FI72920B - Foerfarande foer framstaellning av en kombinationsprodukt av polytetrafluoreten. - Google Patents
Foerfarande foer framstaellning av en kombinationsprodukt av polytetrafluoreten. Download PDFInfo
- Publication number
- FI72920B FI72920B FI810449A FI810449A FI72920B FI 72920 B FI72920 B FI 72920B FI 810449 A FI810449 A FI 810449A FI 810449 A FI810449 A FI 810449A FI 72920 B FI72920 B FI 72920B
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- FI
- Finland
- Prior art keywords
- segments
- contact
- ptfe
- fine structure
- melting point
- Prior art date
Links
- 238000000034 method Methods 0.000 claims description 8
- 230000001413 cellular effect Effects 0.000 claims description 7
- 238000002844 melting Methods 0.000 claims description 7
- 230000008018 melting Effects 0.000 claims description 7
- 239000013078 crystal Substances 0.000 claims description 6
- 238000005304 joining Methods 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 5
- -1 polyethylene Polymers 0.000 claims description 3
- 230000006835 compression Effects 0.000 claims 2
- 238000007906 compression Methods 0.000 claims 2
- 239000004698 Polyethylene Substances 0.000 claims 1
- 229920000573 polyethylene Polymers 0.000 claims 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 21
- 239000004810 polytetrafluoroethylene Substances 0.000 description 21
- 238000000635 electron micrograph Methods 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000002131 composite material Substances 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 238000004026 adhesive bonding Methods 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000009958 sewing Methods 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- 229920006358 Fluon Polymers 0.000 description 1
- 229920000544 Gore-Tex Polymers 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 210000001124 body fluid Anatomy 0.000 description 1
- 239000010839 body fluid Substances 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000004870 electrical engineering Methods 0.000 description 1
- 238000005188 flotation Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000001356 surgical procedure Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/12—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives
- C08J5/121—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives by heating
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F2/00—Filters implantable into blood vessels; Prostheses, i.e. artificial substitutes or replacements for parts of the body; Appliances for connecting them with the body; Devices providing patency to, or preventing collapsing of, tubular structures of the body, e.g. stents
- A61F2/02—Prostheses implantable into the body
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- A61F2/06—Blood vessels
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- B29C53/00—Shaping by bending, folding, twisting, straightening or flattening; Apparatus therefor
- B29C53/36—Bending and joining, e.g. for making hollow articles
- B29C53/38—Bending and joining, e.g. for making hollow articles by bending sheets or strips at right angles to the longitudinal axis of the article being formed and joining the edges
- B29C53/385—Bending and joining, e.g. for making hollow articles by bending sheets or strips at right angles to the longitudinal axis of the article being formed and joining the edges using several sheets to form the circumference
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- B29C61/00—Shaping by liberation of internal stresses; Making preforms having internal stresses; Apparatus therefor
- B29C61/006—Shaping by liberation of internal stresses; Making preforms having internal stresses; Apparatus therefor the force created by the liberation of the internal stresses being used for compression moulding or for pressing preformed material
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- B29C66/05—Particular design of joint configurations
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- B29C66/43—Joining a relatively small portion of the surface of said articles
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- B29C66/80—General aspects of machine operations or constructions and parts thereof
- B29C66/82—Pressure application arrangements, e.g. transmission or actuating mechanisms for joining tools or clamps
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- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
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- B29C66/7371—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the state of the material of the parts to be joined oriented or heat-shrinkable
- B29C66/73711—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the state of the material of the parts to be joined oriented or heat-shrinkable oriented
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- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08J2327/18—Homopolymers or copolymers of tetrafluoroethylene
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1328—Shrinkable or shrunk [e.g., due to heat, solvent, volatile agent, restraint removal, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1328—Shrinkable or shrunk [e.g., due to heat, solvent, volatile agent, restraint removal, etc.]
