FI63053B - Anvaendning av en smoerjmedelskomposition foer smoerjning av en tvaotaktsfoerbraenningsmotor - Google Patents

Anvaendning av en smoerjmedelskomposition foer smoerjning av en tvaotaktsfoerbraenningsmotor Download PDF

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FI63053B
FI63053B FI762915A FI762915A FI63053B FI 63053 B FI63053 B FI 63053B FI 762915 A FI762915 A FI 762915A FI 762915 A FI762915 A FI 762915A FI 63053 B FI63053 B FI 63053B
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use according
group
substituent
aromatic
bond
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FI762915A
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FI63053C (fi
FI762915A (sv
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Kirk Emerson Davis
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Lubrizol Corp
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Claims (31)

1. Användning för smörjning av en tvätaktsförbränningsmotor av en smörj-medelskompositiön innefattande 55-98, företrädesvis 70-90 viktprocent av minst en oija med smörjande viskositet och 2-30, företrädesvis 5-20 viktprocent av minst ett aminoinnehällande tillsatsmedel, som (a) har formeIn <OH)c (Rts- Ar -(NH2)b väri R är en i huvudsak mättad, kolvätebaserad substituent med 30-400 alifatiska kolatomer; a, b och c vardera och oberoende av var-andra är ett heltal som är 1-3 gänger antalet aromatiska kärnor närvarande i Ar, varvid summan av a, b och c icke överstiger de omättade valenserna av Ar; och Ar är en aromatisk grupp med 0-3 eventuella substituenter,vilka är lägre alkyl, lägre alkoxyl, nitro, halogen eller kombination av tvä eller flera av nämnda eventuella substituenter, varvid när Ar är en bensenkärna med endast en hydro-xylgrupp och en R-substituent, R-substituenten föreligger i orto-eller paraställning i förhällande tili nämnda hydroxylgrupp, eller (b) är framställd genom (I) nitrering med ätminstone ett nitreringsmedel av minst en förenlng med formeln 34 , % 63053 (OH)c (R)-- Ar' a väri R är en i huvudsak mättad, kolvätebaseras substituent med 30-400 ali-fatiska kolatomer; a och c vardera och oberoende av varandra är ett heltal som är. 1-3 ganger antalet aromatiska kärnor närvarande i Ar, varvid summan av a, b och c icke överstiger de omättade valen-serna av Ar'; och Ar' är en aromatisk grupp med 0-3 eventuella subs-tituenter vilka är lägre alkyl, lägre alkoxyl, nitro eller halogen eller kombinationer av tva eller flera eventuella substituenter, varvid (a) Ar' har minst en väteatom direkt bunden till en kolatom som utgör en del av en aromatisk kärna, och (b) när Ar är bensen med endast en hydroxylgrupp och en R-substituent, R-substituenten före-ligger i orto- eller paraställning i förhillande till nämnda hydro-xylgrupp, till bildning av en första reaktionsblandning innehillan-de en nitromellanprodukt, och (II) reduktion av itminstone cirka 50 procent av nitrogrupper-na i nämnda första reaktionsblandning till aminogrupper; eller (c) är framställd genom reduktion av itminstone cirka 50 procent av nitrogrupperna tili aminogrupper i en förening eller blandning av föreningar med formeln <omc <R>5- Ar -(N02)b väri R är en i huvudsak mättad, kolvätebaserad substituent med 30-400 alifatiska kolatomer; a, b och c vardera och oberoende av varandra är ett heltal som är 1-3 ginger antalet aromatiska kärnor närvarande i Ar, varvid summan av a, b och c icke överstiger de omättade valenserna för Ar; och Ar är en aromatisk grupp med 0-3 eventuella substituenter vilka är lägre alkyl, lägre alkoxyl, nitro, halogen eller kombinationer av tvi eller flera av nämnda eventuella substituenter, varvid när Ar är en bensenkärna med endast en hydroxy1-grupp och en R-substituent, R-substituenten föreligger i orto- eller paraställning i förhillande tili nämnda hydroxylgrupp; varvid resten av kompositionen utgöres av eventuellt närvarande andra i och för sig kända tillsatsmedel. 63053 35
2. Användning enligt patentkravet 1, kännetecknad därav, att R är en ren hydrokarbylsubstituent.
3. Användning enligt patentkravet 2, kännetecknad därav, att R är alkyl eller alkenyl.
4. Användning enligt nägot av patentkraven 1-3, k ä n n e - t e c k n a d därav, att R är en substituent erhällen frän homopo-lymeriserade eller sampolymeriserade c2_^g-olefiner.
5. Användning enligt patentkravet 4, kännetecknad därav, att C2_<j Q-olefinema är C2_^ Q-1-olef iner eller blandningar därav.
6. Användning enligt patentkravet 5, kännetecknad därav, att 1-olefinen är etylen, propylen, butylen eller blandningar därav.
