FR2453124A1 - PROCESS FOR PRODUCING ALCOHOLS, IN THE PRESENCE OF AN ORGANOMETALLIC COMPLEX CATALYST AND A NITRILE OR AMMONIA-BASED PROMOTER, AND NOVEL PRODUCTS THUS OBTAINED - Google Patents

PROCESS FOR PRODUCING ALCOHOLS, IN THE PRESENCE OF AN ORGANOMETALLIC COMPLEX CATALYST AND A NITRILE OR AMMONIA-BASED PROMOTER, AND NOVEL PRODUCTS THUS OBTAINED

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Publication number
FR2453124A1
FR2453124A1 FR8007354A FR8007354A FR2453124A1 FR 2453124 A1 FR2453124 A1 FR 2453124A1 FR 8007354 A FR8007354 A FR 8007354A FR 8007354 A FR8007354 A FR 8007354A FR 2453124 A1 FR2453124 A1 FR 2453124A1
Authority
FR
France
Prior art keywords
nitrile
ammonia
organometallic complex
complex catalyst
novel products
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR8007354A
Other languages
French (fr)
Other versions
FR2453124B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Honeywell UOP LLC
Original Assignee
UOP LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US06/026,477 external-priority patent/US4219684A/en
Application filed by UOP LLC filed Critical UOP LLC
Publication of FR2453124A1 publication Critical patent/FR2453124A1/en
Application granted granted Critical
Publication of FR2453124B1 publication Critical patent/FR2453124B1/en
Expired legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/60—Preparation of compounds containing amino groups bound to a carbon skeleton by condensation or addition reactions, e.g. Mannich reaction, addition of ammonia or amines to alkenes or to alkynes or addition of compounds containing an active hydrogen atom to Schiff's bases, quinone imines, or aziranes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/16—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxo-reaction combined with reduction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Un procédé pour la production d'un alcool consiste à faire réagir un composé oléfinique, de l'oxyde de carbone et de l'hydrogène en présence d'un catalyseur complexe organométallique, le métal étant du groupe VIII, et d'un promoteur à base de nitrile ou d'un promoteur à base d'ammoniac, dans des conditions réactionnelles, et à récupérer l'alcool résultant; ces conditions réactionnelles comprennent une température dans l'intervalle d'environ 50 à environ 250 degrés C et une pression dans la gamme d'environ 10 à environ 300 atmosphères.A process for the production of an alcohol consists in reacting an olefinic compound, carbon monoxide and hydrogen in the presence of an organometallic complex catalyst, the metal being of group VIII, and of a promoter with nitrile-based or an ammonia-based promoter, under reaction conditions, and recovering the resulting alcohol; these reaction conditions include a temperature in the range of about 50 to about 250 degrees C and a pressure in the range of about 10 to about 300 atmospheres.

FR8007354A 1979-04-02 1980-04-01 PROCESS FOR PRODUCING ALCOHOLS, IN THE PRESENCE OF AN ORGANOMETALLIC COMPLEX CATALYST AND A NITRILE OR AMMONIA-BASED PROMOTER, AND NOVEL PRODUCTS THUS OBTAINED Expired FR2453124B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/026,477 US4219684A (en) 1979-04-02 1979-04-02 Synthesis of alcohols by hydroformylation with nitrile promoter
US3963379A 1979-05-16 1979-05-16

Publications (2)

Publication Number Publication Date
FR2453124A1 true FR2453124A1 (en) 1980-10-31
FR2453124B1 FR2453124B1 (en) 1985-06-14

Family

ID=26701295

Family Applications (1)

Application Number Title Priority Date Filing Date
FR8007354A Expired FR2453124B1 (en) 1979-04-02 1980-04-01 PROCESS FOR PRODUCING ALCOHOLS, IN THE PRESENCE OF AN ORGANOMETALLIC COMPLEX CATALYST AND A NITRILE OR AMMONIA-BASED PROMOTER, AND NOVEL PRODUCTS THUS OBTAINED

Country Status (6)

Country Link
BR (1) BR8002015A (en)
DE (1) DE3012729C2 (en)
FR (1) FR2453124B1 (en)
GB (1) GB2049673B (en)
IT (1) IT1147333B (en)
MX (1) MX152374A (en)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2705729A (en) * 1951-04-26 1955-04-05 Exxon Research Engineering Co Carbonylation of olefins
FR1284232A (en) * 1961-03-14 1962-02-09 Basf Ag Process for the production of alcohols
FR1564932A (en) * 1967-03-17 1969-04-25
GB1206063A (en) * 1967-10-24 1970-09-23 Montedison Spa Hydroformylation of olefins
US3627843A (en) * 1968-03-13 1971-12-14 Montedison Spa Hydroformylation of propene
FR2133001A5 (en) * 1971-04-05 1972-11-24 Azote & Prod Chim Alkylaminopropionitrile -modified cobalt carbonyl - - hydroformylation catalyst for aldehyde prepn
GB1448255A (en) * 1973-11-13 1976-09-02 Mobil Oil Corp Hydroformylation process

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2705729A (en) * 1951-04-26 1955-04-05 Exxon Research Engineering Co Carbonylation of olefins
FR1284232A (en) * 1961-03-14 1962-02-09 Basf Ag Process for the production of alcohols
FR1564932A (en) * 1967-03-17 1969-04-25
GB1206063A (en) * 1967-10-24 1970-09-23 Montedison Spa Hydroformylation of olefins
US3627843A (en) * 1968-03-13 1971-12-14 Montedison Spa Hydroformylation of propene
FR2133001A5 (en) * 1971-04-05 1972-11-24 Azote & Prod Chim Alkylaminopropionitrile -modified cobalt carbonyl - - hydroformylation catalyst for aldehyde prepn
GB1448255A (en) * 1973-11-13 1976-09-02 Mobil Oil Corp Hydroformylation process

Also Published As

Publication number Publication date
IT1147333B (en) 1986-11-19
IT8021113A0 (en) 1980-04-01
DE3012729C2 (en) 1983-08-25
MX152374A (en) 1985-07-09
GB2049673B (en) 1983-03-30
GB2049673A (en) 1980-12-31
DE3012729A1 (en) 1980-10-16
BR8002015A (en) 1980-11-25
FR2453124B1 (en) 1985-06-14

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