10S585/94—Opening of hydrocarbon ring

Abstract

Procedimiento de obtención de un material conteniendo sílice del tipo de las zeolitas, que tiene el modelo de difracción de rayos X indicado en la table I anterior y que tiene la composición química expresada por la fórmula: 0,6 a 1,4 R2O Al2O3 * más de 5 SiO2. 0 a 40 H2O en donde R es un catión monovalente o 1/n de un catión de valencia n; caracterizado porque comprende hacer reaccionar una mezcla acuosa consistente en al menos una fuente de sílice, al menos una fuente de alúmina y al menos un compuesto de amonio cuaternario metilado o un compuesto de fosfonio cuaternario metilado, teniendo la mezcla la siguiente composición molar: SiO/Al2O3 al menos 10 OH-/SiO2 0,2 a 12,0 X-/SiO2 0 a 3,0 Q+ /(Q+ + AK+) 0,05 a 1,0 OH- /Ak+/(Q+ + AK+)/SiO2 0, a 0,8 H2O/OH- 25 a 250 en donde O+ es el ión amonio o fosfonio cuaternario metilado; Ak+ es un ión de metal alcalino; y X- es un anión monovalente de un anión de ácido fuerte o 1/n de un anión de ácido fuerte de valencia n, eligiéndose las condiciones para producir un precipitado que contiene al menos 20% p/p de material conteniendo sílice del tipo de las zeolitas.
ES463862A 1976-11-05 1977-11-04 Procedimiento de obtencion de un material conteniendo silicedel tipo de las zeolitas. Expired ES463862A1 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB46130/76A GB1563346A (en) 1976-11-05 1976-11-05 Silica-containing material and manufacture of hydrocarbons catalysed thereby
GB2826777 1977-07-06

Publications (1)

Publication Number Publication Date
ES463862A1 true ES463862A1 (es) 1978-12-16

Family

ID=26259293

Family Applications (2)

Application Number Title Priority Date Filing Date
ES463862A Expired ES463862A1 (es) 1976-11-05 1977-11-04 Procedimiento de obtencion de un material conteniendo silicedel tipo de las zeolitas.
ES467610A Expired ES467610A1 (es) 1976-11-05 1978-03-07 Procedimiento de conversion de hidrocarburos

Family Applications After (1)

Application Number Title Priority Date Filing Date
ES467610A Expired ES467610A1 (es) 1976-11-05 1978-03-07 Procedimiento de conversion de hidrocarburos

Country Status (9)

