FR2356695A1 - Colourless, transparent, heat stabilised PVC - contg. metal salts, diketone (deriv.) and polyol - Google Patents

Colourless, transparent, heat stabilised PVC - contg. metal salts, diketone (deriv.) and polyol

Info

Publication number
FR2356695A1
FR2356695A1 FR7620181A FR7620181A FR2356695A1 FR 2356695 A1 FR2356695 A1 FR 2356695A1 FR 7620181 A FR7620181 A FR 7620181A FR 7620181 A FR7620181 A FR 7620181A FR 2356695 A1 FR2356695 A1 FR 2356695A1
Authority
FR
France
Prior art keywords
gps
opt
pts
cycloaliphatic
aryl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7620181A
Other languages
French (fr)
Other versions
FR2356695B1 (en
Inventor
Michel Gay
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhone Poulenc Industries SA
Original Assignee
Rhone Poulenc Industries SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhone Poulenc Industries SA filed Critical Rhone Poulenc Industries SA
Priority to FR7620181A priority Critical patent/FR2356695A1/en
Priority to NL7706976A priority patent/NL7706976A/en
Priority to MX775836U priority patent/MX4810E/en
Priority to NZ184467A priority patent/NZ184467A/en
Priority to PT66716A priority patent/PT66716B/en
Priority to ZA00773798A priority patent/ZA773798B/en
Priority to GB26612/77A priority patent/GB1567257A/en
Priority to LU77610A priority patent/LU77610A1/xx
Priority to AU26470/77A priority patent/AU511924B2/en
Priority to TR19632A priority patent/TR19632A/en
Priority to GR53812A priority patent/GR61996B/en
Priority to DE2728865A priority patent/DE2728865B2/en
Priority to SE7707410A priority patent/SE417834B/en
Priority to JP7643277A priority patent/JPS533443A/en
Priority to FI771998A priority patent/FI771998A/en
Priority to DK284077A priority patent/DK284077A/en
Priority to DD7700199716A priority patent/DD131032A5/en
Priority to NO772264A priority patent/NO772264L/en
Priority to BR7704169A priority patent/BR7704169A/en
Priority to CA281,457A priority patent/CA1090931A/en
Priority to ES460176A priority patent/ES460176A1/en
Priority to AT459177A priority patent/AT350278B/en
Priority to IT25154/77A priority patent/IT1086240B/en
Priority to CH793977A priority patent/CH622275A5/fr
Priority to SU772496801A priority patent/SU673183A3/en
Priority to BE178865A priority patent/BE856216A/en
Priority to US05/810,845 priority patent/US4123399A/en
Publication of FR2356695A1 publication Critical patent/FR2356695A1/en
Application granted granted Critical
Publication of FR2356695B1 publication Critical patent/FR2356695B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/07—Aldehydes; Ketones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0016—Plasticisers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/05—Alcohols; Metal alcoholates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/05—Alcohols; Metal alcoholates
    • C08K5/053—Polyhydroxylic alcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098—Metal salts of carboxylic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A plasticised PVC compsn. contains (a) 5-120 pts. wt. of a normal PVC plasticiser, (b) 0.1-5 pts. wt. of a pair of organic acid salts of Ca and Zn, (c) 0.03-1 pts. wt. of a linear polyol with is not 4 OH gps., of which is not S1 is a prim. alcoholic OH gp. and (d) 0.05-5 pts. wt. or a cpd. of formula R1-CO-CHR2-CO-R (I) (where R1 and R3 are (un)branched 36C alk(en)yl gps., 7-36C aralkyl gps. or 14C aryl or cycloaliphatic gps. gp. opt. contg. C=C bonds, opt. substd. by halogen, by aryl or cycloaliphatic gps. or by (m)ethyl, or may be modified by is not 1 -O-, -CO-O-, or -CO- in the aliphatic chain and may also form together a 2-5C alkylene gp., opt. carrying O or N; and R2 is h, 36C alk(en)yl opt. carrying -O-, -CO-O- or -CO- gps., a radical of formula -CO-R4, where R4 is 1-36C alkyl or is aryl, a radical of formula where R5 is 1-6C alkyl; in addn., in in r1 and r3, the C atom linked to the CO gp. is free from ethylenic, carbonyl or aromatic unsaturation, one of R1 or R3 may be H; and R1 and R2 together may form a 7-36C aralkylene gp., or a 14C arylene or cycloaliphatic gp., opt contg. C=C bonds; and where these gps. may opt. be substd. by halogen, by aryl or cycloaliphatic gps., or by (m)ethyl, and may also be modified by -O-, -CO-O- or -CO- in the aliphatic chain. The compsn. contains no toxic component, gives colourless, transparent goods, and does not change colour after 1 hour at 180 degrees C. Addn of the polyol greatly improves the heat stability. The compsns. are suitable for food applications.
FR7620181A 1976-06-28 1976-06-28 Colourless, transparent, heat stabilised PVC - contg. metal salts, diketone (deriv.) and polyol Granted FR2356695A1 (en)

