FI74716B - Polyvinylalkoholbaserade klisterkompositioner. - Google Patents
Polyvinylalkoholbaserade klisterkompositioner. Download PDFInfo
- Publication number
- FI74716B FI74716B FI821264A FI821264A FI74716B FI 74716 B FI74716 B FI 74716B FI 821264 A FI821264 A FI 821264A FI 821264 A FI821264 A FI 821264A FI 74716 B FI74716 B FI 74716B
- Authority
- FI
- Finland
- Prior art keywords
- pva
- salt
- polyvinyl alcohol
- composition
- quaternary
- Prior art date
Links
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 60
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 54
- 239000000203 mixture Substances 0.000 claims description 37
- 239000000853 adhesive Substances 0.000 claims description 20
- 230000001070 adhesive effect Effects 0.000 claims description 19
- 150000003839 salts Chemical class 0.000 claims description 17
- 239000000654 additive Substances 0.000 claims description 12
- 230000000996 additive effect Effects 0.000 claims description 11
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- 150000001450 anions Chemical group 0.000 claims description 6
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical group C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 claims description 4
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- 150000001805 chlorine compounds Chemical group 0.000 claims description 2
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 claims description 2
- 150000003863 ammonium salts Chemical group 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- ZITBHNVGLSVXEF-UHFFFAOYSA-N 2-[2-(16-methylheptadecoxy)ethoxy]ethanol Chemical compound CC(C)CCCCCCCCCCCCCCCOCCOCCO ZITBHNVGLSVXEF-UHFFFAOYSA-N 0.000 description 10
- 239000000243 solution Substances 0.000 description 9
- 239000001993 wax Substances 0.000 description 9
- 238000004026 adhesive bonding Methods 0.000 description 7
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 7
- 239000004744 fabric Substances 0.000 description 7
- 239000003760 tallow Substances 0.000 description 7
- 239000004753 textile Substances 0.000 description 7
- 238000010521 absorption reaction Methods 0.000 description 6
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000003292 glue Substances 0.000 description 4
- 239000004014 plasticizer Substances 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000009941 weaving Methods 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 239000002979 fabric softener Substances 0.000 description 2
- 239000003317 industrial substance Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000004005 microsphere Substances 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000000375 suspending agent Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- IYAQFFOKAFGDKE-UHFFFAOYSA-N 4,5-dihydro-1h-imidazol-3-ium;methyl sulfate Chemical compound C1CN=CN1.COS(O)(=O)=O IYAQFFOKAFGDKE-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- -1 aliphatic quaternary ammonium salt Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 125000005210 alkyl ammonium group Chemical group 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- FPDLLPXYRWELCU-UHFFFAOYSA-M dimethyl(dioctadecyl)azanium;methyl sulfate Chemical compound COS([O-])(=O)=O.CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC FPDLLPXYRWELCU-UHFFFAOYSA-M 0.000 description 1
- IQDGSYLLQPDQDV-UHFFFAOYSA-N dimethylazanium;chloride Chemical compound Cl.CNC IQDGSYLLQPDQDV-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- OVBCZFVMOZVLPM-UHFFFAOYSA-N docosan-1-amine;hydrochloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[NH3+] OVBCZFVMOZVLPM-UHFFFAOYSA-N 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 239000003974 emollient agent Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000001046 green dye Substances 0.000 description 1
- 238000013007 heat curing Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- RNYJXPUAFDFIQJ-UHFFFAOYSA-N hydron;octadecan-1-amine;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[NH3+] RNYJXPUAFDFIQJ-UHFFFAOYSA-N 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 238000011005 laboratory method Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000006140 methanolysis reaction Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
- D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Claims (9)
1. Polyvinylalkoholbaserad klisterkomposition, k ä n -netecknad därav, att den väsentligen innehäller 5 a) en vinylalkoholpolymer, som är polyvinylalkohol eller en vinylalkohol/metylmetakrylatsampolymer, b) ett salttillsatsmedel, vilket är 00 ett kvartärt imidazoliniumsalt med formeln 10 - “if r Ί 2+ N —CH- N CH» CH= N / I ii R-C/ v- R-C CH- CH- C-R 2X \ \/ 'V / «Her \-CH, eller Υ-__- „___χ2'
15 CH3 0 / 22 Ih I CH2-CH2NH-C-r| [_* 3 _ väri X är en anjon och R är C^2_^galkyl eller 20 (|?>) ett kvartärt ammoniumsalt med formeln λΊ + /\ K R4_ väri R^ är C^_galkyl, R2 är C^^^alkyl eller C^2_22alkyl, R3 och är C^2_22alkyler, och X är en anjon, och varvid 30 viktförhällandet salttillsatsmedel till vinylalkoholpolymer är ca. 0,001:1 - 0,02:1.
