FI121426B - Process för framställning av polyolefiner - Google Patents

Process för framställning av polyolefiner Download PDF

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Publication number
FI121426B
FI121426B FI20065405A FI20065405A FI121426B FI 121426 B FI121426 B FI 121426B FI 20065405 A FI20065405 A FI 20065405A FI 20065405 A FI20065405 A FI 20065405A FI 121426 B FI121426 B FI 121426B
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catalyst
distillation column
process according
reactor
dimerization
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FI20065405A
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English (en)
Finnish (fi)
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FI20065405A0 (sv
FI20065405A (sv
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Kari Kulmala
Fredrik Nissfolk
Vesa-Matti Lehtinen
Marja Tiitta
Anna-Mari Illikainen
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Neste Oil Oyj
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Priority to FI20065405A priority Critical patent/FI121426B/sv
Publication of FI20065405A0 publication Critical patent/FI20065405A0/sv
Priority to AU2007259108A priority patent/AU2007259108B2/en
Priority to CN2007800268475A priority patent/CN101490218B/zh
Priority to RU2009100932/04A priority patent/RU2437920C2/ru
Priority to CA2654940A priority patent/CA2654940C/en
Priority to MYPI20085055A priority patent/MY150103A/en
Priority to MX2008015844A priority patent/MX2008015844A/es
Priority to KR1020097000726A priority patent/KR101166477B1/ko
Priority to PCT/FI2007/050357 priority patent/WO2007144474A1/en
Priority to JP2009514830A priority patent/JP2009539945A/ja
Priority to EP07788742.0A priority patent/EP2029701B2/en
Priority to BRPI0713262A priority patent/BRPI0713262B1/pt
Publication of FI20065405A publication Critical patent/FI20065405A/sv
Priority to IL195733A priority patent/IL195733A/en
Priority to ZA200810485A priority patent/ZA200810485B/xx
Publication of FI121426B publication Critical patent/FI121426B/sv
Application granted granted Critical
Priority to JP2013175655A priority patent/JP5715207B2/ja

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/005—Mixtures of molecular sieves comprising at least one molecular sieve which is not an aluminosilicate zeolite, e.g. from groups B01J29/03 - B01J29/049 or B01J29/82 - B01J29/89
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/0308—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/041—Mesoporous materials having base exchange properties, e.g. Si/Al-MCM-41
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80—Mixtures of different zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/90—Regeneration or reactivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12—Treating with free oxygen-containing gas
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/12—Catalytic processes with crystalline alumino-silicates or with catalysts comprising molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/04—Reduction, e.g. hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1088—Olefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4087—Catalytic distillation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/44—Solvents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/10—Lubricating oil
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Claims (15)

1. Process för framställning av polyo le finer, kännetecknad därav, att en inmatning, som omfattar en n-olefin eller en blandning av n-olefiner och väljs bland C8-C30 nolefiner, dimeriseras i närvaro av en fast sur katalysator pä sädant sätt, att inmatningen leds tili en katalytisk destillator, som omfattar antingen a) en kombination av en 10 destillationskolonn och en reaktor, vilken kombination omfattar minst en katalysatorbädd, eller b) en destillationskolonn, tili vilken är anslutna en eller flera sidoreaktorer, som omfattar minst ett katalysatorskikt och katalysator omfattar ett fast surt katalysatormaterial, vars mesoporyta är över 100 m2/g, 15 aluminiumhalten är 0,2-30 vikt-%, mängden sura punkter är 50 - 500 pmol/g och som väljs bland sura amorfa aluminiumsilikater, dealuminerade Yzeo liter och mesoporösa molekylsiktar, i vilka har inbäddats zcolit, dcn orcagcradc n-olcfincn tas ut frän dcn övrc dclcn av destillationskolonnen eller kombinationen av destillationskolonn 20 och reaktor som ett sidoflöde, som förenas med inmatningen, och den frän dimeriseringen erhällna reaktionsprodukten hydreras.
2. Process enligt patentkravet 1, kännetecknad därav, att inmatningen omfattar minst en n-olefin, som väljs bland 1-deken, blandningar av 25 dekener, 1-dodeken, blandningar av dodekener, 1-hexadeken, blandningar av hexadekener, 1-teradeken, 1-oktadeken, blandningar av oktadekener, l-C2o-C22-olefiner och blandningar av dessa.
3. Process enligt patentkravet 1 eller 2, kännetecknad därav, att 30 katalysatormaterialets mesoporyta är över 300 m2/g.
4. Process enligt nägot av patentkraven 1-3, kännetecknad därav, att katalysatormaterialet är ett amorft aluminiumsilikat, vars mesoporyta är over 300 m2/g.
5. Process enligt nägot av patentkraven 1 - 4, kännetecknad därav, att katalysatormaterial är mesoporös molekylsikt, i vilken har inbäddats zeolit, och zeoliten är ZSM-5, beta-zeolit eller MCM-22 och den mesoporösa molekylsikten är MCM-41, som har en regelbunden molekylstruktur. 10
6. Process enligt nägot av patentkraven 1-5, kännetecknad därav, att en del av sidoflödet avlägsnas frän den övre delen av destillationskolonnen eller kombinationen av destillationskolonn och reaktor. 15
7. Process enligt nägot av patentkraven 1-6, kännetecknad därav, att i inmatningen tillsätts ett lösningsmedel eller en blandning av lösningsmcdcl valda bland kolvätcn.
8. Process enligt nägot av patentkraven 1 - 7, kännetecknad därav, att en torkning genornförs pä inmatningen.
9. Process enligt nägot av patentkraven 1-8, kännetecknad därav, att dimeriseringen genomförs vid en temperatur av 25-200 °C, 25 fördelaktigt 50-150 °C, och vid ett tryck pä 0,001 mbar - 50 bar, fördelaktigt 0,5 mbar - 30 bar. 1 Process enligt nägot av patentkraven 1-9, kännetecknad därav, att hydreringen genomförs vid ett tryck pä 5-100 bar, fördelaktigt vid 30 ett tryck pä 10-70 bar, och vid en temperatur av 100-400 °C, fördelaktigt vid en temperatur av 150-250 °C, i närvaro av en hydreringskatalysator.
11. Process enligt nägot av patentkraven 1-10, kännetecknad därav, 5 att inmatningen omfattar 1-deken.
12. Process enligt nägot av patentkraven 1-11, kännetecknad därav, att inmatningen omfattar 1-hexadeken.
13. Process enligt nägot av patentkraven 1 - 12, kännetecknad därav, att inmatningen omfattar olefiner av bioursprung, vilka är framställda av biologiska räämnen.
14. Process enligt nägot av patentkraven 1-13, kännetecknad därav, 15 att destination genomförs efter dimeriseringen eller efter hydreringen eller efter vardera.
15. Process enligt nägot av patentkraven 1-14, kännetecknad därav, att en basolja eller en basoljekomponent framställs med processen. 20
16. Användning av en anläggning, som omfattar 1) en altemativ tork för en inmatning, 2) en katalytisk destillator, som omfattar antingen a) en kombination av en destillationskolonn och en reaktor, vilken kombination omfattar minst en katalysatorbädd omfattande en fast och 25 sur katalysator, eller b) en destillationskolonn, tili vilken är anslutna en eller flera sidoreaktorer, som omfattar minst en katalysatorbädd omfattande en fast och sur katalysator, 3) en hydreringsreaktor, och en altemativ destillationskolonn efter den katalytiska destillatom och/eller hydreringsreaktom, i en process enligt nägot av patentkraven 30 1-15.
FI20065405A 2006-06-14 2006-06-14 Process för framställning av polyolefiner FI121426B (sv)

Priority Applications (15)

Application Number Priority Date Filing Date Title
FI20065405A FI121426B (sv) 2006-06-14 2006-06-14 Process för framställning av polyolefiner
BRPI0713262A BRPI0713262B1 (pt) 2006-06-14 2007-06-14 processo para a produção de oligômeros de olefina
KR1020097000726A KR101166477B1 (ko) 2006-06-14 2007-06-14 올레핀 소중합체 제조 방법
EP07788742.0A EP2029701B2 (en) 2006-06-14 2007-06-14 Process for the manufacture of olefin oligomers
RU2009100932/04A RU2437920C2 (ru) 2006-06-14 2007-06-14 Способ получения олефиновых олигомеров
CA2654940A CA2654940C (en) 2006-06-14 2007-06-14 Process for the manufacture of olefin oligomers
MYPI20085055A MY150103A (en) 2006-06-14 2007-06-14 Process for the manufacture of olefin oligomers
MX2008015844A MX2008015844A (es) 2006-06-14 2007-06-14 Proceso para la manufactura de oligomeros de olefinas.
AU2007259108A AU2007259108B2 (en) 2006-06-14 2007-06-14 Process for the manufacture of olefin oligomers
PCT/FI2007/050357 WO2007144474A1 (en) 2006-06-14 2007-06-14 Process for the manufacture of olefin oligomers
JP2009514830A JP2009539945A (ja) 2006-06-14 2007-06-14 オレフィンオリゴマーの製造方法
CN2007800268475A CN101490218B (zh) 2006-06-14 2007-06-14 制备烯烃低聚物的方法
IL195733A IL195733A (en) 2006-06-14 2008-12-04 Procedure for the production of carbon-saturated oligomers
ZA200810485A ZA200810485B (en) 2006-06-14 2008-12-10 Process for the manufacture of olefin oligomers
JP2013175655A JP5715207B2 (ja) 2006-06-14 2013-08-27 オレフィンオリゴマーの製造方法

