FI80208B - Haorfaerger. - Google Patents
Haorfaerger. Download PDFInfo
- Publication number
- FI80208B FI80208B FI852675A FI852675A FI80208B FI 80208 B FI80208 B FI 80208B FI 852675 A FI852675 A FI 852675A FI 852675 A FI852675 A FI 852675A FI 80208 B FI80208 B FI 80208B
- Authority
- FI
- Finland
- Prior art keywords
- group
- acid
- dyes
- hair
- nitrobenzoic acid
- Prior art date
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- 239000001257 hydrogen Substances 0.000 claims abstract description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 5
- 125000000896 monocarboxylic acid group Chemical group 0.000 claims abstract description 5
- 230000003647 oxidation Effects 0.000 claims abstract description 4
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 4
- 239000000975 dye Substances 0.000 claims description 29
- 150000001875 compounds Chemical class 0.000 claims description 14
- 239000000982 direct dye Substances 0.000 claims description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims description 8
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 claims description 6
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 239000003086 colorant Substances 0.000 claims description 4
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 4
- QQANOUXMWFQYFE-UHFFFAOYSA-N 5-nitro-2-piperidin-1-ylbenzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC([N+]([O-])=O)=CC=C1N1CCCCC1 QQANOUXMWFQYFE-UHFFFAOYSA-N 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical group C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 2
- 125000004103 aminoalkyl group Chemical group 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 2
- QWVBKFGEFAYHRR-UHFFFAOYSA-N NC1=C(C(=O)O)C=CC(=C1)[N+](=O)[O-].N1(CCCCC1)C1=C(C(=O)O)C=C(C=C1)[N+](=O)[O-].C(C)NC1=C(C=C(C(=O)O)C=C1)[N+](=O)[O-].CNC1=C(C=C(C(=O)O)C=C1)[N+](=O)[O-] Chemical compound NC1=C(C(=O)O)C=CC(=C1)[N+](=O)[O-].N1(CCCCC1)C1=C(C(=O)O)C=C(C=C1)[N+](=O)[O-].C(C)NC1=C(C=C(C(=O)O)C=C1)[N+](=O)[O-].CNC1=C(C=C(C(=O)O)C=C1)[N+](=O)[O-] QWVBKFGEFAYHRR-UHFFFAOYSA-N 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 239000000118 hair dye Substances 0.000 abstract description 26
- 239000002243 precursor Substances 0.000 abstract description 11
- 238000002360 preparation method Methods 0.000 abstract description 10
- 230000037308 hair color Effects 0.000 abstract description 7
- 125000001424 substituent group Chemical group 0.000 abstract description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 229910006069 SO3H Inorganic materials 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 abstract 1
- 230000002110 toxicologic effect Effects 0.000 abstract 1
- 231100000723 toxicological property Toxicity 0.000 abstract 1
- 240000007817 Olea europaea Species 0.000 description 15
- 230000001590 oxidative effect Effects 0.000 description 13
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 13
- 239000007800 oxidant agent Substances 0.000 description 7