- Y10T428/1331—Single layer [continuous layer]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/19—Sheets or webs edge spliced or joined
- Y10T428/192—Sheets or webs coplanar
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Heart & Thoracic Surgery (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Gastroenterology & Hepatology (AREA)
- Pulmonology (AREA)
- Cardiology (AREA)
- Toxicology (AREA)
- Transplantation (AREA)
- Biomedical Technology (AREA)
- Manufacturing & Machinery (AREA)
- Vascular Medicine (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Lining Or Joining Of Plastics Or The Like (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
- Prostheses (AREA)
- Shaping Of Tube Ends By Bending Or Straightening (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Laminated Bodies (AREA)
Description
72920
Menetelmä polytetrafluorieteeni-yhdiatelmäkappaieen valmistamiseksi Tämä keksintö koskee menetelmää uuden yhdistelmä-kappaleen valmistamiseksi solu-polytetrafluorieteenistä.
5 Polytetrafluorieteeni (jäljempänä PTFE) omaa erinomaisen lämmönkestävyyden, kemiallisen kestävyyden, eristysomainaisuudet, takertumattomuuden ja itsevoitelu-vuuden. Tätä polymeeriä käytetään laajalti lääketieteessä, teollisuudessa ja vapaa-ajan tuotteissa.
10 Eräs viimeaikainen keksintö (US-patenttijulkaisu 3 953 566) tar joaa menetelmän voimakkaasti huokoisten, kuitenkin lujien PTFE-muotokappaleiden valmistamiseksi. Tämä menetelmä käsittää voimakkaasti kiteisen, jauhemaisen PTFE:n sekoittamisen nestemäisen voiteluaineen 15 kanssa; tämän seoksen suulakepuristamisen, jolloin suulakkeella voi olla haluttu poikkileikkaus sekä välittömästi muotokappaleen vaahdotuksen yhdessä tai useammassa suunnassa, nopeudella yli 10 % sekunnissa.
Tällä menetelmällä valmistetut tuotteet on 20 hyväksytty käyttöön laajalti teollisuudessa, lääketieteessä, sähkötekniikassa ja vaatetusalalla. Menetelmä on jonkin verran rajoittunut sikäli, että se ei ole helposti sovellettavissa suurten, poikkileikkaukseltaan monimutkaisten kappaleiden valmistukseen. Tällaisten 25 kappaleiden tarvetta esiintyy esimerkiksi teollisen suodatuksen alalla ja suurten verisuonten kirurgiassa. Vaikkakin suuria yhdistelmäkappaleitä voidaan valmistaa liittämällä yhteen pienempiä kappaleita tavanomaisilla menetelmillä, kuten ompelemalla, hitsaamalla tai liimaa-30 maila, on tällaisissa kappaleissa epäjatkuvuutta saumassa. Monissa sovellutuksissa tämä ei synnytä vakavia ongelmia, kun taas toisissa, kuten suodatuksessa ja kehon osien korvaamisessa, on äärimmäisen tärkeää, että kappaleen rakenne on kauttaaltaan mahdollisimman 2 72920 yhtenäinen. Jos suurten kappaleiden tuottamiseen käytetään hitsausta tai liimausta, syntyy tiivis ei-huokoinen alue. Toisaalta ompelu voi synnyttää alueita, joissa huokoisuus on suurempi kuin kappaleen 5 muissa osissa. On huomattu, että kyhmyjen ja säikeiden muodostama hienorakenne, joka esiintyy US-patentti-julkaisun 3 953 5&6 mukaisesti valmistetuissa tuotteissa, on erityisen toivottava sekä suodatusväliaineena että veren ja muiden kehon nesteiden kanssa kosketuksiin 10 joutuvana pintana. Olisi siten toivottavaa valmistaa monimutkaisia yhdistelmäinuoto j a liittämällä solu-PTFE:stä valmistettuja kappaleita, joilla on tämä hienorakenne, sillä tavoin, että hienorakenne säilyy olennaisesti keskeytymättömänä yli liitoksen 15 t ai s auman .
Tämän keksinnön kohteena on menetelmä sellaisen PTFB-yhdistelmämuotokappaleen valmistamiseksi, jossa on käy-tännöllisesti keskeytymätön, säikeiden yhdistämien kyhmyjen muodostama hienorakenne liitoksen yli. Tällainen kap-20 pale valmistetaan liittämällä yhteen p ienempikoko ist en kap paleiden segmenttejä. Näitä pienempiä segmenttejä pidetään yhdessä ja niiden lämpötila nostetaan yli kidesulamispisteen. Niiden annetaan sitten jäähtyä huoneen lämpötilaan kappaleen käsittelyn helpottamiseksi.
25 Kuvio 1 on kaavamainen esitys esillä olevan keksinnön eräästä sovellutusmuodo st a.
Kuvio 2 - 1+(b ) ovat elektronimikroskooppivalokuvia keksinnön mukaisesti valmistetun putken eri pinnoista.
PTFE:n liittäminen PTFB:iin pitämällä osat kosketuk-30 sessa mekaanisesti ja kuumentamalla niitä yli PTFE:n kidesulamispisteen on tunnettua. Tästä on kuitenkin yleisesti tuloksena kiinteä, ei-huokoinen sauma.
3 72920
Esillä oleva keksintö on tunnetun menetelmän muunnos sellaisen tuotteen valmistamiseksi, jossa molemmissa osissa esiintyvä kyhmy-säie-hienorakenne säilytetään käytännöllisesti katsoen keskeytymättömänä yli sauman. Tulokin sena on saumaton tuote. Tässä yhteydessä sanonnalla "reunat" tarkoitetaan solu-PTFE-kappaleen sitä osaa, joka on tarkoitus liittää,ja "sauma" tarkoittaa näin liitettyä aluetta. Kappaleet tarkoittavat mitä tahansa poikki-leikkausmuotoa, esim. putkea, tankoa, levyä tai segmenttiä. 10 PTFE-ainesta on saatavana monissa muodoissa, käsittäen levyt, tangot ja putket, W. L. Gore & Associates, Inc.-lta. Liitettävät kappaleet leikataan tarvittavaan kokoon. On huolehdittava siitä, että liitettävät reunat ovat puhtaat, so. eivät risaiset eivätkä likaiset.
15 Reunat asetetaan sitten tiukasti lähekkäin, so. koskettamaan toisiaan.
Jos solu-PTFE:ä kuumennetaan yli kidesulamispis-teensä vapaassa tilassa, aineella on taipumus kutistua ja sulautua kiinteäksi massaksi. Jotta varmistettaisiin 20 yhteenliitettävien kappaleiden pysyminen kosketuksessa niitä kuumennettaessa, on tämän vuoksi käytettävä mekaanisia keinoja niiden pitämiseksi tällä tavalla kosketuksessa.
Esimerkiksi voidaan, kuten kuviossa 1 on esitetty, 25 tehdä iso putki levyistä tai useista pienempien putkien leikkeistä. Levyt 1+ siistitään reunoiltaan 6(a) ja 6(b) sen varmistamiseksi, että nämä reunat ovat puhtaat, so. eivät risaiset eivätkä likaiset. Levyt t asetetaan sitten tuurnan 2 ympärille. Kunkin levyn k reunat 6(a) 30 ja 6(b) asetetaan tiiviisti viereisen levyn reunoja b(a) ja 6(b) vasten. Levyjen päät A ja B kiinnitetään näissä kohdissa tuurnaan. Tämä voidaan suorittaa monilla tavoilla, kuten letkupuristimilla tai sitomalla levyt tuurnaan langalla. Tällaisella putken kiinnittämisellä 35 on tarkoitus estää PTFE:n pituussuuntainen vetäytyminen kuumennettaessa.
