FI86748B - FOERFARANDE FOER ATT FRAMSTAELLA EN SPRUTAD YTA MED EN BESTAEMD STRAEVHET OCH DESS ANVAENDNING. - Google Patents
FOERFARANDE FOER ATT FRAMSTAELLA EN SPRUTAD YTA MED EN BESTAEMD STRAEVHET OCH DESS ANVAENDNING. Download PDFInfo
- Publication number
- FI86748B FI86748B FI881474A FI881474A FI86748B FI 86748 B FI86748 B FI 86748B FI 881474 A FI881474 A FI 881474A FI 881474 A FI881474 A FI 881474A FI 86748 B FI86748 B FI 86748B
- Authority
- FI
- Finland
- Prior art keywords
- carbide
- roughness
- weight
- matrix
- process according
- Prior art date
Links
- 238000000034 method Methods 0.000 claims description 16
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 10
- 239000011159 matrix material Substances 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 238000009826 distribution Methods 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 229910052759 nickel Inorganic materials 0.000 claims description 7
- 230000003746 surface roughness Effects 0.000 claims description 6
- 239000008187 granular material Substances 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 150000001247 metal acetylides Chemical class 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 238000001694 spray drying Methods 0.000 claims description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 6
- 239000000956 alloy Substances 0.000 claims 4
- 229910045601 alloy Inorganic materials 0.000 claims 4
- 229910018487 Ni—Cr Inorganic materials 0.000 claims 1
- 239000000853 adhesive Substances 0.000 claims 1
- 230000001070 adhesive effect Effects 0.000 claims 1
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- 235000019592 roughness Nutrition 0.000 description 15
- 239000010410 layer Substances 0.000 description 6
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 3
- 229910052721 tungsten Inorganic materials 0.000 description 3
- 239000010937 tungsten Substances 0.000 description 3
- 150000004767 nitrides Chemical class 0.000 description 2
- 229910021332 silicide Inorganic materials 0.000 description 2
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 239000011111 cardboard Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/06—Metallic material
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Coating By Spraying Or Casting (AREA)
Description
86748 MENETELMÄ MÄÄRÄTTYÄ KARHEUTTA OLEVAN RUISKUTETUN PINNAN VALMISTAMISEKSI SEKÄ SEN KÄYTTÖ86748 METHOD OF MANUFACTURING AND USING AN INJECTED SURFACE OF A SPECIFIC ROUGHNESS
Keksintö koskee menetelmää määrättyä karheutta olevan ruiskutetun pinnan valmistamiseksi työkappaleeseen kuten myös menetelmän esim. tällä tavoin tuotetun pinnan käyttöä.The invention relates to a method for producing an injected surface of a certain roughness in a workpiece as well as to the use of a method e.g. produced in this way.
Termisesti ruiskutetut kerrokset ovat ruiskutuksen jälkeen karheita pinnaltaan karheusasteen ollessa suhteellisen suuren vaihtelualueen sisällä. Karheudet saadaan aikaan ruiskuttamalla ja antamalla sulan rakeen osua päällystettävän työkap-paleen pintaan. Tämä ruiskuttaminen voi aina rakeiden lämpötilan mukaan olla vahvempi tai heikompi, jonka takia hyvin erilaisia karheuksia voi esiintyä yhdellä ainoalla pinnalla. Sellaisten pintakäsitteltyjen pintojen käyttö alueilla, joissa toisaalta pintojen tietty karheus on tarpeellinen, toisaalta joissa tämä karheus ei saa johtaa tuotteen vioittumiseen, ei ole alussa kuvatuissa kerroksissa mainittujen kar-heusvaihtelujen takia mahdollisia. Lisäksi tällaisten pintojen kestävyydet ovat aina käytetyn kerroksen mukaan useissa käyttötarkoituksissa liian vähäiset. Tähän saatiin parannus hyvällä menestyksellä siten, että toisena työvaiheena ruiskutetut pinnat hiottiin ja sillä tavalla päästiin tietyissä rajoissa määrättyyn karheuteen.The thermally sprayed layers have a rough surface after spraying with a roughness within a relatively large range. Roughness is achieved by spraying and allowing the molten granule to hit the surface of the workpiece to be coated. This spraying can always be stronger or weaker depending on the temperature of the granules, due to which very different roughnesses can occur on a single surface. The use of surface-treated surfaces in areas where, on the one hand, a certain roughness of the surfaces is necessary and, on the other hand, where this roughness must not lead to damage to the product, is not possible due to the roughness variations mentioned in the initially described layers. In addition, the durability of such surfaces is always too low for many applications, depending on the layer used. This was improved with good success by sanding the surfaces sprayed in the second step and thus achieving a certain roughness within certain limits.
Huomioon ottaen nämä vaikeudet keksijä on asettanut tavoitteekseen alussa mainitun menetelmän parantamisen ja ainutker- : täisen määrättyä karheutta olevan pintakerroksen tuomisen käyttöön suhteellisen yksinkertaisella käsittelyllä.In view of these difficulties, the inventor has set himself the objective of improving the method mentioned at the outset and of providing a unique surface layer with a defined roughness with a relatively simple treatment.
: Tämän tehtävän ratkaisemiseksi esitetään, että ... pinnalle ruiskutetaan jauhemainen aine sisältäen Ni-, Co- - ja/tai Fe-perusmatriisin ja kovametallien seoksen kova- metallin rae jakauman ollessa maksimaaliselta osaltaan 25 -150 ^im:n välillä, jolloin ruiskutetun - mutta sint-raantumattoman - kerroksen pintakarheus on karheusar- 86748 2 voitaan alueella 10 - 100 yum määrätyn karheuden ollessa kar-heusarvoltaan x i 20 p ja x on joku luku 10 - 100 yum.: To solve this problem, it is proposed that ... a powdery substance containing a base matrix of Ni, Co and / or Fe and a carbide mixture is sprayed on the surface with a maximum carbide grain distribution between 25 and 150 microns, whereby the sprayed - but the surface roughness of the Sint-unbreakable layer is a roughness value of 86748 2 can be obtained in the range of 10 to 100 μm with a defined roughness value of xi 20 p and x is a number of 10 to 100 μm.
Lisäksi on osoittautunut edulliseksi, että pinnalle ruiskutetulla kerroksella on määrätty pintakarheus, jonka karheusarvo on x i 10 ym. Mukana olevien kovametallien sulamispiste on yleensä noin 1200 °C ja sitä korkeampi.In addition, it has proven advantageous that the layer sprayed on the surface has a certain surface roughness with a roughness value of x i 10. The melting point of the carbides involved is generally about 1200 ° C and higher.
Kerroksen lisäyksityiskohdat ovat pääteltävissä alivaatimuk-sista.Further details of the layer can be deduced from the subclaims.
Pintojen päällystäminen määrätyllä karheudella, joka on x ± 20 yarn, edullisesti ± 10 ym - jolloin x on toivottu pinnan karheus yjm:nä - alueella 10 - 100 ^pm johtaa suuriin seisonta--aikoihin, kun jauhemaisena aineena käytetään jauhesekoitus-ta, joka koostuu kahdesta tai useammasta komponentista, joilla on suurempi sulamisalue samoin kuin kovametalleilla. Parhaiten sellaiseen matriisiin sopivat jauhemaiset aineet, joiden seosperustana on Ni, Co ja/tai rauta. Näiden seosten sulamispistealue pitää keksinnön mukaan olla välillä 900 -1400 °C, edullisesti välillä 1000 - 1300 °C ja yhden alueen pitää olla enemmän kuin 50 °C.Coating the surfaces with a defined roughness of x ± 20 yarns, preferably ± 10 μm - where x is the desired surface roughness in μm - in the range of 10 to 100 μm results in high downtimes when a powder mixture consisting of two or more components with a larger melting range as well as carbides. Powdered substances based on a mixture of Ni, Co and / or iron are most suitable for such a matrix. According to the invention, the melting point range of these mixtures should be between 900 and 1400 ° C, preferably between 1000 and 1300 ° C and one range should be more than 50 ° C.
Tukiaineena karheuden aikaansaamiseksi käytetään kova-metallia, kuten karbidia, boridia, nitridiä, silisidiä ja oksidia. Molempien komponenttien matriisin/kovametal1 in sekoitussuhde pitää olla välillä 20 - 80 paino-%, edullisesti 30 - 60 paino-%, kovametalliaineen osuuden suhteen. Vaikutus pinnan karheuteen on seurausta kovametalliaineosan rae-jakaumasta, so. jakauman maksimaalinen osuus pidetään hyvin kapeana kokona is jakauman ollessa alueilla 37 - 125 ym, 45 -105 yum, 45 - 90 yarn tai 37 - 75 yarn.A hard metal such as carbide, boride, nitride, silicide and oxide are used as a support to provide roughness. The matrix / carbide mixing ratio of both components should be between 20 and 80% by weight, preferably between 30 and 60% by weight, based on the proportion of carbide. The effect on surface roughness is a result of the grain distribution of the carbide component, i. the maximum proportion of the distribution is considered to be a very narrow size, the distribution being in the ranges 37 to 125 μm, 45 to 105 μm, 45 to 90 yarn or 37 to 75 yarn.
