FR2067436A5 - N-carbamoyl benzimidazol-2-yl carbamic acid esters prepn - Google Patents
N-carbamoyl benzimidazol-2-yl carbamic acid esters prepnInfo
- Publication number
- FR2067436A5 FR2067436A5 FR6937806A FR6937806A FR2067436A5 FR 2067436 A5 FR2067436 A5 FR 2067436A5 FR 6937806 A FR6937806 A FR 6937806A FR 6937806 A FR6937806 A FR 6937806A FR 2067436 A5 FR2067436 A5 FR 2067436A5
- Authority
- FR
- France
- Prior art keywords
- carbamoyl
- halogen
- prepn
- benzimidazol
- acid esters
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D235/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings
- C07D235/02—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings condensed with carbocyclic rings or ring systems
- C07D235/04—Benzimidazoles; Hydrogenated benzimidazoles
- C07D235/24—Benzimidazoles; Hydrogenated benzimidazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached in position 2
- C07D235/30—Nitrogen atoms not forming part of a nitro radical
- C07D235/32—Benzimidazole-2-carbamic acids, unsubstituted or substituted; Esters thereof; Thio-analogues thereof
Abstract
N-carbamoyl benzimidazol-2-yl carbamic acid esters prepn. Cpds. of formula (I) (where R = one or more halogen, alkyl aryl, alkoxy, CN or NO2; R'=alkenyl, cycloalkyl, cyclodialkyl, (ar) alkyl, aryl, heteroaryl, heteroaralkyl, any of which opt. substd. by halogen, alkoxy, NO2 or CN; R2= (hetero)aryl, opt. substd. by halogen, alkyl, alkoxy, alkylthio, CN, NO2) are prepd. from a cpd. (II) (I; CONHR'=H) and a cpd. COX2 e.g. phosgene and treating the product with an amine R'-NH2 III or by treating II with a carbamoyl halide of formula R'-NH-CO-X (where X is halogen). The process avoids the use of expensive isocyanates used in conventional processes.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR6937806A FR2067436A5 (en) | 1969-11-03 | 1969-11-03 | N-carbamoyl benzimidazol-2-yl carbamic acid esters prepn |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR6937806A FR2067436A5 (en) | 1969-11-03 | 1969-11-03 | N-carbamoyl benzimidazol-2-yl carbamic acid esters prepn |
Publications (1)
Publication Number | Publication Date |
---|---|
FR2067436A5 true FR2067436A5 (en) | 1971-08-20 |
Family
ID=9042547
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR6937806A Expired FR2067436A5 (en) | 1969-11-03 | 1969-11-03 | N-carbamoyl benzimidazol-2-yl carbamic acid esters prepn |
Country Status (1)
Country | Link |
---|---|
FR (1) | FR2067436A5 (en) |
-
1969
- 1969-11-03 FR FR6937806A patent/FR2067436A5/en not_active Expired
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |