FI59077C - Foerfarande foer rening av vaotprocessfosforsyra - Google Patents
Foerfarande foer rening av vaotprocessfosforsyra Download PDFInfo
- Publication number
- FI59077C FI59077C FI1342/73A FI134273A FI59077C FI 59077 C FI59077 C FI 59077C FI 1342/73 A FI1342/73 A FI 1342/73A FI 134273 A FI134273 A FI 134273A FI 59077 C FI59077 C FI 59077C
- Authority
- FI
- Finland
- Prior art keywords
- acid
- phosphoric acid
- extract
- aqueous
- water
- Prior art date
Links
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 168
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 84
- 239000002253 acid Substances 0.000 claims description 65
- 238000000034 method Methods 0.000 claims description 42
- 239000000284 extract Substances 0.000 claims description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 24
- 238000005406 washing Methods 0.000 claims description 20
- 239000013078 crystal Substances 0.000 claims description 16
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 claims description 15
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 claims description 15
- 239000002904 solvent Substances 0.000 claims description 15
- 239000012535 impurity Substances 0.000 claims description 14
- 239000012452 mother liquor Substances 0.000 claims description 10
- 239000012074 organic phase Substances 0.000 claims description 10
- 239000012071 phase Substances 0.000 claims description 8
- 238000002425 crystallisation Methods 0.000 claims description 7
- 230000008025 crystallization Effects 0.000 claims description 7
- 239000008346 aqueous phase Substances 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 239000011260 aqueous acid Substances 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 24
- 150000002576 ketones Chemical class 0.000 description 22
- 238000000605 extraction Methods 0.000 description 20
- 239000007788 liquid Substances 0.000 description 11
- 239000000243 solution Substances 0.000 description 10
- 239000000203 mixture Substances 0.000 description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 239000007864 aqueous solution Substances 0.000 description 7
- 239000011777 magnesium Substances 0.000 description 7
- 239000000047 product Substances 0.000 description 6
- 238000000746 purification Methods 0.000 description 6
- 238000000638 solvent extraction Methods 0.000 description 6
- 229910052585 phosphate mineral Inorganic materials 0.000 description 5
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 229910052749 magnesium Inorganic materials 0.000 description 4
- 229910017604 nitric acid Inorganic materials 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- 150000002170 ethers Chemical class 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- -1 alkyl phosphates Chemical class 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000003337 fertilizer Substances 0.000 description 2
- 238000002955 isolation Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- RPAJSBKBKSSMLJ-DFWYDOINSA-N (2s)-2-aminopentanedioic acid;hydrochloride Chemical class Cl.OC(=O)[C@@H](N)CCC(O)=O RPAJSBKBKSSMLJ-DFWYDOINSA-N 0.000 description 1
- QQZOPKMRPOGIEB-UHFFFAOYSA-N 2-Oxohexane Chemical compound CCCCC(C)=O QQZOPKMRPOGIEB-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000001175 calcium sulphate Substances 0.000 description 1
- 235000011132 calcium sulphate Nutrition 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 125000002243 cyclohexanonyl group Chemical group *C1(*)C(=O)C(*)(*)C(*)(*)C(*)(*)C1(*)* 0.000 description 1
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexyloxide Natural products O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000005446 dissolved organic matter Substances 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 150000004673 fluoride salts Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 235000020079 raki Nutrition 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000005185 salting out Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/46—Preparation involving solvent-solvent extraction
- C01B25/461—Preparation involving solvent-solvent extraction the phosphoric acid present in the medium obtained after reaction being first extracted from the liquid phase formed or separated then re-extracted as free acid by using water or as a phosphate by using a basic compound
- C01B25/463—Preparation involving solvent-solvent extraction the phosphoric acid present in the medium obtained after reaction being first extracted from the liquid phase formed or separated then re-extracted as free acid by using water or as a phosphate by using a basic compound the extracting agent being a ketone or a mixture of ketones
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/18—Phosphoric acid
- C01B25/22—Preparation by reacting phosphate-containing material with an acid, e.g. wet process
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/18—Phosphoric acid
- C01B25/234—Purification; Stabilisation; Concentration
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/18—Phosphoric acid
- C01B25/234—Purification; Stabilisation; Concentration
- C01B25/2343—Concentration concomitant with purification, e.g. elimination of fluorine
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Extraction Or Liquid Replacement (AREA)
- Cleaning Or Drying Semiconductors (AREA)
- Encapsulation Of And Coatings For Semiconductor Or Solid State Devices (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI803070A FI803070A7 (fi) | 1972-04-26 | 1980-09-29 | Foerfarande foer rening av vaotprocessfosforsyra |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1947672A GB1436113A (en) | 1972-04-26 | 1972-04-26 | Purification of phosphoric acid |
| GB1947672 | 1972-04-26 | ||
| GB4538072 | 1972-10-02 | ||
| GB4538072 | 1972-10-02 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FI59077B FI59077B (fi) | 1981-02-27 |
| FI59077C true FI59077C (fi) | 1981-06-10 |
Family
ID=26254071
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI1342/73A FI59077C (fi) | 1972-04-26 | 1973-04-26 | Foerfarande foer rening av vaotprocessfosforsyra |
Country Status (20)
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IL48207A (en) * | 1974-10-07 | 1978-12-17 | Pennzoil Co | Production of fluoride-free phosphates |
| CA1139956A (en) * | 1978-10-10 | 1983-01-25 | Mark A. Rose | Process for extracting uranium from crude phosphoric acids |
| DE3246415A1 (de) * | 1982-12-15 | 1984-06-20 | Hoechst Ag, 6230 Frankfurt | Verfahren zur reinigung von nassverfahrenphosphorsaeure |
| DE3246416A1 (de) * | 1982-12-15 | 1984-06-20 | Hoechst Ag, 6230 Frankfurt | Verfahren zur reinigung von nassverfahrensphosphorsaeure |
| JP2512429Y2 (ja) * | 1993-07-12 | 1996-10-02 | 北陸電気工業株式会社 | 高電圧抵抗パック |
| IT1285694B1 (it) * | 1996-05-08 | 1998-06-18 | Azionaria Costruzioni Acma Spa | Metodo ed unita' per la formazione ed il convogliamento di gruppi di prodotti |
| DE19703884C2 (de) | 1997-02-03 | 1999-04-29 | Bk Giulini Chem Gmbh & Co Ohg | Verfahren zur Reinigung von Naßverfahrensphosphorsäure |
| RU2166476C2 (ru) * | 1998-12-04 | 2001-05-10 | Зайцев Борис Николаевич | Способ очистки экстракционной фосфорной кислоты |
| RU2191745C1 (ru) * | 2001-04-25 | 2002-10-27 | Зайцев Борис Николаевич | Способ очистки экстракционной фосфорной кислоты |
| RU2337060C1 (ru) * | 2007-06-04 | 2008-10-27 | Открытое акционерное общество "Научно-исследовательский институт по удобрениям и инсектофунгицидам им. Я.В. Самойлова" | Способ восстановления органического экстрагента |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL298968A (enrdf_load_stackoverflow) | 1963-10-08 | |||
| GB1142719A (en) * | 1968-10-24 | 1969-02-12 | Israel Mining Ind Inst For Res | Phosphoric acid recovery |
| DE2334019C3 (de) * | 1973-07-04 | 1982-11-04 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Reinigung von verunreinigter wäßriger Phosphorsäure |
-
1972
- 1972-04-26 GB GB1947672A patent/GB1436113A/en not_active Expired
-
1973
- 1973-04-17 NO NO1639/73A patent/NO137082C/no unknown
- 1973-04-18 IE IE614/73A patent/IE37549B1/xx unknown
- 1973-04-24 CA CA170,075A patent/CA1004828A/en not_active Expired
- 1973-04-25 ES ES414069A patent/ES414069A1/es not_active Expired
- 1973-04-25 FR FR7314935A patent/FR2182055B1/fr not_active Expired
- 1973-04-25 NL NL7305765A patent/NL7305765A/xx not_active Application Discontinuation
- 1973-04-25 SE SE7305814A patent/SE395263B/xx unknown
- 1973-04-25 TR TR18445A patent/TR18445A/xx unknown
- 1973-04-25 DE DE2320877A patent/DE2320877B2/de not_active Ceased
- 1973-04-25 IN IN966/CAL/73A patent/IN140334B/en unknown
- 1973-04-26 RO RO7374626A patent/RO67820A/ro unknown
- 1973-04-26 FI FI1342/73A patent/FI59077C/fi active
- 1973-04-26 BE BE130427A patent/BE798737A/xx unknown
- 1973-04-26 DD DD170600A patent/DD109362A5/xx unknown
- 1973-04-26 JP JP48046871A patent/JPS4999993A/ja active Pending
- 1973-04-26 CH CH599273A patent/CH613916A5/xx not_active IP Right Cessation
- 1973-04-26 OA OA54887A patent/OA04403A/xx unknown
- 1973-04-26 RO RO7385793A patent/RO69802A/ro unknown
-
1975
- 1975-10-24 AU AU85994/75A patent/AU8599475A/en not_active Expired
- 1975-12-11 FR FR7538023A patent/FR2289442A1/fr active Granted
- 1975-12-11 FR FR7538022A patent/FR2289441A1/fr active Granted
-
1978
- 1978-12-31 MY MY197885A patent/MY7800085A/xx unknown
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