FR2288610A1 - Moulding closed cell phenolic resin foams for insulated roofing - using fillers and mould temp differentials to modify the foam - Google Patents

Moulding closed cell phenolic resin foams for insulated roofing - using fillers and mould temp differentials to modify the foam

Info

Publication number
FR2288610A1
FR2288610A1 FR7404186A FR7404186A FR2288610A1 FR 2288610 A1 FR2288610 A1 FR 2288610A1 FR 7404186 A FR7404186 A FR 7404186A FR 7404186 A FR7404186 A FR 7404186A FR 2288610 A1 FR2288610 A1 FR 2288610A1
Authority
FR
France
Prior art keywords
mould
moulding
fillers
foam
closed cell
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7404186A
Other languages
French (fr)
Other versions
FR2288610B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to FR7404186A priority Critical patent/FR2288610A1/en
Priority to BE166301A priority patent/BE840923A/en
Priority to DE19762617414 priority patent/DE2617414A1/en
Publication of FR2288610A1 publication Critical patent/FR2288610A1/en
Application granted granted Critical
Publication of FR2288610B1 publication Critical patent/FR2288610B1/fr
Granted legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/02Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles
    • B29C44/04Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles consisting of at least two parts of chemically or physically different materials, e.g. having different densities
    • B29C44/0407Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles consisting of at least two parts of chemically or physically different materials, e.g. having different densities by regulating the temperature of the mould or parts thereof, e.g. cold mould walls inhibiting foaming of an outer layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/02Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles
    • B29C44/12Incorporating or moulding on preformed parts, e.g. inserts or reinforcements
    • B29C44/1271Incorporating or moulding on preformed parts, e.g. inserts or reinforcements the preformed parts being partially covered
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0066Use of inorganic compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/34Chemical features in the manufacture of articles consisting of a foamed macromolecular core and a macromolecular surface layer having a higher density than the core
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04DROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
    • E04D3/00Roof covering by making use of flat or curved slabs or stiff sheets
    • E04D3/35Roofing slabs or stiff sheets comprising two or more layers, e.g. for insulation
    • E04D3/351Roofing slabs or stiff sheets comprising two or more layers, e.g. for insulation at least one of the layers being composed of insulating material, e.g. fibre or foam material
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04DROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
    • E04D3/00Roof covering by making use of flat or curved slabs or stiff sheets
    • E04D3/35Roofing slabs or stiff sheets comprising two or more layers, e.g. for insulation
    • E04D3/351Roofing slabs or stiff sheets comprising two or more layers, e.g. for insulation at least one of the layers being composed of insulating material, e.g. fibre or foam material
    • E04D3/352Roofing slabs or stiff sheets comprising two or more layers, e.g. for insulation at least one of the layers being composed of insulating material, e.g. fibre or foam material at least one insulating layer being located between non-insulating layers, e.g. double skin slabs or sheets
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04DROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
    • E04D3/00Roof covering by making use of flat or curved slabs or stiff sheets
    • E04D3/35Roofing slabs or stiff sheets comprising two or more layers, e.g. for insulation
    • E04D3/358Roofing slabs or stiff sheets comprising two or more layers, e.g. for insulation with at least one of the layers being offset with respect to another layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00Moulds or cores; Details thereof or accessories therefor
    • B29C33/02Moulds or cores; Details thereof or accessories therefor with incorporated heating or cooling means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2061/00Use of condensation polymers of aldehydes or ketones or derivatives thereof, as moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/04Condition, form or state of moulded material or of the material to be shaped cellular or porous
    • B29K2105/043Skinned foam
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/12Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts of short lengths, e.g. chopped filaments, staple fibres or bristles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/16Fillers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/10Building elements, e.g. bricks, blocks, tiles, panels, posts, beams
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2361/00Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
    • C08J2361/04Condensation polymers of aldehydes or ketones with phenols only
    • C08J2361/06Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Laminated Bodies (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

Mouldings made of phenol-formaldehyde resin by blending successively with the resin powdered and fibrous fillers, acidic or basic catalysts and a low boiling pt. blowing agent, then injecting the mixt into a mould having temp. gradients between different regions of the cavity. The different temps. result in different degrees of cell expansion and hence different densities within the moulding. Specif. the upper part of the mould is relatively hot. The moulding is formed with a strong skin and closed cell foam core which is less dense in its higher parts (as moulded). Esp. for mfr. of insulating roofing materials, with the foam being developed in a mould lined with e.g. cement or stone tiles which become integrally anchored to the moulding surface. Produces lightweight panels of inflammable insulating materials. The presence of fillers reduces the brittleness of the foamed resin.
FR7404186A 1974-02-07 1974-02-07 Moulding closed cell phenolic resin foams for insulated roofing - using fillers and mould temp differentials to modify the foam Granted FR2288610A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
FR7404186A FR2288610A1 (en) 1974-02-07 1974-02-07 Moulding closed cell phenolic resin foams for insulated roofing - using fillers and mould temp differentials to modify the foam
BE166301A BE840923A (en) 1974-02-07 1976-04-20 PROCESS FOR THE MANUFACTURING BY MOLDING OF OBJECTS AND FORMO-PHENOLIC RESIN
DE19762617414 DE2617414A1 (en) 1974-02-07 1976-04-21 Moulding phenol-formaldehyde resin article - contg powder and fibre filler in differentially heated mould to produce high density skin

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
FR7404186A FR2288610A1 (en) 1974-02-07 1974-02-07 Moulding closed cell phenolic resin foams for insulated roofing - using fillers and mould temp differentials to modify the foam
BE166301A BE840923A (en) 1974-02-07 1976-04-20 PROCESS FOR THE MANUFACTURING BY MOLDING OF OBJECTS AND FORMO-PHENOLIC RESIN
BE840923 1976-04-20
DE19762617414 DE2617414A1 (en) 1974-02-07 1976-04-21 Moulding phenol-formaldehyde resin article - contg powder and fibre filler in differentially heated mould to produce high density skin