- 239000002453 shampoo Substances 0.000 description 7
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- -1 4-Methylamino-3-nitrobenzenesulfonic acid 2-Piperidino-5-nitrobenzenesulfonic acid 2-Morpholino-5-nitrobenzenesulfonic acid sulfone Chemical class 0.000 description 5
- 235000019646 color tone Nutrition 0.000 description 5
- 239000006071 cream Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- 239000003581 cosmetic carrier Substances 0.000 description 4
- 239000007822 coupling agent Substances 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 150000002191 fatty alcohols Chemical class 0.000 description 4
- VBEGHXKAFSLLGE-UHFFFAOYSA-N n-phenylnitramide Chemical class [O-][N+](=O)NC1=CC=CC=C1 VBEGHXKAFSLLGE-UHFFFAOYSA-N 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 239000003638 chemical reducing agent Substances 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 239000000499 gel Substances 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 150000005181 nitrobenzenes Chemical class 0.000 description 3
- 238000005691 oxidative coupling reaction Methods 0.000 description 3
- GHOKWGTUZJEAQD-ZETCQYMHSA-N (D)-(+)-Pantothenic acid Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCC(O)=O GHOKWGTUZJEAQD-ZETCQYMHSA-N 0.000 description 2
- DOWIJKGYCPKWNC-UHFFFAOYSA-N 2-(dimethylamino)-5-nitrobenzoic acid Chemical compound CN(C)C1=CC=C([N+]([O-])=O)C=C1C(O)=O DOWIJKGYCPKWNC-UHFFFAOYSA-N 0.000 description 2
- LTASFWDWBYFZQQ-UHFFFAOYSA-N 2-amino-5-nitrobenzenesulfonic acid Chemical compound NC1=CC=C([N+]([O-])=O)C=C1S(O)(=O)=O LTASFWDWBYFZQQ-UHFFFAOYSA-N 0.000 description 2
- XPLTXYDVYDWSSO-UHFFFAOYSA-N 4-(ethylamino)-3-nitrobenzoic acid Chemical compound CCNC1=CC=C(C(O)=O)C=C1[N+]([O-])=O XPLTXYDVYDWSSO-UHFFFAOYSA-N 0.000 description 2
- KSMLIIWEQBYUKA-UHFFFAOYSA-N 4-(methylamino)-3-nitrobenzoic acid Chemical compound CNC1=CC=C(C(O)=O)C=C1[N+]([O-])=O KSMLIIWEQBYUKA-UHFFFAOYSA-N 0.000 description 2
- UEALKTCRMBVTFN-UHFFFAOYSA-N 4-nitroanthranilic acid Chemical compound NC1=CC([N+]([O-])=O)=CC=C1C(O)=O UEALKTCRMBVTFN-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 2
- 239000000443 aerosol Substances 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 239000001000 anthraquinone dye Substances 0.000 description 2
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- XXQBEVHPUKOQEO-UHFFFAOYSA-N potassium superoxide Chemical compound [K+].[K+].[O-][O-] XXQBEVHPUKOQEO-UHFFFAOYSA-N 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- 150000005207 1,3-dihydroxybenzenes Chemical class 0.000 description 1
- RQSZZLSHECUEDX-UHFFFAOYSA-N 19555-48-7 Chemical compound OC(=O)C1=CC([N+]([O-])=O)=CC=C1N1CCCC1 RQSZZLSHECUEDX-UHFFFAOYSA-N 0.000 description 1
- ZHLLWDOGYSLSPA-UHFFFAOYSA-N 2-(2-hydroxyethylamino)-5-nitrobenzenesulfonic acid Chemical compound OCCNC1=CC=C([N+]([O-])=O)C=C1S(O)(=O)=O ZHLLWDOGYSLSPA-UHFFFAOYSA-N 0.000 description 1
- ZCXBRELULXFLOW-UHFFFAOYSA-N 2-(2-hydroxyethylamino)-5-nitrobenzoic acid Chemical compound OCCNC1=CC=C([N+]([O-])=O)C=C1C(O)=O ZCXBRELULXFLOW-UHFFFAOYSA-N 0.000 description 1
- WJHYMUFMUDHQRH-UHFFFAOYSA-N 2-(dimethylamino)-5-nitrobenzenesulfonic acid Chemical compound CN(C)C1=CC=C([N+]([O-])=O)C=C1S(O)(=O)=O WJHYMUFMUDHQRH-UHFFFAOYSA-N 0.000 description 1
- HDYDAVTYZWGYTF-UHFFFAOYSA-N 2-(ethylamino)-5-nitrobenzenesulfonic acid Chemical compound CCNC1=CC=C([N+]([O-])=O)C=C1S(O)(=O)=O HDYDAVTYZWGYTF-UHFFFAOYSA-N 0.000 description 1
- FAVDVRYGVZMEFI-UHFFFAOYSA-N 2-(methylamino)-5-nitrobenzoic acid Chemical compound CNC1=CC=C([N+]([O-])=O)C=C1C(O)=O FAVDVRYGVZMEFI-UHFFFAOYSA-N 0.000 description 1
- JUNACKVGXUTVCN-UHFFFAOYSA-N 2-amino-4-[2-(dimethylamino)ethyl]-3-nitrobenzoic acid Chemical compound CN(C)CCC1=CC=C(C(O)=O)C(N)=C1[N+]([O-])=O JUNACKVGXUTVCN-UHFFFAOYSA-N 0.000 description 1
- VRTVSMSGHQTRFG-UHFFFAOYSA-N 2-amino-4-nitrobenzoic acid 2-(methylamino)-5-nitrobenzoic acid Chemical compound CNC1=C(C(=O)O)C=C(C=C1)[N+](=O)[O-].NC1=C(C(=O)O)C=CC(=C1)[N+](=O)[O-] VRTVSMSGHQTRFG-UHFFFAOYSA-N 0.000 description 1
- GNTARUIZNIWBCN-UHFFFAOYSA-N 2-chloro-5-nitrobenzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC([N+]([O-])=O)=CC=C1Cl GNTARUIZNIWBCN-UHFFFAOYSA-N 0.000 description 1
- CCDVXIZHZZZDSV-UHFFFAOYSA-N 2-morpholin-4-yl-5-nitrobenzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC([N+]([O-])=O)=CC=C1N1CCOCC1 CCDVXIZHZZZDSV-UHFFFAOYSA-N 0.000 description 1
- MRCONLVSTRNJQT-UHFFFAOYSA-N 2-morpholino-5-nitrobenzoic acid Chemical compound OC(=O)C1=CC([N+]([O-])=O)=CC=C1N1CCOCC1 MRCONLVSTRNJQT-UHFFFAOYSA-N 0.000 description 1
- QUEKGYQTRJVEQC-UHFFFAOYSA-N 2516-96-3 Chemical compound OC(=O)C1=CC([N+]([O-])=O)=CC=C1Cl QUEKGYQTRJVEQC-UHFFFAOYSA-N 0.000 description 1
- MVKNRNGHKLVGRO-UHFFFAOYSA-N 3-amino-2-(2-hydroxyethyl)-5-nitrobenzoic acid Chemical compound NC1=CC([N+]([O-])=O)=CC(C(O)=O)=C1CCO MVKNRNGHKLVGRO-UHFFFAOYSA-N 0.000 description 1
- CWLKGDAVCFYWJK-UHFFFAOYSA-N 3-aminophenol Chemical class NC1=CC=CC(O)=C1 CWLKGDAVCFYWJK-UHFFFAOYSA-N 0.000 description 1
- QWIWYBUPJLCBSE-UHFFFAOYSA-N 3-chloro-2-nitrobenzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC(Cl)=C1[N+]([O-])=O QWIWYBUPJLCBSE-UHFFFAOYSA-N 0.000 description 1
- CLQHQKVADUXBRZ-UHFFFAOYSA-N 3-nitro-4-piperidin-1-ylbenzenesulfonic acid Chemical compound [O-][N+](=O)C1=CC(S(=O)(=O)O)=CC=C1N1CCCCC1 CLQHQKVADUXBRZ-UHFFFAOYSA-N 0.000 description 1
- YVODCTHEVCBRCV-UHFFFAOYSA-N 3-nitro-4-piperidin-1-ylbenzoic acid Chemical compound [O-][N+](=O)C1=CC(C(=O)O)=CC=C1N1CCCCC1 YVODCTHEVCBRCV-UHFFFAOYSA-N 0.000 description 1
- MKTQASLRSMDHRE-UHFFFAOYSA-N 3-nitro-4-pyrrolidin-1-ylbenzoic acid Chemical compound [O-][N+](=O)C1=CC(C(=O)O)=CC=C1N1CCCC1 MKTQASLRSMDHRE-UHFFFAOYSA-N 0.000 description 1
- ZNMGCJDUZADKPW-UHFFFAOYSA-N 3-nitroaniline-4-sulfonic acid Chemical compound NC1=CC=C(S(O)(=O)=O)C([N+]([O-])=O)=C1 ZNMGCJDUZADKPW-UHFFFAOYSA-N 0.000 description 1