2. Komposition enligt patentkravet 1, k ä n netecknad därav, att anjonen X i det kvartära imidazo-liniumsaltet eller ammoniumsaltet är klorid eller metyl- 35 sulfat.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US25237281 | 1981-04-09 | ||
| US06/252,372 US4383063A (en) | 1981-04-09 | 1981-04-09 | Polyvinyl alcohol based size composition |
Publications (4)
| Publication Number | Publication Date |
|---|---|
| FI821264A0 FI821264A0 (fi) | 1982-04-08 |
| FI821264L FI821264L (fi) | 1982-10-10 |
| FI74716B true FI74716B (fi) | 1987-11-30 |
| FI74716C FI74716C (sv) | 1988-03-10 |
Family
ID=22955741
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI821264A FI74716C (sv) | 1981-04-09 | 1982-04-08 | Polyvinylalkoholbaserade klisterkompositioner. |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US4383063A (sv) |
| EP (1) | EP0063329B1 (sv) |
| JP (1) | JPS57179237A (sv) |
| AR (1) | AR228089A1 (sv) |
| BR (1) | BR8201909A (sv) |
| CA (1) | CA1198537A (sv) |
| DE (1) | DE3265749D1 (sv) |
| DK (1) | DK154658C (sv) |
| ES (1) | ES8402632A1 (sv) |
| FI (1) | FI74716C (sv) |
| MX (1) | MX157124A (sv) |
| NO (1) | NO156212C (sv) |
| PT (1) | PT74726B (sv) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3373492D1 (en) * | 1983-06-10 | 1987-10-15 | Camp Jabones | Stable concentrated aqueous dispersions of water-insoluble cationic compounds and preparation thereof |
| GB8520803D0 (en) * | 1985-08-20 | 1985-09-25 | Procter & Gamble | Textile treatment compositions |
| US4797127A (en) * | 1985-10-09 | 1989-01-10 | Air Products And Chemicals, Inc. | Low foaming, high weaving efficiency polyvinyl alcohol size composition |
| US4845140A (en) * | 1986-07-07 | 1989-07-04 | Air Products And Chemicals, Inc. | Waxless polyvinyl alcohol size composition |
| WO1991016490A1 (en) * | 1990-04-12 | 1991-10-31 | George Bodnar | Fabric stabiliser |
| JPH0517285U (ja) * | 1991-08-16 | 1993-03-05 | エヌテーシー工業株式会社 | 電動弁 |
| CA2106173A1 (en) * | 1992-09-23 | 1994-03-24 | Kalliopi S. Haley | Fabric finish stiffening composition |
| US5362515A (en) * | 1994-02-28 | 1994-11-08 | E. I. Du Pont De Nemours And Company | Poly(vinyl alcohol)copolymer sizes having high capacity to be desized |
| ES2675226T3 (es) | 2005-02-02 | 2018-07-09 | Novapharm Research (Australia) Pty. Limited | Polímero biostático |
| GB0705170D0 (en) * | 2007-03-17 | 2007-04-25 | Secr Defence | Water-permeable protective material |
| EP2126614B1 (en) | 2007-03-22 | 2019-04-24 | Novartis AG | Silicone-containing prepolymers with hydrophilic polymeric chains |
| IT1403597B1 (it) * | 2010-12-21 | 2013-10-31 | Marzo Gaetano Manifattura | Procedimento per il trattamento di materiali tessili |
| CN106832705B (zh) * | 2017-02-27 | 2020-03-17 | 四川大学 | 可热塑性加工聚乙烯醇树脂及其制备方法和应用 |
| CN109553904B (zh) * | 2018-12-10 | 2021-07-20 | 怀化学院 | 具有羟乙基的季铵盐在聚乙烯醇加工中的应用 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3087920A (en) * | 1959-10-12 | 1963-04-30 | Kurashiki Rayon Co | Cold-water-soluble polyvinyl alcohol |