Publications (2)

Publication Number Publication Date
FR2288610A1 true FR2288610A1 (en) 1976-05-21
FR2288610B1 FR2288610B1 (en) 1978-02-17

Family

ID=61223468

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7404186A Granted FR2288610A1 (en) 1974-02-07 1974-02-07 Moulding closed cell phenolic resin foams for insulated roofing - using fillers and mould temp differentials to modify the foam

Country Status (3)

Country Link
BE (1) BE840923A (en)
DE (1) DE2617414A1 (en)
FR (1) FR2288610A1 (en)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2491821A1 (en) * 1980-10-14 1982-04-16 Sommer Sa Moulding chopped fibres with phenolic resin and blowing agent - to produce insulating panels from recycled materials
FR2506813A1 (en) * 1981-06-02 1982-12-03 Bouygues Sa Modular roofing panels - comprising large hollow insulated mouldings linked to resemble overlapping tile slate structures
FR2581683A1 (en) * 1985-05-09 1986-11-14 Angers Ardoisieres Roof and cladding panel and method of manufacture
EP0276430A1 (en) * 1986-12-24 1988-08-03 AUST, Else, geb. Böhme Densely filled phenolic resin foams, and their use as insulation material
EP0285509A1 (en) * 1987-03-31 1988-10-05 Hutchinson Building construction elements, especially for coverings and/or claddings, and devices for their attachment to an underlying support
FR2646454A1 (en) * 1989-04-28 1990-11-02 Desplanques Yves Method and installation for covering a roof panel with an insulating material
WO1993024305A1 (en) * 1992-06-04 1993-12-09 Vilcsek Dünnsteintechnik Manufaktur Kg Process for manufacturing a composite slab
EP0609721A2 (en) * 1993-02-05 1994-08-10 Glaswerk Schuller GmbH Skinlayer for foam core sandwich structure and its manufacturing process
US5716563A (en) * 1992-02-05 1998-02-10 Weyerhaeuser Company Method of forming a surfaced cellulosic composite panel
GB2357992A (en) * 1999-10-08 2001-07-11 Thorstone Business Man Ltd Foam laminates
WO2013151419A1 (en) * 2012-04-05 2013-10-10 Enkev B.V. Method for manufacturing a composite element and support element provided thereby

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1150450A (en) * 1978-09-14 1983-07-19 Company 'a' (Foam) Limited Foamed plastics materials
ATE182509T1 (en) * 1992-03-26 1999-08-15 Isoflam Int Ltd METHOD FOR PRODUCING FOAM BOARDS FROM PHENOL-FORMALDEHYDE
US6586501B1 (en) 1999-01-20 2003-07-01 Cabot Corporation Aggregates having attached polymer groups and polymer foams
US6258864B1 (en) 1999-01-20 2001-07-10 Cabot Corporation Polymer foam containing chemically modified carbonaceous filler

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
NEANT *

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2491821A1 (en) * 1980-10-14 1982-04-16 Sommer Sa Moulding chopped fibres with phenolic resin and blowing agent - to produce insulating panels from recycled materials
FR2506813A1 (en) * 1981-06-02 1982-12-03 Bouygues Sa Modular roofing panels - comprising large hollow insulated mouldings linked to resemble overlapping tile slate structures
FR2581683A1 (en) * 1985-05-09 1986-11-14 Angers Ardoisieres Roof and cladding panel and method of manufacture
EP0276430A1 (en) * 1986-12-24 1988-08-03 AUST, Else, geb. Böhme Densely filled phenolic resin foams, and their use as insulation material
EP0285509A1 (en) * 1987-03-31 1988-10-05 Hutchinson Building construction elements, especially for coverings and/or claddings, and devices for their attachment to an underlying support
FR2613404A1 (en) * 1987-03-31 1988-10-07 Hutchinson Sa CONSTRUCTION ELEMENTS OF BUILDINGS, IN PARTICULAR COVERING AND / OR CLOTHING, AND THEIR FIXING DEVICES ON AN UNDERLYING SUPPORT
FR2646454A1 (en) * 1989-04-28 1990-11-02 Desplanques Yves Method and installation for covering a roof panel with an insulating material
US5716563A (en) * 1992-02-05 1998-02-10 Weyerhaeuser Company Method of forming a surfaced cellulosic composite panel
WO1993024305A1 (en) * 1992-06-04 1993-12-09 Vilcsek Dünnsteintechnik Manufaktur Kg Process for manufacturing a composite slab
EP0609721A2 (en) * 1993-02-05 1994-08-10 Glaswerk Schuller GmbH Skinlayer for foam core sandwich structure and its manufacturing process
EP0609721A3 (en) * 1993-02-05 1994-09-14 Schuller Gmbh Glaswerk Skinlayer for foam core sandwich structure and its manufacturing process.
GB2357992A (en) * 1999-10-08 2001-07-11 Thorstone Business Man Ltd Foam laminates
GB2357992B (en) * 1999-10-08 2003-10-29 Thorstone Business Man Ltd Glass-faced architectural panels
US7112364B1 (en) 1999-10-08 2006-09-26 Thorstone Business Management Limited Foam laminates
WO2013151419A1 (en) * 2012-04-05 2013-10-10 Enkev B.V. Method for manufacturing a composite element and support element provided thereby

Also Published As

Publication number Publication date
DE2617414A1 (en) 1977-11-10
FR2288610B1 (en) 1978-02-17
BE840923A (en) 1976-08-16

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