- UCQALGQGCKIQCB-UHFFFAOYSA-N 4-(2-hydroxyethylamino)-3-nitrobenzenesulfonic acid Chemical compound OCCNC1=CC=C(S(O)(=O)=O)C=C1[N+]([O-])=O UCQALGQGCKIQCB-UHFFFAOYSA-N 0.000 description 1
- WTZIRHQYKCHHNN-UHFFFAOYSA-N 4-(dimethylamino)-3-nitrobenzenesulfonic acid Chemical compound CN(C)C1=CC=C(S(O)(=O)=O)C=C1[N+]([O-])=O WTZIRHQYKCHHNN-UHFFFAOYSA-N 0.000 description 1
- ZXBMWJZLUDXEPS-UHFFFAOYSA-N 4-(dimethylamino)-3-nitrobenzoic acid Chemical compound CN(C)C1=CC=C(C(O)=O)C=C1[N+]([O-])=O ZXBMWJZLUDXEPS-UHFFFAOYSA-N 0.000 description 1
- YDIYEOMDOWUDTJ-UHFFFAOYSA-N 4-(dimethylamino)benzoic acid Chemical compound CN(C)C1=CC=C(C(O)=O)C=C1 YDIYEOMDOWUDTJ-UHFFFAOYSA-N 0.000 description 1
- RPKWNMFDAOACCX-UHFFFAOYSA-N 4-chloro-3-nitrobenzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=C(Cl)C([N+]([O-])=O)=C1 RPKWNMFDAOACCX-UHFFFAOYSA-N 0.000 description 1
- VCHSXYHBMFKRBK-UHFFFAOYSA-N 4771-47-5 Chemical compound OC(=O)C1=CC=CC(Cl)=C1[N+]([O-])=O VCHSXYHBMFKRBK-UHFFFAOYSA-N 0.000 description 1
- KZZWQCKYLNIOBT-UHFFFAOYSA-N 5-amino-2-nitrobenzoic acid Chemical compound NC1=CC=C([N+]([O-])=O)C(C(O)=O)=C1 KZZWQCKYLNIOBT-UHFFFAOYSA-N 0.000 description 1
- BJFMTEPHRNENIO-UHFFFAOYSA-N 5-nitro-2-piperidin-1-ylbenzoic acid Chemical compound OC(=O)C1=CC([N+]([O-])=O)=CC=C1N1CCCCC1 BJFMTEPHRNENIO-UHFFFAOYSA-N 0.000 description 1
- QHMVCKFDGPANNT-UHFFFAOYSA-N 5-nitro-2-pyrrolidin-1-ylbenzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC([N+]([O-])=O)=CC=C1N1CCCC1 QHMVCKFDGPANNT-UHFFFAOYSA-N 0.000 description 1
- DFXQXFGFOLXAPO-UHFFFAOYSA-N 96-99-1 Chemical compound OC(=O)C1=CC=C(Cl)C([N+]([O-])=O)=C1 DFXQXFGFOLXAPO-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- VQCDBSFFXISVEA-UHFFFAOYSA-N C(C)NC1=C(C=C(C=C1)[N+](=O)[O-])S(=O)(=O)O.NC1=C(C=C(C=C1)[N+](=O)[O-])S(=O)(=O)O Chemical compound C(C)NC1=C(C=C(C=C1)[N+](=O)[O-])S(=O)(=O)O.NC1=C(C=C(C=C1)[N+](=O)[O-])S(=O)(=O)O VQCDBSFFXISVEA-UHFFFAOYSA-N 0.000 description 1
- SXGYXSMCSWZGCB-UHFFFAOYSA-N CNC1=C(C=C(C(=O)O)C=C1)[N+](=O)[O-].C(C)N(C1=C(C=C(C(=O)O)C=C1)[N+](=O)[O-])CC.NC1=C(C=C(C(=O)O)C=C1)[N+](=O)[O-].O1CCN(CC1)C1=C(C(=O)O)C=C(C=C1)[N+](=O)[O-].N1(CCCCC1)C1=C(C(=O)O)C=C(C=C1)[N+](=O)[O-].CN(C1=C(C(=O)O)C=C(C=C1)[N+](=O)[O-])C Chemical compound CNC1=C(C=C(C(=O)O)C=C1)[N+](=O)[O-].C(C)N(C1=C(C=C(C(=O)O)C=C1)[N+](=O)[O-])CC.NC1=C(C=C(C(=O)O)C=C1)[N+](=O)[O-].O1CCN(CC1)C1=C(C(=O)O)C=C(C=C1)[N+](=O)[O-].N1(CCCCC1)C1=C(C(=O)O)C=C(C=C1)[N+](=O)[O-].CN(C1=C(C(=O)O)C=C(C=C1)[N+](=O)[O-])C SXGYXSMCSWZGCB-UHFFFAOYSA-N 0.000 description 1
- GHOKWGTUZJEAQD-UHFFFAOYSA-N Chick antidermatitis factor Natural products OCC(C)(C)C(O)C(=O)NCCC(O)=O GHOKWGTUZJEAQD-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- POHBJMZNEOCEQP-UHFFFAOYSA-N N1(CCCC1)C1=C(C=C(C(=O)O)C=C1)[N+](=O)[O-].N1(CCCCC1)C1=C(C=C(C(=O)O)C=C1)[N+](=O)[O-] Chemical compound N1(CCCC1)C1=C(C=C(C(=O)O)C=C1)[N+](=O)[O-].N1(CCCCC1)C1=C(C=C(C(=O)O)C=C1)[N+](=O)[O-] POHBJMZNEOCEQP-UHFFFAOYSA-N 0.000 description 1
- WBRXZQGELADMBX-UHFFFAOYSA-N N1(CCCCC1)C1=C(C=C(C=C1)S(=O)(=O)O)[N+](=O)[O-].NC1=C(C=CC(=C1)[N+](=O)[O-])S(=O)(=O)O.NC1=CC(=C(C=C1)S(=O)(=O)O)[N+](=O)[O-].NC=1C(=C(C=CC1)S(=O)(=O)O)[N+](=O)[O-].NC1=C(C=CC=C1[N+](=O)[O-])S(=O)(=O)O Chemical compound N1(CCCCC1)C1=C(C=C(C=C1)S(=O)(=O)O)[N+](=O)[O-].NC1=C(C=CC(=C1)[N+](=O)[O-])S(=O)(=O)O.NC1=CC(=C(C=C1)S(=O)(=O)O)[N+](=O)[O-].NC=1C(=C(C=CC1)S(=O)(=O)O)[N+](=O)[O-].NC1=C(C=CC=C1[N+](=O)[O-])S(=O)(=O)O WBRXZQGELADMBX-UHFFFAOYSA-N 0.000 description 1
- VISVBMMDFRXBIC-UHFFFAOYSA-N O1CCN(CC1)C1=C(C=C(C(=O)O)C=C1)[N+](=O)[O-].[N+](=O)([O-])C1=C(C(=O)O)C=CC=C1.C(C)NC1=C(C=C(C(=O)O)C=C1)[N+](=O)[O-] Chemical compound O1CCN(CC1)C1=C(C=C(C(=O)O)C=C1)[N+](=O)[O-].[N+](=O)([O-])C1=C(C(=O)O)C=CC=C1.C(C)NC1=C(C=C(C(=O)O)C=C1)[N+](=O)[O-] VISVBMMDFRXBIC-UHFFFAOYSA-N 0.000 description 1
- UJCJYUNMROVZFK-UHFFFAOYSA-N OCCC1=C(C=C(C=C1N)[N+](=O)[O-])S(=O)(=O)O Chemical compound OCCC1=C(C=C(C=C1N)[N+](=O)[O-])S(=O)(=O)O UJCJYUNMROVZFK-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 239000001166 ammonium sulphate Substances 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 229940051880 analgesics and antipyretics pyrazolones Drugs 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 229920006317 cationic polymer Polymers 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 235000012000 cholesterol Nutrition 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 235000010944 ethyl methyl cellulose Nutrition 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 235000012907 honey Nutrition 0.000 description 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 150000004988 m-phenylenediamines Chemical class 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 229920003087 methylethyl cellulose Polymers 0.000 description 1
- DILRJUIACXKSQE-UHFFFAOYSA-N n',n'-dimethylethane-1,2-diamine Chemical compound CN(C)CCN DILRJUIACXKSQE-UHFFFAOYSA-N 0.000 description 1
- 150000004780 naphthols Chemical class 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 229940055726 pantothenic acid Drugs 0.000 description 1
- 235000019161 pantothenic acid Nutrition 0.000 description 1
- 239000011713 pantothenic acid Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 150000003142 primary aromatic amines Chemical class 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- JEXVQSWXXUJEMA-UHFFFAOYSA-N pyrazol-3-one Chemical class O=C1C=CN=N1 JEXVQSWXXUJEMA-UHFFFAOYSA-N 0.000 description 1
- ZZYXNRREDYWPLN-UHFFFAOYSA-N pyridine-2,3-diamine Chemical class NC1=CC=CN=C1N ZZYXNRREDYWPLN-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/418—Amines containing nitro groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
- A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
- C07D295/14—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D295/155—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals with the ring nitrogen atoms and the carbon atoms with three bonds to hetero atoms separated by carbocyclic rings or by carbon chains interrupted by carbocyclic rings
