FR2317269A1 - Procede de fabrication d'acides et d'esters alcane carboxyliques par reaction d'alcools avec le monoxyde de carbone en presence de catalyseurs contenant de l'iridium - Google Patents
Procede de fabrication d'acides et d'esters alcane carboxyliques par reaction d'alcools avec le monoxyde de carbone en presence de catalyseurs contenant de l'iridiumInfo
- Publication number
- FR2317269A1 FR2317269A1 FR7522032A FR7522032A FR2317269A1 FR 2317269 A1 FR2317269 A1 FR 2317269A1 FR 7522032 A FR7522032 A FR 7522032A FR 7522032 A FR7522032 A FR 7522032A FR 2317269 A1 FR2317269 A1 FR 2317269A1
- Authority
- FR
- France
- Prior art keywords
- prepn
- alkanoic acids
- iridium
- bromine
- iodine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 title abstract 4
- 239000002253 acid Substances 0.000 title abstract 2
- 150000007513 acids Chemical class 0.000 title abstract 2
- 150000002148 esters Chemical class 0.000 title abstract 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 title 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 title 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title 1
- 150000001298 alcohols Chemical class 0.000 title 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 title 1
- 229910052794 bromium Inorganic materials 0.000 title 1
- 229910002091 carbon monoxide Inorganic materials 0.000 title 1
- 229910052802 copper Inorganic materials 0.000 title 1
- 239000010949 copper Substances 0.000 title 1
- 229910052740 iodine Inorganic materials 0.000 title 1
- 239000011630 iodine Substances 0.000 title 1
- 229910052741 iridium Inorganic materials 0.000 title 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 title 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 abstract 2
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 abstract 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 abstract 1
- -1 methyl acetate Chemical class 0.000 abstract 1
- 229910000510 noble metal Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7522032A FR2317269A1 (fr) | 1975-07-10 | 1975-07-10 | Procede de fabrication d'acides et d'esters alcane carboxyliques par reaction d'alcools avec le monoxyde de carbone en presence de catalyseurs contenant de l'iridium |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7522032A FR2317269A1 (fr) | 1975-07-10 | 1975-07-10 | Procede de fabrication d'acides et d'esters alcane carboxyliques par reaction d'alcools avec le monoxyde de carbone en presence de catalyseurs contenant de l'iridium |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2317269A1 true FR2317269A1 (fr) | 1977-02-04 |
| FR2317269B1 FR2317269B1 (enExample) | 1979-01-19 |
Family
ID=9157902
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR7522032A Granted FR2317269A1 (fr) | 1975-07-10 | 1975-07-10 | Procede de fabrication d'acides et d'esters alcane carboxyliques par reaction d'alcools avec le monoxyde de carbone en presence de catalyseurs contenant de l'iridium |
Country Status (1)
| Country | Link |
|---|---|
| FR (1) | FR2317269A1 (enExample) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4670570A (en) * | 1984-07-20 | 1987-06-02 | Union Carbide Corporation | Production of carboxylic acids from alcohols using rhodium complex catalysts |
| US5026907A (en) * | 1984-08-16 | 1991-06-25 | Union Carbide Chemicals And Plastics Technology Corporation | Production of carboxylic acids from alcohols using rhodium complex catalysts and organic ester source |
| EP0618184A1 (fr) * | 1993-03-31 | 1994-10-05 | Pardies Acetiques | Procédé de préparation d'acides carboxyliques ou des esters correspondants en présence d'un catalyseur à base d'irridium |
| FR2703352A1 (fr) * | 1993-03-31 | 1994-10-07 | Rhone Poulenc Chimie | Procédé de préparation d'acides carboxyliques ou des esters correspondants en présence d'un catalyseur à base d'iridium. |
| EP0749948A1 (en) * | 1995-06-21 | 1996-12-27 | BP Chemicals Limited | Process for the carbonylation of alkyl alcohols and/or reactive derivatives thereof |
| US5625094A (en) * | 1993-03-31 | 1997-04-29 | Rhone-Poulenc Chimie | Rhodium/iridium catalyzed synthesis of carboxylic acids or esters thereof |
-
1975
- 1975-07-10 FR FR7522032A patent/FR2317269A1/fr active Granted
Non-Patent Citations (1)
| Title |
|---|
| NEANT * |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4670570A (en) * | 1984-07-20 | 1987-06-02 | Union Carbide Corporation | Production of carboxylic acids from alcohols using rhodium complex catalysts |
| US5026907A (en) * | 1984-08-16 | 1991-06-25 | Union Carbide Chemicals And Plastics Technology Corporation | Production of carboxylic acids from alcohols using rhodium complex catalysts and organic ester source |
| EP0618184A1 (fr) * | 1993-03-31 | 1994-10-05 | Pardies Acetiques | Procédé de préparation d'acides carboxyliques ou des esters correspondants en présence d'un catalyseur à base d'irridium |
| FR2703352A1 (fr) * | 1993-03-31 | 1994-10-07 | Rhone Poulenc Chimie | Procédé de préparation d'acides carboxyliques ou des esters correspondants en présence d'un catalyseur à base d'iridium. |
| US5625094A (en) * | 1993-03-31 | 1997-04-29 | Rhone-Poulenc Chimie | Rhodium/iridium catalyzed synthesis of carboxylic acids or esters thereof |
| CN1055914C (zh) * | 1993-03-31 | 2000-08-30 | 派蒂斯艾西提克公司 | 在基于铱的催化剂存在下制备羧酸或其酯的方法 |
| EP0749948A1 (en) * | 1995-06-21 | 1996-12-27 | BP Chemicals Limited | Process for the carbonylation of alkyl alcohols and/or reactive derivatives thereof |
| US5696284A (en) * | 1995-06-21 | 1997-12-09 | Bp Chemicals Limited | Process for the carbonylation of alkyl alcohols and/or reactive derivatives thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2317269B1 (enExample) | 1979-01-19 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |