FI95477B - Förfarande för stabilisering av en leukofärgämneslösning och strålningspolymeriserbar blandning innehållande leukofärgämnet - Google Patents
Förfarande för stabilisering av en leukofärgämneslösning och strålningspolymeriserbar blandning innehållande leukofärgämnet Download PDFInfo
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- FI95477B FI95477B FI894724A FI894724A FI95477B FI 95477 B FI95477 B FI 95477B FI 894724 A FI894724 A FI 894724A FI 894724 A FI894724 A FI 894724A FI 95477 B FI95477 B FI 95477B
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- Prior art keywords
- compound
- weight
- piperidine
- solution
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- 238000000034 method Methods 0.000 title claims abstract description 12
- 239000000203 mixture Substances 0.000 title claims description 38
- 230000000087 stabilizing effect Effects 0.000 title claims description 6
- 150000001875 compounds Chemical class 0.000 claims abstract description 41
- 230000005855 radiation Effects 0.000 claims abstract description 14
- 239000003960 organic solvent Substances 0.000 claims abstract description 13
- 230000003647 oxidation Effects 0.000 claims abstract description 6
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 6
- 239000000975 dye Substances 0.000 claims description 26
- -1 piperidine compound Chemical class 0.000 claims description 14
- 239000003381 stabilizer Substances 0.000 claims description 9
- 239000011230 binding agent Substances 0.000 claims description 8
- NQRYJNQNLNOLGT-UHFFFAOYSA-N tetrahydropyridine hydrochloride Natural products C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 claims description 8
- 238000009835 boiling Methods 0.000 claims description 6
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- WVWHRXVVAYXKDE-UHFFFAOYSA-N piperine Natural products O=C(C=CC=Cc1ccc2OCOc2c1)C3CCCCN3 WVWHRXVVAYXKDE-UHFFFAOYSA-N 0.000 claims 1
- 235000019100 piperine Nutrition 0.000 claims 1
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- 238000005516 engineering process Methods 0.000 description 1
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- 238000005530 etching Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
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- 238000005755 formation reaction Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
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- FDZZZRQASAIRJF-UHFFFAOYSA-M malachite green Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C(C=1C=CC=CC=1)=C1C=CC(=[N+](C)C)C=C1 FDZZZRQASAIRJF-UHFFFAOYSA-M 0.000 description 1
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- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
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- QBRHXTCIXTXYEV-UHFFFAOYSA-N n-acridin-9-ylacetamide Chemical compound C1=CC=C2C(NC(=O)C)=C(C=CC=C3)C3=NC2=C1 QBRHXTCIXTXYEV-UHFFFAOYSA-N 0.000 description 1
- 150000002896 organic halogen compounds Chemical class 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 1
- FZUGPQWGEGAKET-UHFFFAOYSA-N parbenate Chemical compound CCOC(=O)C1=CC=C(N(C)C)C=C1 FZUGPQWGEGAKET-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000036211 photosensitivity Effects 0.000 description 1
- 239000003504 photosensitizing agent Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 229920001290 polyvinyl ester Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 150000003248 quinolines Chemical class 0.000 description 1
- 239000012088 reference solution Substances 0.000 description 1
- ORIHZIZPTZTNCU-YVMONPNESA-N salicylaldoxime Chemical compound O\N=C/C1=CC=CC=C1O ORIHZIZPTZTNCU-YVMONPNESA-N 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229910001631 strontium chloride Inorganic materials 0.000 description 1
- AHBGXTDRMVNFER-UHFFFAOYSA-L strontium dichloride Chemical compound [Cl-].[Cl-].[Sr+2] AHBGXTDRMVNFER-UHFFFAOYSA-L 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 238000012719 thermal polymerization Methods 0.000 description 1
- YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 1
- RLGKSXCGHMXELQ-ZRDIBKRKSA-N trans-2-styrylquinoline Chemical compound C=1C=C2C=CC=CC2=NC=1\C=C\C1=CC=CC=C1 RLGKSXCGHMXELQ-ZRDIBKRKSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 125000003866 trichloromethyl group Chemical group ClC(Cl)(Cl)* 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 150000003732 xanthenes Chemical class 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/0083—Solutions of dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/0077—Preparations with possibly reduced vat, sulfur or indigo dyes
- C09B67/0078—Preparations of vat, sulfur or indigo dyes in liquid form
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/09—Photosensitive materials characterised by structural details, e.g. supports, auxiliary layers
- G03F7/105—Photosensitive materials characterised by structural details, e.g. supports, auxiliary layers having substances, e.g. indicators, for forming visible images
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Architecture (AREA)
- Structural Engineering (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Polymerisation Methods In General (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Hydrogenated Pyridines (AREA)
- Photosensitive Polymer And Photoresist Processing (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Claims (13)
1. Förfarande för stabilisering av en leukofärgäm-neslösning i ett organiskt lösningsmedel mot oxidation i 5 luften, kännetecknat av, att i lösningen tillsätts en förening, som innehäller ätminstone en 2,2,6,6,-tetraalkylpiperidin-, en 2,2-dialkylpiperidin-6-spirocykloalkan- eller en piperidin-2,6-dispirocyklo-alkangrupp. 10
2. Förfarande enligt patentkrav 1, känne tecknat av, att en piperidinförening tillsätts, som uppvisar en väteatom eller en eventuellt substituerad al-kylgrupp bunden vid kväveatomen.
