FR2317365A1 - Manganese ions removal from zinc sulphate soln. - obtd. during extn. of zinc by oxidising to manganese dioxide and pptn. - Google Patents

Manganese ions removal from zinc sulphate soln. - obtd. during extn. of zinc by oxidising to manganese dioxide and pptn.

Info

Publication number
FR2317365A1
FR2317365A1 FR7617888A FR7617888A FR2317365A1 FR 2317365 A1 FR2317365 A1 FR 2317365A1 FR 7617888 A FR7617888 A FR 7617888A FR 7617888 A FR7617888 A FR 7617888A FR 2317365 A1 FR2317365 A1 FR 2317365A1
Authority
FR
France
Prior art keywords
zinc
soln
manganese
pptn
extn
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7617888A
Other languages
French (fr)
Other versions
FR2317365B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Newmont Exploration Ltd
Original Assignee
Newmont Exploration Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/682,442 external-priority patent/US4067789A/en
Application filed by Newmont Exploration Ltd filed Critical Newmont Exploration Ltd
Publication of FR2317365A1 publication Critical patent/FR2317365A1/en
Application granted granted Critical
Publication of FR2317365B1 publication Critical patent/FR2317365B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B19/00—Obtaining zinc or zinc oxide
    • C22B19/20—Obtaining zinc otherwise than by distilling
    • C22B19/26—Refining solutions containing zinc values, e.g. obtained by leaching zinc ores
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/02—Oxides; Hydroxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G9/00—Compounds of zinc
    • C01G9/06—Sulfates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/74—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by peak-intensities or a ratio thereof only
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/80—Compositional purity
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

Method of removing soluble manganous ions from a soln. contg. zinc sulphate comprises treatment of (part of) the soln. with an oxidant which can oxidise the manganous ions to insoluble filterable alpha-MnO2, the oxidant being in amount 130-150% of that theoretically required to remove all the Mn ++, and separating off the ppte. The process is effected at between 90 degrees C and the b.pt. of the soln. in 1/2-2 hrs. Used in the recovery of zinc from a concentrate of Zn contg. Mn, the concentrate having been roasted and leached to dissolve the zinc and treated to remove iron. Process may also be used in removing manganese from other metal salt solutions. In the subsequent process of electrolysing the zinc sulphate to extract the zinc, improved yields are obtained of zinc uncontaminated with Mn, having improved physical and chemical properties.
FR7617888A 1975-07-09 1976-06-11 Manganese ions removal from zinc sulphate soln. - obtd. during extn. of zinc by oxidising to manganese dioxide and pptn. Granted FR2317365A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US59427875A 1975-07-09 1975-07-09
US05/682,442 US4067789A (en) 1975-07-09 1976-05-03 Process for manganese removal from zinc metal bearing solutions

Publications (2)

Publication Number Publication Date
FR2317365A1 true FR2317365A1 (en) 1977-02-04
FR2317365B1 FR2317365B1 (en) 1980-10-24

Family

ID=27081922

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7617888A Granted FR2317365A1 (en) 1975-07-09 1976-06-11 Manganese ions removal from zinc sulphate soln. - obtd. during extn. of zinc by oxidising to manganese dioxide and pptn.

Country Status (8)

Country Link
AR (1) AR214399A1 (en)
AU (1) AU498352B2 (en)
CA (1) CA1070122A (en)
DE (1) DE2626679A1 (en)
ES (2) ES448693A1 (en)
FI (1) FI65815C (en)
FR (1) FR2317365A1 (en)
NL (1) NL7606394A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0001680A1 (en) * 1977-09-17 1979-05-02 Interox Chemicals Limited Process for the recovery of manganese from aqueous acidic solutions
EP0013098A1 (en) * 1978-12-20 1980-07-09 Sherritt Gordon Mines Limited Removal of manganese ions from zinc and manganese containing solutions

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4100911A1 (en) * 1991-01-15 1992-07-16 Bayer Ag Sepg. zinc from pyrolusite by washing with dil. mineral acid - also giving manganese di:oxide useful in pigment, oxidant and ferrite mfr. and e.g. zinc sulphate
US12000014B2 (en) 2018-08-09 2024-06-04 Bromine Compounds Ltd. Process for recovering metals from recycled rechargeable batteries

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE303802C (en) *
DE154085C (en) *
GB100171A (en) * 1915-03-16 1900-01-01 Bonastre Llopart Ramon Process of Preparing and Inalternate White Product for Painting and other Purposes.
FR464038A (en) * 1913-09-02 1914-03-11 Shunjiro Araki Process for preparing a solution of pure zinc sulphate using zinc ores
GB138946A (en) * 1918-05-22 1920-02-26 Samuel Field Improvements in or relating to the purification of zinc solutions
US1395811A (en) * 1919-11-07 1921-11-01 Electrolytic Zinc Company Treatment of zinc-bearing ores
US1937633A (en) * 1931-03-18 1933-12-05 Niels C Christensen Process of treating zinc ores
US3436177A (en) * 1968-02-28 1969-04-01 Kennecott Copper Corp Continuous process for removing multivalent impurities from copper-bearing leach solutions
FR2025077A1 (en) * 1968-12-03 1970-09-04 Norddeutsche Affinerie
US3691038A (en) * 1969-09-25 1972-09-12 Det Norske Zenkkompani As Process for the recovery of zinc from zinc- and iron-containing materials

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE303802C (en) *
DE154085C (en) *
FR464038A (en) * 1913-09-02 1914-03-11 Shunjiro Araki Process for preparing a solution of pure zinc sulphate using zinc ores
GB100171A (en) * 1915-03-16 1900-01-01 Bonastre Llopart Ramon Process of Preparing and Inalternate White Product for Painting and other Purposes.
GB138946A (en) * 1918-05-22 1920-02-26 Samuel Field Improvements in or relating to the purification of zinc solutions
US1395811A (en) * 1919-11-07 1921-11-01 Electrolytic Zinc Company Treatment of zinc-bearing ores
US1937633A (en) * 1931-03-18 1933-12-05 Niels C Christensen Process of treating zinc ores
US3436177A (en) * 1968-02-28 1969-04-01 Kennecott Copper Corp Continuous process for removing multivalent impurities from copper-bearing leach solutions
FR2025077A1 (en) * 1968-12-03 1970-09-04 Norddeutsche Affinerie
US3691038A (en) * 1969-09-25 1972-09-12 Det Norske Zenkkompani As Process for the recovery of zinc from zinc- and iron-containing materials

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0001680A1 (en) * 1977-09-17 1979-05-02 Interox Chemicals Limited Process for the recovery of manganese from aqueous acidic solutions
EP0013098A1 (en) * 1978-12-20 1980-07-09 Sherritt Gordon Mines Limited Removal of manganese ions from zinc and manganese containing solutions

Also Published As

Publication number Publication date
NL7606394A (en) 1977-01-11
AR214399A1 (en) 1979-06-15
CA1070122A (en) 1980-01-22
FI65815C (en) 1984-07-10
AU1429576A (en) 1977-12-01
FR2317365B1 (en) 1980-10-24
DE2626679A1 (en) 1977-01-27
ES448693A1 (en) 1977-11-16
AU498352B2 (en) 1979-03-08
FI761659A (en) 1977-01-10
ES458525A1 (en) 1978-04-01
FI65815B (en) 1984-03-30

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Legal Events

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