ES8704146A1 - Un procedimiento para la preparacion de hidrocarburos por reaccion catalitica de monoxido de carbono con hidrogeno - Google Patents

Un procedimiento para la preparacion de hidrocarburos por reaccion catalitica de monoxido de carbono con hidrogeno

Info

Publication number
ES8704146A1
ES8704146A1 ES550935A ES550935A ES8704146A1 ES 8704146 A1 ES8704146 A1 ES 8704146A1 ES 550935 A ES550935 A ES 550935A ES 550935 A ES550935 A ES 550935A ES 8704146 A1 ES8704146 A1 ES 8704146A1
Authority
ES
Spain
Prior art keywords
hydrocarbons
preparation
catalyst
over
recycle
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES550935A
Other languages
English (en)
Other versions
ES550935A0 (es
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of ES8704146A1 publication Critical patent/ES8704146A1/es
Publication of ES550935A0 publication Critical patent/ES550935A0/es
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B01J23/864—Cobalt and chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913—Cobalt and noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0485—Set-up of reactors or accessories; Multi-step processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/06—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen in the presence of organic compounds, e.g. hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/26—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/75—Cobalt
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S208/00—Mineral oils: processes and products
    • Y10S208/95—Processing of "fischer-tropsch" crude

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PROCEIDMIENTO PARA LA PREPARACION DE HIDROCARBUROS POR REACCION CATALITICA DE MONOXIDO DE CARBONO CON HIDROGENO. CONSISTE EN PONER EN CONTACTO UNA MEZCLA DE MONOXIDO DE CARBONO E HIDROGENO A TEMPERATURA Y PRESION ELEVADAS CON UN CATALIZADOR QUE COMPRENDE DE 3 A 60 PARTES EN PESO DE COBALTO Y DE 0,1 A 100 PARTES EN PESO DE OTRO METAL SELECCIONADO ENTRE ZIRCONIO, TITANIO, CROMO Y RUTENIO POR CADA 100 PARTES EN PESO DE SILICE, ALUMINA O SILICE-ALUMINA Y QUE SE HA PREPARADO POR AMASADO Y/O IMPREGNACION; DONDE EL CATALIZADOR ESTA PRESENTE EN LA FORMA DE UN LECHO FIJO QUE TIENE UNA SUPERFICIE ESPECIFICA EXTERNA SE (EN CM/ML), Y DONDE DURANTE EL PROCEDIMIENTO SE HACE PASAR UN LIQUIDO CONSTITUIDO POR UNO O MAS HIDROCARBUROS A TRAVES DEL LECHO CATALITICO EN DIRECCION DESCENDENTE JUNTO CON EL GAS DE ALIMENTACION, A UNA VELOCIDAD SUPERFICIAL DE FLUJO DEL LIQUIDO VS (EN CM/S) A LA ENTRADA DEL LECHO CATALITICO. TIENE UTILIDAD EN LA PREPARACION DE DESTILADOS INDUSTRIALES.
ES550935A 1985-01-18 1986-01-16 Un procedimiento para la preparacion de hidrocarburos por reaccion catalitica de monoxido de carbono con hidrogeno Expired ES8704146A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL8500121 1985-01-18

Publications (2)

Publication Number Publication Date
ES8704146A1 true ES8704146A1 (es) 1987-03-16
ES550935A0 ES550935A0 (es) 1987-03-16

Family

ID=19845379

Family Applications (1)

Application Number Title Priority Date Filing Date
ES550935A Expired ES8704146A1 (es) 1985-01-18 1986-01-16 Un procedimiento para la preparacion de hidrocarburos por reaccion catalitica de monoxido de carbono con hidrogeno

Country Status (12)

Country Link
US (1) US4686238A (es)
EP (1) EP0188304B1 (es)
JP (1) JPH0653687B2 (es)
AT (1) ATE47827T1 (es)
AU (1) AU584968B2 (es)
BR (1) BR8600145A (es)
CA (1) CA1262362A (es)
DE (1) DE3666803D1 (es)
ES (1) ES8704146A1 (es)
GB (1) GB2169919B (es)
IN (1) IN166813B (es)
ZA (1) ZA86321B (es)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5004862A (en) 1988-06-27 1991-04-02 Hildinger Henry W Process for recycling and purifying condensate from a hydrocarbon or alcohol synthesis process
GB8911075D0 (en) * 1989-05-15 1989-06-28 Shell Int Research Process for the preparation of hydrocarbons
CA2038773C (en) * 1990-04-04 1999-06-08 Kym B. Arcuri Slurry fischer-tropsch process with co/ti02 catalyst
US5292705A (en) * 1992-09-24 1994-03-08 Exxon Research & Engineering Co. Activation of hydrocarbon synthesis catalyst
US5639798A (en) * 1994-12-15 1997-06-17 Wexford P.A. Syncrude Limited Partnership Process and catalyst for production of hydrocarbons
FR2736650B1 (fr) * 1995-07-13 1997-09-05 Inst Francais Du Petrole Procede de conversion du gaz de synthese en phase liquide
FR2745820B1 (fr) * 1996-03-08 1998-04-17 Inst Francais Du Petrole Conversion du gaz de synthese en hydrocarbures en presence d'une phase liquide
US6472441B1 (en) * 2000-07-24 2002-10-29 Chevron U.S.A. Inc. Methods for optimizing Fischer-Tropsch synthesis of hydrocarbons in the distillate fuel and/or lube base oil ranges
MX2007008365A (es) 2001-01-10 2007-09-21 Compactgtl Plc Reactor catalitico.
DE60230422D1 (de) * 2001-08-24 2009-01-29 Shell Int Research Verfahren zur herstellung von kohlenwasserstoffen
JP4732703B2 (ja) * 2004-03-25 2011-07-27 Ｊｘ日鉱日石エネルギー株式会社 オレフィンに富む炭化水素を製造するための触媒
JP5619356B2 (ja) * 2005-08-22 2014-11-05 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイＳｈｅｌｌ Ｉｎｔｅｒｎａｔｉｏｎａｌｅ Ｒｅｓｅａｒｃｈ Ｍａａｔｓｃｈａｐｐｉｊ Ｂｅｓｌｏｔｅｎｖｅｎｎｏｏｔｓｈａｐ ディーゼル燃料及びディーゼルエンジンの操作法
US20080260631A1 (en) 2007-04-18 2008-10-23 H2Gen Innovations, Inc. Hydrogen production process
ITMI20131439A1 (it) 2013-09-03 2015-03-04 Eni Spa Reattore tubolare a letto impaccato per reazioni catalitiche eterogenee esotermiche o endotermiche
US9358526B2 (en) 2013-11-19 2016-06-07 Emerging Fuels Technology, Inc. Optimized fischer-tropsch catalyst
US9180436B1 (en) 2013-11-19 2015-11-10 Emerging Fuels Technology, Inc. Optimized fischer-tropsch catalyst
JP6978844B2 (ja) * 2017-03-22 2021-12-08 岩谷産業株式会社 炭化水素合成触媒の製造方法、炭化水素製造方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2318602A (en) * 1938-06-02 1943-05-11 Standard Catalytic Co Synthesis of hydrocarbons
GB783061A (en) * 1955-03-15 1957-09-18 Koppers Gmbh Heinrich Process for the production of hydrocarbons
DE1030319B (de) * 1955-03-30 1958-05-22 Ruhrchemie Ag Verfahren zur Kohlenoxydhydrierung unter erhoehtem Druck und unter Extraktion des Katalysators im Syntheseofen
NL7612460A (nl) * 1976-11-10 1978-05-12 Shell Int Research Werkwijze voor de bereiding van koolwater- stoffen.
FR2494682A1 (fr) * 1980-11-25 1982-05-28 Inst Francais Du Petrole Procede pour la mise en oeuvre de reactions tres exothermiques
NL8006484A (nl) * 1980-11-28 1982-06-16 Shell Int Research Werkwijze voor de bereiding van koolwaterstoffen.
ATE21684T1 (de) * 1982-08-02 1986-09-15 Shell Int Research Verfahren zur herstellung von kohlenwasserstoffen.
EP0110449B1 (en) * 1982-11-22 1986-08-13 Shell Internationale Researchmaatschappij B.V. Process for the preparation of a fischer-tropsch catalyst, a catalyst so prepared and use of this catalyst in the preparation of hydrocarbons
DE3375913D1 (en) * 1982-11-22 1988-04-14 Shell Int Research Process for the preparation of hydrocarbons
US4522939A (en) * 1983-05-31 1985-06-11 Shell Oil Company Preparation of catalyst for producing middle distillates from syngas
IN164465B (es) * 1984-07-06 1989-03-18 Shell Int Research
GB8508613D0 (en) * 1985-04-02 1985-05-09 British Petroleum Co Plc Chemical process

Also Published As

Publication number Publication date
EP0188304A1 (en) 1986-07-23
GB8601026D0 (en) 1986-02-19
AU584968B2 (en) 1989-06-08
JPS61167628A (ja) 1986-07-29
AU5240286A (en) 1986-07-24
ZA86321B (en) 1986-08-27
DE3666803D1 (en) 1989-12-14
BR8600145A (pt) 1986-09-23
ATE47827T1 (de) 1989-11-15
GB2169919B (en) 1988-09-14
US4686238A (en) 1987-08-11
IN166813B (es) 1990-07-21
JPH0653687B2 (ja) 1994-07-20
EP0188304B1 (en) 1989-11-08
CA1262362A (en) 1989-10-17
GB2169919A (en) 1986-07-23
ES550935A0 (es) 1987-03-16

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Legal Events

Date Code Title Description
FD1A Patent lapsed

Effective date: 20050115