FI118735B - Förfarande för framställning av peroxisyror - Google Patents
Förfarande för framställning av peroxisyror Download PDFInfo
- Publication number
- FI118735B FI118735B FI20050913A FI20050913A FI118735B FI 118735 B FI118735 B FI 118735B FI 20050913 A FI20050913 A FI 20050913A FI 20050913 A FI20050913 A FI 20050913A FI 118735 B FI118735 B FI 118735B
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- FI
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- acid
- solution
- weight
- amount
- carboxylic
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- 150000004965 peroxy acids Chemical class 0.000 title claims abstract description 77
- 238000000034 method Methods 0.000 title claims abstract description 22
- 230000008569 process Effects 0.000 title claims abstract description 19
- 238000002360 preparation method Methods 0.000 title abstract description 7
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims abstract description 116
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 86
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims abstract description 58
- 235000019253 formic acid Nutrition 0.000 claims abstract description 58
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims abstract description 29
- 239000000645 desinfectant Substances 0.000 claims abstract description 13
- 244000005700 microbiome Species 0.000 claims abstract description 4
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 claims description 97
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 74
- 239000002253 acid Substances 0.000 claims description 54
- 239000000203 mixture Substances 0.000 claims description 29
- 235000011054 acetic acid Nutrition 0.000 claims description 20
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 13
- -1 dipicolinic acid Chemical compound 0.000 claims description 11
- 150000001735 carboxylic acids Chemical class 0.000 claims description 10
- 239000003381 stabilizer Substances 0.000 claims description 10
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 9
- WJJMNDUMQPNECX-UHFFFAOYSA-N dipicolinic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=N1 WJJMNDUMQPNECX-UHFFFAOYSA-N 0.000 claims description 8
- 230000012010 growth Effects 0.000 claims description 8
- 230000000813 microbial effect Effects 0.000 claims description 8
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 8
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 7
- 239000003054 catalyst Substances 0.000 claims description 7
- 238000004659 sterilization and disinfection Methods 0.000 claims description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 6
- 239000011707 mineral Substances 0.000 claims description 6
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000001630 malic acid Substances 0.000 claims description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 4
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 4
- 239000001530 fumaric acid Substances 0.000 claims description 4
- 239000011976 maleic acid Substances 0.000 claims description 4
- 235000011090 malic acid Nutrition 0.000 claims description 4
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 3
- 235000006408 oxalic acid Nutrition 0.000 claims description 3
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical group [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims description 3
- SIOXPEMLGUPBBT-UHFFFAOYSA-N picolinic acid Chemical compound OC(=O)C1=CC=CC=N1 SIOXPEMLGUPBBT-UHFFFAOYSA-N 0.000 claims description 3
- CZPZWMPYEINMCF-UHFFFAOYSA-N propaneperoxoic acid Chemical compound CCC(=O)OO CZPZWMPYEINMCF-UHFFFAOYSA-N 0.000 claims description 3
- 235000019260 propionic acid Nutrition 0.000 claims description 3
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 3
- 239000002351 wastewater Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 150000007524 organic acids Chemical group 0.000 claims description 2
- 101100289061 Drosophila melanogaster lili gene Proteins 0.000 claims 1
- LJGHYPLBDBRCRZ-UHFFFAOYSA-N 3-(3-aminophenyl)sulfonylaniline Chemical compound NC1=CC=CC(S(=O)(=O)C=2C=C(N)C=CC=2)=C1 LJGHYPLBDBRCRZ-UHFFFAOYSA-N 0.000 abstract 3
- 239000000243 solution Substances 0.000 description 101
- 238000006243 chemical reaction Methods 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 8
- 238000011065 in-situ storage Methods 0.000 description 7
- 238000003860 storage Methods 0.000 description 7
- 150000007513 acids Chemical class 0.000 description 6
- 239000000123 paper Substances 0.000 description 6
- 239000003139 biocide Substances 0.000 description 5
- 150000002978 peroxides Chemical class 0.000 description 5
- 241000196324 Embryophyta Species 0.000 description 4
- 239000003377 acid catalyst Substances 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 239000007844 bleaching agent Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 230000009257 reactivity Effects 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 3
- 230000003115 biocidal effect Effects 0.000 description 3
- 238000004061 bleaching Methods 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 3
- 235000013365 dairy product Nutrition 0.000 description 3
- 238000006731 degradation reaction Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 235000015097 nutrients Nutrition 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000845 anti-microbial effect Effects 0.000 description 2
- 238000003556 assay Methods 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 230000002779 inactivation Effects 0.000 description 2
- 229920005610 lignin Polymers 0.000 description 2
- 230000003389 potentiating effect Effects 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 230000035899 viability Effects 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- SQERDRRMCKKWIL-UHFFFAOYSA-N 2-hydroperoxy-2-oxoacetic acid Chemical compound OOC(=O)C(O)=O SQERDRRMCKKWIL-UHFFFAOYSA-N 0.000 description 1
- CNJLMVZFWLNOEP-UHFFFAOYSA-N 4,7,7-trimethylbicyclo[4.1.0]heptan-5-one Chemical compound O=C1C(C)CCC2C(C)(C)C12 CNJLMVZFWLNOEP-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 241000959949 Deinococcus geothermalis Species 0.000 description 1
- 235000015854 Heliotropium curassavicum Nutrition 0.000 description 1
- 244000301682 Heliotropium curassavicum Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 241000921347 Meiothermus Species 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- YZCKVEUIGOORGS-IGMARMGPSA-N Protium Chemical compound [1H] YZCKVEUIGOORGS-IGMARMGPSA-N 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 description 1
- 238000007171 acid catalysis Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000003808 active oxygen stabilizer Substances 0.000 description 1
- 230000005791 algae growth Effects 0.000 description 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 230000000843 anti-fungal effect Effects 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000003385 bacteriostatic effect Effects 0.000 description 1
- 244000309464 bull Species 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000007809 chemical reaction catalyst Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000003657 drainage water Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000003898 horticulture Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 229920000137 polyphosphoric acid Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000004076 pulp bleaching Methods 0.000 description 1
- 238000004537 pulping Methods 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 230000009182 swimming Effects 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
- C07C407/003—Separation; Purification; Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group; Thio analogues thereof
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/722—Oxidation by peroxides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/24—Peroxy compounds the —O—O— group being bound between a >C=O group and hydrogen, i.e. peroxy acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/24—Peroxy compounds the —O—O— group being bound between a >C=O group and hydrogen, i.e. peroxy acids
- C07C409/26—Peracetic acid
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/24—Peroxy compounds the —O—O— group being bound between a >C=O group and hydrogen, i.e. peroxy acids
- C07C409/30—Peroxy compounds the —O—O— group being bound between a >C=O group and hydrogen, i.e. peroxy acids a >C=O group being bound to a carbon atom of a six-membered aromatic ring
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/02—Agents for preventing deposition on the paper mill equipment, e.g. pitch or slime control
- D21H21/04—Slime-control agents
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Environmental Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Inorganic Chemistry (AREA)
Claims (21)
1. Förfarande för att framställa en lösning, vilken lösning innefattar en första peroxisyra, innefattande permyrsyra, och en andra peroxisyra, varvid vid nämnda förfarande bildas en karboxylsyralösning, innefattande en första karboxyisyra, 10 innefattande myrsyra, en andra karboxyisyra och väteperoxid, varvid myrsyran utgör 0,5-20 viktprocent beräknat pä den andra karboxylsyrans mängd, och kom-ponenterna fär reagera, sä att det bildas en lösning som innefattar permyrsyra och nämnda andra peroxisyra, varvid peroxisyrornas mängd utgör minst 5 viktprocent.
2. Förfarande enligt patentkrav 1, varvid peroxisyrornas mängd i erhällna lös-15 ning utgör 5-20 viktprocent.
3. Förfarande enligt patentkrav 1 eller 2, varvid molförhällandet mellan karboxyl-syrorna och väteperoxiden i karboxylsyralösningen är 0,5:1-8:1, företrädesvis 0,7:1-2:1.