Kovametalliaineen rakeet pitää valmistaa suihkukuivaamalla, agglomeroimalla sintterien kanssa tai ilman niitä tai sulattamalla ja jälkeenpäin murskaamalla ja jauhamalla.Carbide granules should be prepared by spray drying, agglomeration with or without sinter, or melting and subsequent crushing and grinding.
86748 386748 3
Myöhempi päällystäminen kovametalliaineilla Ni-, Co- ja/tai Fe:n kanssa on osoittautunut edulliseksi. Osuuden pitää olla alle 40 paino-%, edullisesti alle 20 paino-%.Subsequent coating with carbide materials with Ni, Co and / or Fe has proven advantageous. The proportion should be less than 40% by weight, preferably less than 20% by weight.
Erilaisia vaihtoehtoja on olemassa, esim. karbidi voi olla kovametallikomponenttina, erityisesti wolframipohjäinen karbidi, edullisesti wolframisulakarbidi, esim. karbidi wolfra-mikarbidikoboltista kobolttipitoisuuden ollessa alle 25 %Various alternatives exist, e.g. the carbide may be as a carbide component, in particular a tungsten-based carbide, preferably a tungsten fused carbide, e.g. a carbide from tungsten micarbide cobalt with a cobalt content of less than 25%
Co. Kovametallikomponentteina voi olla boridi tai silisidi, tai vaikka nitridi tai oksidi. Matriisina voidaan käyttää esim. kobolttipohjäistä seosta tai rautapohjaista seosta. Matriisiseoksen raejakautuma on esim. 150 - 5 ^im.C/o. The carbide components may be boride or silicide, or even nitride or oxide. As the matrix, for example, a cobalt-based mixture or an iron-based mixture can be used. The grain distribution of the matrix mixture is e.g. 150 to 5.
Kovametallirakeiden raemuoto voi olla pallomainen tai monikulmainen. Pinnan päällystyksessä voidaan käyttää esim. kaasuliekkiruiskutinlaitetta tai plasmaliekkiruiskutinta.The granular shape of the carbide grains can be spherical or polygonal. For example, a gas flame sprayer or a plasma flame sprayer can be used for surface coating.
Kuvatulla menetelmällä saadut pinnat voidaan käyttää hyväksi erityisen edullisesti paperiteollisuudessa, jossa kuljetus-rullien tai tartuntakynsien pitää ottaa vastaan ohuita paperiratoja tai kartonkiarkkeja, ilman että kuljetettaville tavaroille tulee vähäisintäkään vauriota.The surfaces obtained by the described method can be utilized particularly advantageously in the paper industry, where the transport rollers or gripping nails have to receive thin webs of paper or cardboard sheets without the slightest damage to the goods to be transported.
Ei vain edullisilla käyttöalueilla vaan aivan yleisesti on osoitettu keksinnön mukaisen menetelmän erityisenä etuna, että valmistustapahtuman aikana syntyy määrätty pinta, joka ei tarvitse enää jälkikäsittelyä.Not only in the preferred areas of use, but quite generally, it has been shown as a particular advantage of the method according to the invention that a certain surface is created during the manufacturing process which no longer requires post-treatment.
