FR2363538A1 - PROCESS FOR THE PREPARATION OF GLYCOL-ALDEHYDE AND ETHYLENE-GLYCOL - Google Patents

PROCESS FOR THE PREPARATION OF GLYCOL-ALDEHYDE AND ETHYLENE-GLYCOL

Info

Publication number
FR2363538A1
FR2363538A1 FR7727928A FR7727928A FR2363538A1 FR 2363538 A1 FR2363538 A1 FR 2363538A1 FR 7727928 A FR7727928 A FR 7727928A FR 7727928 A FR7727928 A FR 7727928A FR 2363538 A1 FR2363538 A1 FR 2363538A1
Authority
FR
France
Prior art keywords
glycol
ethylene
aldehyde
preparation
formaldehyde
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7727928A
Other languages
French (fr)
Other versions
FR2363538B1 (en
Inventor
Richard Walter Goetz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Millennium Petrochemicals Inc
Original Assignee
National Destillers and Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by National Destillers and Chemical Corp filed Critical National Destillers and Chemical Corp
Publication of FR2363538A1 publication Critical patent/FR2363538A1/en
Application granted granted Critical
Publication of FR2363538B1 publication Critical patent/FR2363538B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
    • C07C47/19—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen containing hydroxy groups
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Abstract

L'invention concerne un procédé de production de glycol-aldéhyde et d'éthylène-glycol. On fait réagir du formaldéhyde, de l'oxyde de carbone et de l'hydrogène à température et sous pression élevées, en présence d'un catalyseur au rhodium pour former du glycolaldéhyde et à partir de celui-ci dans une seconde étape, on effectue une hydrogénation catalytique pour parvenir à l'éthylène-glycol. Le procédé est sélectif et assure des rendements élevés.The invention relates to a process for the production of glycol-aldehyde and ethylene-glycol. Formaldehyde, carbon monoxide and hydrogen are reacted at elevated temperature and pressure, in the presence of a rhodium catalyst to form glycolaldehyde and from it in a second step, one carries out catalytic hydrogenation to achieve ethylene glycol. The process is selective and ensures high yields.

FR7727928A 1976-09-17 1977-09-15 PROCESS FOR THE PREPARATION OF GLYCOL-ALDEHYDE AND ETHYLENE-GLYCOL Granted FR2363538A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US72412676A 1976-09-17 1976-09-17

Publications (2)

Publication Number Publication Date
FR2363538A1 true FR2363538A1 (en) 1978-03-31
FR2363538B1 FR2363538B1 (en) 1983-11-18

Family

ID=24909126

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7727928A Granted FR2363538A1 (en) 1976-09-17 1977-09-15 PROCESS FOR THE PREPARATION OF GLYCOL-ALDEHYDE AND ETHYLENE-GLYCOL

Country Status (16)

Country Link
JP (2) JPS5337606A (en)
BE (1) BE858806A (en)
BR (1) BR7706226A (en)
CA (1) CA1089877A (en)
DE (1) DE2741589C2 (en)
DK (1) DK411477A (en)
ES (1) ES462430A1 (en)
FI (1) FI772720A (en)
FR (1) FR2363538A1 (en)
GB (1) GB1585604A (en)
IE (1) IE45512B1 (en)
IT (1) IT1086478B (en)
LU (1) LU78137A1 (en)
MX (1) MX146305A (en)
NL (1) NL7710187A (en)
NO (1) NO773188L (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0158517A2 (en) * 1984-04-05 1985-10-16 Montvale Process Company Incorporated Process for the production of ethylene glycol

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1089876A (en) * 1976-10-21 1980-11-18 Robert G. Wall Alcohol production
DE2861830D1 (en) * 1977-12-16 1982-07-01 Monsanto Co Hydroformylation of formaldehyde with rhodium catalyst
US4317946A (en) 1980-06-27 1982-03-02 The Halcon Sd Group, Inc. Process for producing ethylene glycol via catalytic hydrogenation of glycolaldehyde
US4321414A (en) * 1980-08-26 1982-03-23 The Halcon Sd Group, Inc. Catalytic hydrogenation of glycolaldehyde to produce ethylene glycol
US4382148A (en) * 1981-03-24 1983-05-03 Shell Oil Company Process for the preparation of glycol aldehyde
US4414421A (en) * 1981-08-03 1983-11-08 Shell Oil Company Process for the preparation of glycol aldehyde
US7420093B2 (en) 2006-09-29 2008-09-02 Eastman Chemical Company Process for the preparation of glycolaldehyde

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2451333A (en) * 1945-04-28 1948-10-12 Du Pont Synthesis of polyhydroxy compounds
FR2233308A1 (en) * 1973-06-12 1975-01-10 Ajinomoto Kk
FR2375172A1 (en) * 1976-10-21 1978-07-21 Chevron Res Catalytic prepn. of ethylene glycol from formaldehyde - with carbon monoxide and hydrogen using a rhodium cpd. catalyst

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS521821B2 (en) * 1971-09-23 1977-01-18
US3833634A (en) * 1971-12-21 1974-09-03 Union Carbide Corp Manufacture of polyfunctional compounds
JPS5615935B2 (en) * 1973-05-31 1981-04-13

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2451333A (en) * 1945-04-28 1948-10-12 Du Pont Synthesis of polyhydroxy compounds
FR2233308A1 (en) * 1973-06-12 1975-01-10 Ajinomoto Kk
US3920753A (en) * 1973-06-12 1975-11-18 Ajinomoto Kk Method of producing glycolaldehyde
FR2375172A1 (en) * 1976-10-21 1978-07-21 Chevron Res Catalytic prepn. of ethylene glycol from formaldehyde - with carbon monoxide and hydrogen using a rhodium cpd. catalyst

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
CA1972 *
CA1977 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0158517A2 (en) * 1984-04-05 1985-10-16 Montvale Process Company Incorporated Process for the production of ethylene glycol
EP0158517A3 (en) * 1984-04-05 1986-12-10 The Halcon Sd Group, Inc. Process for the production of ethylene glycol through the hydroformylation of glycol aldehyde

Also Published As

Publication number Publication date
IT1086478B (en) 1985-05-28
GB1585604A (en) 1981-03-11
BR7706226A (en) 1978-07-04
NO773188L (en) 1978-03-20
CA1089877A (en) 1980-11-18
BE858806A (en) 1978-03-16
JPH0132214B2 (en) 1989-06-29
JPS62116536A (en) 1987-05-28
DE2741589A1 (en) 1978-03-23
FI772720A (en) 1978-03-18
MX146305A (en) 1982-06-03
IE45512L (en) 1978-03-17
ES462430A1 (en) 1978-06-01
NL7710187A (en) 1978-03-21
LU78137A1 (en) 1978-06-01
JPS627177B2 (en) 1987-02-16
DK411477A (en) 1978-03-18
IE45512B1 (en) 1982-09-08
DE2741589C2 (en) 1986-10-23
FR2363538B1 (en) 1983-11-18
JPS5337606A (en) 1978-04-06

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