• * · : 4. Förfarande enligt nägot av patentkraven 1-3, varvid erhällna lösning är en ·:·*: 20 jämviktslösning, innefattande dessutom myrsyra, den andra karboxylsyran och :T: Väteperoxid. • ·· • ·
5. Förfarande enligt patentkrav 4, varvid mängden myrsyra och permyrsyra i jämviktslösningen är 2-20 viktprocent. • * • * ···
6. Förfarande enligt nägot av patentkraven 1-5, varvid nämnda andra karboxyl- f... 25 syra är ättikssyra, propionsyra, ftalsyra, oxalsyra, äppelsyra, maleinsyra eller ,···. fumarsyra eller en blandning av dessa, och nämnda andra peroxisyra är *"t perättikssyra, perpropionsyra, peroxiftalsyra, peroxioxalsyra, peroxiäppelsyra, "**: peroximaleinsyra eller peroxifumarsyra eller en blandning av dessa.
«*· • · • · «** .· . 7. Förfarande enligt nägot av patentkraven 1-6, varvid en katalysator tillsätts • t · *· " 30 lösningen. • · ΊΙΛ' ·Μ«' t .·— ··«' .·. ««* .- .-·*Λ· “--------------1............m Π 1 11 n i~ i i ι i ...................- i Ιί i irm-ni uhMmihmihhmjbh imu m .ι.,ηπ.- - i -tiiimwbiiikiiji. imi u mu i ......_____m . ι .1 .1,.,11.,.1, ......... ji ji _t_ium n.u u iU 118735
8. Förfarande enligt patentkrav 7, varvid katalysatorn är en mineralsyra, företrä-desvis svavelsyra eller klorvätesyra eller en blandning av dessa.
9. Förfarande enligt patentkrav 7, varvid katalysatorn är en organisk syra, företrädesvis myrsyra. 5
10. Förfarande enligt nägot av patentkraven 1-9, varvid ett stabiliseringsmedel tillsätts lösningen.
11. Förfarande enligt patentkrav 10, varvid stabiliseringsmedlet är ett fosfonat, säsom 1-hydroxietylen-1,1-difosfonsyra, eller en pyridinkarboxylsyra, säsom dipikolinsyra, eller en blandning av dessa.
12. Lagringsduglig lösning som innefattar en första peroxisyra, innefattande per- myrsyra, en andra peroxisyra, en första karboxylsyra, innefattande myrsyra, en andra karboxylsyra och väteperoxid, varvid myrsyrans och permyrsyrans mängd är 0,5-20 viktprocent beräknat pä den andra karboxylsyrans och den andra peroxisyrans totala mängd, och peroxisyrornas mängd är minst 5 viktprocent. 15
13. Lösning enligt patentkrav 12, varvid peroxisyrornas mängd i lösningen utgör 5-20 viktprocent.
14. Lösning enligt patentkrav 12 eller 13, varvid peroxisyrornas och karboxyl-syrornas molförhällande tili väteperoxid är 0,5:1-8:1, företrädesvis 0,7:1-2:1.
·· · • · · : \ 15. Lösning enligt nägot av patentkraven 12-14, varvid lösningen är en jämvikts- 20 lösning.
• ♦ · • · ♦ :***; 16. Lösning enligt nägot av patentkraven 12-15, varvid myrsyrans och permyr- ··1 : .·. syrans mängd i lösningen utgör 2-20 viktprocent.
