EP0287023A2 - Process for producing a sprayed surface with a particular roughness, and its use - Google Patents
Process for producing a sprayed surface with a particular roughness, and its use Download PDFInfo
- Publication number
- EP0287023A2 EP0287023A2 EP88105778A EP88105778A EP0287023A2 EP 0287023 A2 EP0287023 A2 EP 0287023A2 EP 88105778 A EP88105778 A EP 88105778A EP 88105778 A EP88105778 A EP 88105778A EP 0287023 A2 EP0287023 A2 EP 0287023A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- hard material
- matrix
- microns
- sprayed
- hard
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/06—Metallic material
Definitions
- the invention relates to a method for producing a sprayed surface with a defined roughness on a workpiece and the use of the method or the surface produced thereby.
- thermally sprayed layers After spraying, thermally sprayed layers have a rough surface, the degree of roughness of which lies within a relatively large fluctuation range.
- the roughness results from the splintering of molten particles when they hit the workpiece surface to be coated. This sputtering can be stronger or weaker depending on the temperature of the particle, which means that very different roughness can occur on a single surface. If such surfaces are used in areas where, on the one hand, a special grip of the surface is required and, on the other hand, this grip must not damage the product, the use of the layers described at the outset is not possible due to the roughness fluctuations mentioned. In addition, depending on the alloy used, the service life of such surfaces is too short for many applications. A remedy was achieved here with moderate success by grinding the sprayed surfaces in a second operation and thus achieving a defined roughness within certain limits.
- the inventor has set himself the goal of improving the method of the type mentioned at the outset and including a surface layer to offer clearly defined roughness in relatively easy handling.
- the solution to this problem is that a powdery material made of a mixture of a matrix based on Ni, Co and / or Fe-based alloy and hard materials and a grain size distribution of these hard materials with a maximum proportion between 25 to 150 microns, the sprayed - but unsintered layer has a surface roughness in the range Ra 10 to 100 ⁇ m with a defined roughness of Ra.x ⁇ 20 ⁇ m and x is a number from 10 to 100 ⁇ m.
- the sprayed-on layer has a defined surface roughness of Ra.x ⁇ 10 ⁇ m.
- the hard materials have a melting point of about 1200 ° C and higher.
- the coating of surfaces with a defined roughness of x ⁇ 20 ⁇ m, preferably ⁇ 10 ⁇ m - where x is the desired surface roughness in ⁇ m - in the range from 10 to 100 ⁇ m leads to long service lives if a mixed powder is used as the powdery material uses, which consists of two or more components that have a larger melting interval and hard materials. Powdery materials based on an alloy of Ni, Co and / or iron are best suited for such a matrix. According to the invention, the melting point interval of these alloys should be between 900 and 1400 ° C., preferably between 1000 and 1300 ° C., and should have an interval of more than 50 ° C.
- Hard material particles such as carbides, borides, nitrides, silicides and oxides are used as carriers for the roughness.
- the mixing ratio of the two components matrix / hard material should be between 20 and 80% by weight, preferably 30 to 60% by weight, for the hard material portion.
- the surface roughness is influenced via the grain distribution of the hard material portion, i. H. the maximum proportion of the grain distribution is kept very narrow, while the total distribution is in the ranges from 37 to 125 ⁇ m or 45 to 105 ⁇ m or 45 to 90 ⁇ m or 37 to 75 ⁇ m.
- the hard material particles should be produced by spray drying, agglomerating with and without sintering or by melting with subsequent breaking and grinding. Later coating of the hard materials with Ni, Co and / or Fe has proven to be advantageous.
- the proportion should be below 40% by weight, preferably below 20% by weight.
Abstract
Description
Die Erfindung betrifft ein Verfahren zum Herstellen einer gespritzten Oberfläche mit definierter Rauhigkeit auf einem Werkstück sowie die Verwendung des Verfahrens bzw. der dadurch erzeugten Oberfläche.The invention relates to a method for producing a sprayed surface with a defined roughness on a workpiece and the use of the method or the surface produced thereby.
