FR2133001A5 - Alkylaminopropionitrile -modified cobalt carbonyl - - hydroformylation catalyst for aldehyde prepn - Google Patents

Alkylaminopropionitrile -modified cobalt carbonyl - - hydroformylation catalyst for aldehyde prepn

Info

Publication number
FR2133001A5
FR2133001A5 FR7111936A FR7111936A FR2133001A5 FR 2133001 A5 FR2133001 A5 FR 2133001A5 FR 7111936 A FR7111936 A FR 7111936A FR 7111936 A FR7111936 A FR 7111936A FR 2133001 A5 FR2133001 A5 FR 2133001A5
Authority
FR
France
Prior art keywords
alkylaminopropionitrile
prepn
aldehyde
hydroformylation catalyst
cobalt carbonyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
FR7111936A
Other languages
French (fr)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Azote et Produits Chimiques SA
Original Assignee
Azote et Produits Chimiques SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Azote et Produits Chimiques SA filed Critical Azote et Produits Chimiques SA
Priority to FR7111936A priority Critical patent/FR2133001A5/en
Priority to NL7202847A priority patent/NL7202847A/xx
Priority to DE19722210937 priority patent/DE2210937A1/en
Priority to IT49272/72A priority patent/IT952415B/en
Priority to BE781639A priority patent/BE781639A/en
Priority to DD162042A priority patent/DD96228A5/xx
Application granted granted Critical
Publication of FR2133001A5 publication Critical patent/FR2133001A5/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt

Abstract

Stable Co carbonyl hydroformylation catalyst modified with an alkylaminopropionitrile complex former of formula: R-NHCHR1-CH2CN (I) (where R is 4-20 C alkyl and R1 is H or 1-5 C n-alkyl), is prepd. by reacting Co or a Co salt with (I), under H2 in presence of CO, using 3-10 (I): Co molar ratio, and used for hydroformylation of all 2-20 (2-12)C olefinically unsatd. aliphatic, cycloaliphatic or araliphatic cpds., pref. at 70-200 (100-140) degrees C, under 20-300 (50-200) atmos. press., using 0.7 to 2 H2:CO ratio and 0.1-2wt.% catalyst, w.r.t. Co and olefinic cpd., esp. in presence of an inert solvent.
FR7111936A 1971-04-05 1971-04-05 Alkylaminopropionitrile -modified cobalt carbonyl - - hydroformylation catalyst for aldehyde prepn Expired FR2133001A5 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
FR7111936A FR2133001A5 (en) 1971-04-05 1971-04-05 Alkylaminopropionitrile -modified cobalt carbonyl - - hydroformylation catalyst for aldehyde prepn
NL7202847A NL7202847A (en) 1971-04-05 1972-03-03
DE19722210937 DE2210937A1 (en) 1971-04-05 1972-03-07 Process for the hydroformylation of olefinic compounds and hydroformylation catalyst based on cobalt carbonyl modified by complex formation
IT49272/72A IT952415B (en) 1971-04-05 1972-03-28 PERFECTED PROCEDURE FOR HYDROFORMILATION OF OLEPHIN COMPOUNDS
BE781639A BE781639A (en) 1971-04-05 1972-04-04 PERFECTED PROCESS FOR HYDROFORMYLATION OF OLEFINIC COMPOUNDS
DD162042A DD96228A5 (en) 1971-04-05 1972-04-04

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7111936A FR2133001A5 (en) 1971-04-05 1971-04-05 Alkylaminopropionitrile -modified cobalt carbonyl - - hydroformylation catalyst for aldehyde prepn

Publications (1)

Publication Number Publication Date
FR2133001A5 true FR2133001A5 (en) 1972-11-24

Family

ID=9074755

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7111936A Expired FR2133001A5 (en) 1971-04-05 1971-04-05 Alkylaminopropionitrile -modified cobalt carbonyl - - hydroformylation catalyst for aldehyde prepn

Country Status (6)

Country Link
BE (1) BE781639A (en)
DD (1) DD96228A5 (en)
DE (1) DE2210937A1 (en)
FR (1) FR2133001A5 (en)
IT (1) IT952415B (en)
NL (1) NL7202847A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2453124A1 (en) * 1979-04-02 1980-10-31 Uop Inc PROCESS FOR PRODUCING ALCOHOLS, IN THE PRESENCE OF AN ORGANOMETALLIC COMPLEX CATALYST AND A NITRILE OR AMMONIA-BASED PROMOTER, AND NOVEL PRODUCTS THUS OBTAINED
EP0037716A1 (en) * 1980-04-03 1981-10-14 Mitsubishi Gas Chemical Company, Inc. Process for producing catalyst
EP0208921A2 (en) * 1985-06-20 1987-01-21 HENKEL CORPORATION (a Delaware corp.) Hydroformylation of olefinic compounds in the presence of soluble cobalt salt catalysts and an organic nitrile promoter

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2453124A1 (en) * 1979-04-02 1980-10-31 Uop Inc PROCESS FOR PRODUCING ALCOHOLS, IN THE PRESENCE OF AN ORGANOMETALLIC COMPLEX CATALYST AND A NITRILE OR AMMONIA-BASED PROMOTER, AND NOVEL PRODUCTS THUS OBTAINED
EP0037716A1 (en) * 1980-04-03 1981-10-14 Mitsubishi Gas Chemical Company, Inc. Process for producing catalyst
EP0208921A2 (en) * 1985-06-20 1987-01-21 HENKEL CORPORATION (a Delaware corp.) Hydroformylation of olefinic compounds in the presence of soluble cobalt salt catalysts and an organic nitrile promoter
EP0208921A3 (en) * 1985-06-20 1988-03-16 HENKEL CORPORATION (a Delaware corp.) Hydroformylation of olefinic compounds in the presence of soluble cobalt salt catalysts and an organic nitrile promoter

Also Published As

Publication number Publication date
NL7202847A (en) 1972-10-09
DD96228A5 (en) 1973-03-12
IT952415B (en) 1973-07-20
BE781639A (en) 1972-10-04
DE2210937A1 (en) 1972-10-19

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Legal Events

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