k 72920
Kaistale vaahdotettua PTFE-kalvoa, noin 19 mm leveä, jonka matriisivetolujuus pitkittäissuunnassa on noin i+ 80 MPa, kierretään levyjen päälle tuurnalle ja kiinnitetään tuurnan päässä, niin ettei se pääse 5 kiertymään auki. Kuumennettaessa tämä pidättävä kalvo kutistuu kohdistaen levyihin paineen ja pitäen reunat 6(a) ja 6(b) tiiviissä kosketuksessa. Käyttökelpoista kalvoa on saatavissa nimellä GORE-TEX vaahdotettuna säiöksenä W.L. Gore & Associates, Inc:lta, P.O. Box 1220, 10 Elkton, Maryland 29121. Vaikkakin käärintä solu-PTFE-kalvolla on edullinen tapa mekaanisesti pidättää ja pitää levyjen reunat kosketuksessa kuumennuksen aikana, voidaan muitakin keinoja käyttää.
Tärkeätä on, että sintrauksen aikana täytyy olla 15 saumaan kohtisuorasti vaikuttava voima. Vetäytyes sään kokoon synnyttää putken ympäri kiedottu kalvo tarvittavan voiman.
Käärityn putken kuumentaminen voidaan suorittaa suolahauteessa,ilmauunissa, säteilyuunissa tai muulla 20 tavoin. Sopiva suolahaude voi olla natriumnitriitin ja -nitraatin sula seos, jota pidetään segmenttien kidesulamispisteen ylittävässä lämpötilassa. Putki poistetaan sitten ja sen annetaan jäähtyä, edelleenkin pidätettynä. Aika kidesulamispisteen ylittävässä lämpö-25 tilassa vaihtelee, riippuen käytettävästä ainemäärästä ja polymeerin ominaisuuksista. Optimiliitoksen edellyttämä tarkka aika riippuu useista tekijöistä, kuten ainesmäärästä ja valmistettavan kappaleen muodosta.
Tämä aika on kuitenkin helposti määritetty pienellä 30 kokeilulla. Seuraavan esimerkin on tarkoitus valaista eikä rajoittaa esillä olevaa keksintöä.
Menettelytapaa voidaan käyttää useisiin eri muotoihin ja kokoihin, milloin on tärkeää säilyttää käytännöllisesti katsoen keskeytymätön hienorakenne minkä tahansa 35 liitoslinjan tai sauman yli.
5 72920 ESIMERKKI 1
Kolme 6,5 cm:n pituista 120°:n segmenttiä leikattiin sisähalkaisijaltaan 20 mm:n putkista, jotka oli valmistettu US-patenttijulkaisun 3 953 566 mukaisesti.
5 Käytetty polymeeri oli Fluon 123, joka on hieno jauhe mainen PTFE, saatavissa ICI America:lta. Nämä segmentit siistittiin huolellisesti, puskuliitettäviksi tarkoitettujen reunojen puhtauden varmistamiseksi. Segmentit asetettiin sitten huolellisesti sileän,ulkohalkaisijal-10 taan 20 mm olevan ruostumattoman teräsputken ympärille.
Segmentit järjestettiin siten, että ne tulivat tarkasti kiinni toisiinsa. Tämän jälkeen ne käärittiin 19 mm leveällä solu-PTFE-kalvolla, jonka matriisivetolujuus oli noin 480 MPa ja joka oli valmistettu US-patentin 15 3 962 153 mukaisesti.
Tuurna asetettiin sitten ilmauuniin 3Ö0°C:n lämpötilaan 12 minuutiksi. Uunista poistamisen jälkeen tuurnan annettiin jäähtyä huoneen lämpötilaan ja muodostunut PTFE-putki pujotettiin varovasti pois tuurnalta.
20 Kokeen tarkoitusta silmällä pitäen poistettiin käärintäkalvo varovasti putkelta rakenteen valokuvaamiseksi saumakohdassa.
Kuvio 2 on vinosti otettu elektronimikroskooppi-kuva yhdestä, esimerkissä 1 valmistetusta saumasta. Ylä-25 osa 10 on topografinen kuvanto putken sisäpinnasta. Ala osa 12 on poikkileikkauskuvanto putkesta. Kuviossa 2 kulkee sauma suunnassa X -* Y. Suurennus on 1 4 6-kertain en .