3. Förfarande enligt patentkrav 1, k ä n n e - 15 tecknat av, att en förening tillsätts, i vilken pi-peridinringen i 4-ställning är bunden vid en syre- eller kväveatom i en substituent.
4. Förfarande enligt patentkrav 1, kännetecknat av, att en förening tillsätts, som innehäl- 20 ler 1-30 substituerade piperidingrupper i en molekyl.
5. Leukofärgämneslösning i ett organiskt lösningsmedel, kännetecknad av, att den innehäller en förening med minst en 2,2,6,6-tetraalkylpiperidin-, en 2,2-dialkylpiperidin-6-spirocykloalkan- eller en piperi- 25 din-2,6-dispirocykloalkangrupp.
6. Lösning enligt patentkrav 5, kännetecknad av, att det organiska lösningsmedlet är en alkohol, ett keton, en ester, en eter eller ett halogeni-serat kolväte. 30
7. Lösning enligt patentkrav 5, känne tecknad av, att ätminstone 90 % av lösningsmedlen har en kokpunkt under 100 °C.
8. Lösning enligt patentkrav 5, kännetecknad av, att leukofärgämnet är ett trifenylme- 35 tan- eller xantenfärgämne. Il i»'· Mi· I · i SI · 2i 95477
9. Lösning enligt patentkrav 5, k ä n n e - t e c k n a d av, att den ytterligare innehäller en strälningskänslig trihalogenmetylförening.
10. Lösning enligt patentkrav 5, k ä n n e - 5 tecknad av, att den innehäller 0,1 - 150 viktdelar piperinförening per 100 viktdelar leukofärgämne.
11. Under strälning polymeriserbar blandning, som i väsentliga beständsdelar innehäller en polymeriserbar fö-rening med minst en etylensk dubbelbindning i ändläge och 10 med en kokpunkt vid normaltryck över 100 °C, en förening som under aktinisk strälning förmär inleda en polymerise-ring av den omättade föreningen, ett organiskt lösningsme-del och leukof ärgämne, kännetecknad av, att den ytterligare innehäller en förening med minst en 15 2,2,6,6-tetraalkylpiperidin-, en 2,2-dialkylpiperidin-6- spirocykloalkan- eller en piperidin-2,6-dispirocykloalkan-grupp.
12. Under strälning polymeriserbar blandning enligt patentkrav 11, kännetecknad av, att den yt- 20 terligare innehäller ett polymert bindemedel.
13. Under strälning polymeriserbar blandning enligt patentkrav 11, kännetecknad av, att den ytterligare som stabilisator innehäller en epoxiförening. « ·
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3834299A DE3834299A1 (de) | 1988-10-08 | 1988-10-08 | Verfahren zum stabilisieren einer leukofarbstoffloesung und durch strahlung polymerisierbares, einen leukofarbstoff enthaltendes gemisch |
| DE3834299 | 1988-10-08 |
Publications (4)
| Publication Number | Publication Date |
|---|---|
| FI894724A0 FI894724A0 (sv) | 1989-10-05 |
| FI894724A FI894724A (sv) | 1990-04-09 |
| FI95477B true FI95477B (sv) | 1995-10-31 |
| FI95477C FI95477C (sv) | 1996-02-12 |
Family
ID=6364680
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI894724A FI95477C (sv) | 1988-10-08 | 1989-10-05 | Förfarande för stabilisering av en leukofärgämneslösning och strålningspolymeriserbar blandning innehållande leukofärgämnet |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US5085669A (sv) |
| EP (1) | EP0363775B1 (sv) |
| JP (1) | JPH0796650B2 (sv) |
| KR (1) | KR970007344B1 (sv) |
| AT (1) | ATE127821T1 (sv) |
| AU (1) | AU628865B2 (sv) |
| CA (1) | CA2000051C (sv) |
| DE (2) | DE3834299A1 (sv) |
| ES (1) | ES2076186T3 (sv) |
| FI (1) | FI95477C (sv) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2653458B2 (ja) * | 1988-03-26 | 1997-09-17 | 旭化成工業株式会社 | 凸版印刷版用感光性樹脂組成物 |
| US5599650A (en) * | 1995-04-28 | 1997-02-04 | Polaroid Corporation | Photoreaction quenchers in on-press developable lithographic printing plates |
| US6723493B2 (en) * | 2001-06-04 | 2004-04-20 | Gary Ganghui Teng | Negative lithographic printing plate comprising a specific compound in the photosensitive layer |
| EP1783548B1 (en) * | 2005-11-08 | 2017-03-08 | Rohm and Haas Electronic Materials LLC | Method of forming a patterned layer on a substrate |
| US7923488B2 (en) * | 2006-10-16 | 2011-04-12 | Trillion Science, Inc. | Epoxy compositions |
| KR100942439B1 (ko) * | 2007-12-28 | 2010-02-17 | 전자부품연구원 | 마이크로 가스센서 및 제조방법 |
| JP6152347B2 (ja) * | 2012-02-09 | 2017-06-21 | 協和メデックス株式会社 | ロイコ型色原体含有水溶液の保存方法 |
| KR101197288B1 (ko) | 2012-02-13 | 2012-11-05 | 금호석유화학 주식회사 | 탄소나노소재 분말의 펠릿과 그 제조 방법 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3042575A (en) * | 1958-11-24 | 1962-07-03 | Stiftelsen Svensk Cellulosafor | Methods of improving the yield in alkaline digestion of cellulosic material |
| JPS5555335A (en) * | 1978-10-19 | 1980-04-23 | Fuji Photo Film Co Ltd | Photosensitive composition |
| US4423139A (en) * | 1980-12-22 | 1983-12-27 | Minnesota Mining And Manufacturing Company | Stabilizer combination for dye oxidation |
| DE3131448A1 (de) * | 1981-08-07 | 1983-02-24 | Basf Ag, 6700 Ludwigshafen | Fuer die herstellung von photoresistschichten geeignete photopolymerisierbare aufzeichnungsmasse |
| JPS60239744A (ja) * | 1984-05-14 | 1985-11-28 | Fuji Photo Film Co Ltd | 感光性組成物 |
| JPS6187147A (ja) * | 1984-09-27 | 1986-05-02 | Fuji Photo Film Co Ltd | 光重合性組成物 |
| DE3602215A1 (de) * | 1986-01-25 | 1987-07-30 | Hoechst Ag | Photopolymerisierbares gemisch und dieses enthaltendes photopolymerisierbares aufzeichnungsmaterial |
| ES2054699T3 (es) * | 1986-04-10 | 1994-08-16 | Sandoz Ag | Pigmentos que contienen grupos de piperidilo. |
| DE3641014A1 (de) * | 1986-12-19 | 1988-06-16 | Wolfen Filmfab Veb | Fotopolymerisierbares material |
| JPH06431B2 (ja) * | 1987-09-25 | 1994-01-05 | 神崎製紙株式会社 | 多色感熱記録体 |
| DE3735088A1 (de) * | 1987-10-16 | 1989-04-27 | Hoechst Ag | Photopolymerisierbares gemisch |
-
1988
- 1988-10-08 DE DE3834299A patent/DE3834299A1/de not_active Withdrawn
-
1989
- 1989-10-02 EP EP89118228A patent/EP0363775B1/de not_active Expired - Lifetime
- 1989-10-02 AT AT89118228T patent/ATE127821T1/de not_active IP Right Cessation
- 1989-10-02 DE DE58909432T patent/DE58909432D1/de not_active Expired - Fee Related
- 1989-10-02 CA CA002000051A patent/CA2000051C/en not_active Expired - Fee Related
- 1989-10-02 ES ES89118228T patent/ES2076186T3/es not_active Expired - Lifetime
- 1989-10-05 FI FI894724A patent/FI95477C/sv active IP Right Grant
- 1989-10-06 US US07/418,335 patent/US5085669A/en not_active Expired - Lifetime
- 1989-10-06 AU AU42665/89A patent/AU628865B2/en not_active Ceased
- 1989-10-06 KR KR1019890014354A patent/KR970007344B1/ko not_active IP Right Cessation
- 1989-10-07 JP JP1262842A patent/JPH0796650B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0796650B2 (ja) | 1995-10-18 |
| AU4266589A (en) | 1990-04-12 |
| US5085669A (en) | 1992-02-04 |
| JPH02142856A (ja) | 1990-05-31 |
| FI894724A0 (sv) | 1989-10-05 |
| ATE127821T1 (de) | 1995-09-15 |
| KR970007344B1 (ko) | 1997-05-07 |
| CA2000051C (en) | 1997-09-16 |
| DE58909432D1 (de) | 1995-10-19 |
| KR900006453A (ko) | 1990-05-08 |
| ES2076186T3 (es) | 1995-11-01 |
| DE3834299A1 (de) | 1990-04-12 |
| CA2000051A1 (en) | 1990-04-08 |
| AU628865B2 (en) | 1992-09-24 |
| EP0363775A2 (de) | 1990-04-18 |
| FI95477C (sv) | 1996-02-12 |
| EP0363775A3 (de) | 1991-11-13 |
| EP0363775B1 (de) | 1995-09-13 |
| FI894724A (sv) | 1990-04-09 |
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| GB | Transfer or assigment of application |
Owner name: MORTON INTERNATIONAL, INC. |
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| FG | Patent granted |
Owner name: MORTON INTERNATIONAL, INC. |