Thermisch gespritzte Schichten weisen nach dem Spritzen eine rauhe Oberfläche auf, deren Rauhigkeitsmaß innerhalb eines verhältnismäßig großen Schwankungsbereiches liegt. Die Rauhigkeiten ergeben sich durch das Zerspratzen schmelzflüssiger Partikel beim Auftreffen auf die zu beschichtende Werkstückoberfläche. Dieses Zerspratzen kann je nach Temperatur des Partikels stärker oder schwächer sein, wodurch sehr unterschiedliche Rauhigkeiten auf einer einzeigen Oberfläche auftreten können. Bei Einsatz solcher Oberflächen in Bereichen, in denen einerseits eine besondere Griffigkeit der Oberfläche erforderlich ist, anderseits diese Griffigkeit nicht zu einer Beschädigung des Produktes führen darf, ist die Verwendung der eingangs beschriebenen Schichten durch die genannten Rauhigkeitsschwankungen nicht möglich. Zudem sind die Standzeiten solcher Oberflächen je nach verwendeter Legierung für viele Anwendungszwecke zu gering. Eine Abhilfe wurde hier mit mäßigem Erfolg dadurch erreicht, daß man die gespritzten Oberflächen in einem zweiten Arbeitsgang schleift und damit in gewissen Grenzen zu einer definierten Rauhigkeit gelangt.After spraying, thermally sprayed layers have a rough surface, the degree of roughness of which lies within a relatively large fluctuation range. The roughness results from the splintering of molten particles when they hit the workpiece surface to be coated. This sputtering can be stronger or weaker depending on the temperature of the particle, which means that very different roughness can occur on a single surface. If such surfaces are used in areas where, on the one hand, a special grip of the surface is required and, on the other hand, this grip must not damage the product, the use of the layers described at the outset is not possible due to the roughness fluctuations mentioned. In addition, depending on the alloy used, the service life of such surfaces is too short for many applications. A remedy was achieved here with moderate success by grinding the sprayed surfaces in a second operation and thus achieving a defined roughness within certain limits.
Angesichts dieser Schwierigkeiten hat sich der Erfinder das Ziel gesetzt, das Verfahren der eingangs erwähnten Art zu verbessern und eine Oberflächenschicht mit ein deutig definierter Rauhigkeit in verhältnismäßig einfacher Handhabung anzubieten.In view of these difficulties, the inventor has set himself the goal of improving the method of the type mentioned at the outset and including a surface layer to offer clearly defined roughness in relatively easy handling.
Zur Lösung dieser Aufgabe führt, daß ein pulverförmiger Werkstoff aus einer Mischung von einer Matrix auf Ni,Co und/oder Fe-Basislegierung und Hartstoffen sowie einer Kornverteilung dieser Hartstoffe mit maximalem Anteil zwischen 25 bis 150 µm aufgespritzt wird, wobei die gespritzte -- aber ungesinterte -- Schicht eine Oberflächenrauhigkeit im Bereich Ra 10 bis 100 µm mit einer definierten Rauhigkeit von Ra.x± 20 µm aufweist und x eine Zahl von 10 bis 100 µm ist.The solution to this problem is that a powdery material made of a mixture of a matrix based on Ni, Co and / or Fe-based alloy and hard materials and a grain size distribution of these hard materials with a maximum proportion between 25 to 150 microns, the sprayed - but unsintered layer has a surface roughness in the range Ra 10 to 100 µm with a defined roughness of Ra.x ± 20 µm and x is a number from 10 to 100 µm.
Zudem hat es sich als günstig erwiesen, daß die aufgespritzte Schicht eine definierte Oberflächenrauhigkeit von Ra.x± 10 µm aufweist. Die Hartstoffe weisen dabei im übrigen einen Schmelzpunkt von etwa 1200° C und höher auf.In addition, it has proven to be advantageous that the sprayed-on layer has a defined surface roughness of Ra.x ± 10 µm. The hard materials have a melting point of about 1200 ° C and higher.
Weitere Einzelheiten der Schicht sind den Unteransprüchen zu entnehmen.Further details of the layer can be found in the subclaims.