Landscapes
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Cosmetics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Treating Waste Gases (AREA)
Claims (5)
1. Härfärger innehällande substantlva härfärgs-medel, kännetecknade därav, att som substan- 5 tivt härfärgsmedel används minst en förening med den all-männa formeIn 1: A Α2ν_μ |1 -no2 i 10 där A är en S03H-grupp eller en COOH-grupp, R1 och R2 betecknar väte, en alkylgrupp med 1-4 C-atomer, en grupp där n = 2-4 och X är en hydroxylgrupp eller en grupp
15 -NR3R4, där R3 och R4 betecknar väte, en alkylgrupp med 1-4 C-atomer, en hydroxialkylgrupp med 2-4 C-atomer eller en aminoalkylgrupp med 2-4 C-atomer, eller R1 och R2 bildar tillsammans med kväveatomen en piperldin-, pyrrolidin-, piperazin- eller morfolinring, eller ett vattenlösligt 20 sait därav.
2. Härfärger enligt patentkravet 1, kännetecknade därav, att de som substantivt härfärgsme-del innehäller minst en förening ur gruppen: 2-piperidino-5-nitrobensensulfonsyra 4-(6-hydrox±etyl)- 25 amino-3-nitro-bensensulfonsyra eller ett vattenlösligt sait därav.
3. Härfärger enligt patentkravet 1, kännetecknade därav, att de som substantivt härfärgsme-del innehäller minst en förening ur gruppen: 30 4-metylamino-3-nitrobensoesyra 4-etylamino-3-nitrobensoesyra 2-piperidino-5-nitrobensoesyra 2-amino-4-nitrobensoesyra eller ett vattenlösligt sait därav. 35 4. Härfärger enligt patentkraven 1-3, k ä n - 14 80208 netecknade därav, att 0,01-5 viktprocent substantivt härfärgsmedel änvänds, beräknat ρά härfärgens totalt vikt.
5. Härfärger enligt patentkraven 1-4, k ä n -5 netecknade därav, att de ytterligare innehäller 0,01-5 viktprocent, företrädesvis 1-3 viktprocent kända oxida-tionshärfärgsförprodukter.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3425151 | 1984-07-07 | ||
| DE19843425151 DE3425151A1 (de) | 1984-07-07 | 1984-07-07 | Haarfaerbemittel |
Publications (4)
| Publication Number | Publication Date |
|---|---|
| FI852675A0 FI852675A0 (fi) | 1985-07-05 |
| FI852675L FI852675L (fi) | 1986-01-08 |
| FI80208B true FI80208B (fi) | 1990-01-31 |
| FI80208C FI80208C (sv) | 1990-05-10 |
Family
ID=6240139
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI852675A FI80208C (sv) | 1984-07-07 | 1985-07-05 | Hårfärger |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US4619666A (sv) |
| EP (1) | EP0170069B1 (sv) |
| JP (1) | JPS6124513A (sv) |
| AT (1) | ATE47033T1 (sv) |
| DE (2) | DE3425151A1 (sv) |
| DK (1) | DK163564C (sv) |
| FI (1) | FI80208C (sv) |
| NO (1) | NO167437C (sv) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3706223A1 (de) * | 1987-02-26 | 1988-09-08 | Henkel Kgaa | Haarfaerbemittel mit direktziehenden nitrodiphenylamin-derivaten |
| JPH0794372B2 (ja) * | 1987-12-22 | 1995-10-11 | ホーユー株式会社 | クリーム状染毛剤第１剤組成物 |
| US4980158A (en) * | 1989-04-04 | 1990-12-25 | Clairol Incorporated | Nitroaniline dyes with a cyano substituent group |