| NL257705A (sv) | 1959-11-09 | |||
| US3154489A (en) * | 1960-07-18 | 1964-10-27 | Armour & Co | Surface active compositions |
| US3268470A (en) * | 1960-11-15 | 1966-08-23 | American Cyanamid Co | Cationic sizing agent and its solubilization with a cationic quaternary compound |
| US3360470A (en) * | 1963-05-28 | 1967-12-26 | Colgate Palmolive Co | Laundering compositions |
| US3415771A (en) * | 1965-05-21 | 1968-12-10 | Du Pont | Coating compositions and processes |
| US3686025A (en) * | 1968-12-30 | 1972-08-22 | Procter & Gamble | Textile softening agents impregnated into absorbent materials |
| US3734873A (en) * | 1970-12-15 | 1973-05-22 | Nalco Chemical Co | Rapid dissolving water-soluble polymers |
| US3896033A (en) * | 1972-07-03 | 1975-07-22 | Colgate Palmolive Co | Encapsulated fabric softener |
| US3936538A (en) * | 1974-03-18 | 1976-02-03 | Calgon Consumer Products Company Inc. | Polymeric film dryer-added fabric softening compositions |
| CA1132285A (en) * | 1978-05-01 | 1982-09-21 | Richard W. Rees | Polyvinyl alcohol warp size for filament yarn |
-
1981
- 1981-04-09 US US06/252,372 patent/US4383063A/en not_active Expired - Lifetime
-
1982
- 1982-03-30 CA CA000399857A patent/CA1198537A/en not_active Expired
- 1982-04-05 BR BR8201909A patent/BR8201909A/pt not_active IP Right Cessation
- 1982-04-06 NO NO821169A patent/NO156212C/no unknown
- 1982-04-07 ES ES511287A patent/ES8402632A1/es not_active Expired
- 1982-04-07 MX MX192213A patent/MX157124A/es unknown
- 1982-04-07 DK DK162482A patent/DK154658C/da not_active IP Right Cessation
- 1982-04-07 AR AR289039A patent/AR228089A1/es active
- 1982-04-08 EP EP82103049A patent/EP0063329B1/en not_active Expired
- 1982-04-08 DE DE8282103049T patent/DE3265749D1/de not_active Expired
- 1982-04-08 FI FI821264A patent/FI74716C/sv not_active IP Right Cessation
- 1982-04-08 PT PT74726A patent/PT74726B/pt not_active IP Right Cessation
- 1982-04-09 JP JP57058419A patent/JPS57179237A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| DK154658B (da) | 1988-12-05 |
| DK154658C (da) | 1989-06-19 |
| EP0063329A1 (en) | 1982-10-27 |
| EP0063329B1 (en) | 1985-08-28 |
| DK162482A (da) | 1982-10-10 |
| NO156212C (no) | 1987-08-12 |
| FI821264L (fi) | 1982-10-10 |
| US4383063A (en) | 1983-05-10 |
| PT74726A (en) | 1982-05-01 |
| CA1198537A (en) | 1985-12-24 |
| JPS57179237A (en) | 1982-11-04 |
| FI74716C (sv) | 1988-03-10 |
| FI821264A0 (fi) | 1982-04-08 |
| ES511287A0 (es) | 1983-12-01 |
| NO156212B (no) | 1987-05-04 |
| BR8201909A (pt) | 1983-03-08 |
| AR228089A1 (es) | 1983-01-14 |
| MX157124A (es) | 1988-10-28 |
| DE3265749D1 (en) | 1985-10-03 |
| NO821169L (no) | 1982-10-11 |
| PT74726B (en) | 1983-10-25 |
| ES8402632A1 (es) | 1983-12-01 |
| JPS6228978B2 (sv) | 1987-06-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM | Patent lapsed | ||
| MM | Patent lapsed |
Owner name: E.I. DU PONT DE NEMOURS AND COMPANY |