Das Beschichten von Oberflächen mit einer definierten Rauhigkeit von x± 20 µm, vorzugsweise ± 10 µm -- wobei x die gewünschte Oberflächenrauhigkeit in µm ist -- im Bereich von 10 bis 100 µm führt zu großen Standzeiten, wenn man als pulverförmigen Werkstoff ein gemischtes Pulver einsetzt, welches aus zwei oder mehreren Komponenten besteht, die ein größeres Schmelzintervall sowie Hartstoffe aufweisen. Am besten eignen sich für eine solche Matrix pulverförmige Werkstoffe auf einer Legierungsbasis von Ni,Co und/oder Eisen. Das Schmelzpunktintervall dieser Legierungen soll erfindungsgemäß zwischen 900 und 1400° C liegen, vorzugsweise zwischen 1000 und 1300°C, und ein Intervall von mehr als 50°C aufweisen.The coating of surfaces with a defined roughness of x ± 20 µm, preferably ± 10 µm - where x is the desired surface roughness in µm - in the range from 10 to 100 µm leads to long service lives if a mixed powder is used as the powdery material uses, which consists of two or more components that have a larger melting interval and hard materials. Powdery materials based on an alloy of Ni, Co and / or iron are best suited for such a matrix. According to the invention, the melting point interval of these alloys should be between 900 and 1400 ° C., preferably between 1000 and 1300 ° C., and should have an interval of more than 50 ° C.
Als Träger für die Rauhigkeit werden Hartstoffpartikel, wie Karbide, Boride, Nitride, Silicide und Oxyde verwendet. Das Mischungsverhältnis der beiden Komponenten Matrix/Hartstoff sollte zwischen 20 und 80 Gew.-%, bevorzugt 30 bis 60 Gew.-%, für den Hartstoffanteil liegen. Die Beeinflussung der Oberflächenrauhigkeit erfolgt über die Kornverteilung des Hartstoffanteils, d. h. der maximale Anteil der Kornverteilung wird sehr eng gehalten, während die Gesamtverteilung in den Bereichen von 37 bis 125 µm bzw. 45 bis 105 µm bzw. 45 bis 90 µm bzw. 37 bis 75 µm liegt.Hard material particles such as carbides, borides, nitrides, silicides and oxides are used as carriers for the roughness. The mixing ratio of the two components matrix / hard material should be between 20 and 80% by weight, preferably 30 to 60% by weight, for the hard material portion. The surface roughness is influenced via the grain distribution of the hard material portion, i. H. the maximum proportion of the grain distribution is kept very narrow, while the total distribution is in the ranges from 37 to 125 µm or 45 to 105 µm or 45 to 90 µm or 37 to 75 µm.
Die Hartstoffpartikel sollten durch Sprühtrocknen, Agglomerieren mit und ohne Sintern oder durch Schmelzen mit nachträglichem Brechen und Mahlen hergestellt werden. Ein späteres Überziehen der Hartstoffe mit Ni,Co und/oder Fe hat sich als vorteilhaft herausgestellt. Der Anteil sollte unter 40 Gew.-% liegen, bevorzugt unter 20 Gew.-%.The hard material particles should be produced by spray drying, agglomerating with and without sintering or by melting with subsequent breaking and grinding. Later coating of the hard materials with Ni, Co and / or Fe has proven to be advantageous. The proportion should be below 40% by weight, preferably below 20% by weight.
Die durch das beschriebene Verfahren entstehenden Oberflächen können mit besonderen Vorteilen in der Papierindustrie eingesetzt werden, wo Transportrollen oder Greiferfinger dünne Papierbahnen oder Kartonbögen aufnehmen sollen, ohne daß es zu den geringsten Beschädigungen des transportierten Gutes kommt.The surfaces created by the process described can be used with particular advantages in the paper industry, where transport rollers or gripper fingers are to take up thin paper webs or cardboard sheets without causing the slightest damage to the transported goods.
Nicht nur bei den bevorzugten Verwendungsgebieten, sondern ganz allgemein hat es sich als besonderer Vorteil des erfindungsgemäßen Verfahrens erwiesen, daß während des Herstellungsvorganges eine bestimmte Oberfläche entsteht, die einer Nachbehandlung nicht mehr bedarf.Not only in the preferred fields of use, but very generally, it has proven to be a particular advantage of the method according to the invention that a certain surface is created during the manufacturing process, which no longer requires post-treatment.
