FI104739B - Menetelmä ei-rautametallien talteenottamiseksi sula- ja sulakalvosulfatoinnilla - Google Patents
Menetelmä ei-rautametallien talteenottamiseksi sula- ja sulakalvosulfatoinnilla Download PDFInfo
- Publication number
- FI104739B FI104739B FI981279A FI981279A FI104739B FI 104739 B FI104739 B FI 104739B FI 981279 A FI981279 A FI 981279A FI 981279 A FI981279 A FI 981279A FI 104739 B FI104739 B FI 104739B
- Authority
- FI
- Finland
- Prior art keywords
- iron
- sulfate
- iii
- melt
- solution
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 61
- 238000005670 sulfation reaction Methods 0.000 title claims description 32
- 230000019635 sulfation Effects 0.000 title claims description 27
- 229910052751 metal Inorganic materials 0.000 title claims description 24
- 239000002184 metal Substances 0.000 title claims description 24
- -1 ferrous metals Chemical class 0.000 title claims description 13
- 238000011084 recovery Methods 0.000 title claims description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 75
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 41
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 41
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 37
- 239000011734 sodium Substances 0.000 claims description 36
- 239000000203 mixture Substances 0.000 claims description 34
- 238000001556 precipitation Methods 0.000 claims description 34
- 229910052742 iron Inorganic materials 0.000 claims description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 29
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 claims description 29
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 29
- 239000000347 magnesium hydroxide Substances 0.000 claims description 29
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 29
- 230000003179 granulation Effects 0.000 claims description 28
- 238000005469 granulation Methods 0.000 claims description 28
- 229910000360 iron(III) sulfate Inorganic materials 0.000 claims description 24
- 229910052783 alkali metal Inorganic materials 0.000 claims description 23
- 150000001340 alkali metals Chemical class 0.000 claims description 23
- 239000000463 material Substances 0.000 claims description 23
- 229910052708 sodium Inorganic materials 0.000 claims description 23
- 239000002244 precipitate Substances 0.000 claims description 20
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 18
- 238000006243 chemical reaction Methods 0.000 claims description 17
- 239000012071 phase Substances 0.000 claims description 17
- 229910052700 potassium Inorganic materials 0.000 claims description 17
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 16
- 229910052935 jarosite Inorganic materials 0.000 claims description 16
- 239000010949 copper Substances 0.000 claims description 14
- 239000011777 magnesium Substances 0.000 claims description 14
- 239000011572 manganese Substances 0.000 claims description 14
- 239000000155 melt Substances 0.000 claims description 14
- 229910052782 aluminium Inorganic materials 0.000 claims description 13
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 13
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 12
- 229910052749 magnesium Inorganic materials 0.000 claims description 12
- 239000011701 zinc Substances 0.000 claims description 12
- 229910052936 alkali metal sulfate Inorganic materials 0.000 claims description 11
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 claims description 11
- 238000002844 melting Methods 0.000 claims description 11
- 230000008018 melting Effects 0.000 claims description 11
- 230000003472 neutralizing effect Effects 0.000 claims description 11
- 229910052759 nickel Inorganic materials 0.000 claims description 11
- 238000000926 separation method Methods 0.000 claims description 11
- 230000015572 biosynthetic process Effects 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 150000002739 metals Chemical class 0.000 claims description 10
- 239000011541 reaction mixture Substances 0.000 claims description 9
- 239000007787 solid Substances 0.000 claims description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
- 229910052802 copper Inorganic materials 0.000 claims description 8
- 229910052595 hematite Inorganic materials 0.000 claims description 8
- 239000011019 hematite Substances 0.000 claims description 8
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 8
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 7
- 238000005406 washing Methods 0.000 claims description 7
- 238000004090 dissolution Methods 0.000 claims description 6
- 229910052748 manganese Inorganic materials 0.000 claims description 6
- 239000007858 starting material Substances 0.000 claims description 6
- 229910052725 zinc Inorganic materials 0.000 claims description 6
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 5
- 150000002736 metal compounds Chemical class 0.000 claims description 5
- 230000001590 oxidative effect Effects 0.000 claims description 5
- 238000005979 thermal decomposition reaction Methods 0.000 claims description 5
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 4
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 3
- 239000011230 binding agent Substances 0.000 claims description 3
- 239000010941 cobalt Substances 0.000 claims description 3
- 229910017052 cobalt Inorganic materials 0.000 claims description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 238000005342 ion exchange Methods 0.000 claims description 3
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 3
- 238000000622 liquid--liquid extraction Methods 0.000 claims description 3
- 239000007790 solid phase Substances 0.000 claims description 3
- 238000000638 solvent extraction Methods 0.000 claims description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- 238000002203 pretreatment Methods 0.000 claims description 2
- 239000002893 slag Substances 0.000 claims description 2
- CBXWGGFGZDVPNV-UHFFFAOYSA-N so4-so4 Chemical compound OS(O)(=O)=O.OS(O)(=O)=O CBXWGGFGZDVPNV-UHFFFAOYSA-N 0.000 claims description 2
- 235000008331 Pinus X rigitaeda Nutrition 0.000 claims 1
- 235000011613 Pinus brutia Nutrition 0.000 claims 1
- 241000018646 Pinus brutia Species 0.000 claims 1
- 230000000052 comparative effect Effects 0.000 claims 1
- 239000007791 liquid phase Substances 0.000 claims 1
- 238000007669 thermal treatment Methods 0.000 claims 1
- 239000000243 solution Substances 0.000 description 58
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 21
- 238000002386 leaching Methods 0.000 description 21
- 239000008187 granular material Substances 0.000 description 16
- 229910052938 sodium sulfate Inorganic materials 0.000 description 16
- 235000011152 sodium sulphate Nutrition 0.000 description 16
- 238000001704 evaporation Methods 0.000 description 10
- 239000000047 product Substances 0.000 description 10
- 230000008020 evaporation Effects 0.000 description 9
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 8
- 239000000920 calcium hydroxide Substances 0.000 description 8
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 8
- 239000012141 concentrate Substances 0.000 description 8
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 229910052602 gypsum Inorganic materials 0.000 description 6
- 239000010440 gypsum Substances 0.000 description 6
- 230000001180 sulfating effect Effects 0.000 description 6
- 229910000859 α-Fe Inorganic materials 0.000 description 6
- 239000003153 chemical reaction reagent Substances 0.000 description 5
- 229910052681 coesite Inorganic materials 0.000 description 5
- 229910052906 cristobalite Inorganic materials 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 239000012528 membrane Substances 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 229910052682 stishovite Inorganic materials 0.000 description 5