··· · • · · *···: 17. Lösning enligt nägot av patentkraven 12-16, varvid nämnda andra karboxyl syra är ättikssyra, propionsyra, ftalsyra, oxalsyra, äppelsyra, maleinsyra eller • 1·· 25 fumarsyra eller en blandning av dessa, och nämnda andra peroxisyra är perättiks- syra, perpropionsyra, peroxiftalsyra, peroxioxalsyra, peroxiäppelsyra, peroxi-maleinsyra eller peroxifumarsyra eller en blandning av dessa. • ♦
18. Lösning enligt nägot av patentkraven 12-17, innefattande dessutom ett : stabiliseringsmedel. • ·# w ·· · . n. uj >|i.iu m tmviWWlUllUM/l—.»« wnrai’H.lili'lwil«wiliw>.lM··-»·· ·ιιι.·ι»ιι·ι·ί·η·^>-^.^,· I I —-i- Hi VwinmL"3il1IWTO13tJT.<; · 118735
19. Lösning enligt patentkrav 18, varvid stabiliseringsmedlet är ett fosfonat, säsom 1“hydroxietylen-1,1-difosfonsyra, eller en pyridinkarboxylsyra, sasom dipikolinsyra, eller en blandning av dessa.
20. Användning av en lösning enligt nägot av patentkraven 12-19 som desinfek-5 tionsmedel för bekämpning av mikroorganismer.
21. Användning enligt patentkrav 20 för desinfektion av växthus eller desinfektion av avloppsvatten eller för bekämpning av mikrobtillväxt pä pappersmaskiner. ·· · · · • · • 1 • · **♦ • · » • · a Ψ • · 1 • · • · »«I • · « · · « · · 1«· · • · · • · • · ··· ·· • · • ·· • « · • · • · • · ♦ a ·«« • 1 • a * · · * · • t · • ·1 • ·
Priority Applications (13)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI20050913A FI118735B (sv) | 2005-09-13 | 2005-09-13 | Förfarande för framställning av peroxisyror |
| CA2627597A CA2627597C (en) | 2005-09-13 | 2006-09-13 | Process for the preparation of peroxy acids |
| JP2008530553A JP2009507903A (ja) | 2005-09-13 | 2006-09-13 | 過酸の調製方法 |
| BRPI0615696-7A BRPI0615696A2 (pt) | 2005-09-13 | 2006-09-13 | processo para a preparação de peroxiácidos |
| AT06778512T ATE489362T1 (de) | 2005-09-13 | 2006-09-13 | Verfahren zur darstellung von peroxysäuren |
| KR1020087006098A KR101325236B1 (ko) | 2005-09-13 | 2006-09-13 | 과산화산의 제조 방법 |
| PCT/FI2006/000303 WO2007031596A2 (en) | 2005-09-13 | 2006-09-13 | Process for the preparation of peroxy acids |
| US12/066,686 US8828910B2 (en) | 2005-09-13 | 2006-09-13 | Process for the preparation of peroxy acids |
| ES06778512T ES2359261T3 (es) | 2005-09-13 | 2006-09-13 | Procedimiento para la preparación de peroxiácidos. |
| CN2006800335742A CN101268045B (zh) | 2005-09-13 | 2006-09-13 | 过氧酸的制备方法 |
| DE602006018491T DE602006018491D1 (sv) | 2005-09-13 | 2006-09-13 | |
| EP06778512A EP1931628B1 (en) | 2005-09-13 | 2006-09-13 | Process for the preparation of peroxy acids |
| NO20080974A NO340754B1 (no) | 2005-09-13 | 2008-02-26 | Fremgangsmåte for fremstilling av peroksysyrer, løsning som kan lagres og anvendelse derav |
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| FI20050913A FI118735B (sv) | 2005-09-13 | 2005-09-13 | Förfarande för framställning av peroxisyror |
| FI20050913 | 2005-09-13 |
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| FI20050913A0 FI20050913A0 (sv) | 2005-09-13 |
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| EP (1) | EP1931628B1 (sv) |