Claims (18)
dadurch gekennzeichnet,
daß ein pulverförmiger Werkstoff aus einer Mischung von einer Matrix auf Ni, Co und/oder Fe-Basislegierung und Hartstoffen sowie einer Kornverteilung der Hartstoffe mit maximalem Anteil zwischen 25 bis 150 µm aufgespritzt wird, wobei die gespritzte, ungesinterte Schicht eine Oberflächenrauhigkeit im Bereich von Ra 10 bis 100 µm mit einer definierten Rauhigkeit von Ra.x± 20 µm aufweist und x eine Zahl von 10 bis 100 µm ist.1. Method for producing a sprayed surface with a defined roughness on a workpiece,
characterized,
that a powdery material from a mixture of a matrix based on Ni, Co and / or Fe-based alloy and hard materials and a grain distribution of hard materials is sprayed with a maximum proportion between 25 to 150 microns, the sprayed, unsintered layer having a surface roughness in the range of Ra 10 to 100 µm with a defined roughness of Ra.x ± 20 µm and x is a number from 10 to 100 µm.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3712684 | 1987-04-14 | ||
DE19873712684 DE3712684A1 (en) | 1987-04-14 | 1987-04-14 | METHOD FOR PRODUCING A SPRAYED SURFACE WITH DEFINED ROUGHNESS, AND USE THEREOF |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0287023A2 true EP0287023A2 (en) | 1988-10-19 |
EP0287023A3 EP0287023A3 (en) | 1990-06-20 |
Family
ID=6325622
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP88105778A Withdrawn EP0287023A3 (en) | 1987-04-14 | 1988-04-12 | Process for producing a sprayed surface with a particular roughness, and its use |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP0287023A3 (en) |
CN (1) | CN88102725A (en) |
BR (1) | BR8801864A (en) |
CA (1) | CA1315613C (en) |
DE (1) | DE3712684A1 (en) |
FI (1) | FI86748B (en) |
IN (1) | IN169734B (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0383466A1 (en) * | 1989-02-16 | 1990-08-22 | Valmet-Tampella Inc. | A Yankee cylinder and a method for coating a Yankee cylinder |
EP0425464A1 (en) * | 1989-10-27 | 1991-05-02 | Valmet Paper Machinery Inc. | Roll for use in the production of paper and method for the manufacture of the roll |
EP0493326A2 (en) * | 1990-12-26 | 1992-07-01 | Eltech Systems Corporation | Substrate of improved melt sprayed surface morphology |
EP0631961A1 (en) * | 1993-06-19 | 1995-01-04 | Hoechst Aktiengesellschaft | Yarn guiding component with an improved outer surface |
WO1997017478A1 (en) * | 1995-11-08 | 1997-05-15 | Fissler Gmbh | Process for producing a non-stick coating and objects provided with such a coating |
WO2000009774A1 (en) * | 1998-08-12 | 2000-02-24 | Wolfgang Wiesener | Surface coating, granular mixture for feeding to a plasma coating, and a surface coating method |
CN107130204A (en) * | 2017-05-22 | 2017-09-05 | 河南中原吉凯恩气缸套有限公司 | A kind of wear-resistant coating cylinder jacket and its preparation technology |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4226789A1 (en) * | 1992-08-13 | 1994-02-17 | Sigri Great Lakes Carbon Gmbh | Fiber-reinforced plastic roller with outer, wear-resistant, filler-containing plastic layer |
DE4238508C2 (en) * | 1992-11-14 | 1995-07-20 | Gf Flamm Metallspritz Gmbh | Process for applying a fine, rough coating to the surface of a roller |
US20050202945A1 (en) * | 2004-03-11 | 2005-09-15 | Leung Chi K. | Thermal spray grit roller |
CN110983232B (en) * | 2019-11-06 | 2022-11-01 | 苏州合志杰新材料技术有限公司 | Method for preparing wear-resistant anti-sticking coating by using special spraying power |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2129679A1 (en) * | 1970-06-15 | 1972-01-27 | Fuji Photo Film Co Ltd | Process for the production of guide materials for magnetic recording tapes |
US3679460A (en) * | 1970-10-08 | 1972-07-25 | Union Carbide Corp | Composite wear resistant material and method of making same |
GB2060436A (en) * | 1979-09-22 | 1981-05-07 | Rolls Royce | Method of applying a ceramic coating to a metal workpiece |