Claims (11)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19873712684 DE3712684A1 (en) | 1987-04-14 | 1987-04-14 | METHOD FOR PRODUCING A SPRAYED SURFACE WITH DEFINED ROUGHNESS, AND USE THEREOF |
| DE3712684 | 1987-04-14 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| FI881474A0 FI881474A0 (en) | 1988-03-29 |
| FI881474L FI881474L (en) | 1988-10-15 |
| FI86748B true FI86748B (en) | 1992-06-30 |
Family
ID=6325622
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI881474A FI86748B (en) | 1987-04-14 | 1988-03-29 | FOERFARANDE FOER ATT FRAMSTAELLA EN SPRUTAD YTA MED EN BESTAEMD STRAEVHET OCH DESS ANVAENDNING. |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP0287023A3 (en) |
| CN (1) | CN88102725A (en) |
| BR (1) | BR8801864A (en) |
| CA (1) | CA1315613C (en) |
| DE (1) | DE3712684A1 (en) |
| FI (1) | FI86748B (en) |
| IN (1) | IN169734B (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FI82094C (en) * | 1989-02-16 | 1997-09-09 | Valmet Corp | Anvaendning av en legering av ett metallpulver och en carbid eller nitride innefattande belaeggningskomposition Foer en i en pappersmaskin anvaendbar yankeecylinder |
| FI86566C (en) * | 1989-10-27 | 1992-09-10 | Valmet Paper Machinery Inc | VALS FOER ANVAENDNING VID PAPPERSFRAMSTAELLNING OCH FOERFARANDE FOER FRAMSTAELLNING AV VALSEN. |
| TW197475B (en) * | 1990-12-26 | 1993-01-01 | Eltech Systems Corp | |
| DE4226789A1 (en) * | 1992-08-13 | 1994-02-17 | Sigri Great Lakes Carbon Gmbh | Fiber-reinforced plastic roller with outer, wear-resistant, filler-containing plastic layer |
| DE4238508C2 (en) * | 1992-11-14 | 1995-07-20 | Gf Flamm Metallspritz Gmbh | Process for applying a fine, rough coating to the surface of a roller |
| DE59404761D1 (en) * | 1993-06-19 | 1998-01-22 | Hoechst Ag | Thread-guiding component with an improved surface |
| EP0839216B1 (en) * | 1995-11-08 | 2000-03-08 | Fissler Gmbh | Process for producing a non-stick coating and objects provided with such a coating |
| DE19836392A1 (en) * | 1998-08-12 | 2000-02-17 | Wolfgang Wiesener | Low cost wear resistant coating, used as a plasma sprayed coating for tools such as screwdrivers, comprises hard metal grains in a binder metal matrix |
| US20050202945A1 (en) * | 2004-03-11 | 2005-09-15 | Leung Chi K. | Thermal spray grit roller |
| CN107130204A (en) * | 2017-05-22 | 2017-09-05 | 河南中原吉凯恩气缸套有限公司 | A kind of wear-resistant coating cylinder jacket and its preparation technology |
| CN110983232B (en) * | 2019-11-06 | 2022-11-01 | 苏州合志杰新材料技术有限公司 | Method for preparing wear-resistant anti-sticking coating by using special spraying power |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3679460A (en) * | 1970-10-08 | 1972-07-25 | Union Carbide Corp | Composite wear resistant material and method of making same |
| GB2060436B (en) * | 1979-09-22 | 1984-03-21 | Rolls Royce | Method of applying a ceramic coating to a metal workpiece |
| US4513020A (en) * | 1981-07-22 | 1985-04-23 | Allied Corporation | Platelet metal powder for coating a substrate |
| DE3506726A1 (en) * | 1985-02-26 | 1986-08-28 | Reifenhäuser GmbH & Co Maschinenfabrik, 5210 Troisdorf | WEAR-RESISTANT COATING ON THE CYLINDER AND ON THE SCREW OF A PLASTIC SCREW PRESS |
| US4618511A (en) * | 1985-05-31 | 1986-10-21 | Molnar William S | Method for applying non-skid coating to metal bars with electric arc or gas flame spray and article formed thereby |
-
1987
- 1987-04-14 DE DE19873712684 patent/DE3712684A1/en active Granted
-
1988
- 1988-03-29 FI FI881474A patent/FI86748B/en not_active Application Discontinuation
- 1988-04-12 EP EP88105778A patent/EP0287023A3/en not_active Withdrawn
- 1988-04-13 CA CA000563978A patent/CA1315613C/en not_active Expired - Fee Related
- 1988-04-13 IN IN303/CAL/88A patent/IN169734B/en unknown
- 1988-04-14 BR BR8801864A patent/BR8801864A/en not_active IP Right Cessation
- 1988-04-14 CN CN198888102725A patent/CN88102725A/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| EP0287023A2 (en) | 1988-10-19 |
| BR8801864A (en) | 1988-11-22 |
| CA1315613C (en) | 1993-04-06 |
| FI881474L (en) | 1988-10-15 |
| DE3712684A1 (en) | 1988-10-27 |
| DE3712684C2 (en) | 1991-06-06 |
| CN88102725A (en) | 1988-11-23 |
| FI881474A0 (en) | 1988-03-29 |
| EP0287023A3 (en) | 1990-06-20 |
| IN169734B (en) | 1991-12-14 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| CD | Patent refused following opposition | ||
| FC | Application refused |
Owner name: CASTOLIN S.A. |