| JP (1) | JP2009507903A (sv) |
| KR (1) | KR101325236B1 (sv) |
| CN (1) | CN101268045B (sv) |
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| BR (1) | BRPI0615696A2 (sv) |
| CA (1) | CA2627597C (sv) |
| DE (1) | DE602006018491D1 (sv) |
| ES (1) | ES2359261T3 (sv) |
| FI (1) | FI118735B (sv) |
| NO (1) | NO340754B1 (sv) |
| WO (1) | WO2007031596A2 (sv) |
Families Citing this family (42)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101801521B (zh) | 2007-05-14 | 2015-06-17 | 纽约州立大学研究基金会 | 生物膜中细菌细胞内的生理学分散响应诱导 |
| US8809392B2 (en) | 2008-03-28 | 2014-08-19 | Ecolab Usa Inc. | Sulfoperoxycarboxylic acids, their preparation and methods of use as bleaching and antimicrobial agents |
| US8871807B2 (en) | 2008-03-28 | 2014-10-28 | Ecolab Usa Inc. | Detergents capable of cleaning, bleaching, sanitizing and/or disinfecting textiles including sulfoperoxycarboxylic acids |
| WO2009118714A2 (en) | 2008-03-28 | 2009-10-01 | Ecolab Inc. | Sulfoperoxycarboxylic acids, their preparation and methods of use as bleaching and antimicrobial agents |
| US20110311645A1 (en) * | 2010-06-16 | 2011-12-22 | Diaz Raul O | Microbiological control in oil and gas operations |
| EP2615932B1 (en) | 2010-09-14 | 2021-09-08 | Pimi Agro Cleantech Ltd. (Israel) | Methods of treating edible matter and substrates therefor |
| US8933263B2 (en) | 2010-12-29 | 2015-01-13 | Ecolab Usa Inc. | Water temperature as a means of controlling kinetics of onsite generated peracids |
| US9321664B2 (en) | 2011-12-20 | 2016-04-26 | Ecolab Usa Inc. | Stable percarboxylic acid compositions and uses thereof |
| PT2609990T (pt) * | 2011-12-30 | 2022-08-25 | Kemira Oyj | Método para prevenção de crescimento microbiano em membrana de filtração |
| CN104254496B (zh) | 2012-03-30 | 2016-10-26 | 艺康美国股份有限公司 | 过乙酸/过氧化氢和过氧化物还原剂用于处理钻井液、压裂液、回流水和排放水的用途 |
| US8835140B2 (en) * | 2012-06-21 | 2014-09-16 | Ecolab Usa Inc. | Methods using peracids for controlling corn ethanol fermentation process infection and yield loss |
| US8822719B1 (en) | 2013-03-05 | 2014-09-02 | Ecolab Usa Inc. | Peroxycarboxylic acid compositions suitable for inline optical or conductivity monitoring |
| US10165774B2 (en) | 2013-03-05 | 2019-01-01 | Ecolab Usa Inc. | Defoamer useful in a peracid composition with anionic surfactants |
| US20140256811A1 (en) | 2013-03-05 | 2014-09-11 | Ecolab Usa Inc. | Efficient stabilizer in controlling self accelerated decomposition temperature of peroxycarboxylic acid compositions with mineral acids |
| JP6427334B2 (ja) * | 2014-04-22 | 2018-11-21 | 保土谷化学工業株式会社 | 非腐食性過酢酸製剤とその製造方法 |
| FI126082B (sv) | 2014-07-15 | 2016-06-15 | Kemira Oyj | Förfarande för att förebygga slambildning |
| WO2016100700A1 (en) | 2014-12-18 | 2016-06-23 | Ecolab Usa Inc. | Methods for forming peroxyformic acid and uses thereof |
| CA2971411C (en) | 2014-12-18 | 2022-03-22 | Ecolab Usa Inc. | Generation of peroxyformic acid through polyhydric alcohol formate |
| US11040902B2 (en) | 2014-12-18 | 2021-06-22 | Ecolab Usa Inc. | Use of percarboxylic acids for scale prevention in treatment systems |
