FR1261568A - Process for the production of acrylonitrile or methacrylonitrile - Google Patents

Process for the production of acrylonitrile or methacrylonitrile

Info

Publication number
FR1261568A
FR1261568A FR891492A FR891492A FR1261568A FR 1261568 A FR1261568 A FR 1261568A FR 891492 A FR891492 A FR 891492A FR 891492 A FR891492 A FR 891492A FR 1261568 A FR1261568 A FR 1261568A
Authority
FR
France
Prior art keywords
oxides
tin
antimony
oxygen
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
FR891492A
Other languages
French (fr)
Inventor
John Lynn Barclay
John Bernard Bream
David James Hadley
David Gordon Stewart
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Distillers Co Yeast Ltd
Distillers Co Ltd
Original Assignee
Distillers Co Yeast Ltd
Distillers Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Distillers Co Yeast Ltd, Distillers Co Ltd filed Critical Distillers Co Yeast Ltd
Application granted granted Critical
Publication of FR1261568A publication Critical patent/FR1261568A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/18—Arsenic, antimony or bismuth
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Acrylonitrile or methacrylonitrile are prepared by reacting propylene or isobutene at an elevated temperature in the vapour phase with oxygen and ammonia over an oxidation catalyst comprising (i) a mixture of the oxides of antimony and tin, and/or (ii) a compound of antimony, tin and oxygen (see Group III).ALSO:Catalysts suitable for the production of acrylonitrile and methacrylonitrile (see Group IV(b)) comprise (i) a mixture of the oxides of antimony and tin, and/or (ii) a compound of antimony, tin and oxygen, such as tin antimonate. The catalyst may be prepared from the oxides or from compounds, such as the hydroxides, which on heating in the presence of an oxygen-containing gas are converted to the oxides. Specified oxides are antimony trioxide, tetroxide and pentoxide and their mixtures; stannic oxide, stannous oxide, metastannic acid and their mixtures. Hydrated forms of the oxides may be used, such as those formed by the action of aqueous nitric acid on antimony or tin metals or their mixtures. The catalyst mixture may be pre-heated in the presence of an oxygen-containing gas such as air, for instance at a temperature between 550 and 1100 DEG C. Cationic salts of the metals, such as the chlorides may be hydrolysed with water or aqueous ammonia and the resulting precipitate heated. The catalyst may be supported, e.g. on silica.
FR891492A 1962-12-08 1960-06-29 Process for the production of acrylonitrile or methacrylonitrile Expired FR1261568A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB46395/62A GB976008A (en) 1962-12-08 1962-12-08 Improvements in and relating to the production of unsaturated aliphatic nitriles

Publications (1)

Publication Number Publication Date
FR1261568A true FR1261568A (en) 1961-05-19

Family

ID=10441080

Family Applications (2)

Application Number Title Priority Date Filing Date
FR891492A Expired FR1261568A (en) 1962-12-08 1960-06-29 Process for the production of acrylonitrile or methacrylonitrile
FR956234A Expired FR84892E (en) 1962-12-08 1963-12-06 Process for the production of acrylonitrile or methacrylonitrile

Family Applications After (1)

Application Number Title Priority Date Filing Date
FR956234A Expired FR84892E (en) 1962-12-08 1963-12-06 Process for the production of acrylonitrile or methacrylonitrile

Country Status (7)

Country Link
BE (2) BE592434A (en)
CA (2) CA677475A (en)
DE (1) DE1203757B (en)
FR (2) FR1261568A (en)
GB (2) GB876446A (en)
IT (2) IT795163A (en)
NL (2) NL301435A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1231675B (en) * 1961-03-29 1967-01-05 Electro Chimie Metal Process for the production of catalysts for the production of acrolein, acrylonitrile and their alkyl derivatives
DE1243176B (en) * 1961-04-18 1967-06-29 Knapsack Ag Process for the production of acrylic acid nitrile or methacrylic acid nitrile by reacting propylene or isobutylene with air and / or oxygen and ammonia
DE1255105B (en) * 1961-07-14 1967-11-30 Edison Soc Process for the production of acrylic acid nitrile and methacrylic acid nitrile from propylene or isobutylene, ammonia and oxygen
DE1255656B (en) * 1961-06-20 1967-12-07 Lentia Gmbh Process for the production of acrylic acid nitrile or methacrylic acid nitrile from propylene or isobutylene, ammonia and oxygen
DE1284950B (en) * 1960-04-26 1968-12-12 Distillers Co Yeast Ltd Process for the production of an oxidation catalyst
DE1286024B (en) * 1962-09-01 1969-01-02 Knapsack Ag Process for the production of acrylic or methacrylic acid nitrile from propylene or isobutylene, ammonia and oxygen
DE1296622B (en) * 1961-11-30 1969-06-04 Toyo Rayon Co Ltd Process for the production of acrylic acid nitrile or methacrylic acid nitrile by reacting propylene or isobutylene with oxygen and ammonia

