FR2224196A1 - Sulphur recovery from waste gases - by contacting with alumina-(silica) adsorbent, regenerating adsorbent with hot gas, - Google Patents

Sulphur recovery from waste gases - by contacting with alumina-(silica) adsorbent, regenerating adsorbent with hot gas,

Info

Publication number
FR2224196A1
FR2224196A1 FR7312460A FR7312460A FR2224196A1 FR 2224196 A1 FR2224196 A1 FR 2224196A1 FR 7312460 A FR7312460 A FR 7312460A FR 7312460 A FR7312460 A FR 7312460A FR 2224196 A1 FR2224196 A1 FR 2224196A1
Authority
FR
France
Prior art keywords
adsorbent
alumina
contacting
gas
silica
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7312460A
Other languages
French (fr)
Other versions
FR2224196B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Societe Nationale des Petroles dAquitaine SA
Original Assignee
Societe Nationale des Petroles dAquitaine SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Societe Nationale des Petroles dAquitaine SA filed Critical Societe Nationale des Petroles dAquitaine SA
Priority to FR7312460A priority Critical patent/FR2224196A1/en
Priority to US350913A priority patent/US3890120A/en
Priority to LU67449A priority patent/LU67449A1/xx
Priority to DE2319532A priority patent/DE2319532C2/en
Priority to DK210573AA priority patent/DK141958B/en
Priority to BE130112A priority patent/BE798334A/en
Priority to GB1849373A priority patent/GB1420270A/en
Priority to IE610/73A priority patent/IE39138B1/en
Priority to DD170276A priority patent/DD104065A5/xx
Priority to CA169,921A priority patent/CA1024904A/en
Priority to NLAANVRAGE7305496,A priority patent/NL179979C/en
Priority to JP4401773A priority patent/JPS5549002B2/ja
Priority to IT23144/73A priority patent/IT990536B/en
Publication of FR2224196A1 publication Critical patent/FR2224196A1/en
Application granted granted Critical
Publication of FR2224196B1 publication Critical patent/FR2224196B1/fr
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B01D53/52—Hydrogen sulfide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/02—Preparation of sulfur; Purification
    • C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/02—Preparation of sulfur; Purification
    • C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
    • C01B17/0404—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
    • C01B17/0456—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process the hydrogen sulfide-containing gas being a Claus process tail gas

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Treating Waste Gases (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

Sulphur is recovered from waste gases contg. low concentrations of H2S, SO2 and opt. S droplets by (a) passing the waste gases at a temp. between ambient and 180 degress C over an adsorbent selected from alumina or silica-alumina, and (b) contacting the S-loaded adsorbent with a hot gas to desorb the S and regenerate the adsorbent. The contact time between the waste gas and the adsorbent is 1-25 esp. 4-10 secs., regeneration of the adsorbent is effected with an oxygen-free gas at 200-350 degrees C and regeneration is followed by washing the regenerated adsorbent with an oxygen-free gas at a temp. below 180 degrees C to place the adsorbant at the temp. required for contacting the waste gas. The washing gas is mixed with steam during at least a part of washing in order to ensure a rehydration of the adsorbent so that it adsorbs no more steam when contacted with the waste gas.
FR7312460A 1972-04-18 1973-04-06 Sulphur recovery from waste gases - by contacting with alumina-(silica) adsorbent, regenerating adsorbent with hot gas, Granted FR2224196A1 (en)

Priority Applications (13)

Application Number Priority Date Filing Date Title
FR7312460A FR2224196A1 (en) 1973-04-06 1973-04-06 Sulphur recovery from waste gases - by contacting with alumina-(silica) adsorbent, regenerating adsorbent with hot gas,
US350913A US3890120A (en) 1972-04-18 1973-04-13 Process to recover sulphur from the sulphur compounds contained in residual gases
IE610/73A IE39138B1 (en) 1972-04-18 1973-04-17 Process for desulphursing gases
DK210573AA DK141958B (en) 1972-04-18 1973-04-17 Process for desulphurizing gases.
BE130112A BE798334A (en) 1972-04-18 1973-04-17 PROCESS FOR RECOVERY IN THE FORM OF SULFUR OF SULPHIDE COMPOUNDS CONTAINED IN GASES
GB1849373A GB1420270A (en) 1972-04-18 1973-04-17 Process for desulphurizing gases
LU67449A LU67449A1 (en) 1972-04-18 1973-04-17
DE2319532A DE2319532C2 (en) 1972-04-18 1973-04-17 Process for the desulphurization of exhaust gases
DD170276A DD104065A5 (en) 1972-04-18 1973-04-18
CA169,921A CA1024904A (en) 1972-04-18 1973-04-18 Process for recovering sulphur from sulfuric compositions contained in gases
NLAANVRAGE7305496,A NL179979C (en) 1972-04-18 1973-04-18 PROCESS FOR THE DESULFULURATION OF WASTE GASES CONTAINING LOW CONCENTRATIONS SULFUR HYDROGEN AND SULFUR DIOXIDE.
JP4401773A JPS5549002B2 (en) 1972-04-18 1973-04-18
IT23144/73A IT990536B (en) 1972-04-18 1973-04-19 PROCEDURE FOR THE RECOVERY IN THE FORM OF SULFUR OF SOL-PERFORATED COMPOUNDS CONTAINED IN GAS

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7312460A FR2224196A1 (en) 1973-04-06 1973-04-06 Sulphur recovery from waste gases - by contacting with alumina-(silica) adsorbent, regenerating adsorbent with hot gas,

Publications (2)

Publication Number Publication Date
FR2224196A1 true FR2224196A1 (en) 1974-10-31
FR2224196B1 FR2224196B1 (en) 1975-12-26

Family

ID=9117531

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7312460A Granted FR2224196A1 (en) 1972-04-18 1973-04-06 Sulphur recovery from waste gases - by contacting with alumina-(silica) adsorbent, regenerating adsorbent with hot gas,

Country Status (1)

Country Link
FR (1) FR2224196A1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2368439A1 (en) * 1976-10-25 1978-05-19 Metallgesellschaft Ag PROCESS FOR THE PREPARATION OF SULFUR
EP0324091A2 (en) * 1987-11-28 1989-07-19 Gastec N.V. A process for the removal of hydrogen sulfide from gases
FR2823131A1 (en) * 2001-04-04 2002-10-11 Pro Catalyse PROCESS FOR REMOVING ORGANIC OXYGEN MOLECULES PRESENT IN AN ORGANIC EFFLUENT USING ALUMINUM AGGLOMERS

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2368439A1 (en) * 1976-10-25 1978-05-19 Metallgesellschaft Ag PROCESS FOR THE PREPARATION OF SULFUR
EP0324091A2 (en) * 1987-11-28 1989-07-19 Gastec N.V. A process for the removal of hydrogen sulfide from gases
EP0324091A3 (en) * 1987-11-28 1989-08-09 Veg-Gasinstituut N.V. A process for the removal of hydrogen sulfide from gases
US5152970A (en) * 1987-11-28 1992-10-06 Veg-Gasinstituut N.V. Process for the removal of hydrogen sulfide from gases
FR2823131A1 (en) * 2001-04-04 2002-10-11 Pro Catalyse PROCESS FOR REMOVING ORGANIC OXYGEN MOLECULES PRESENT IN AN ORGANIC EFFLUENT USING ALUMINUM AGGLOMERS
WO2002081047A1 (en) * 2001-04-04 2002-10-17 Axens Method for eliminating oxygenated organic molecules that are present in an organic effluent using alumina agglomerates

Also Published As

Publication number Publication date
FR2224196B1 (en) 1975-12-26

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