| FI127444B (sv) * | 2015-05-27 | 2018-06-15 | Kemira Oyj | Förfarande för att minska massans viskositet i framställning av dissolvingmassa |
| CN104961209A (zh) * | 2015-07-10 | 2015-10-07 | 江苏鸿佑环保有限公司 | 污水高效无氯消毒杀菌系统 |
| CN104944540A (zh) * | 2015-07-10 | 2015-09-30 | 江苏鸿佑环保有限公司 | 智能化自来水无氯消毒杀菌系统 |
| CN104973666B (zh) * | 2015-07-10 | 2017-07-04 | 江苏鸿佑环保有限公司 | 智能化污水无氯消毒杀菌系统 |
| CN104944539A (zh) * | 2015-07-10 | 2015-09-30 | 江苏鸿佑环保有限公司 | 自来水无氯消毒杀菌系统 |
| US9814796B2 (en) | 2015-07-31 | 2017-11-14 | Performance Packaging Of Nevada, Llc | Methods for sterilization and/or disinfection |
| US10172351B2 (en) | 2015-09-04 | 2019-01-08 | Ecolab Usa Inc. | Performic acid on-site generator and formulator |
| US10285401B2 (en) | 2015-09-10 | 2019-05-14 | Ecolab Usa Inc. | Self indicating antimicrobial chemistry |
| BR112018007928A2 (pt) | 2015-11-12 | 2018-10-30 | Ecolab Usa Inc. | método para inibir corrosão, e, composição. |
| WO2017106623A1 (en) | 2015-12-16 | 2017-06-22 | Ecolab Usa Inc. | Peroxyformic acid compositions for membrane filtration cleaning |
| US9907305B2 (en) | 2016-03-22 | 2018-03-06 | Solvay Sa | Production of disinfecting solutions |
| WO2017181005A1 (en) | 2016-04-15 | 2017-10-19 | Ecolab Usa Inc. | Performic acid biofilm prevention for industrial co2 scrubbers |
| WO2018111341A1 (en) | 2016-12-15 | 2018-06-21 | Ecolab Usa Inc. | Peroxyformic acid compositions for membrane filtration cleaning in energy services |
| US11541105B2 (en) | 2018-06-01 | 2023-01-03 | The Research Foundation For The State University Of New York | Compositions and methods for disrupting biofilm formation and maintenance |
| CN112312769A (zh) | 2018-06-15 | 2021-02-02 | 埃科莱布美国股份有限公司 | 用于乳头治疗的现场产生的过甲酸组合物 |
| AU2019325568B2 (en) * | 2018-08-22 | 2022-03-10 | Ecolab Usa Inc. | Hydrogen peroxide and peracid stabilization with molecules based on a pyridine carboxylic acid at C-3, -4 or -5 |
| CN109535055A (zh) * | 2019-01-10 | 2019-03-29 | 浙江工业大学 | 一种利用微波技术强化过氧酸制备的方法 |
| US11713436B2 (en) | 2019-06-17 | 2023-08-01 | Ecolab Usa Inc. | Textile bleaching and disinfecting using the mixture of hydrophilic and hydrophobic peroxycarboxylic acid composition |
| AU2020315254A1 (en) * | 2019-07-12 | 2022-02-03 | Arxada, LLC | Anti-microbial composition and method of using same |
| EP3797592A1 (en) * | 2019-09-25 | 2021-03-31 | Sani-Marc Inc. | Peracetic compositions, methods and kits for removing biofilms from an enclosed surface |
| KR20230033843A (ko) | 2021-09-02 | 2023-03-09 | 정도성 | 포름산을 이용한 과산화카르복시산의 현장 제조방법 |
| CN115893610A (zh) * | 2022-11-30 | 2023-04-04 | 广东省科学院生物与医学工程研究所 | 一种新型环保净水剂的制备方法及其应用 |
| CN115784393A (zh) * | 2022-11-30 | 2023-03-14 | 广东省科学院生物与医学工程研究所 | 过甲酸溶液在制备消毒剂中的应用 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4304762A (en) * | 1978-09-27 | 1981-12-08 | Lever Brothers Company | Stabilization of hydrogen peroxide |
| GB8531384D0 (en) | 1985-12-20 | 1986-02-05 | Unilever Plc | Sanitizing process |
| US5200189A (en) | 1991-07-23 | 1993-04-06 | Ecolab Inc. | Peroxyacid antimicrobial composition |
