FI87556B - Foerfarande foer framstaellning av klorerade olefiner - Google Patents

Foerfarande foer framstaellning av klorerade olefiner Download PDF

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Publication number
FI87556B
FI87556B FI881254A FI881254A FI87556B FI 87556 B FI87556 B FI 87556B FI 881254 A FI881254 A FI 881254A FI 881254 A FI881254 A FI 881254A FI 87556 B FI87556 B FI 87556B
Authority
FI
Finland
Prior art keywords
acid
reaction
dimethyl
general formula
formula
Prior art date
Application number
FI881254A
Other languages
English (en)
Finnish (fi)
Other versions
FI87556C (sv
FI881254A0 (fi
FI881254A (fi
Inventor
Toshiki Mori
Shigeaki Suzuki
Takashi Onishi
Yoshiji Fujita
Original Assignee
Kuraray Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kuraray Co filed Critical Kuraray Co
Publication of FI881254A0 publication Critical patent/FI881254A0/fi
Publication of FI881254A publication Critical patent/FI881254A/fi
Application granted granted Critical
Publication of FI87556B publication Critical patent/FI87556B/fi
Publication of FI87556C publication Critical patent/FI87556C/sv

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/18—Preparation of ethers by reactions not forming ether-oxygen bonds
    • C07C41/22—Preparation of ethers by reactions not forming ether-oxygen bonds by introduction of halogens; by substitution of halogen atoms by other halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/287—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by introduction of halogen; by substitution of halogen atoms by other halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/58—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Claims (5)

1. Förfarande för framställning av en klorerad olefin med formeln I, 5 CH0 I 3 CH =C-CH-R (I ) z I Cl 10 där R är en alkyl-, aralkyl- eller alkenylgrupp, som kan vara substiuerad med en lägre acyloxi-, lägre alkyloxi-, alkenyloxi- eller bensyloxigrupp, kännetecknat därav, att hypoklorsyrlighet, som bildas medelst en reaktion mellan natriumhypoklorit och en stark mineralsyra, 15 omsätts med en olefin med formeln CH„ I 3 CH3-C=CH-R (II) 20 där R betecknar samma som ovan, i ett tväfassystem, som utgörs av en vattenfas och en i vatten oblandbar organisk lösningsmedelsfas.
2. Förfarande enligt patentkravet 1, kännetecknat därav, att som stark mineralsyra används 25 sait- eller svavelsyra.
3. Förfarande enligt patentkravet 1, kännetecknat därav, att R i formeln II är en 5-( lägre acyloxi)-3-metyl-3-penten-l-ylgrupp.
4. Förfarande enligt patentkravet 1, k ä n n e - 30 tecknat därav, att som organiskt lösningsmedel används ett kolväte eller halogenerat kolväte.
5. Förfarande enligt patentkravet 1, kännetecknat därav, att reaktionen utförs vid en tempe-ratur av 0-25°C.
FI881254A 1987-03-17 1988-03-16 Förfarande för framställning av klorerade olefiner FI87556C (sv)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP6341887 1987-03-17
JP62063418A JPS63227530A (ja) 1987-03-17 1987-03-17 塩素化オレフイン性化合物の製造方法

Publications (4)

Publication Number Publication Date
FI881254A0 FI881254A0 (fi) 1988-03-16
FI881254A FI881254A (fi) 1988-09-18
FI87556B true FI87556B (fi) 1992-10-15
FI87556C FI87556C (sv) 1993-01-25

Family

ID=13228722

Family Applications (1)

Application Number Title Priority Date Filing Date
FI881254A FI87556C (sv) 1987-03-17 1988-03-16 Förfarande för framställning av klorerade olefiner

Country Status (6)

Country Link
US (1) US4827056A (sv)
EP (1) EP0282914B1 (sv)
JP (1) JPS63227530A (sv)
DE (1) DE3884430T2 (sv)
DK (1) DK142788A (sv)
FI (1) FI87556C (sv)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113501757B (zh) * 2021-07-30 2022-12-13 长沙创新药物工业技术研究院有限公司 一种高纯氯代丙二酸二乙酯的制备和精制方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0131254B1 (de) * 1983-07-08 1988-05-25 L. GIVAUDAN & CIE Société Anonyme Verfahren zur Herstellung substituierter Tetrahydrofurane
JPS6067439A (ja) * 1983-09-22 1985-04-17 Kuraray Co Ltd ３−クロル−２，６−ジメチル−１，５−ヘプタジエン及びその製造方法
US4745229A (en) * 1986-02-28 1988-05-17 Kuraray Company Ltd. Process for preparing α, β-unsaturated aldehydes

Also Published As

Publication number Publication date
FI87556C (sv) 1993-01-25
EP0282914A2 (en) 1988-09-21
DK142788A (da) 1988-09-18
DE3884430D1 (de) 1993-11-04
FI881254A0 (fi) 1988-03-16
EP0282914B1 (en) 1993-09-29
DE3884430T2 (de) 1994-03-24
EP0282914A3 (en) 1990-12-12
FI881254A (fi) 1988-09-18
DK142788D0 (da) 1988-03-16
US4827056A (en) 1989-05-02
JPS63227530A (ja) 1988-09-21

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MM Patent lapsed

Owner name: KURARAY CO., LTD.