7. Användning enligt nägot av patentkraven 1-6, kännetecknad därav, att Ar innehäller ätminstone tvä sammanbundna och/eller kondenserade polynukleära aromatiska kärnor.
8. Användning enligt patentkravet 7, kännetecknad därav, att Ar är en naftalenkärna,
9. Användning enligt patentkravet 7, kännetecknad därav, att den aromatiska kärnan Ar motsvarar formeln ar -(- Lng-ar -^- <Q)mw väri ar är en enkel ring eller en kondenserad ringkärna med 4-10 kol-atomer, varvid det finns minst 3 omättade valenser i totalt alla grupper ar, w är ett heltal san är 1-20 odi vardera gruppen Lng är en bindnlngslänk som oberoende av de andra kan vara en kol-kolenkelbindning, eterbindning, sulfidbindning, polysulfidbindning med 2-6 svavelato-mer, sulfinylbindning, sulfonylbindning, lägre alkylenbindning, di(lägre alkylJmetylenbindning, lägre alkyleneterbindning, lägre alkylensulfidbindning, lägre alkylenpolysulfidbindning, aminobind-ning eller kombination av sädana bindningslänkar, Q är en lägre alkyl-grupp, lägre alkoxylgrupp, nitrogrupp eller halogenatom och m är 0-3.
10. Användning enligt nägot av patentkraven 1-6, kännetecknad därav, att Ar är en bensenkärna med 0-3 eventuella substituenter och att a, b och c vardera är 1.
11. Användning enligt nägot av patentkraven 1-6, kännetecknad därav, att det aminoinnehällande tillsatsmedlet har 63053 36 formeln OH --fir' (κ···)ζ väri R1 är en i huvudsak mättad, kolvätebaserad substituent med i medeltal frän cirka 30 - cirka 400 alifatiska kolatomer och be-lägen i orto- eller paraställning i förhällande till hydroxylgrup-pen, R''' är lägre alkyl, lägre alkoxyl, nitro eller halogen, och z är 0 eller 1.
12. Användning enligt patentkravet 11, kännetecknad därav, att R' innehäller minst cirka 50 alifatiska kolatomer.
13. Användning enligt patentkravet 11 eller 12, kännetecknad därav, att R' är i en huvudsak mättad, rent alifa-tisk grupp.
14. Användning enligt nägot av patentkraven 11-13, kännetecknad därav, att R' är belägen i paraställning i förhäl-lande tili substituenten -OH och att z är 0.
15. Användning enligt nägot av patentkraven 11-14, kännetecknad därav, att R' är en alkyl- eller alkenylsubstituent.
16. Användning enligt nägot av patentkraven 11-15, kännetecknad därav, att R' är en substituent härledd frän homopo-lymeriserade eller sampolymeriserade C2_^g_olefiner.
17. Användning enligt patentktavet 16, kännetecknad därav, att C2-1o”olefinerna är valda bland c2_1 0_1 -olefiner eller blandningar därav.
18. Användning enligt patentkravet 17, kännetecknad därav, att 1-olefinen är etylen, propylen, butylen eller en bland-ning därav.
19. Användning enligt nägot av patentkraven 1-6 eller 10-18, kännetecknad därav, att det aminoinnehällande tillsats-medlet har formeln 63053 37 OH rV”"’ <«"·>*—r \ R" väri R" är härledd frän homopolymeriserade eller sampolymerisera-de C2_^ q~1 -olefiner och har i medeltal frän cirka 30 -cirka 300 alifatiska kolatomer, R''' är lägre alkyl, lägre alkoxyl, nitro eller halogen, och z är 0 eller 1.
20. Användning enligt patentkravet 19, kännetecknad därav, att 1-olefinen är etylen, propylen, butylen eller en bland-ning därav.
21. Användning enligt patentkravet 20, kännetecknad därav, att R" är härledd frän polymeriserad isobuten.
22. Användning enligt nägot av patentkraven 19-21, kännetecknad därav, att R" är en alkyl- eller alkenylgrupp inne-hällande i medeltal minst cirka 50 alifatiska kolatomer.
23. Användning enligt nägot av patentkraven 19-22, kännetecknad därav, att z är 0.
24. Användning enligt nägot av de föregäende patentkraven, kännetecknad därav, att R har i medeltal upp tili cirka 300 kolatomer.
25. Användning enligt nägot av de föregäende patentkraven, kännetecknad därav, att Ar1 har minst en väteatom direkt bunden tili en kolatom i en aromatisk ring, vilken kolatom förelig-ger i a- eller γ-ställning i förhällande tili en aromatisk kolatom bärande en hydroxylgrupp.
26. Användning enligt patentkravet 25, kännetecknad därav, att Ar' är en bensenkärna.
27. Användning enligt nägot av de föregäende patentkraven, kännetecknad därav, att nitreringsmedlet är salpetersyra.
28. Användning enligt nlgot av de föregäende patentkraven, kännetecknad därav, att nitromellanprodukten reduceras med väte i närvaro av en metallisk hydreringskatalysator.
29. Användning enligt nägot av patentkraven 1-6 eller 10-28,
FI762915A 1975-10-14 1976-10-13 Anvaendning av en smoerjmedelskomposition foer smoerjning av en tvaotaktsfoerbraenningsmotor FI63053C (fi)

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JP (1) JPS5284204A (sv)
AU (1) AU511718B2 (sv)
BE (1) BE847220A (sv)
CA (1) CA1096848A (sv)
DE (1) DE2646215A1 (sv)
DK (1) DK159932C (sv)
ES (1) ES452359A1 (sv)
FI (1) FI63053C (sv)
FR (1) FR2328036A1 (sv)
GB (1) GB1565548A (sv)
IN (1) IN145083B (sv)
IT (1) IT1069077B (sv)
MX (1) MX145598A (sv)
NL (1) NL186328C (sv)
SE (1) SE423403B (sv)
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US2065568A (en) * 1929-12-18 1936-12-29 Gasoline Antioxidant Company Gum inhibitor for hydrocarbon fuels
US2367377A (en) * 1940-02-03 1945-01-16 Socony Vacuum Oil Co Inc Mineral oil compoisition and improving agents therefor
US2502708A (en) * 1945-03-31 1950-04-04 Harvel Corp Nitro-hydrogenated cardanols and process for preparing same
GB662509A (en) * 1948-08-21 1951-12-05 British Resin Prod Ltd The manufacture of 4-amino cardanol and compositions thereof
US2831898A (en) * 1954-04-29 1958-04-22 Ethyl Corp Phenol alkylation process
US2859251A (en) * 1955-04-27 1958-11-04 Universal Oil Prod Co Alkylation of aromatic compounds
GB963263A (en) * 1961-01-20 1964-07-08 Socony Mobil Oil Co Inc Reaction products of alkyl hydroxyaromatic compounds with polyalkyleneamines and fuel compositions containing such products
US3798153A (en) * 1973-01-26 1974-03-19 Chevron Res Crude oil processing
US3903002A (en) * 1973-10-09 1975-09-02 Chevron Res Lubricant

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DK159932B (da) 1990-12-31
FR2328036B1 (sv) 1979-06-22
GB1565548A (en) 1980-04-23
DE2646215A1 (de) 1977-04-28
NL186328C (nl) 1990-11-01
IN145083B (sv) 1978-08-19
ES452359A1 (es) 1978-01-16
IT1069077B (it) 1985-03-25
SE7611380L (sv) 1977-04-15
AU511718B2 (en) 1980-09-04
FI63053C (fi) 1983-04-11
DE2646215C2 (sv) 1992-01-23
FR2328036A1 (fr) 1977-05-13
CA1096848A (en) 1981-03-03
AU1859776A (en) 1978-04-20
SE423403B (sv) 1982-05-03
NL186328B (nl) 1990-06-01
JPS5284204A (en) 1977-07-13
DK159932C (da) 1991-05-21
NL7611250A (nl) 1977-04-18
BE847220A (fr) 1977-04-13
MX145598A (es) 1982-03-12
DK461476A (da) 1977-04-15
ZA766087B (en) 1978-05-30
FI762915A (sv) 1977-04-15
JPS6252000B2 (sv) 1987-11-02

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