Priority Applications (27)

Application Number Priority Date Filing Date Title
FR7620181A FR2356695A1 (en) 1976-06-28 1976-06-28 Colourless, transparent, heat stabilised PVC - contg. metal salts, diketone (deriv.) and polyol
NL7706976A NL7706976A (en) 1976-06-28 1977-06-23 WEEKLY-MADE AND STABILIZED PREPARATIONS BASED ON VAL POLYVINYL CHLORIDE.
MX775836U MX4810E (en) 1976-06-28 1977-06-23 IMPROVED STABILIZED COMPOSITION OF VINYL POLYCHLORIDE
NZ184467A NZ184467A (en) 1976-06-28 1977-06-23 Plasticized stabilized poly(vinyl chloride)
ZA00773798A ZA773798B (en) 1976-06-28 1977-06-24 Plasticised and stabilised poly(vinyl chloride)compositions
GB26612/77A GB1567257A (en) 1976-06-28 1977-06-24 Plasticised and stabilised poly-(vinyl chhloride)compositions
LU77610A LU77610A1 (en) 1976-06-28 1977-06-24
AU26470/77A AU511924B2 (en) 1976-06-28 1977-06-24 Plasticised and stabilised poly (vinyl chlorile) compositions
PT66716A PT66716B (en) 1976-06-28 1977-06-24 PROCESS FOR THE PREPARATION OF PLASTICATED AND STABILIZED COMPOSITIONS BASED ON POLY (VINYL CHLORIDE)
DK284077A DK284077A (en) 1976-06-28 1977-06-27 BLOODED AND STABILIZED COMPOSITIONS BASED ON POLYVINYL CHLORIDE
DE2728865A DE2728865B2 (en) 1976-06-28 1977-06-27 Stabilized molding compounds based on vinyl chloride polymers
SE7707410A SE417834B (en) 1976-06-28 1977-06-27 SOFT AND STABILIZED COMPOSITIONS BASED ON POLYVINYL CHLORIDE
JP7643277A JPS533443A (en) 1976-06-28 1977-06-27 Plastilized and stabilized composition based on polyvinyl chloride
FI771998A FI771998A (en) 1976-06-28 1977-06-27 PLASTIC PLANT AND STABILIZER POLYVINYL CHLORIDE COMPOSITION
TR19632A TR19632A (en) 1976-06-28 1977-06-27 POLIVINYL KLORUER, BASED PLASTICIZED AND STABILIZED COMPOSITIONS
DD7700199716A DD131032A5 (en) 1976-06-28 1977-06-27 HEAT-STABILIZED MOLDING BASED ON VINYL CHLORIDE POLYMERIZES
NO772264A NO772264L (en) 1976-06-28 1977-06-27 SOFTENED AND STABILIZED COMPOSITIONS POLYVINYL CHLORIDE BASIS
BR7704169A BR7704169A (en) 1976-06-28 1977-06-27 POLY (VINYL CHLORIDE) PLASTIFIED COMPOSITES
CA281,457A CA1090931A (en) 1976-06-28 1977-06-27 Plastified, stabilized compositions of poly (vinyl chloride)
GR53812A GR61996B (en) 1976-06-28 1977-06-27 Plasticized and stabilized compositions with poly(vinylchloride)base
AT459177A AT350278B (en) 1976-06-28 1977-06-28 SOFTENED AND STABILIZED MOLDING COMPOUNDS BASED ON POLYVINYL CHLORIDE
IT25154/77A IT1086240B (en) 1976-06-28 1977-06-28 PLASTICIZED AND STABILIZED COMPOSITIONS, POLY BASED (VINYL-CHLORIDE)
CH793977A CH622275A5 (en) 1976-06-28 1977-06-28
SU772496801A SU673183A3 (en) 1976-06-28 1977-06-28 Polymeric composition
ES460176A ES460176A1 (en) 1976-06-28 1977-06-28 Plasticized, heat-stabilized PVC compositions
BE178865A BE856216A (en) 1976-06-28 1977-06-28 PLASTICIZED AND STABILIZED COMPOSITIONS BASED ON POLY (VINYL CHLORIDE)
US05/810,845 US4123399A (en) 1976-06-28 1977-06-28 Plasticized, heat-stabilized PVC compositions