| NL9300445A (nl) | 1993-03-12 | 1994-10-03 | Kemira Peroxides Bv | Werkwijze voor het ontsmetten van water zoals "drain water" in de tuinbouw, alsmede daarbij toe te passen inrichting. |
| DE19812591A1 (de) | 1998-03-23 | 1999-09-30 | Degussa | Verfahren zur Bekämpfung pflanzenpathogener Mikroorganismen in Wasserkreisläufen von Gewächshäusern |
| DE19812589A1 (de) | 1998-03-23 | 1999-10-07 | Degussa | Perameisensäure enthaltendes wäßriges Desinfektionsmittel, Verfahren zu dessen Herstellung und deren Verwendung |
| DE19856071A1 (de) * | 1998-12-04 | 2000-06-15 | Degussa | Verfahren zur Vermeidung einer Gewässerkontamination mit ortsfremden Organismen |
| DE19856198A1 (de) | 1998-12-05 | 2000-06-08 | Degussa | Verfahren zur Schwimmbadwasseraufbereitung |
| US6955766B2 (en) | 1999-11-24 | 2005-10-18 | Degussa Ag | Method for reducing harmful organisms in currents of water |
| FR2814180B1 (fr) | 2000-09-18 | 2003-12-05 | Michel Delmas | Procede de blanchiment de pates a papier en milieu organique a hydratation controlee |
| KR101388611B1 (ko) * | 2002-10-16 | 2014-04-23 | 퍼듀 퍼머 엘피 | 세포-연관된 ｃａ 125/ｏ772ｐ에 결합하는 항체들 및 그것의 용도의 방법들 |
| FI117056B (sv) | 2003-11-06 | 2006-05-31 | Kemira Oyj | Förfarande för övervakning av närvaro av biofilm bildande mikroorganismer vid pappersindustrin |
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2006
- 2006-09-13 KR KR1020087006098A patent/KR101325236B1/ko active IP Right Grant
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- 2006-09-13 ES ES06778512T patent/ES2359261T3/es active Active
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- 2006-09-13 BR BRPI0615696-7A patent/BRPI0615696A2/pt not_active IP Right Cessation
- 2006-09-13 AT AT06778512T patent/ATE489362T1/de not_active IP Right Cessation
- 2006-09-13 EP EP06778512A patent/EP1931628B1/en active Active
- 2006-09-13 US US12/066,686 patent/US8828910B2/en active Active
- 2006-09-13 WO PCT/FI2006/000303 patent/WO2007031596A2/en active Application Filing
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- 2006-09-13 JP JP2008530553A patent/JP2009507903A/ja not_active Withdrawn
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Also Published As
| Publication number | Publication date |
|---|---|
| ES2359261T3 (es) | 2011-05-19 |
| FI20050913A (sv) | 2007-03-14 |
| DE602006018491D1 (sv) | 2011-01-05 |
| KR20080049738A (ko) | 2008-06-04 |
| NO340754B1 (no) | 2017-06-12 |
| US20090221704A1 (en) | 2009-09-03 |
| US8828910B2 (en) | 2014-09-09 |
| WO2007031596A3 (en) | 2007-06-07 |
| JP2009507903A (ja) | 2009-02-26 |
| NO20080974L (no) | 2008-05-29 |
| CA2627597A1 (en) | 2007-03-22 |
| EP1931628B1 (en) | 2010-11-24 |
| CN101268045A (zh) | 2008-09-17 |
| CN101268045B (zh) | 2011-04-13 |
| ATE489362T1 (de) | 2010-12-15 |
| WO2007031596A2 (en) | 2007-03-22 |
| BRPI0615696A2 (pt) | 2012-04-10 |
| FI20050913A0 (sv) | 2005-09-13 |
| CA2627597C (en) | 2013-10-22 |
| EP1931628A2 (en) | 2008-06-18 |
| KR101325236B1 (ko) | 2013-11-04 |
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