Kuvio 3(a) on elektronimikroskooppikuva esimerkissä 1 valmistetun putken sisäpinnasta. Sauma kulkee 30 suunnassa X -» Y. Suurennus on 122-kertainen. Kuvio 3(h) on elektronimikroskooppikuva kuvioon 3(a) rajatusta alueesta. Sauma kulkee suunnassa X-► Y ja suurennus on 610-kertainen.
Kuvio 4(a) on elektronimikroskooppikuva esimerkis-35 sä 1 valmistetun putken ulkopinnasta kalvon poistamisen jälkeen. Sauma kulkee suunnassa X -» Y ja suurennus on 6 72920 90-kertainen. Kuvio U(b) on elektronimikroskooppikuva kuvioon 4(a) rajatusta alueesta. Sauma kulkee suunnassa X -* Y ja suurennus on 4 50-kertainen .
Näistä elektronimikroskooppikuvista on yllättävää 5 havaita, että kyhmy-säiehienorakenne on käytännöllisesti katsoen keskeytymätön yli sauman. Vaikkakin tätä keksintöä valaisemaan käytettiin esimerkkiä pienessä mitassa, voidaan tekniikka helposti laajentaa käsittämään suuret putket, joiden halkaisija on useita 10 tuumia. Vastaavasti tekniikkaa voidaan käyttää useiden erilaisten muotojen yhteydessä, eikä se rajoitu putkimaisiin poikkileikkauksiin. Esimerkiksi voitaisiin yhteenliittää levyjä yksisuuntaisesti vaahdotetusta PTFErstä, jonka paksuus on noin 0,1 mm... yli 2,5 mm.
15 seuraavalla tavalla. Pidätetään PTFE-levyt niiden vaah- dotussuunnassa, asetetaan ne reunat vastakkain 1,5 mm paksuisten s il ikonikumilevyjen (durometrikovuus 60) väliin (kummallekin puolelle PTFE:ä kaksi kumilevyä, jotka ovat hieman erillään toisistaan; noin 0,25 mm:n rako, 20 joka vastaa saumaa PTFE-1evyissä ) , ja asetetaan PTFE- ja kumilevyt puristimeen, jonka laatat on kuumennettu noin 380°C:n lämpötilaan. Puristin voidaan sulkea, hyvin pienen paineen kohdistamiseksi kumin päällä oleviin levyihin. Tämä synnyttää tarvittavan kohtisuoran 25 voiman saumaan, tällä kertaa tasomuodossa. Sopivan ajan, likimääräisesti 15 minuutin, kuluttua voidaan puristimen sähkökuument, imet kytkeä pois ja jäähdyttää laatat paineilmavirralla. Laattojen jäähdyttyä huoneen lämpötilaan voidaan paine laskea ja levyt poistaa.
Claims (2)
1. Menetelmä useiden sellaisten kutistuvien solupoly- 5 tetra f1uorieteenisegmen11ien (4) yhteen 1ii11ämiseksi , joista kullakin on säikeiden yhteenliittämistä kyhmyistä koostuva hienorakenne, jonka menetelmän mukaan segmentit (4) saatetaan aiottujen saumojen (6) kohdalta keskinäiseen kohdakkaiskosketukseen mekaanisin 10 keinoin, segmenttejä (4) estetään kutistumasta missään suunnassa, - ne kuumennetaan ennalta määrätyksi ajaksi lämpöti laan, joka on segmenttien (4) kide su1amispiste en 15 yläpuolella, ja - niiden annetaan jäähtyä kide su1 amispisteen sä alapuolelle, tunnettu siitä, että segmenttien (4) välinen tiivis kosketus saadaan 20 aikaan oleellisesti ilman puristusta ja näin saatuihin segmenttien (4) välisiin kosketuskohtiin (6) sovitetaan kosketuskohtaa vastaan kohtisuoraan vaikuttava puristusvoima, jolloin saumakohtiin (6) saadaan käytännöllisesti katsoen 25 keskeytymätön hienorakenne.
