FI123109B - Behandling av massa medelst antrakinon - Google Patents
Behandling av massa medelst antrakinon Download PDFInfo
- Publication number
- FI123109B FI123109B FI20070586A FI20070586A FI123109B FI 123109 B FI123109 B FI 123109B FI 20070586 A FI20070586 A FI 20070586A FI 20070586 A FI20070586 A FI 20070586A FI 123109 B FI123109 B FI 123109B
- Authority
- FI
- Finland
- Prior art keywords
- additive
- liquid
- temperature
- slurry
- alkali
- Prior art date
Links
- 238000011282 treatment Methods 0.000 title claims description 22
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 title description 25
- 150000004056 anthraquinones Chemical class 0.000 title description 25
- 239000000654 additive Substances 0.000 claims description 57
- 230000000996 additive effect Effects 0.000 claims description 54
- 239000003513 alkali Substances 0.000 claims description 41
- 238000000034 method Methods 0.000 claims description 39
- 239000007788 liquid Substances 0.000 claims description 38
- 239000002002 slurry Substances 0.000 claims description 36
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 27
- 239000000463 material Substances 0.000 claims description 18
- 239000002657 fibrous material Substances 0.000 claims description 13
- 229920001131 Pulp (paper) Polymers 0.000 claims description 6
- 238000010924 continuous production Methods 0.000 claims 1
- 238000010411 cooking Methods 0.000 description 29
- 238000005470 impregnation Methods 0.000 description 11
- 239000012530 fluid Substances 0.000 description 7
- 239000002023 wood Substances 0.000 description 7
- 238000010025 steaming Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 5
- 230000015556 catabolic process Effects 0.000 description 5
- 238000006731 degradation reaction Methods 0.000 description 5
- 239000005077 polysulfide Substances 0.000 description 5
- 229920001021 polysulfide Polymers 0.000 description 5
- 150000008117 polysulfides Polymers 0.000 description 5
- 230000000712 assembly Effects 0.000 description 4
- 238000000429 assembly Methods 0.000 description 4
- 229920002678 cellulose Polymers 0.000 description 4
- 239000001913 cellulose Substances 0.000 description 4
- 239000000706 filtrate Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 229920005610 lignin Polymers 0.000 description 3
- 230000035515 penetration Effects 0.000 description 3
- 238000002203 pretreatment Methods 0.000 description 3
- 238000005086 pumping Methods 0.000 description 3
- 229910021653 sulphate ion Inorganic materials 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 230000029087 digestion Effects 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 238000004537 pulping Methods 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 238000012216 screening Methods 0.000 description 2
- 239000011122 softwood Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- -1 steam condensate Substances 0.000 description 2
- 229920002488 Hemicellulose Polymers 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000005903 acid hydrolysis reaction Methods 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 150000002605 large molecules Chemical group 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 238000007781 pre-processing Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C3/00—Pulping cellulose-containing materials
- D21C3/02—Pulping cellulose-containing materials with inorganic bases or alkaline reacting compounds, e.g. sulfate processes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C1/00—Pretreatment of the finely-divided materials before digesting
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C1/00—Pretreatment of the finely-divided materials before digesting
- D21C1/04—Pretreatment of the finely-divided materials before digesting with acid reacting compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C1/00—Pretreatment of the finely-divided materials before digesting
