ES8600081A1 - Procedimiento para la separacion de alquinos de corrientes hidrocarbonadas que contienen 1,3-butadieno - Google Patents

Procedimiento para la separacion de alquinos de corrientes hidrocarbonadas que contienen 1,3-butadieno

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Publication number
ES8600081A1
ES8600081A1 ES526675A ES526675A ES8600081A1 ES 8600081 A1 ES8600081 A1 ES 8600081A1 ES 526675 A ES526675 A ES 526675A ES 526675 A ES526675 A ES 526675A ES 8600081 A1 ES8600081 A1 ES 8600081A1
Authority
ES
Spain
Prior art keywords
alkynes
catalyst
dienes
selective hydrogenation
diene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES526675A
Other languages
English (en)
Other versions
ES526675A0 (es
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US06/473,293 external-priority patent/US4440956A/en
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of ES526675A0 publication Critical patent/ES526675A0/es
Publication of ES8600081A1 publication Critical patent/ES8600081A1/es
Expired legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/08Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of carbon-to-carbon triple bonds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72Copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04Alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889Manganese, technetium or rhenium
    • B01J23/8892Manganese
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8926Copper and noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00Aliphatic unsaturated hydrocarbons
    • C07C11/12Alkadienes
    • C07C11/16Alkadienes with four carbon atoms
    • C07C11/1671, 3-Butadiene
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00Purification; Separation; Use of additives
    • C07C7/148Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
    • C07C7/163Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound by hydrogenation
    • C07C7/167Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound by hydrogenation for removal of compounds containing a triple carbon-to-carbon bond
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/32Selective hydrogenation of the diolefin or acetylene compounds
    • C10G45/34Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/61310-100 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/615100-500 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63Pore volume
    • B01J35/6350.5-1.0 ml/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64Pore diameter
    • B01J35/6472-50 nm
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64Pore diameter
    • B01J35/65150-500 nm
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64Pore diameter
    • B01J35/653500-1000 nm
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66Pore distribution
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66Pore distribution
    • B01J35/67Pore distribution monomodal
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66Pore distribution
    • B01J35/69Pore distribution bimodal
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04Alumina
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/72Copper

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PROCEDIMIENTO PARA PREPARAR NUEVOS CATALIZADORES PARA LA HIDROGENACION SELECTIVA DE ALQUINOS EN PRESENTA DE DIENOS.COMPRENDE: A) IMPREGNAR UN SOPORTE DE ALUMINA CON SOLUCIONES DE SALES DE CU, Y ORO O MAS ACTIVADORES; B) SECAR EL SOPORTE IMPREGNADO A UNA TEMPERATURA ENTRE 90 Y 130JC Y DURANTE 1 A 24 HORAS; Y C) CALCINAR EL SOPORTE, IMPREGNADO Y SECADO, A 300-500J DURANTE 3 A 12 HORAS, PARA DESCOMPONER A LAS SALES Y DEPOSITAR SOBRE EL SOPORTE A LOS ELEMENTOS EN ESTADO METALICO FINAMENTE DIVIDIDO. EL SOPORTE DE ALUMINA, ESTA CONSTITUIDO POR UNA GAMMA-ALUMINA CON UNA SUPERFICIE ESPECIFICA DE 68 A 350 M2/G Y CON UNA DISTRIBUCION DE POROS TAL QUE EL 60 AL 90 DE LOS MISMOS TIENE UN DIAMETRO MEDIO DE 4 A 12 MM EL 2 A 25 DE LOS MISMOS TIENE UN DIAMETRO MEDIO DE 100 A 1.000 MM Y CONTIENE UN 0,1 DE NA2O Y DE 0,15 DE SIO2, UN 0,01 DE S Y UN 0,06 DE FE2O3 Y EL ACTIVADOR METALICO SE ELIGE ENTRE, AG, PT, PD, MN, CO, NI, O MO.
ES526675A 1983-03-08 1983-10-21 Procedimiento para la separacion de alquinos de corrientes hidrocarbonadas que contienen 1,3-butadieno Expired ES8600081A1 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/473,293 US4440956A (en) 1982-10-25 1983-03-08 Selective hydrogenation of acetylenes in the presence of butadiene and catalyst used in the hydrogenation
EP83306347A EP0139051B1 (en) 1983-03-08 1983-10-19 Catalyst for selective hydrogenation of alkynes in the presence of dienes

Publications (2)

Publication Number Publication Date
ES526675A0 ES526675A0 (es) 1985-10-01
ES8600081A1 true ES8600081A1 (es) 1985-10-01

Family

ID=26089693

Family Applications (1)