2. Patenttivaatimuksen 1 mukainen menetelmä, t u n -n e t t u siitä, että segmenttien (4) välinen kosketus toteutetaan sovittamalla segmentit (4) tuurnan (2) ympärille, ja käärimällä segmenttien (4) ympärille suuren lujuuden 30 omaava s o1u-PTFE-ka1vo, joka 1ämmitysvaih e en aikana kut istuessaan saa aikaan kohtisuoran puristuksen kosketuskohtiin (6).
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/121,365 US4283448A (en) | 1980-02-14 | 1980-02-14 | Composite polytetrafluoroethylene article and a process for making the same |
US12136580 | 1980-02-14 |
Publications (3)
Publication Number | Publication Date |
---|---|
FI810449L FI810449L (fi) | 1981-08-15 |
FI72920B true FI72920B (fi) | 1987-04-30 |
FI72920C FI72920C (fi) | 1987-08-10 |
Family
ID=22396215
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FI810449A FI72920C (fi) | 1980-02-14 | 1981-02-13 | Foerfarande foer framstaellning av en kombinationsprodukt av polytetrafluoreten. |
Country Status (20)
Country | Link |
---|---|
US (1) | US4283448A (fi) |
JP (1) | JPS5746835A (fi) |
AT (1) | AT386416B (fi) |
AU (1) | AU541290B2 (fi) |
BE (1) | BE887501A (fi) |
BR (1) | BR8100852A (fi) |
CA (1) | CA1165080A (fi) |
CH (1) | CH652072A5 (fi) |
DE (2) | DE3104037C2 (fi) |
DK (1) | DK156419C (fi) |
FI (1) | FI72920C (fi) |
FR (1) | FR2475974B1 (fi) |
GB (1) | GB2068827B (fi) |
GR (1) | GR73849B (fi) |
IN (1) | IN155688B (fi) |
IT (1) | IT1135417B (fi) |
NL (1) | NL185906C (fi) |
NO (1) | NO810506L (fi) |
SE (1) | SE448968B (fi) |
ZA (1) | ZA81678B (fi) |
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US20090053371A1 (en) * | 2007-08-21 | 2009-02-26 | Carolie Hancock | Package for storing, shipping, preparing and dispensing a meal |
EP3075767A4 (en) * | 2013-11-29 | 2017-07-05 | Daikin Industries, Ltd. | Porous body, polymer electrolyte membrane, filter material for filter, and filter unit |
US9814560B2 (en) | 2013-12-05 | 2017-11-14 | W. L. Gore & Associates, Inc. | Tapered implantable device and methods for making such devices |
CN107666882B (zh) | 2015-06-05 | 2020-01-10 | W.L.戈尔及同仁股份有限公司 | 带有渐缩部的低渗血量可植入假体 |
US10413635B2 (en) * | 2015-08-17 | 2019-09-17 | Vivex Biomedical, Inc. | Umbilical cord transplant product |
US11378214B2 (en) | 2020-06-26 | 2022-07-05 | Lawrence Wolf | Coaxial tubing systems with securable spacers |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
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US612897A (en) * | 1898-10-25 | Construction of tubes and cylinders | ||
US3207644A (en) * | 1959-07-20 | 1965-09-21 | Garlock Inc | Method of making a fluorocarbon resin jacketed gasket |
US3356551A (en) * | 1961-08-21 | 1967-12-05 | Martin Marietta Corp | Method of joining bodies of polytetrafluoroethylene |
SE392582B (sv) * | 1970-05-21 | 1977-04-04 | Gore & Ass | Forfarande vid framstellning av ett porost material, genom expandering och streckning av en tetrafluoretenpolymer framstelld i ett pastabildande strengsprutningsforfarande |
