FI94974C - Paperin liimausmenetelmiä ja koostumuksia - Google Patents
Paperin liimausmenetelmiä ja koostumuksia Download PDFInfo
- Publication number
- FI94974C FI94974C FI891184A FI891184A FI94974C FI 94974 C FI94974 C FI 94974C FI 891184 A FI891184 A FI 891184A FI 891184 A FI891184 A FI 891184A FI 94974 C FI94974 C FI 94974C
- Authority
- FI
- Finland
- Prior art keywords
- rosin
- resin
- cationic
- paper
- aluminum
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 30
- 238000000034 method Methods 0.000 title claims description 26
- 238000004513 sizing Methods 0.000 claims abstract description 32
- 239000003795 chemical substances by application Substances 0.000 claims abstract 7
- 239000011347 resin Substances 0.000 claims description 62
- 229920005989 resin Polymers 0.000 claims description 62
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 53
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 53
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 53
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 15
- -1 aluminum compound Chemical class 0.000 claims description 15
- 229910052782 aluminium Inorganic materials 0.000 claims description 13
- 125000002091 cationic group Chemical group 0.000 claims description 13
- 239000000839 emulsion Substances 0.000 claims description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 7
- 125000000129 anionic group Chemical group 0.000 claims description 6
- 229920002401 polyacrylamide Polymers 0.000 claims description 6
- 239000004606 Fillers/Extenders Substances 0.000 claims description 5
- 239000003784 tall oil Substances 0.000 claims description 5
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 claims description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 4
- 229920002472 Starch Polymers 0.000 claims description 4
- 235000019698 starch Nutrition 0.000 claims description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 239000004202 carbamide Substances 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 239000004952 Polyamide Substances 0.000 claims description 2
- 229920002873 Polyethylenimine Polymers 0.000 claims description 2
- 150000001805 chlorine compounds Chemical class 0.000 claims description 2
- LVYZJEPLMYTTGH-UHFFFAOYSA-H dialuminum chloride pentahydroxide dihydrate Chemical compound [Cl-].[Al+3].[OH-].[OH-].[Al+3].[OH-].[OH-].[OH-].O.O LVYZJEPLMYTTGH-UHFFFAOYSA-H 0.000 claims description 2
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 claims description 2
- 239000001530 fumaric acid Substances 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- 150000005846 sugar alcohols Polymers 0.000 claims description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 2
- 235000013877 carbamide Nutrition 0.000 claims 2
- 238000009472 formulation Methods 0.000 claims 2
- 239000003760 tallow Substances 0.000 claims 2
- PMVSDNDAUGGCCE-TYYBGVCCSA-L Ferrous fumarate Chemical compound [Fe+2].[O-]C(=O)\C=C\C([O-])=O PMVSDNDAUGGCCE-TYYBGVCCSA-L 0.000 claims 1
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 claims 1
- 239000002202 Polyethylene glycol Substances 0.000 claims 1
- 230000000996 additive effect Effects 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 239000000945 filler Substances 0.000 claims 1
- 239000003607 modifier Substances 0.000 claims 1
- 229920001223 polyethylene glycol Polymers 0.000 claims 1
- 150000003672 ureas Chemical class 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 abstract description 9
- 230000007935 neutral effect Effects 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 150000001399 aluminium compounds Chemical class 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 description 11
- 230000001070 adhesive effect Effects 0.000 description 11
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 9
- 125000004432 carbon atom Chemical group C* 0.000 description 8
- 238000004026 adhesive bonding Methods 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 5
- 239000011436 cob Substances 0.000 description 5
- 239000003292 glue Substances 0.000 description 5
- 239000000835 fiber Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000000344 soap Substances 0.000 description 4
- 229940037003 alum Drugs 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 239000000084 colloidal system Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 239000005018 casein Substances 0.000 description 2