| US5171889A (en) * | 1990-10-31 | 1992-12-15 | Clairol Incorporated | Compositions containing nitroaniline dyes having a carbamide substituent group |
| US5042988A (en) * | 1990-10-31 | 1991-08-27 | Clairol Incorporated | Compositions containing nitroaniline dyes having a carbamide substituent group |
| DE4115983A1 (de) * | 1991-05-16 | 1992-11-19 | Henkel Kgaa | Haarfaerbemittel |
| JP3013948B2 (ja) * | 1992-03-27 | 2000-02-28 | 株式会社資生堂 | 頭髪用酸性染毛料組成物 |
| DE4240684A1 (de) * | 1992-12-03 | 1994-06-09 | Henkel Kgaa | Allylamino-nitroaromaten |
| DE10036748A1 (de) * | 2000-07-28 | 2002-02-07 | Henkel Kgaa | Pyrrolylsubstituierte Nitrophenole als Direktfarbstoffe |
| US8834847B2 (en) * | 2010-08-12 | 2014-09-16 | Pacific Biosciences Of California, Inc. | Photodamage mitigation compounds and systems |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE204884C (sv) * | ||||
| DE418989C (de) * | 1923-12-14 | 1925-09-17 | Farbenfab Vorm Bayer F & Co | Verfahren zum Faerben von kuenstlicher Seide aus Celluloseestern und -aethern oder ihren Umwandlungsprodukten |
| FR1310072A (sv) * | 1964-06-12 | 1963-03-04 | ||
| US4417896A (en) * | 1974-11-05 | 1983-11-29 | Societe Anonyme Dite: L'oreal | Hair dye compositions and new compounds useful therein |
| US4066457A (en) * | 1974-12-10 | 1978-01-03 | Gaf Corporation | Color developer for diffusion transfer |
| LU76819A1 (sv) * | 1977-02-22 | 1978-10-18 | ||
| LU83686A1 (fr) * | 1981-10-08 | 1983-06-08 | Oreal | Composition tinctoriale pour fibres keratiniques a base de colorants nitres benzeniques |
-
1984
- 1984-07-07 DE DE19843425151 patent/DE3425151A1/de not_active Withdrawn
-
1985
- 1985-06-29 EP EP85108107A patent/EP0170069B1/de not_active Expired
- 1985-06-29 AT AT85108107T patent/ATE47033T1/de not_active IP Right Cessation
- 1985-06-29 DE DE8585108107T patent/DE3573531D1/de not_active Expired
- 1985-07-05 NO NO852731A patent/NO167437C/no unknown
- 1985-07-05 DK DK309885A patent/DK163564C/da not_active IP Right Cessation
- 1985-07-05 JP JP14688685A patent/JPS6124513A/ja active Granted
- 1985-07-05 FI FI852675A patent/FI80208C/sv not_active IP Right Cessation
- 1985-07-08 US US06/752,889 patent/US4619666A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE3425151A1 (de) | 1986-01-16 |
| JPS6124513A (ja) | 1986-02-03 |
| DK309885D0 (da) | 1985-07-05 |
| FI852675A0 (fi) | 1985-07-05 |
| DK163564C (da) | 1992-08-03 |
| FI80208C (sv) | 1990-05-10 |
| NO167437B (no) | 1991-07-29 |
| ATE47033T1 (de) | 1989-10-15 |
| DK163564B (da) | 1992-03-16 |
| NO167437C (no) | 1991-11-06 |
| DE3573531D1 (en) | 1989-11-16 |
| NO852731L (no) | 1986-01-08 |
| FI852675L (fi) | 1986-01-08 |
| US4619666A (en) | 1986-10-28 |
| DK309885A (da) | 1986-01-08 |
| JPH0469604B2 (sv) | 1992-11-06 |
| EP0170069B1 (de) | 1989-10-11 |
| EP0170069A1 (de) | 1986-02-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM | Patent lapsed | ||
| MM | Patent lapsed |
Owner name: HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN |