FI58647C - Foerfarande foer homo- och kopolymerisering av diener sinsemellan eller med vinylaromatiska foereningar utan loesningsmedel - Google Patents
Foerfarande foer homo- och kopolymerisering av diener sinsemellan eller med vinylaromatiska foereningar utan loesningsmedel Download PDFInfo
- Publication number
- FI58647C FI58647C FI750317A FI750317A FI58647C FI 58647 C FI58647 C FI 58647C FI 750317 A FI750317 A FI 750317A FI 750317 A FI750317 A FI 750317A FI 58647 C FI58647 C FI 58647C
- Authority
- FI
- Finland
- Prior art keywords
- reaction
- process according
- monomers
- group
- reactor
- Prior art date
Links
- 238000006243 chemical reaction Methods 0.000 claims description 60
- -1 vinyl aromatic compounds Chemical class 0.000 claims description 37
- 239000000178 monomer Substances 0.000 claims description 35
- 238000006116 polymerization reaction Methods 0.000 claims description 29
- 238000000034 method Methods 0.000 claims description 25
- 150000001875 compounds Chemical class 0.000 claims description 17
- 229920000642 polymer Polymers 0.000 claims description 15
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 13
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 13
- 239000012967 coordination catalyst Substances 0.000 claims description 10
- 239000002904 solvent Substances 0.000 claims description 10
- 229920002554 vinyl polymer Polymers 0.000 claims description 7
- 229920001577 copolymer Polymers 0.000 claims description 6
- 150000001993 dienes Chemical class 0.000 claims description 6
- 238000005187 foaming Methods 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 3
- 125000001188 haloalkyl group Chemical group 0.000 claims description 3
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 2
- 125000003106 haloaryl group Chemical group 0.000 claims description 2
- 125000006684 polyhaloalkyl group Polymers 0.000 claims description 2
- 238000009834 vaporization Methods 0.000 claims description 2
- 230000008016 vaporization Effects 0.000 claims description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 33
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 19
- 239000003054 catalyst Substances 0.000 description 15
- 239000006260 foam Substances 0.000 description 14
- 238000001704 evaporation Methods 0.000 description 7
- 230000008020 evaporation Effects 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 239000005062 Polybutadiene Substances 0.000 description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000002518 antifoaming agent Substances 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 229920002857 polybutadiene Polymers 0.000 description 5
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000003963 antioxidant agent Substances 0.000 description 3
- 230000003078 antioxidant effect Effects 0.000 description 3
- 238000012662 bulk polymerization Methods 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229920001195 polyisoprene Polymers 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 229920001921 poly-methyl-phenyl-siloxane Polymers 0.000 description 2
- 229920003051 synthetic elastomer Polymers 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 2
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- 239000002879 Lewis base Substances 0.000 description 1
- OUBMGJOQLXMSNT-UHFFFAOYSA-N N-isopropyl-N'-phenyl-p-phenylenediamine Chemical compound C1=CC(NC(C)C)=CC=C1NC1=CC=CC=C1 OUBMGJOQLXMSNT-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229910018557 Si O Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000005234 alkyl aluminium group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000008378 aryl ethers Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000002238 attenuated effect Effects 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- SIPUZPBQZHNSDW-UHFFFAOYSA-N bis(2-methylpropyl)aluminum Chemical compound CC(C)C[Al]CC(C)C SIPUZPBQZHNSDW-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 150000001638 boron Chemical class 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- FXNONNRUNQPNLF-UHFFFAOYSA-N cerium;2-ethylhexanoic acid Chemical compound [Ce].CCCCC(CC)C(O)=O.CCCCC(CC)C(O)=O.CCCCC(CC)C(O)=O FXNONNRUNQPNLF-UHFFFAOYSA-N 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- HYZXMVILOKSUKA-UHFFFAOYSA-K chloro(dimethyl)alumane;dichloro(methyl)alumane Chemical compound C[Al](C)Cl.C[Al](Cl)Cl HYZXMVILOKSUKA-UHFFFAOYSA-K 0.000 description 1
- 150000001868 cobalt Chemical class 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- PPQUYYAZSOKTQD-UHFFFAOYSA-M diethylalumanylium;iodide Chemical compound CC[Al](I)CC PPQUYYAZSOKTQD-UHFFFAOYSA-M 0.000 description 1
- CQYBWJYIKCZXCN-UHFFFAOYSA-N diethylaluminum Chemical compound CC[Al]CC CQYBWJYIKCZXCN-UHFFFAOYSA-N 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 150000007527 lewis bases Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- UIEKYBOPAVTZKW-UHFFFAOYSA-L naphthalene-2-carboxylate;nickel(2+) Chemical compound [Ni+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 UIEKYBOPAVTZKW-UHFFFAOYSA-L 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 150000003961 organosilicon compounds Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000000707 stereoselective effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003623 transition metal compounds Chemical class 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D19/00—Degasification of liquids