US4513020A (en) * | 1981-07-22 | 1985-04-23 | Allied Corporation | Platelet metal powder for coating a substrate |
GB2171418A (en) * | 1985-02-26 | 1986-08-28 | Reifenhaeuser Masch | Facing of cylinders and worms in plastics worm extruders to enhance wear resistance |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4618511A (en) * | 1985-05-31 | 1986-10-21 | Molnar William S | Method for applying non-skid coating to metal bars with electric arc or gas flame spray and article formed thereby |
-
1987
- 1987-04-14 DE DE19873712684 patent/DE3712684A1/en active Granted
-
1988
- 1988-03-29 FI FI881474A patent/FI86748B/en not_active Application Discontinuation
- 1988-04-12 EP EP88105778A patent/EP0287023A3/en not_active Withdrawn
- 1988-04-13 CA CA000563978A patent/CA1315613C/en not_active Expired - Fee Related
- 1988-04-13 IN IN303/CAL/88A patent/IN169734B/en unknown
- 1988-04-14 CN CN198888102725A patent/CN88102725A/en active Pending
- 1988-04-14 BR BR8801864A patent/BR8801864A/en not_active IP Right Cessation
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2129679A1 (en) * | 1970-06-15 | 1972-01-27 | Fuji Photo Film Co Ltd | Process for the production of guide materials for magnetic recording tapes |
US3679460A (en) * | 1970-10-08 | 1972-07-25 | Union Carbide Corp | Composite wear resistant material and method of making same |
GB2060436A (en) * | 1979-09-22 | 1981-05-07 | Rolls Royce | Method of applying a ceramic coating to a metal workpiece |
US4513020A (en) * | 1981-07-22 | 1985-04-23 | Allied Corporation | Platelet metal powder for coating a substrate |
GB2171418A (en) * | 1985-02-26 | 1986-08-28 | Reifenhaeuser Masch | Facing of cylinders and worms in plastics worm extruders to enhance wear resistance |
Non-Patent Citations (1)
Title |
---|
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A, Band 3, Nr. 6, November-Dezember 1985, Seiten 2490-2493, New York, US; O. KNOTEK et al.: "On plasma sprayed WSi2 and Cr3C2-Ni coatings" * |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0383466A1 (en) * | 1989-02-16 | 1990-08-22 | Valmet-Tampella Inc. | A Yankee cylinder and a method for coating a Yankee cylinder |
EP0425464A1 (en) * | 1989-10-27 | 1991-05-02 | Valmet Paper Machinery Inc. | Roll for use in the production of paper and method for the manufacture of the roll |
EP0493326A2 (en) * | 1990-12-26 | 1992-07-01 | Eltech Systems Corporation | Substrate of improved melt sprayed surface morphology |
EP0493326A3 (en) * | 1990-12-26 | 1993-03-17 | Eltech Systems Corporation | Substrate of improved melt sprayed surface morphology |
AU643350B2 (en) * | 1990-12-26 | 1993-11-11 | Eltech Systems Corporation | Substrate of improved plasma sprayed surface morphology |
EP0631961A1 (en) * | 1993-06-19 | 1995-01-04 | Hoechst Aktiengesellschaft | Yarn guiding component with an improved outer surface |
US5528799A (en) * | 1993-06-19 | 1996-06-25 | Hoechst Aktiengesellschaft | Thread-guiding component with improved surface |
WO1997017478A1 (en) * | 1995-11-08 | 1997-05-15 | Fissler Gmbh | Process for producing a non-stick coating and objects provided with such a coating |
WO2000009774A1 (en) * | 1998-08-12 | 2000-02-24 | Wolfgang Wiesener | Surface coating, granular mixture for feeding to a plasma coating, and a surface coating method |
CN107130204A (en) * | 2017-05-22 | 2017-09-05 | 河南中原吉凯恩气缸套有限公司 | A kind of wear-resistant coating cylinder jacket and its preparation technology |
Also Published As
Publication number | Publication date |
---|---|
CA1315613C (en) | 1993-04-06 |
FI86748B (en) | 1992-06-30 |
DE3712684C2 (en) | 1991-06-06 |
CN88102725A (en) | 1988-11-23 |
FI881474A (en) | 1988-10-15 |
IN169734B (en) | 1991-12-14 |
EP0287023A3 (en) | 1990-06-20 |
FI881474A0 (en) | 1988-03-29 |
DE3712684A1 (en) | 1988-10-27 |
BR8801864A (en) | 1988-11-22 |
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