- D21C1/06—Pretreatment of the finely-divided materials before digesting with alkaline reacting compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C3/00—Pulping cellulose-containing materials
- D21C3/04—Pulping cellulose-containing materials with acids, acid salts or acid anhydrides
- D21C3/06—Pulping cellulose-containing materials with acids, acid salts or acid anhydrides sulfur dioxide; sulfurous acid; bisulfites sulfites
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C3/00—Pulping cellulose-containing materials
- D21C3/04—Pulping cellulose-containing materials with acids, acid salts or acid anhydrides
- D21C3/06—Pulping cellulose-containing materials with acids, acid salts or acid anhydrides sulfur dioxide; sulfurous acid; bisulfites sulfites
- D21C3/12—Pulping cellulose-containing materials with acids, acid salts or acid anhydrides sulfur dioxide; sulfurous acid; bisulfites sulfites sodium bisulfite
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C3/00—Pulping cellulose-containing materials
- D21C3/22—Other features of pulping processes
- D21C3/222—Use of compounds accelerating the pulping processes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C3/00—Pulping cellulose-containing materials
- D21C3/22—Other features of pulping processes
- D21C3/24—Continuous processes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C3/00—Pulping cellulose-containing materials
- D21C3/22—Other features of pulping processes
- D21C3/26—Multistage processes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C7/00—Digesters
- D21C7/06—Feeding devices
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C7/00—Digesters
- D21C7/14—Means for circulating the lye
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Paper (AREA)
Claims (4)
1. Förfarande för behandling av finmalet cellulosahaltigt fibermaterial genom väsentligen kontinuerlig 5 (a) behandling av slurryn av det finmalade cellulosahaltiga fibermaterialet med en första vätska som tili huvuddelen eller väsentligen uteslutande utgörs av vatten som innehaller antrakinon-tillsatsmedel (AQ), varvid halten av effektivt alkali är väsentligen noll, vid en första temperatur av ca 80-130 °C, under en period av ca 20 sekunder - 60 minuter, vid ett tryck som överskrider atmosfärstrycket; 10 och (b) behandling av materialet i slurryn med en andra vätska efter steget (a), utgängshalten av effektivt alkali i vilken andra vätska överskrider 10 g/1, uttryckt som NaOH, vid en andra temperatur över 130 °C, för att producera kemisk cellulosamassa. 15
2. Förfarande enligt patentkravet 1, där slurryn behandlas mellan stegen (a) och (b) ännu i steg (c) med en tredje vätska, som innehaller AQ-tillsatsmedel och vars högsta hait av effektivt alkali är högre än den första vätskans och lägre än den andra vätskans, vid en tredje temperatur som är högre än den första temperaturen 20 och lägre än 130 °C. CM i σ> o ,1
3. Förfarande enligt patentkravet 2, där ytterligare AQ-tillsatsmedel tillsätts ännu i CM x samband med behandlingen (c). Q. CO CO g 25
4. Förfarande enligt patentkravet 1, där steget (a) förverkligas i ett matningssystem h- § för ett kontinuerligt kokarkärl och steget (b) förverkligas i ett kontinuerligt CM kokarkärl.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US15323799P | 1999-09-13 | 1999-09-13 | |
US15323799 | 1999-09-13 | ||
US65891000 | 2000-09-12 | ||
US09/658,910 US6576084B1 (en) | 1999-09-13 | 2000-09-12 | Method of pretreating pulp with yield or strength-enhancing additive |
Publications (2)
Publication Number | Publication Date |
---|---|
FI20070586A FI20070586A (sv) | 2007-08-06 |
FI123109B true FI123109B (sv) | 2012-11-15 |
Family
ID=22546345
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FI20002011A FI122897B (sv) | 1999-09-13 | 2000-09-13 | Behandling av massa medelst antrakinon |
FI20070586A FI123109B (sv) | 1999-09-13 | 2007-08-06 | Behandling av massa medelst antrakinon |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FI20002011A FI122897B (sv) | 1999-09-13 | 2000-09-13 | Behandling av massa medelst antrakinon |