Application Number Title Priority Date Filing Date
ES526675A Expired ES8600081A1 (es) 1983-03-08 1983-10-21 Procedimiento para la separacion de alquinos de corrientes hidrocarbonadas que contienen 1,3-butadieno

Country Status (9)

Country Link
EP (1) EP0139051B1 (es)
JP (1) JPS59162949A (es)
KR (1) KR900003942B1 (es)
AU (1) AU559034B2 (es)
CA (1) CA1212373A (es)
DE (1) DE3374666D1 (es)
ES (1) ES8600081A1 (es)
IN (1) IN161477B (es)
ZA (1) ZA837785B (es)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2553760B1 (fr) * 1983-10-25 1986-05-02 Inst Francais Du Petrole Procede d'hydrogenation selective en presence de solvant des composes acetyleniques d'une coupe d'hydrocarbures c4 riche en butadiene
CA1304069C (en) * 1986-08-25 1992-06-23 Johannes C. Oudejans Hydrogenation catalyst
GB2199589B (en) * 1986-12-30 1991-07-24 Labofina Sa Improved process for the selective hydrogenation of acetylenes
GB8717989D0 (en) * 1987-07-29 1987-09-03 Davy Mckee Ltd Catalyst
DE19636064A1 (de) * 1996-09-05 1998-03-12 Basf Ag Verfahren zur Hydrierung
GB0212321D0 (en) 2002-05-29 2002-07-10 Johnson Matthey Plc Catalyst composition
US6576588B2 (en) * 2000-04-07 2003-06-10 Catalytic Distillation Technologies Process for selective hydrogenation of alkynes and catalyst therefor
CN1090997C (zh) * 2000-04-30 2002-09-18 中国石油化工集团公司 一种选择加氢除炔多金属催化剂
US20040030207A1 (en) * 2002-08-08 2004-02-12 Catalytic Distillation Technologies Selective hydrogenation of acetylenes
KR100780173B1 (ko) * 2006-12-29 2007-11-28 주식회사 효성 2,6-나프탈렌디카르복실산 정제용 촉매, 그 제조방법 및이를 이용한 정제공정
US10792647B2 (en) 2009-04-21 2020-10-06 Johnson Matthey Public Limited Company Base metal catalysts for the oxidation of carbon monoxide and volatile organic compounds
FR3011844A1 (fr) 2013-10-16 2015-04-17 IFP Energies Nouvelles Procede d'hydrogenation selective mettant en œuvre un catalyseur contenant du cuivre et au moins un metal choisi parmi le nickel ou le cobalt
CN108779045A (zh) * 2016-03-31 2018-11-09 日本瑞翁株式会社 氢化方法
FR3059253B1 (fr) * 2016-11-29 2020-01-17 IFP Energies Nouvelles Catalyseur d'hydrogenation selective d'une coupe d'hydrocarbures c3.
FR3059252B1 (fr) * 2016-11-29 2018-11-16 IFP Energies Nouvelles Catalyseur d’hydrogenation selective de coupes c3 de vapocraquage et/ou de craquage catalytique

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB945403A (en) * 1960-07-11 1963-12-23 Continental Oil Co Improvements in or relating to the production of alumina
US3770617A (en) * 1970-12-28 1973-11-06 Exxon Research Engineering Co Hydrodesulfurization with a specified pore size distribution in silica-stabilized alumina
FR2179967B1 (es) * 1972-04-13 1978-03-03 Norton Co
US3850849A (en) * 1972-05-24 1974-11-26 Norton Co Formed alumina bodies for catalytic uses
GB1465523A (en) * 1973-01-26 1977-02-23 Norton Co Low surface area alumina
US3912789A (en) * 1973-12-17 1975-10-14 Dow Chemical Co Dealkynation of olefin and diolefin streams
US4101451A (en) * 1977-01-19 1978-07-18 The Dow Chemical Company Enhancement of promoted copper catalyst
GB1586398A (en) * 1977-07-15 1981-03-18 Gen Motors Corp Pellet type oxidation catalyst
US4301037A (en) * 1980-04-01 1981-11-17 W. R. Grace & Co. Extruded alumina catalyst support having controlled distribution of pore sizes

Also Published As

Publication number Publication date
JPH0341212B2 (es) 1991-06-21
DE3374666D1 (en) 1988-01-07
ES526675A0 (es) 1985-10-01
EP0139051A1 (en) 1985-05-02
KR840007826A (ko) 1984-12-11
CA1212373A (en) 1986-10-07
EP0139051B1 (en) 1987-11-25
JPS59162949A (ja) 1984-09-13
AU2030083A (en) 1984-09-13
KR900003942B1 (ko) 1990-06-05
IN161477B (es) 1987-12-12
ZA837785B (en) 1985-06-26
AU559034B2 (en) 1987-02-19

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