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7620181A FR2356695A1 (en) 1976-06-28 1976-06-28 Colourless, transparent, heat stabilised PVC - contg. metal salts, diketone (deriv.) and polyol

Publications (2)

Publication Number Publication Date
FR2356695A1 true FR2356695A1 (en) 1978-01-27
FR2356695B1 FR2356695B1 (en) 1978-12-15

Family

ID=9175144

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7620181A Granted FR2356695A1 (en) 1976-06-28 1976-06-28 Colourless, transparent, heat stabilised PVC - contg. metal salts, diketone (deriv.) and polyol

Country Status (7)

Country Link
AU (1) AU511924B2 (en)
BE (1) BE856216A (en)
CA (1) CA1090931A (en)
FR (1) FR2356695A1 (en)
GR (1) GR61996B (en)
SU (1) SU673183A3 (en)
ZA (1) ZA773798B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0062813A1 (en) * 1981-04-03 1982-10-20 Henkel Kommanditgesellschaft auf Aktien Stable polyvinylchloride moulded mass
EP2206739A2 (en) 2009-01-09 2010-07-14 Sumitomo Chemical Company, Limited Polymer stabilizer

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2918775A1 (en) 1979-05-10 1980-11-20 Merck Patent Gmbh DIKETONES, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE AS COMPONENT LIQUID CRYSTAL IN DIELECTRICS
NZ217159A (en) * 1985-08-26 1989-04-26 Goodrich Co B F Clear polyvinyl chloride compositions

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
NEANT *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0062813A1 (en) * 1981-04-03 1982-10-20 Henkel Kommanditgesellschaft auf Aktien Stable polyvinylchloride moulded mass
EP2206739A2 (en) 2009-01-09 2010-07-14 Sumitomo Chemical Company, Limited Polymer stabilizer
EP2206739A3 (en) * 2009-01-09 2011-03-16 Sumitomo Chemical Company, Limited Polymer stabilizer

Also Published As

Publication number Publication date
AU511924B2 (en) 1980-09-11
BE856216A (en) 1977-12-28
CA1090931A (en) 1980-12-02
GR61996B (en) 1979-02-14
AU2647077A (en) 1979-01-04
FR2356695B1 (en) 1978-12-15
ZA773798B (en) 1978-05-30
SU673183A3 (en) 1979-07-05

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TP Transmission of property
ST Notification of lapse