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA715118A (en) * 1961-01-23 1965-08-03 Eastman Kodak Company Catalytic synthesis of acrylonitrile from olefins, ammonia and oxygen
GB997490A (en) * 1963-04-05 1965-07-07 Distillers Co Yeast Ltd Improvements in or relating to oxidation catalysts
NL135670C (en) * 1963-05-09
GB1007685A (en) * 1963-06-20 1965-10-22 Distillers Co Yeast Ltd Improvements in or relating to catalyst compositions
GB1026477A (en) * 1963-07-30 1966-04-20 Distillers Co Yeast Ltd Improvements in or relating to catalytic compositions useful in the production of unsaturated aliphatic nitriles
GB1488375A (en) * 1974-06-25 1977-10-12 Bp Chem Int Ltd Chemical composition
DK160995C (en) * 1977-10-25 1991-11-04 Phillips Petroleum Co POLLUTION DISABLED CRACKING CATALYST, ITS APPLICATION AND MEDICINE FOR ITS PREPARATION
US4255287A (en) 1978-09-12 1981-03-10 Phillips Petroleum Company Cracking catalyst
US4321129A (en) 1978-09-12 1982-03-23 Phillips Petroleum Company Cracking process employing catalyst having combination of antimony and tin

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2481826A (en) * 1947-02-28 1949-09-13 Allied Chem & Dye Corp Process for making aliphatic nitriles
DE897560C (en) * 1950-12-30 1953-11-23 Distillers Company Process for the production of unsaturated nitriles
GB719635A (en) * 1951-11-08 1954-12-08 Distillers Co Yeast Ltd Manufacture of substantially pure unsaturated nitriles
CA627938A (en) * 1952-10-09 1961-09-26 J. Hadley David Preparation of unsaturated organic nitriles
FR1098400A (en) * 1953-04-13 1955-07-25 Bataafsche Petroleum Process for preparing unsaturated nitriles
GB774011A (en) * 1953-10-27 1957-05-01 Stig Knutsson Picker for looms
IT605134A (en) * 1959-02-24

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1284950B (en) * 1960-04-26 1968-12-12 Distillers Co Yeast Ltd Process for the production of an oxidation catalyst
DE1231675B (en) * 1961-03-29 1967-01-05 Electro Chimie Metal Process for the production of catalysts for the production of acrolein, acrylonitrile and their alkyl derivatives
DE1243176B (en) * 1961-04-18 1967-06-29 Knapsack Ag Process for the production of acrylic acid nitrile or methacrylic acid nitrile by reacting propylene or isobutylene with air and / or oxygen and ammonia
DE1255656B (en) * 1961-06-20 1967-12-07 Lentia Gmbh Process for the production of acrylic acid nitrile or methacrylic acid nitrile from propylene or isobutylene, ammonia and oxygen
DE1255105B (en) * 1961-07-14 1967-11-30 Edison Soc Process for the production of acrylic acid nitrile and methacrylic acid nitrile from propylene or isobutylene, ammonia and oxygen
DE1296622B (en) * 1961-11-30 1969-06-04 Toyo Rayon Co Ltd Process for the production of acrylic acid nitrile or methacrylic acid nitrile by reacting propylene or isobutylene with oxygen and ammonia
DE1286024B (en) * 1962-09-01 1969-01-02 Knapsack Ag Process for the production of acrylic or methacrylic acid nitrile from propylene or isobutylene, ammonia and oxygen

Also Published As

Publication number Publication date
CA718026A (en) 1965-09-14
IT636168A (en)
CA677475A (en) 1964-01-07
FR84892E (en) 1965-04-30
GB876446A (en) 1961-08-30
NL253202A (en)
BE592434A (en)
BE640872A (en)
DE1203757B (en) 1965-10-28
GB976008A (en) 1964-11-25
NL301435A (en)
IT795163A (en)

Similar Documents

Publication Publication Date Title
FR1261568A (en) Process for the production of acrylonitrile or methacrylonitrile
GB904602A (en) Oxidation catalysts
GB897226A (en) Production of unsaturated aliphatic nitriles
US2428590A (en) Production of allyl type compounds
GB971100A (en) Production of acetic acid
GB1051563A (en)
GB1058970A (en) Production of nitric oxide
GB1034914A (en) Improvements in or relating to the production of unsaturated aliphatic acids
GB1064762A (en) Improvements in or relating to the production of acrylonitrile
GB1015079A (en) Fumaric and maleic acid dinitrile
GB954945A (en) Purification of butadiene
Skinner et al. Production of maleic acid by oxidizing butenes
GB1039866A (en) Process for the production of hydroxylamine
GB961468A (en) Production of acrylic and methacrylic acid
GB1035147A (en) Manufacture of unsaturated aliphatic carboxylic acids
GB987960A (en) Improvements in or relating to the production of unsaturated aliphatic nitriles
GB855880A (en) Production of alpha hydroxyisobutyric acid
GB665976A (en) Controlled catalytic vapor phase process
GB589796A (en) Improvements in and relating to the activation of catalysts
GB981134A (en) Preparation of unsaturated aldehydes
GB706552A (en) Manufacture of acrolein
GB981138A (en) Improvements in and relating to the manufacture of acrylonitrile
GB678557A (en) Manufacture of aldehydes
Ito et al. Liquid-phase oxidation of 1, 3, 5-triisopropylbenzene with molecular oxygen
GB993921A (en) Improvements in or relating to the production of unsaturated aliphatic aldehydes