- 229910052905 tridymite Inorganic materials 0.000 description 5
- 229910020598 Co Fe Inorganic materials 0.000 description 4
- 229910017709 Ni Co Inorganic materials 0.000 description 4
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- 229910052593 corundum Inorganic materials 0.000 description 4
- 150000004679 hydroxides Chemical class 0.000 description 4
- 238000006386 neutralization reaction Methods 0.000 description 4
- 239000010970 precious metal Substances 0.000 description 4
- 235000011149 sulphuric acid Nutrition 0.000 description 4
- 229910001845 yogo sapphire Inorganic materials 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- 229910002588 FeOOH Inorganic materials 0.000 description 3
- 239000011790 ferrous sulphate Substances 0.000 description 3
- 235000003891 ferrous sulphate Nutrition 0.000 description 3
- FWFGVMYFCODZRD-UHFFFAOYSA-N oxidanium;hydrogen sulfate Chemical compound O.OS(O)(=O)=O FWFGVMYFCODZRD-UHFFFAOYSA-N 0.000 description 3
- 238000001757 thermogravimetry curve Methods 0.000 description 3
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- 229910017521 Cu Ni Co Fe Inorganic materials 0.000 description 2
- 229910003251 Na K Inorganic materials 0.000 description 2
- 239000007832 Na2SO4 Substances 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 150000001339 alkali metal compounds Chemical class 0.000 description 2
- 229940037003 alum Drugs 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 2
- 229910052939 potassium sulfate Inorganic materials 0.000 description 2
- 235000011151 potassium sulphates Nutrition 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 101100348017 Drosophila melanogaster Nazo gene Proteins 0.000 description 1
- 241000207961 Sesamum Species 0.000 description 1
- 235000003434 Sesamum indicum Nutrition 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- VDQVEACBQKUUSU-UHFFFAOYSA-M disodium;sulfanide Chemical compound [Na+].[Na+].[SH-] VDQVEACBQKUUSU-UHFFFAOYSA-M 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- MKMHAWWAWWQANQ-UHFFFAOYSA-K hydrogen sulfate iron(3+) sulfate Chemical compound [Fe+3].OS([O-])(=O)=O.[O-]S([O-])(=O)=O MKMHAWWAWWQANQ-UHFFFAOYSA-K 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 150000002506 iron compounds Chemical class 0.000 description 1
- 235000014413 iron hydroxide Nutrition 0.000 description 1
- NCNCGGDMXMBVIA-UHFFFAOYSA-L iron(ii) hydroxide Chemical compound [OH-].[OH-].[Fe+2] NCNCGGDMXMBVIA-UHFFFAOYSA-L 0.000 description 1
- 239000012768 molten material Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 150000004682 monohydrates Chemical class 0.000 description 1
- 150000002816 nickel compounds Chemical class 0.000 description 1
- 238000009868 nickel metallurgy Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910052979 sodium sulfide Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- 239000001038 titanium pigment Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/02—Roasting processes
- C22B1/06—Sulfating roasting
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B19/00—Obtaining zinc or zinc oxide
- C22B19/02—Preliminary treatment of ores; Preliminary refining of zinc oxide
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/005—Preliminary treatment of ores, e.g. by roasting or by the Krupp-Renn process
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Compounds Of Iron (AREA)
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI981279A FI104739B (fi) | 1998-06-04 | 1998-06-04 | Menetelmä ei-rautametallien talteenottamiseksi sula- ja sulakalvosulfatoinnilla |
| US09/325,197 US6274104B1 (en) | 1998-06-04 | 1999-06-03 | Non-ferrous metal recovery method utilizing a melt sulphation reaction |
| AU46202/99A AU747980B2 (en) | 1998-06-04 | 1999-06-04 | Melt and melt coating sulphation process |