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical class NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 2
- 235000021240 caseins Nutrition 0.000 description 2
- 239000001913 cellulose Chemical class 0.000 description 2
- 229920002678 cellulose Chemical class 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical class C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 239000013032 Hydrocarbon resin Substances 0.000 description 1
- 108010073771 Soybean Proteins Chemical class 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229920001448 anionic polyelectrolyte Polymers 0.000 description 1
- 229920006318 anionic polymer Polymers 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 229920006317 cationic polymer Polymers 0.000 description 1
- XENVCRGQTABGKY-ZHACJKMWSA-N chlorohydrin Chemical compound CC#CC#CC#CC#C\C=C\C(Cl)CO XENVCRGQTABGKY-ZHACJKMWSA-N 0.000 description 1
- 229940125898 compound 5 Drugs 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000011121 hardwood Substances 0.000 description 1
- 229920006270 hydrocarbon resin Polymers 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- DYUWTXWIYMHBQS-UHFFFAOYSA-N n-prop-2-enylprop-2-en-1-amine Chemical compound C=CCNCC=C DYUWTXWIYMHBQS-UHFFFAOYSA-N 0.000 description 1
- 125000000963 oxybis(methylene) group Chemical group [H]C([H])(*)OC([H])([H])* 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 235000019809 paraffin wax Nutrition 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920000867 polyelectrolyte Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000012260 resinous material Substances 0.000 description 1
- 239000011122 softwood Substances 0.000 description 1
- 229940001941 soy protein Drugs 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 150000003890 succinate salts Chemical class 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
- D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
- D21H23/04—Addition to the pulp; After-treatment of added substances in the pulp
- D21H23/06—Controlling the addition
- D21H23/14—Controlling the addition by selecting point of addition or time of contact between components
- D21H23/18—Addition at a location where shear forces are avoided before sheet-forming, e.g. after pulp beating or refining
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
- D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
- D21H23/22—Addition to the formed paper
- D21H23/24—Addition to the formed paper during paper manufacture
- D21H23/26—Addition to the formed paper during paper manufacture by selecting point of addition or moisture content of the paper
- D21H23/28—Addition before the dryer section, e.g. at the wet end or press section
Landscapes
- Paper (AREA)
- Polymerisation Methods In General (AREA)
- Medicinal Preparation (AREA)
- Making Paper Articles (AREA)
- Basic Packing Technique (AREA)
- Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
- Adhesives Or Adhesive Processes (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8806432 | 1988-03-18 | ||
| GB888806432A GB8806432D0 (en) | 1988-03-18 | 1988-03-18 | Paper sizing methods & compositions |
Publications (4)
| Publication Number | Publication Date |
|---|---|
| FI891184A0 FI891184A0 (fi) | 1989-03-13 |
| FI891184L FI891184L (fi) | 1989-09-19 |
| FI94974B FI94974B (fi) | 1995-08-15 |
| FI94974C true FI94974C (fi) | 1995-11-27 |
Family
ID=10633654
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI891184A FI94974C (fi) | 1988-03-18 | 1989-03-13 | Paperin liimausmenetelmiä ja koostumuksia |
Country Status (14)
| Country | Link |
|---|---|
| EP (1) | EP0333368B1 (da) |
| JP (1) | JP2656830B2 (da) |
| AT (1) | ATE139281T1 (da) |
| AU (1) | AU619260B2 (da) |
| CA (1) | CA1325500C (da) |
| DE (1) | DE68926632T2 (da) |
| DK (1) | DK173063B1 (da) |
| ES (1) | ES2087862T3 (da) |
| FI (1) | FI94974C (da) |
| GB (1) | GB8806432D0 (da) |
| NO (1) | NO180345C (da) |
| NZ (1) | NZ228297A (da) |
| PT (1) | PT90040B (da) |
| ZA (1) | ZA891925B (da) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2799505B2 (ja) * | 1989-07-08 | 1998-09-17 | 荒川化学工業株式会社 | エマルジョンサイズ剤 |
| JP2913756B2 (ja) * | 1990-04-25 | 1999-06-28 | 三菱化学株式会社 | 紙のサイジング方法 |
| DE4032660A1 (de) * | 1990-10-15 | 1992-04-16 | Basf Ag | Verfahren zur masseleimung von papier, pappe und karton |
