FR2325736A1 - Purifying chromium contg. solns. from rinsing baths from pickling - by electrodialysis continuously using specified apparatus - Google Patents
Purifying chromium contg. solns. from rinsing baths from pickling - by electrodialysis continuously using specified apparatusInfo
- Publication number
- FR2325736A1 FR2325736A1 FR7529044A FR7529044A FR2325736A1 FR 2325736 A1 FR2325736 A1 FR 2325736A1 FR 7529044 A FR7529044 A FR 7529044A FR 7529044 A FR7529044 A FR 7529044A FR 2325736 A1 FR2325736 A1 FR 2325736A1
- Authority
- FR
- France
- Prior art keywords
- effluent
- pickling
- cathode
- anode
- contg
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011651 chromium Substances 0.000 title abstract 3
- 238000005554 pickling Methods 0.000 title abstract 3
- 238000000909 electrodialysis Methods 0.000 title abstract 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 title 1
- 229910052804 chromium Inorganic materials 0.000 title 1
- 239000003011 anion exchange membrane Substances 0.000 abstract 2
- 238000011282 treatment Methods 0.000 abstract 2
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 abstract 1
- 238000004140 cleaning Methods 0.000 abstract 1
- 238000009713 electroplating Methods 0.000 abstract 1
- 239000012535 impurity Substances 0.000 abstract 1
- 231100000331 toxic Toxicity 0.000 abstract 1
- 230000002588 toxic effect Effects 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
- B01D61/44—Ion-selective electrodialysis
- B01D61/46—Apparatus therefor
- B01D61/463—Apparatus therefor comprising the membrane sequence AC or CA, where C is a cation exchange membrane
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D21/00—Processes for servicing or operating cells for electrolytic coating
- C25D21/16—Regeneration of process solutions
- C25D21/20—Regeneration of process solutions of rinse-solutions
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/469—Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
- C02F2101/22—Chromium or chromium compounds, e.g. chromates
Landscapes
- Engineering & Computer Science (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Urology & Nephrology (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Abstract
An apparatus for purifying toxic effluent contg. hexavalent Cr continuously by electrodialysis comprises a treatment tank, connected to the effluent tank via pumps and filters, which contains an accessible cathode compartment which is separated from the anode comparment by anion exchange membranes. The cathode surface is low in relation to the anode surface to maintain a strong cathode polarisation by a continuous current from a low voltage generator. The impurities pptd. in the cathode compartment are removed by cleaning. The anion exchange membranes result in enrichment of hexavalent Cr in the anode compartment solution which is recycled as necessary via a control valve for further use. The effluent arises from pickling baths used in electroplating processing. Compared with previous treatments, the above is cheaper, recovers the hexavalent chromium for further use and is continuous. The effluent which is fed from the washing bath after pickling is recycled and therefore the rinsing bath is maintained at a constant quality level.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7529044A FR2325736A1 (en) | 1975-09-23 | 1975-09-23 | Purifying chromium contg. solns. from rinsing baths from pickling - by electrodialysis continuously using specified apparatus |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7529044A FR2325736A1 (en) | 1975-09-23 | 1975-09-23 | Purifying chromium contg. solns. from rinsing baths from pickling - by electrodialysis continuously using specified apparatus |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2325736A1 true FR2325736A1 (en) | 1977-04-22 |
FR2325736B3 FR2325736B3 (en) | 1978-05-05 |
Family
ID=9160314
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7529044A Granted FR2325736A1 (en) | 1975-09-23 | 1975-09-23 | Purifying chromium contg. solns. from rinsing baths from pickling - by electrodialysis continuously using specified apparatus |
Country Status (1)
Country | Link |
---|---|
FR (1) | FR2325736A1 (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2390384A1 (en) * | 1977-05-12 | 1978-12-08 | Fiat Spa | PROCESS FOR DEPURING AQUEOUS EFFLUENT FROM AN ELECTROLYTIC TREATMENT PLANT |
EP0010984A2 (en) * | 1978-11-06 | 1980-05-14 | Innova, Inc. | Layered membrane assembly and electrochemical processes and electrochemical cell utilizing same |
NL9400504A (en) * | 1994-03-30 | 1995-11-01 | Elektrolyse Project B V | Method for purifying a contaminated oxidizing solution in a dialysis cell |
CN100381370C (en) * | 2006-06-14 | 2008-04-16 | 浙江大学 | System for removing and retrieving hexavalent chrome from wastewater |
IT202100017015A1 (en) * | 2021-07-02 | 2023-01-02 | Biored Srl | PROCEDURE AND ELECTROCHEMICAL CELL FOR THE RECOVERY OF PURE CHROME (III) FROM USED BATHS IN THE TANNING INDUSTRY |
-
1975
- 1975-09-23 FR FR7529044A patent/FR2325736A1/en active Granted
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2390384A1 (en) * | 1977-05-12 | 1978-12-08 | Fiat Spa | PROCESS FOR DEPURING AQUEOUS EFFLUENT FROM AN ELECTROLYTIC TREATMENT PLANT |
EP0010984A2 (en) * | 1978-11-06 | 1980-05-14 | Innova, Inc. | Layered membrane assembly and electrochemical processes and electrochemical cell utilizing same |
EP0010984A3 (en) * | 1978-11-06 | 1980-05-28 | Innova, Inc. | Layered membrane assembly and electrochemical processes and electrochemical cell utilizing same |
NL9400504A (en) * | 1994-03-30 | 1995-11-01 | Elektrolyse Project B V | Method for purifying a contaminated oxidizing solution in a dialysis cell |
CN100381370C (en) * | 2006-06-14 | 2008-04-16 | 浙江大学 | System for removing and retrieving hexavalent chrome from wastewater |
IT202100017015A1 (en) * | 2021-07-02 | 2023-01-02 | Biored Srl | PROCEDURE AND ELECTROCHEMICAL CELL FOR THE RECOVERY OF PURE CHROME (III) FROM USED BATHS IN THE TANNING INDUSTRY |
Also Published As
Publication number | Publication date |
---|---|
FR2325736B3 (en) | 1978-05-05 |
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