Country Link
US (2) US4209498A (es)
JP (1) JPS5358500A (es)
CA (1) CA1098104A (es)
DD (1) DD134242A5 (es)
DE (1) DE2748278A1 (es)
DK (1) DK152574C (es)
ES (2) ES463862A1 (es)
FR (1) FR2369871A1 (es)
NL (1) NL7712173A (es)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4191709A (en) * 1978-02-06 1980-03-04 Imperial Chemical Industries Limited Manufacture of amines from alcohols with zeolite FU-1 catalysts
BE875674A (fr) * 1978-04-21 1979-10-18 Ici Ltd Production d'amines
DK155176C (da) * 1978-06-22 1989-07-17 Snam Progetti Fremgangsmaade til fremstilling af aluminiumoxidmodificeret siliciumdioxid
US4247416A (en) * 1979-02-28 1981-01-27 Mobil Oil Corporation Crystalline zeolite ZSM-25
DE3165950D1 (de) * 1980-05-13 1984-10-18 Ici Plc Zeolite nu-3
DE3165380D1 (en) * 1980-06-12 1984-09-13 Ici Plc Zeolite eu-1
DE3170195D1 (en) * 1980-12-19 1985-05-30 Ici Plc Zeolites
JPS57169445A (en) * 1981-04-10 1982-10-19 Nitto Chem Ind Co Ltd Preparation of methylamine
JPS57191222A (en) * 1981-05-13 1982-11-25 Mobil Oil Corp Crystalline zeolite substance, manufacture and conversion of organic raw material using same
DE3372088D1 (en) * 1982-10-04 1987-07-23 Ici Plc Zeolites
US4554146A (en) * 1983-11-10 1985-11-19 Exxon Research And Engineering Co. Process for preparing a zeolite of the L type using organic templates
US4952744A (en) * 1986-01-29 1990-08-28 Chevron Research Company New zeolite SSZ-23 and its use in conversion of lower alkanols into hydrocarbons
US4902844A (en) * 1989-04-05 1990-02-20 Chevron Research Company New zeolite SSZ-23 and xylene isomerization therewith
GB8712880D0 (en) * 1987-06-02 1987-07-08 Shell Int Research Crystalline silicates
US4873387A (en) * 1987-10-13 1989-10-10 Uop Process for the isomerization of aromatics
US5110478A (en) * 1990-06-05 1992-05-05 Mobil Oil Corp. Catalytic conversion over membrane composed of a pure molecular sieve
DE69332602T2 (de) * 1992-10-14 2003-11-13 Sagem Modem enthaltender Fernsprecher
US6512155B1 (en) 2000-04-25 2003-01-28 Uop Llc Process for the activation of an alkylaromatic isomerization catalyst by water
US6890511B2 (en) 2003-03-21 2005-05-10 Uop Llc Crystalline aluminosilicate zeolitic composition: UZM-15
EP1742875A1 (en) * 2004-04-20 2007-01-17 Uop Llc Crystalline aluminosilicate zeolitic composition: uzm-15
FR2937632B1 (fr) 2008-10-29 2010-11-05 Inst Francais Du Petrole PROCEDE DE PREPARATION D'UN SOLIDE CRISTALLISE FU-1 UTILISANT UN CATION DE TYPE POLYMETHYLENE a-w DIAMMONIUM COMME STRUCTURANT ORGANIQUE
JP5613694B2 (ja) * 2012-01-19 2014-10-29 ユーオーピー エルエルシー 結晶性アルミノシリケートゼオライト質組成物：ｕｚｍ−１５

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL150082B (nl) * 1965-11-24 1976-07-15 Mobil Oil Corp Werkwijze ter bereiding van een kristallijn aluminosilicaat-zeoliet, alsmede voorwerpen, geheel of grotendeels bestaande uit kristallijne aluminosilicaten verkregen onder toepassing van deze werkwijze.
US3849463A (en) * 1969-12-18 1974-11-19 Mobil Oil Corp Prevention of silica pore obstruction in crystalline aluminosilicates
US3709979A (en) * 1970-04-23 1973-01-09 Mobil Oil Corp Crystalline zeolite zsm-11
US4052479A (en) * 1973-08-09 1977-10-04 Mobil Oil Corporation Conversion of methanol to olefinic components
US4021502A (en) * 1975-02-24 1977-05-03 Mobil Oil Corporation Converting low molecular weight olefins over zeolites
US4021447A (en) * 1975-04-30 1977-05-03 Mobil Oil Corporation Synthesis of zeolite ZSM-4
US4060590A (en) * 1975-10-03 1977-11-29 Imperial Chemical Industries Limited Zeolite Nu-1
US4066714A (en) * 1975-12-08 1978-01-03 Mobil Oil Corporation Manufacture of light olefins
US4162214A (en) * 1977-10-04 1979-07-24 Gokhman Boris K Method of preparing benzene and xylenes

Also Published As

Publication number Publication date
FR2369871A1 (fr) 1978-06-02
CA1098104A (en) 1981-03-24
JPS618009B2 (es) 1986-03-11
DK152574B (da) 1988-03-21
JPS5358500A (en) 1978-05-26
DD134242A5 (de) 1979-02-14
FR2369871B1 (es) 1982-09-17
US4209498A (en) 1980-06-24
DE2748278A1 (de) 1978-05-11
ES467610A1 (es) 1979-09-01
US4300013A (en) 1981-11-10
DK491977A (da) 1978-05-06
NL7712173A (nl) 1978-05-09
DK152574C (da) 1988-09-05

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