JPS57185228A - Selective hydrogenating method of acetylenic compound - Google Patents
Selective hydrogenating method of acetylenic compoundInfo
- Publication number
- JPS57185228A JPS57185228A JP56070156A JP7015681A JPS57185228A JP S57185228 A JPS57185228 A JP S57185228A JP 56070156 A JP56070156 A JP 56070156A JP 7015681 A JP7015681 A JP 7015681A JP S57185228 A JPS57185228 A JP S57185228A
- Authority
- JP
- Japan
- Prior art keywords
- butadiene
- acetylenic
- acetylenic compounds
- fraction
- groupib
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 150000001875 compounds Chemical class 0.000 title abstract 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 5
- KAKZBPTYRLMSJV-UHFFFAOYSA-N butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N AI2O3 Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 229910052763 palladium Inorganic materials 0.000 abstract 2
- 230000000737 periodic Effects 0.000 abstract 2
- 239000000969 carrier Substances 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000011780 sodium chloride Substances 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Abstract
PURPOSE: To improve the removal ratio without the loss of butadiene in hydrogenating and removing acetylenic comounds in a 4C fraction containing butadiene, by using a catalyst containing Pd and a metal of GroupIb in the periodic table supported on alumina.
CONSTITUTION: Acetylenic compounds in a fraction containing butadiene or 4C hydrocarbons including butadiene essentially are hydrogenated and removed by using a catalyst expressed by the formula Pd-X-Al2O3 (X is a metal of GroupIb in the periodic table or a salt thereof) and containing preferably 0.05W5wt% palladium and X at an atomic ratio based on the palladium of 0.1W10 preferably supported on alumina as a carrier at a reaction temperature in the range of 0W80°C, preferably 5W60°C, and reaction pressure of 2W30kg/cm2.G, preferably 3W15kg/cm2.G. Even if the total concentration of the acetylenic compounds in the C4 fraction is in the range of 0.5W2wt%, the acetylenic compounds can be hydrogenated and removed.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP56070156A JPS57185228A (en) | 1981-05-12 | 1981-05-12 | Selective hydrogenating method of acetylenic compound |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP56070156A JPS57185228A (en) | 1981-05-12 | 1981-05-12 | Selective hydrogenating method of acetylenic compound |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS57185228A true JPS57185228A (en) | 1982-11-15 |
Family
ID=13423423
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP56070156A Pending JPS57185228A (en) | 1981-05-12 | 1981-05-12 | Selective hydrogenating method of acetylenic compound |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS57185228A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS58170541A (en) * | 1982-03-15 | 1983-10-07 | Catalyse Soc Prod Francais | Novel palladium and gold supported catalyst for selective hydrogenation of unsaturated hydrocarbon |
US6627578B2 (en) | 2000-04-30 | 2003-09-30 | China Petro-Chemical Corporation | Catalyst for selective hydrogenation |
JP2005535705A (en) * | 2002-08-08 | 2005-11-24 | キャタリティック・ディスティレイション・テクノロジーズ | Selective hydrogenation of acetylenes. |
US8026194B2 (en) | 2008-11-19 | 2011-09-27 | Uop Llc | Layered sphere catalyst formulations for selective hydrogenation performance |
US8772561B2 (en) | 2008-11-19 | 2014-07-08 | Uop Llc | Methods for selective hydrogenation performance using a layered sphere catalyst with new formulations |
-
1981
- 1981-05-12 JP JP56070156A patent/JPS57185228A/en active Pending
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS58170541A (en) * | 1982-03-15 | 1983-10-07 | Catalyse Soc Prod Francais | Novel palladium and gold supported catalyst for selective hydrogenation of unsaturated hydrocarbon |
JPH0424097B2 (en) * | 1982-03-15 | 1992-04-24 | Furanseezu De Purodeyui Puuru Katariizu Soc | |
US6627578B2 (en) | 2000-04-30 | 2003-09-30 | China Petro-Chemical Corporation | Catalyst for selective hydrogenation |
JP2005535705A (en) * | 2002-08-08 | 2005-11-24 | キャタリティック・ディスティレイション・テクノロジーズ | Selective hydrogenation of acetylenes. |
US8026194B2 (en) | 2008-11-19 | 2011-09-27 | Uop Llc | Layered sphere catalyst formulations for selective hydrogenation performance |
US8772561B2 (en) | 2008-11-19 | 2014-07-08 | Uop Llc | Methods for selective hydrogenation performance using a layered sphere catalyst with new formulations |
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