| JP3223649B2 (ja) * | 1993-06-25 | 2001-10-29 | 日本ピー・エム・シー株式会社 | 中性抄紙用サイズ剤、その製造方法、サイジング方法及びサイジング紙 |
| JPH07276788A (ja) * | 1994-04-02 | 1995-10-24 | Nagoya Pulp Kk | 記録用紙 |
| US5510003A (en) * | 1994-07-20 | 1996-04-23 | Eka Nobel Ab | Method of sizing and aqueous sizing dispersion |
| GB2292158B (en) * | 1994-07-26 | 1998-12-09 | Roe Lee Paper Chemicals Compan | Sizing method |
| US6033526A (en) * | 1994-12-28 | 2000-03-07 | Hercules Incorporated | Rosin sizing at neutral to alkaline pH |
| DE69526715D1 (de) | 1994-12-28 | 2002-06-20 | Hercules Inc | Verfahren zum Leimen von Papier mit einem Kolophonium/Kohlenwasserstoffharz Leimungsmittel |
| GB2326170B (en) * | 1997-06-13 | 2001-05-09 | Raisio Chemicals Uk Ltd | Sizing of fibres |
| US9365979B2 (en) | 2014-08-27 | 2016-06-14 | Ecolab Usa Inc. | Method of increasing paper surface strength by using polyaluminum chloride in a size press formulation containing starch |
| JP6619613B2 (ja) * | 2015-10-21 | 2019-12-11 | 大王製紙株式会社 | 着色紙の製造方法 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2050453B (en) * | 1979-05-23 | 1983-02-09 | Tenneco Chem | Chemical compositions useful in the manufacture of paper sizing agents |
| DE3035634C2 (de) * | 1980-09-20 | 1982-10-21 | Feldmühle AG, 4000 Düsseldorf | Verfahren zur Herstellung eines Calciumcarbonat als Füllstoff enthaltenden massegeleimten Papiers oder Kartons |
| US4522686A (en) * | 1981-09-15 | 1985-06-11 | Hercules Incorporated | Aqueous sizing compositions |
| IT1151847B (it) * | 1982-07-14 | 1986-12-24 | Prodeco Spa | Procedimento per la collatura di carta |
| GB2159183A (en) * | 1984-03-20 | 1985-11-27 | Roe Lee Paper Chemicals Limite | Paper sizing composition |
| SE8405260L (sv) * | 1984-10-22 | 1986-04-23 | Eka Ab | Hydrofoberingsmedel for organiska fibrer, serskilt cellulosafibrer, sett att framstella detta medel samt anvendningen av medlet for meldhydrofobering |
| IT1188086B (it) * | 1985-01-25 | 1987-12-30 | Antonio Corbellini | Metodo per la preparazione di impasti per la produzione di carte collate mediante l'aggiunta di un unico prodotto collante e relativo prodotto collante |
| EP0200002B2 (de) * | 1985-04-13 | 1993-10-27 | Chemische Fabrik Brühl Oppermann GmbH | Papierleimungsmittel und ihre Verwendung |
| GB8712370D0 (en) * | 1987-05-26 | 1987-07-01 | Albright & Wilson | Paper sizing compositions |
-
1988
- 1988-03-18 GB GB888806432A patent/GB8806432D0/en active Pending
-
1989
- 1989-03-07 DE DE68926632T patent/DE68926632T2/de not_active Expired - Fee Related
- 1989-03-07 EP EP89302253A patent/EP0333368B1/en not_active Expired - Lifetime
- 1989-03-07 AT AT89302253T patent/ATE139281T1/de not_active IP Right Cessation
- 1989-03-07 ES ES89302253T patent/ES2087862T3/es not_active Expired - Lifetime
- 1989-03-10 NZ NZ228297A patent/NZ228297A/en unknown
- 1989-03-13 FI FI891184A patent/FI94974C/fi not_active IP Right Cessation
- 1989-03-14 ZA ZA891925A patent/ZA891925B/xx unknown
- 1989-03-15 NO NO891116A patent/NO180345C/no not_active IP Right Cessation
- 1989-03-17 AU AU31429/89A patent/AU619260B2/en not_active Ceased
- 1989-03-17 JP JP1063988A patent/JP2656830B2/ja not_active Expired - Fee Related
- 1989-03-17 CA CA000594070A patent/CA1325500C/en not_active Expired - Fee Related
- 1989-03-17 PT PT90040A patent/PT90040B/pt not_active IP Right Cessation
- 1989-03-17 DK DK198901318A patent/DK173063B1/da not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| PT90040B (pt) | 1995-03-01 |
| PT90040A (pt) | 1989-11-10 |
| JPH026680A (ja) | 1990-01-10 |
| EP0333368A3 (en) | 1991-03-27 |
| EP0333368B1 (en) | 1996-06-12 |
| DK173063B1 (da) | 1999-12-13 |
| DK131889A (da) | 1989-09-19 |
| AU619260B2 (en) | 1992-01-23 |
| DK131889D0 (da) | 1989-03-17 |
| NO891116L (no) | 1989-09-19 |
| FI94974B (fi) | 1995-08-15 |
| DE68926632D1 (de) | 1996-07-18 |
| DE68926632T2 (de) | 1996-11-21 |
| EP0333368A2 (en) | 1989-09-20 |
| GB8806432D0 (en) | 1988-04-20 |
| CA1325500C (en) | 1993-12-28 |
| JP2656830B2 (ja) | 1997-09-24 |
| NO180345B (no) | 1996-12-23 |
| ZA891925B (en) | 1990-05-30 |
| AU3142989A (en) | 1989-09-21 |
| NZ228297A (en) | 1991-07-26 |
| NO891116D0 (no) | 1989-03-15 |
| ES2087862T3 (es) | 1996-08-01 |
| NO180345C (no) | 1997-04-02 |
| FI891184L (fi) | 1989-09-19 |
| FI891184A0 (fi) | 1989-03-13 |
| ATE139281T1 (de) | 1996-06-15 |
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