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CN103282331A (zh) * 2011-01-13 2013-09-04 出光兴产株式会社 烯烃低聚物混合物的制造方法
RU2570650C1 (ru) * 2015-02-26 2015-12-10 Открытое акционерное общество "Нефтяная компания "Роснефть" Способ получения олигомеров альфа-олефина c6, c8 или c10
CN109020774A (zh) * 2018-10-23 2018-12-18 浙江捷达科技有限公司 一种十八烷的正构烷烃制备方法
CN113365965A (zh) * 2019-01-31 2021-09-07 巴斯夫欧洲公司 用于烯烃二聚的催化法
SG10202004243TA (en) * 2019-05-14 2020-12-30 Evonik Operations Gmbh Process for the oligomerization of olefins with control of the oligomer content in the hydrocarbon streams to be oligomerized
US20220289644A1 (en) * 2019-08-09 2022-09-15 Exxonmobil Chemical Patents Inc. Processes for producing poly alpha olefins and apparatuses therefor
FI129793B (sv) 2021-06-15 2022-08-31 Neste Oyj Förfarande och anordning för framställning av polyalfaolefiner

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3702886A (en) 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
US5053569A (en) * 1990-03-28 1991-10-01 Texaco Chemical Company Process for oligomerizing olefins to prepare base stocks for synthetic lubricants
WO1993000165A1 (en) * 1991-06-21 1993-01-07 Mobil Oil Corporation Olefin oligomerization process
FI96852C (sv) * 1992-12-10 1996-09-10 Neste Oy Förfarande och anläggning för oligomerisering av olefiner
US6284104B1 (en) * 1999-03-04 2001-09-04 Catalytic Distillation Technologies Apparatus and process for hydrogenations
US6274783B1 (en) * 2000-03-20 2001-08-14 Catalytic Distillation Technologies Catalytic distillation process for the production of C8 alkanes
US6703356B1 (en) * 2000-03-23 2004-03-09 Exxonmobil Research And Engineering Company Synthetic hydrocarbon fluids
DE10015002A1 (de) 2000-03-25 2001-09-27 Basf Ag Verfahren zur Herstellung von Oligomeren
US6518473B2 (en) * 2001-01-11 2003-02-11 Chevron U.S.A. Inc. Dimerizing olefins to make lube base stocks
US6734328B1 (en) * 2002-11-08 2004-05-11 Catalytic Distillation Technologies Process for the selective hydrogenation of alkynes
US7329788B2 (en) * 2003-12-22 2008-02-12 Neste Oil Oyj Process for producing gasoline components
HUE061093T2 (hu) 2004-12-28 2023-05-28 Neste Oyj Eljárás katalitikus anyagok elõállítására
US8299312B2 (en) * 2005-10-28 2012-10-30 Neste Oil Oyj Process for dimerizing olefins

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EP2029701B2 (en) 2021-10-20
MY150103A (en) 2013-11-29
AU2007259108A1 (en) 2007-12-21
BRPI0713262B1 (pt) 2018-11-13
MX2008015844A (es) 2009-01-12
CN101490218A (zh) 2009-07-22
WO2007144474A1 (en) 2007-12-21
FI20065405A0 (sv) 2006-06-14
AU2007259108B2 (en) 2011-03-24
IL195733A (en) 2013-03-24
EP2029701A4 (en) 2011-11-16
KR20090031901A (ko) 2009-03-30
RU2437920C2 (ru) 2011-12-27
KR101166477B1 (ko) 2012-07-23
RU2009100932A (ru) 2010-07-20
EP2029701A1 (en) 2009-03-04
IL195733A0 (en) 2009-09-01
JP2014001229A (ja) 2014-01-09
CN101490218B (zh) 2013-03-27
FI20065405A (sv) 2007-12-15
JP2009539945A (ja) 2009-11-19
BRPI0713262A2 (pt) 2012-04-10
CA2654940A1 (en) 2007-12-21
CA2654940C (en) 2012-04-17
EP2029701B1 (en) 2015-08-05
JP5715207B2 (ja) 2015-05-07

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