- B01D19/02—Foam dispersion or prevention
- B01D19/04—Foam dispersion or prevention by addition of chemical substances
- B01D19/0404—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance
- B01D19/0409—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance compounds containing Si-atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Toxicology (AREA)
- Dispersion Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Silicon Polymers (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7403892A FR2259837B1 (cg-RX-API-DMAC7.html) | 1974-02-05 | 1974-02-05 | |
| FR7403892 | 1974-02-05 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| FI750317A7 FI750317A7 (cg-RX-API-DMAC7.html) | 1975-08-06 |
| FI58647B FI58647B (fi) | 1980-11-28 |
| FI58647C true FI58647C (fi) | 1981-03-10 |
Family
ID=9134537
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI750317A FI58647C (fi) | 1974-02-05 | 1975-02-05 | Foerfarande foer homo- och kopolymerisering av diener sinsemellan eller med vinylaromatiska foereningar utan loesningsmedel |
Country Status (22)
| Country | Link |
|---|---|
| US (1) | US3962200A (cg-RX-API-DMAC7.html) |
| JP (1) | JPS5250071B2 (cg-RX-API-DMAC7.html) |
| AR (1) | AR207029A1 (cg-RX-API-DMAC7.html) |
| AT (1) | AT337451B (cg-RX-API-DMAC7.html) |
| BE (1) | BE824638A (cg-RX-API-DMAC7.html) |
| BR (1) | BR7500694A (cg-RX-API-DMAC7.html) |
| CA (1) | CA1035097A (cg-RX-API-DMAC7.html) |
| CH (1) | CH601365A5 (cg-RX-API-DMAC7.html) |
| DE (1) | DE2503437A1 (cg-RX-API-DMAC7.html) |
| EG (1) | EG12561A (cg-RX-API-DMAC7.html) |
| ES (1) | ES434237A1 (cg-RX-API-DMAC7.html) |
| FI (1) | FI58647C (cg-RX-API-DMAC7.html) |
| FR (1) | FR2259837B1 (cg-RX-API-DMAC7.html) |
| GB (1) | GB1466541A (cg-RX-API-DMAC7.html) |
| IE (1) | IE40584B1 (cg-RX-API-DMAC7.html) |
| IT (1) | IT1027459B (cg-RX-API-DMAC7.html) |
| LU (1) | LU71785A1 (cg-RX-API-DMAC7.html) |
| NL (1) | NL157614B (cg-RX-API-DMAC7.html) |
| NO (1) | NO146473C (cg-RX-API-DMAC7.html) |
| RO (1) | RO70348A (cg-RX-API-DMAC7.html) |
| SE (1) | SE406593B (cg-RX-API-DMAC7.html) |
| ZA (1) | ZA75737B (cg-RX-API-DMAC7.html) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997045462A1 (en) * | 1996-05-24 | 1997-12-04 | Bp Chemicals Limited | Process for polymerizing olefins |
| WO2005087824A1 (en) * | 2004-03-02 | 2005-09-22 | Bridgestone Corporation | Bulk polymerization process |
| KR101860969B1 (ko) | 2010-12-31 | 2018-05-24 | 가부시키가이샤 브리지스톤 | 니켈-기재 촉매시스템을 이용한 공액 디엔의 벌크중합 |
| EP2658886B1 (en) * | 2010-12-31 | 2017-03-08 | Bridgestone Corporation | Bulk polymerization of conjugated dienes using a nickel-based catalyst system |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2977349A (en) * | 1956-11-07 | 1961-03-28 | Goodrich Gulf Chem Inc | Process for polymerizing dienes |
| GB830424A (en) * | 1957-02-27 | 1960-03-16 | Ici Ltd | Polymerisation catalysts |
| US3062796A (en) * | 1959-05-11 | 1962-11-06 | Shell Oil Co | Production of synthetic elastomers |
| US3182050A (en) * | 1962-10-19 | 1965-05-04 | Phillips Petroleum Co | Bulk polymerization |
| NL155274B (nl) * | 1967-09-19 | 1977-12-15 | Montedison Spa | Werkwijze om polyisopreen te bereiden. |
| US3635852A (en) * | 1969-12-15 | 1972-01-18 | Foster Grant Co Inc | Process of making a general purpose expandable alkenyl aromatic polymer containing di-alkyl polysiloxane internally |
| US3770710A (en) * | 1971-08-23 | 1973-11-06 | Firestone Tire & Rubber Co | Bulk polymerization of diolefins |
-
1973
- 1973-02-05 ZA ZA00750737*DA patent/ZA75737B/xx unknown
-
1974
- 1974-02-05 FR FR7403892A patent/FR2259837B1/fr not_active Expired
-
1975
- 1975-01-01 AR AR257521A patent/AR207029A1/es active
- 1975-01-22 BE BE152590A patent/BE824638A/xx not_active IP Right Cessation
- 1975-01-28 DE DE19752503437 patent/DE2503437A1/de not_active Ceased
- 1975-01-28 JP JP50011845A patent/JPS5250071B2/ja not_active Expired
- 1975-01-29 ES ES434237A patent/ES434237A1/es not_active Expired
- 1975-01-31 US US05/546,136 patent/US3962200A/en not_active Expired - Lifetime
- 1975-01-31 CA CA219,119A patent/CA1035097A/en not_active Expired
- 1975-02-03 LU LU71785A patent/LU71785A1/xx unknown
- 1975-02-03 BR BR694/75A patent/BR7500694A/pt unknown
- 1975-02-04 AT AT82775A patent/AT337451B/de not_active IP Right Cessation
- 1975-02-04 GB GB476575A patent/GB1466541A/en not_active Expired
- 1975-02-04 SE SE7501213A patent/SE406593B/xx not_active IP Right Cessation
- 1975-02-04 EG EG50/75A patent/EG12561A/xx active
- 1975-02-04 IT IT67284/75A patent/IT1027459B/it active
- 1975-02-05 IE IE230/75A patent/IE40584B1/xx unknown
- 1975-02-05 NL NL7501370.A patent/NL157614B/xx not_active IP Right Cessation
- 1975-02-05 RO RO7581348A patent/RO70348A/ro unknown
- 1975-02-05 FI FI750317A patent/FI58647C/fi not_active IP Right Cessation
- 1975-02-05 CH CH137975A patent/CH601365A5/xx not_active IP Right Cessation
- 1975-02-05 NO NO750366A patent/NO146473C/no unknown
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM | Patent lapsed |
Owner name: MICHELIN & CIE |