| CA002333967A CA2333967A1 (en) | 1998-06-04 | 1999-06-04 | Melt and melt coating sulphation process |
| EP99929366A EP1098999A1 (en) | 1998-06-04 | 1999-06-04 | Melt and melt coating sulphation process |
| IDW20002714A ID28078A (id) | 1998-06-04 | 1999-06-04 | Peleburan dan proses sulfasi peleburan pelapisan |
| PCT/FI1999/000486 WO1999063121A1 (en) | 1998-06-04 | 1999-06-04 | Melt and melt coating sulphation process |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI981279 | 1998-06-04 | ||
| FI981279A FI104739B (fi) | 1998-06-04 | 1998-06-04 | Menetelmä ei-rautametallien talteenottamiseksi sula- ja sulakalvosulfatoinnilla |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| FI981279A0 FI981279A0 (fi) | 1998-06-04 |
| FI981279A FI981279A (fi) | 1999-12-05 |
| FI104739B true FI104739B (fi) | 2000-03-31 |
Family
ID=8551910
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI981279A FI104739B (fi) | 1998-06-04 | 1998-06-04 | Menetelmä ei-rautametallien talteenottamiseksi sula- ja sulakalvosulfatoinnilla |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6274104B1 (id) |
| EP (1) | EP1098999A1 (id) |
| AU (1) | AU747980B2 (id) |
| CA (1) | CA2333967A1 (id) |
| FI (1) | FI104739B (id) |
| ID (1) | ID28078A (id) |
| WO (1) | WO1999063121A1 (id) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005007898A2 (en) * | 2003-07-22 | 2005-01-27 | Obschestvo S Ogranichennoy Otvetstvennostyu 'geowest' | Method for processing oxidized nickel-cobalt ore (variants) |
| SE532674C2 (sv) * | 2008-05-13 | 2010-03-16 | Salt Extraction Ab | Förfarande för klorering av malmer, slagger, glödspån, skrot, pulver och andra tillgångar som innehåller utvinnbara metaller |
| CN102787237A (zh) * | 2011-05-20 | 2012-11-21 | 中国科学院广州地球化学研究所 | 一种浸出回收铜尾矿中铁、铜、锌、铅的工艺 |
| CN102367512B (zh) * | 2011-09-07 | 2013-07-10 | 王号德 | 一种红土镍矿含碳球团深还原磁选镍铁方法 |
| WO2014015402A1 (en) * | 2012-07-23 | 2014-01-30 | Vale S.A. | Recovery of base metals from sulphide ores and concentrates |
| CN103114205B (zh) * | 2012-12-07 | 2014-06-25 | 金川集团股份有限公司 | 两步法从黄钠铁矾渣中提取有价金属镍及铜的方法 |
| CN110578056B (zh) * | 2019-08-28 | 2021-07-06 | 江门市长优实业有限公司 | 一种含钴的有色金属冶炼废渣循环利用的方法 |
| US11430997B2 (en) | 2019-11-01 | 2022-08-30 | Battery Reclamation Research Associates Llc | Process for separating and recycling a spent alkaline battery |
| CN110699553B (zh) * | 2019-11-01 | 2021-02-12 | 广西科技师范学院 | 一种从锰硫净化废渣中浸出回收分离镍的方法 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FI65088C (fi) | 1979-05-25 | 1984-03-12 | Pekka Juhani Saikkonen | Foerfarande foer aotervinning av icke-jaernmetaller ur deras mineralier mineralslig oxidiska rostningsprodukter och slagg |
| CA1115961A (en) | 1979-06-14 | 1982-01-12 | Kohur N. Subramanian | Pelletizing sulfation of anode slimes |
| FI83335C (fi) | 1988-03-31 | 1993-06-29 | Pekka Juhani Saikkonen | Foerfarande foer aotervinning av icke-jaernmetaller, speciellt nickel, kobolt, koppar, zink, mangan och magnesium genom smaelt- och smaeltfilmsulfatisering ur raomaterial som innehaoller dessa metaller |
-
1998
- 1998-06-04 FI FI981279A patent/FI104739B/fi active
-
1999
- 1999-06-03 US US09/325,197 patent/US6274104B1/en not_active Expired - Fee Related
- 1999-06-04 ID IDW20002714A patent/ID28078A/id unknown
- 1999-06-04 CA CA002333967A patent/CA2333967A1/en not_active Abandoned
- 1999-06-04 AU AU46202/99A patent/AU747980B2/en not_active Ceased
- 1999-06-04 WO PCT/FI1999/000486 patent/WO1999063121A1/en not_active Application Discontinuation
- 1999-06-04 EP EP99929366A patent/EP1098999A1/en not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| US6274104B1 (en) | 2001-08-14 |
| AU747980B2 (en) | 2002-05-30 |
| CA2333967A1 (en) | 1999-12-09 |
| ID28078A (id) | 2001-05-03 |
| AU4620299A (en) | 1999-12-20 |
| WO1999063121A1 (en) | 1999-12-09 |
| EP1098999A1 (en) | 2001-05-16 |
| FI981279A (fi) | 1999-12-05 |
| FI981279A0 (fi) | 1998-06-04 |
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