Country Status (5)
Country | Link |
---|---|
US (2) | US6576084B1 (sv) |
JP (2) | JP4283981B2 (sv) |
CA (1) | CA2318027C (sv) |
FI (2) | FI122897B (sv) |
SE (1) | SE526202C2 (sv) |
Families Citing this family (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20010032711A1 (en) * | 1998-10-26 | 2001-10-25 | C. Bertil Stromberg | Pulp cooking with particular alkali profiles |
FI20002587A (sv) * | 2000-11-24 | 2002-05-25 | Metso Paper Inc | Förfarande för alkalisk satsvis kokning av fibermaterial |
WO2003002813A2 (de) * | 2001-06-29 | 2003-01-09 | Voith Paper Fiber Systems Gmbh & Co. Kg | Verfahren zum delignifizieren lignocellulosischer rohstoffe |
US20030131956A1 (en) * | 2002-01-16 | 2003-07-17 | Stromberg C. Bertil | Continuous pulping processes and systems |
DE10323376A1 (de) * | 2003-05-21 | 2004-12-16 | Voith Paper Fiber Systems Gmbh & Co. Kg | Verfahren zum Delignifizieren |
US20050155730A1 (en) * | 2004-01-20 | 2005-07-21 | Stigsson Lars L. | Method for the production of high yield chemical pulp from softwood |
FI120547B (sv) * | 2004-10-04 | 2009-11-30 | Metso Paper Inc | Alkaliskt kokförfarande och anläggning för framställning av massa |
FI122841B (sv) * | 2004-10-04 | 2012-07-31 | Metso Paper Inc | Förfarande och anordning för tillverkning av cellulosamassa |
FI126694B (sv) * | 2005-12-02 | 2017-04-13 | Metsä Board Oyj | Kemimekanisk massa och förfarande för framställning av kemimekanisk massa |
US20070240837A1 (en) * | 2006-04-13 | 2007-10-18 | Andritz Inc. | Hardwood alkaline pulping processes and systems |
RU2445414C2 (ru) * | 2006-05-19 | 2012-03-20 | Дзе Рисерч Фаундейшн Оф Стейт Юниверсити Оф Нью Йорк | Способы карбонатной предварительной обработки и варки целлюлозного материала |
US8262856B2 (en) * | 2007-06-18 | 2012-09-11 | Andritz Inc. | Processes and systems for the bleaching of lignocellulosic pulps following cooking with soda and anthraquinone |
CN101235095B (zh) * | 2007-08-03 | 2013-06-05 | 方真 | 一种完全溶解木质纤维素生物质的方法及其设备和应用 |
US7828930B2 (en) * | 2007-11-20 | 2010-11-09 | International Paper Company | Use of polysulfide in modified cooking |
SE0702874L (sv) * | 2007-12-20 | 2009-06-09 | Metso Fiber Karlstad Ab | Förfarande vid tillverkning av sulfatmassa där hemicellulosor återförs |
WO2009117402A2 (en) * | 2008-03-18 | 2009-09-24 | The Research Foundation Of State University Of New York | Methods of pretreating comminuted cellulosic material with carbonate-containing solutions |
US9090915B2 (en) * | 2008-04-22 | 2015-07-28 | Wisconsin Alumni Research Foundation | Sulfite pretreatment for biorefining biomass |
JP5212806B2 (ja) * | 2008-08-01 | 2013-06-19 | 川崎化成工業株式会社 | リグノセルロース材料の蒸解方法 |
US8672588B2 (en) * | 2009-04-15 | 2014-03-18 | Andritz Inc. | Unobstructed low pressure outlet and screen grid for a high pressure feeder |
JP4629164B2 (ja) * | 2009-05-26 | 2011-02-09 | 日本製紙株式会社 | リグノセルロース材料の蒸解法 |
US8815561B2 (en) | 2010-08-23 | 2014-08-26 | Wisconsin Alumni Research Foundation | Metal compounds to eliminate nonproductive enzyme adsorption and enhance enzymatic saccharification of lignocellulose |
CN102154869B (zh) * | 2010-12-28 | 2013-04-10 | 宜宾长毅浆粕有限责任公司 | 一种制备化纤浆粕的蒸煮助剂 |
US8951388B2 (en) | 2011-04-08 | 2015-02-10 | Pec-Tech Engineering And Construction Pte Ltd | Method and system for efficient production of dissolving pulp in a kraft mill producing paper grade pulp with a continuous type digester |
MX2014000245A (es) | 2011-07-07 | 2014-09-15 | Poet Res Inc | Sistemas y metodos para la recirculacion de acido. |
AR091998A1 (es) | 2012-05-03 | 2015-03-18 | Annikki Gmbh | Procedimiento de preparacion de celulosa con baja concentracion de lignina |
US9644317B2 (en) * | 2014-11-26 | 2017-05-09 | International Paper Company | Continuous digester and feeding system |
CN114277590B (zh) * | 2021-12-31 | 2023-05-26 | 郑州运达造纸设备有限公司 | 一种汽蒸仓防架桥槽体 |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA444274A (en) | 1947-09-23 | R. Fuller Robert | Wood pulping process | |
US2944928A (en) | 1957-09-20 | 1960-07-12 | Kibrick | Method of preparing paper pulp |
US3210235A (en) | 1963-04-08 | 1965-10-05 | Scott Paper Co | Pulping of cellulose materials in the presence of free sulfur in a kraft pulping system and cyclic liquor recovery therefor |
US3664919A (en) | 1969-12-09 | 1972-05-23 | Pulp Paper Res Inst | Vapor phase polysulphide liquid pulping of lignocellulosic materials |
US4024229A (en) | 1970-11-06 | 1977-05-17 | The Mead Corporation | Production of polysulfide with PTFE coated catalyst |
GB1449828A (en) | 1973-04-26 | 1976-09-15 | Canadian Ind | Oxygen pulping process |
US4091749A (en) | 1975-01-02 | 1978-05-30 | Macmillan Bloedel Limited | Alkaline pulping of lignocellulosic material with amine pretreatment |
CA1073161A (en) | 1975-09-05 | 1980-03-11 | Canadian Industries Limited | Delignification process |
US4127439A (en) | 1977-01-28 | 1978-11-28 | Crown Zellerbach Corporation | Pretreatment of lignocellulose with anthraquinone prior to pulping |
SE416481B (sv) | 1977-05-02 | 1981-01-05 | Mo Och Domsjoe Ab | Fofarande och anordning for behandling av vedflis for avlegsnande av tungmetaller och harts |
US4310383A (en) | 1979-11-23 | 1982-01-12 | Crown Zellerbach Corporation | Continuous countercurrent pretreatment of lignocellulose with anthraquinone prior to pulping |
US5489363A (en) | 1993-05-04 | 1996-02-06 | Kamyr, Inc. | Pulping with low dissolved solids for improved pulp strength |
US5575890A (en) | 1993-05-04 | 1996-11-19 | Kamyr, Inc. | Method for selectively increasing the sulfide ion concentration and sulfidity of kraft cooking liquor during kraft cooking of wood |
US5536366A (en) | 1993-05-04 | 1996-07-16 | Ahlstrom Machinery Inc. | Digester system for implementing low dissolved solids profiling |
US5622598A (en) * | 1995-04-25 | 1997-04-22 | Ahlstrom Machinery Inc. | Chip pumping to a digester |
SE510775C2 (sv) | 1996-09-26 | 1999-06-21 | Kvaerner Pulping Tech | Svavelfri kokning av kemisk massa |
US5736006A (en) * | 1996-10-10 | 1998-04-07 | Ahlstrom Machinery Inc. | Method and apparatus for pulping with controlled heating to improve delignification and pulp strength |
US5753075A (en) * | 1996-10-25 | 1998-05-19 | Stromberg; C. Bertil | Method and system for feeding comminuted fibrous material |
US5882477A (en) * | 1997-02-10 | 1999-03-16 | Ahlstrom Machinery, Inc. | Continuous digester with a low temperature gas-phase |
US6241851B1 (en) * | 1998-03-03 | 2001-06-05 | Andritz-Ahlstrom Inc. | Treatment of cellulose material with additives while producing cellulose pulp |
SE9903417D0 (sv) | 1999-09-22 | 1999-09-22 | Skogsind Tekn Foskningsinst | A process for the production of sulphate pulp |
-
2000
- 2000-09-12 CA CA002318027A patent/CA2318027C/en not_active Expired - Fee Related
- 2000-09-12 US US09/658,910 patent/US6576084B1/en not_active Expired - Lifetime
- 2000-09-13 FI FI20002011A patent/FI122897B/sv not_active IP Right Cessation
- 2000-09-13 JP JP2000278086A patent/JP4283981B2/ja not_active Expired - Fee Related
- 2000-09-13 SE SE0003249A patent/SE526202C2/sv not_active IP Right Cessation
-
2001
- 2001-11-15 US US09/987,596 patent/US6569289B2/en not_active Expired - Lifetime
-
2007
- 2007-08-06 FI FI20070586A patent/FI123109B/sv not_active IP Right Cessation
-
2008
- 2008-04-28 JP JP2008116793A patent/JP4977086B2/ja not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
FI20002011A (sv) | 2001-03-14 |
CA2318027A1 (en) | 2001-03-13 |
JP2008223217A (ja) | 2008-09-25 |
FI20070586A (sv) | 2007-08-06 |
JP2001192990A (ja) | 2001-07-17 |
SE0003249L (sv) | 2001-03-14 |
FI122897B (sv) | 2012-08-31 |
JP4283981B2 (ja) | 2009-06-24 |
US20020026991A1 (en) | 2002-03-07 |
SE0003249D0 (sv) | 2000-09-13 |
CA2318027C (en) | 2008-07-08 |
JP4977086B2 (ja) | 2012-07-18 |
US6569289B2 (en) | 2003-05-27 |
US6576084B1 (en) | 2003-06-10 |
FI20002011A0 (sv) | 2000-09-13 |
SE526202C2 (sv) | 2005-07-26 |
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