US3767500A (en) * | 1971-12-28 | 1973-10-23 | Tme Corp | Method of laminating long strips of various materials |
US4061517A (en) * | 1975-08-27 | 1977-12-06 | Chemelec Products, Inc. | Method of making fluorocarbon resin covered gaskets |
DE2549475C3 (de) * | 1975-11-05 | 1979-04-19 | Sigri Elektrographit Gmbh, 8901 Meitingen | Verfahren und Vorrichtung zum Verbinden von Formkörpern aus PoIytetrafluoräthylen |
-
1980
- 1980-02-14 US US06/121,365 patent/US4283448A/en not_active Expired - Lifetime
-
1981
- 1981-01-23 SE SE8100407A patent/SE448968B/sv not_active IP Right Cessation
- 1981-02-02 ZA ZA00810678A patent/ZA81678B/xx unknown
- 1981-02-05 DE DE3104037A patent/DE3104037C2/de not_active Expired
- 1981-02-05 GB GB8103585A patent/GB2068827B/en not_active Expired
- 1981-02-05 DE DE3153231A patent/DE3153231C2/de not_active Expired
- 1981-02-10 CH CH888/81A patent/CH652072A5/de not_active IP Right Cessation
- 1981-02-10 AU AU67146/81A patent/AU541290B2/en not_active Ceased
- 1981-02-11 IT IT19659/81A patent/IT1135417B/it active
- 1981-02-12 NL NLAANVRAGE8100672,A patent/NL185906C/xx not_active IP Right Cessation
- 1981-02-12 GR GR64113A patent/GR73849B/el unknown
- 1981-02-12 BE BE0/203784A patent/BE887501A/fr unknown
- 1981-02-12 BR BR8100852A patent/BR8100852A/pt unknown
- 1981-02-13 IN IN167/CAL/81A patent/IN155688B/en unknown
- 1981-02-13 NO NO810506A patent/NO810506L/no unknown
- 1981-02-13 FR FR8102848A patent/FR2475974B1/fr not_active Expired
- 1981-02-13 CA CA000370903A patent/CA1165080A/en not_active Expired
- 1981-02-13 DK DK063581A patent/DK156419C/da not_active IP Right Cessation
- 1981-02-13 JP JP56019161A patent/JPS5746835A/ja active Granted
- 1981-02-13 FI FI810449A patent/FI72920C/fi not_active IP Right Cessation
- 1981-02-16 AT AT0071181A patent/AT386416B/de not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
AU541290B2 (en) | 1985-01-03 |
SE448968B (sv) | 1987-03-30 |
DE3104037A1 (de) | 1981-12-24 |
BE887501A (fr) | 1981-06-01 |
AU6714681A (en) | 1981-08-20 |
FI72920C (fi) | 1987-08-10 |
DK63581A (da) | 1981-08-15 |
IT8119659A0 (it) | 1981-02-11 |
NL185906B (nl) | 1990-03-16 |
DE3104037C2 (de) | 1986-02-27 |
FI810449L (fi) | 1981-08-15 |
GB2068827A (en) | 1981-08-19 |
GR73849B (fi) | 1984-05-07 |
ATA71181A (de) | 1988-01-15 |
FR2475974A1 (fr) | 1981-08-21 |
DE3153231C2 (fi) | 1987-05-21 |
JPS5746835A (en) | 1982-03-17 |
DK156419B (da) | 1989-08-21 |
BR8100852A (pt) | 1981-08-25 |
FR2475974B1 (fr) | 1985-06-21 |
ZA81678B (en) | 1982-03-31 |
IT1135417B (it) | 1986-08-20 |
NL8100672A (nl) | 1981-09-16 |
NO810506L (no) | 1981-08-17 |
CA1165080A (en) | 1984-04-10 |
JPS6315904B2 (fi) | 1988-04-06 |
GB2068827B (en) | 1983-09-21 |
IN155688B (fi) | 1985-02-23 |
US4283448A (en) | 1981-08-11 |
DK156419C (da) | 1990-01-22 |
NL185906C (nl) | 1990-08-16 |
AT386416B (de) | 1988-08-25 |
SE8100407L (sv) | 1981-08-15 |
CH652072A5 (de) | 1985-10-31 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
MM | Patent lapsed |
Owner name: W. L. GORE & ASSOCIATES INC. |